EP0434044A1 - Farbphotographisches lichtempfindliches Material mit ausgezeichneter Farbenreproduktion - Google Patents

Farbphotographisches lichtempfindliches Material mit ausgezeichneter Farbenreproduktion Download PDF

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Publication number
EP0434044A1
EP0434044A1 EP90124807A EP90124807A EP0434044A1 EP 0434044 A1 EP0434044 A1 EP 0434044A1 EP 90124807 A EP90124807 A EP 90124807A EP 90124807 A EP90124807 A EP 90124807A EP 0434044 A1 EP0434044 A1 EP 0434044A1
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EP
European Patent Office
Prior art keywords
group
silver halide
atom
halide emulsion
emulsion layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP90124807A
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English (en)
French (fr)
Inventor
Fumie Fukazawa
Katuya Yabuuchi
Hirofumi Ohtani
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Konica Minolta Inc
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Konica Minolta Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Konica Minolta Inc filed Critical Konica Minolta Inc
Publication of EP0434044A1 publication Critical patent/EP0434044A1/de
Withdrawn legal-status Critical Current

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    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03CPHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C7/00Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
    • G03C7/30Colour processes using colour-coupling substances; Materials therefor; Preparing or processing such materials
    • G03C7/3041Materials with specific sensitometric characteristics, e.g. gamma, density

