EP0426760A1 - Fluoressierendes strassenbelagmaterial. - Google Patents
Fluoressierendes strassenbelagmaterial.Info
- Publication number
- EP0426760A1 EP0426760A1 EP89909635A EP89909635A EP0426760A1 EP 0426760 A1 EP0426760 A1 EP 0426760A1 EP 89909635 A EP89909635 A EP 89909635A EP 89909635 A EP89909635 A EP 89909635A EP 0426760 A1 EP0426760 A1 EP 0426760A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- road
- mineral
- surfacing material
- fluorescent
- additive material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000463 material Substances 0.000 title claims abstract description 43
- 229910052500 inorganic mineral Inorganic materials 0.000 claims abstract description 31
- 239000011707 mineral Substances 0.000 claims abstract description 31
- 239000000654 additive Substances 0.000 claims abstract description 17
- 230000000996 additive effect Effects 0.000 claims abstract description 17
- 239000002245 particle Substances 0.000 claims abstract description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000011044 quartzite Substances 0.000 claims abstract description 8
- 239000000126 substance Substances 0.000 claims abstract description 6
- 229910052681 coesite Inorganic materials 0.000 claims abstract description 4
- 229910052906 cristobalite Inorganic materials 0.000 claims abstract description 4
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 4
- 229910052682 stishovite Inorganic materials 0.000 claims abstract description 4
- 229910052905 tridymite Inorganic materials 0.000 claims abstract description 4
- 239000011230 binding agent Substances 0.000 claims abstract description 3
- 239000011572 manganese Substances 0.000 claims description 5
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 3
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 3
- 229910052748 manganese Inorganic materials 0.000 claims description 3
- 229910052750 molybdenum Inorganic materials 0.000 claims description 3
- 239000011733 molybdenum Substances 0.000 claims description 3
- 229910004829 CaWO4 Inorganic materials 0.000 claims description 2
- 239000002344 surface layer Substances 0.000 claims description 2
- 239000004575 stone Substances 0.000 abstract description 2
- 239000010426 asphalt Substances 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- 230000004927 fusion Effects 0.000 abstract 1
- 230000005855 radiation Effects 0.000 abstract 1
- 235000012239 silicon dioxide Nutrition 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 9
- 239000002019 doping agent Substances 0.000 description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 239000010436 fluorite Substances 0.000 description 2
- 229910052826 autunite Inorganic materials 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 description 1
- 229910001634 calcium fluoride Inorganic materials 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000011490 mineral wool Substances 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000012768 molten material Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 229910052844 willemite Inorganic materials 0.000 description 1
Classifications
-
- E—FIXED CONSTRUCTIONS
- E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
- E01C—CONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
- E01C7/00—Coherent pavings made in situ
- E01C7/08—Coherent pavings made in situ made of road-metal and binders
- E01C7/35—Toppings or surface dressings; Methods of mixing, impregnating, or spreading them
-
- E—FIXED CONSTRUCTIONS
- E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
- E01C—CONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
- E01C7/00—Coherent pavings made in situ
- E01C7/08—Coherent pavings made in situ made of road-metal and binders
- E01C