Definitions

  • the present invention relates to a color photographic light-sensitive material, particularly to a color photographic light-sensitive material having a high saturation and an excellent hue reproduction.
  • a so-called DIR compound which forms a developing inhibitor or a precursor thereof upon reaction with an oxidation product of a color developing agent, to a silver halide multi-layered color photographic light-sensitive material.
  • a developing inhibitor released from such a DIR compound inhibits developing of other color forming layers and thereby produces an inter image effect to improve the color reproduction.
  • the same effect as the inter image effect can be achieved by adding a colored coupler in an amount larger than that necessary to offset useless absorptions.
  • U.S. Patent No. 3,672,898 discloses a spectral sensitivity distribution appropriate to mitigate a fluctuation in color reproduction caused by a difference in light sources at photographing. But, this is not good enough to improve the foregoing poor-reproducible colors.
  • a combination of a spectral sensitivity distribution and an interimage effect is disclosed in Japanese Patent O.P.I. Publication No. 34541/1986, in which an attempt is made to improve the foregoing poor-reproducible colors and seems to produce an effect to some extent. Its typical embodiment is to exercise an interimage effect not only from a centroidal wavelength of each of blue-sensitive, green-sensitive and red-sensitive layers as performed in conventional methods, but also from wavelengths other than the centroid of each color sensitive layer.
  • the object of the present invention is to provide a silver halide color photographic light-sensitive material capable of faithfully reproducing bluish purple, bluish green and green without impairing reproduction of skin color.
  • a color photographic light-sensitive material having on a support at least one layer each of blue-sensitive silver halide emulsion layer (hereinafter occasionally referred to as a blue-sensitive layer), green-sensitive silver halide emulsion layer (hereinafter occasionally referred to as a green-sensitive layer) and red-sensitive silver halide emulsion layer (hereinafter occasionally referred to as a red-sensitive layer), wherein a maximum sensitivity wavelength ⁇ R in a spectral sensitivity distribution of said red-sensitive is in a range of 595 nm ⁇ ⁇ R ⁇ 625 nm and a maximum sensitivity wavelength ⁇ G of a spectral sensitivity distribution of said green-sensitive silver halide emulsion layer is in a range of 530 nm ⁇ ⁇ G ⁇ 560 nm , and a sensitivity of said green-sensitive layer at 500 nm is larger than one-fourth the sensitivity at the maximum sensitivity wavelength ⁇ G .
  • Fig. 1 is a chart showing color reproductions of the samples on the (a *, b * ) plane of the (L *, a *, b*) color system.
  • the spectral sensitivity is shown as a function of a wavelength; that is, when a light-sensitive material is exposed to a spectral light from 400 nm to 700 nm at intervals of several nanometers, on the basis of the exposure to give a prescribed density at each wavelength is evaluated a sensitivity of said wavelength.
  • a proper measure can be arbitrarily taken to obtain the foregoing inventive spectral sensitivity distribution in red-sensitive and green-sensitive layers.
  • Use of a spectral sensitizing dye for example, provides such a spectral sensitivity distribution.
  • Types of spectral sensitizing dyes used in these layers are not limited, but good results can be obtained by using the following spectral sensitizing dyes in combination.
  • spectral sensitivity distribution of a red-sensitive layer can be brought into that specified in the present invention by various means, but such a spectral sensitivity distribution is preferably achieved by a red-sensitive emulsion spectrally sensitized by a combined use of at least one of the sensitizing dyes represented by Formula (I) and at least one of the sensitizing dyes represented by Formula (II) or (III).
  • R1 represents a hydrogen atom, an alkyl group or an aryl group
  • R2 and R3 individually represent an alkyl group
  • Y1 and Y2 individually represent a sulfur atom or a selenium atom
  • Z1 , Z2, Z3 and Z4 individually represent a hydrogen atom, a halogen atom, a hydroxyl group, an alkoxy group, an amino group, an acyl group, an acylamino group, an acyloxy group, an alkoxycarbonyl group, an aryl group, an aryloxy group, an aryloxycarbonyl group, a sulfonyl group, a carbamoyl group, an alkyl group or a cyano group
  • Z1 and Z2 and/or Z3 and Z4 may bond with each other to form a ring
  • X1 represents a cation
  • m represents an integer of 1 or 2, or represents 1 provided that the sensitizing dye forms an intramolecular salt
  • R4 represents a hydrogen atom, an alkyl group or an aryl group
  • R5, R6, R7 and R8 individually represent an alkyl group
  • Y3 represents a nitrogen atom, a sulfur atom or a selenium atom, and no R5 exists when Y3 is a sulfur or selenium atom
  • Z5, Z6, Z7 and Z8 individually represent a hydrogen atom, a halogen atom, a hydroxyl group, an alkoxy group, an amino group, an acyl group, an acylamino group, an acyloxy group, an aryloxy group, an alkoxycarbonyl group, an aryloxycarbonyl group, an alkoxycarbonylamino group, a carbamoyl group, an aryl group, an alkyl group, a cyano group,or a sulfonyl group, Z5 and Z6 and/or Z7 and Z8 may bond with each other to form a ring;
  • Y5 represents a sulfur atom or a selenium atom
  • R18 represents a hydrogen atom, a lower alkyl group (e.g., methyl, ethyl and propyl) or an aryl group (e.g., phenyl)
  • R19 and R20 individually represent a lower alkyl group (e.g., methyl, ethyl, butyl, and an alkyl group having a substituent such as sulfoethyl, carboxypropyl or sulfobutyl)
  • Z17, Z18, Z19 and Z20 individually represent a hydrogen atom, a halogen atom (e.g., chlorine, bromine, iodine and fluorine), a hydroxyl group, an alkoxy group (e.g., methoxy, ethoxy, propoxy and butoxy), an amino group (e.g., amino, methylamino, dimethylamino and diethylamin
  • Typical sensitizing dyes used in the invention and represented by Formulas (I), (II) and (III) are exemplified below, but the scope of the invention is not limited to them.
  • (I-1) through (I-46) are those represented by Formula (I)
  • (II-1) through (II-56) are those represented by Formula (II)
  • (III-1) through (III-12) are those represented by Formula (III).
  • sensitizing dyes represented by Formulas (I), (II) and (III) Besides sensitizing dyes represented by Formulas (I), (II) and (III), supersensitizers such as benzothiazoles and quinolines described in Japanese Patent Examined Publication No. 24533/1982 and quinoline derivatives described in Japanese Patent Examined Publication No. 24899/1982 may be used according to a specific requirement.
  • the green-sensitive layer is brought into the foregoing spectral sensitivity distribution of the invention by adding the following sensitizing dyes singly or in combination.
  • the followings are examples of sensitizing dyes usable in the green-sensitive layer, but useful sensitizing dyes are not limited to them.
  • a silver halide emulsion used in a color photographic light-sensitive material of the invention can be chemically sensitized by a conventional manner.
  • An antifogging agent and a stabilizer may be added to the silver halide emulsion.
  • a binder for said emulsion gelatin is favorably used (but not limited to gelatin).
  • Emulsion layers and other hydrophilic layers may be hardened, and may contain a plasticizer and a latex of water-soluble or scarcely soluble synthetic polymer.
  • the present invention can be preferably applied to color negative films and color reversal films.
  • a color forming coupler is generally used.
  • a colored coupler having a correction effect there may be arbitrarily used a colored coupler having a correction effect, a competitive coupler and a chemical substance which releases a photographically useful fragment such as a developing accelerator, bleaching accelerator, developer, antifogging agent, chemical sensitizer, spectral sensitizer or desensitizer, upon coupling with an oxidation product of a developing agent.
  • a developing accelerator bleaching accelerator, developer, antifogging agent, chemical sensitizer, spectral sensitizer or desensitizer
  • the light-sensitive material may have auxiliary layers such as a filter layer, anti-halation layer and anti-irradiation layer. There may be contained in these auxiliary layers or emulsion layers a dye which is washed away or bleached out in the developing process.
  • the light-sensitive material may also contain a formalin scavenger, brightening agent, matting agent, slipping agent, image stabilizer, surfactant, antistain agent, developing accelerator, developing inhibitor and bleaching accelerator.
  • the support may be any of a paper laminated with polyethylene, polyethylene terephthalate film, baryta paper and triacetylcellulose film.
  • addition amounts to the silver halide light-sensitive material is shown by grams per 1 m2 unless otherwise specified. Addition amounts of silver halide and colloidal silver are given in terms of silver.
  • the layers of the following compositions were formed in sequence on a triacetylcellulose film base to prepare the multi-layered color photographic light-sensitive material sample-101.
  • a coating aid Su-2 In addition to the above compounds, a coating aid Su-2, dispersants Su-3 and Su-4, hardeners H-1 and H-2, a stabilizer ST-1 and antifogging agents AF-1 ( Mw : 10,000) and AF-2 ( Mw : 1,100,000) were added.
  • the emulsions used in preparing the above samples are as follows:
  • Average grain size 0.50 ⁇ m
  • Average silver iodide content 6.0 mol%
  • Average grain size 0.25 ⁇ m
  • Average silver iodide content 6.0 mol%
  • Average grain size 0.85 ⁇ m
  • Average silver iodide content 7.0 mol%
  • a core/shell type monodispersed silver iodobromide emulsion (extent of distribution: 16%) having a silver iodide content of 1 mol% in the outer portion wherein Extent of distribution
  • samples 102 through 109 were prepared in the same manner as in the sample 101, except that the sensitizing dyes in the 3rd and 4th layers and those in the 6th and 7th layers were varied as shown in Table 1.
  • compositions of processing solutions used in the respective processes are as follows:
  • reproduced points of purple (P), bluish purple (BF), bluish green (BG) and green (G) are near to the original in Fig.1; that is, they can achieve a hue reproduction faithful to the original.
  • a reproduction point located far from the origin, on a line connecting an original and the origin means that it has a high color purity (near to the original). It is apparent from Fig. 1 that each of the inventive samples does not cause lowering in purity of skin color.

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Silver Salt Photography Or Processing Solution Therefor (AREA)
EP90124807A 1989-12-22 1990-12-19 Farbphotographisches lichtempfindliches Material mit ausgezeichneter Farbenreproduktion Withdrawn EP0434044A1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP334482/89 1989-12-22
JP1334482A JPH03194547A (ja) 1989-12-22 1989-12-22 色相再現性に優れたカラー写真感光材料

Publications (1)

Publication Number Publication Date
EP0434044A1 true EP0434044A1 (de) 1991-06-26

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EP90124807A Withdrawn EP0434044A1 (de) 1989-12-22 1990-12-19 Farbphotographisches lichtempfindliches Material mit ausgezeichneter Farbenreproduktion

Country Status (3)

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US (1) USH1196H (de)
EP (1) EP0434044A1 (de)
JP (1) JPH03194547A (de)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6143482A (en) * 1998-08-05 2000-11-07 Eastman Kodak Company Photographic film element containing an emulsion with green-red responsivity
US6562557B2 (en) 2000-07-21 2003-05-13 Agfa-Gevaert Color photographic silver halide material

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0115304A2 (de) * 1983-01-19 1984-08-08 Fuji Photo Film Co., Ltd. Multigeschichtetes lichtempfindliches farbphotographisches Silberhalogenidmaterial
JPS62160449A (ja) * 1986-01-08 1987-07-16 Fuji Photo Film Co Ltd カラ−写真感光材料

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE756607R (de) 1969-09-29 1971-03-01 Eastman Kodak Co
JPS61201245A (ja) 1985-03-04 1986-09-05 Fuji Photo Film Co Ltd カラ−写真感光材料

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0115304A2 (de) * 1983-01-19 1984-08-08 Fuji Photo Film Co., Ltd. Multigeschichtetes lichtempfindliches farbphotographisches Silberhalogenidmaterial
JPS62160449A (ja) * 1986-01-08 1987-07-16 Fuji Photo Film Co Ltd カラ−写真感光材料

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6143482A (en) * 1998-08-05 2000-11-07 Eastman Kodak Company Photographic film element containing an emulsion with green-red responsivity
US6251578B1 (en) 1998-08-05 2001-06-26 Eastman Kodak Company Photographic film element containing an emulsion with green-red responsivity
US6562557B2 (en) 2000-07-21 2003-05-13 Agfa-Gevaert Color photographic silver halide material

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Publication number Publication date
USH1196H (en) 1993-06-01
JPH03194547A (ja) 1991-08-26

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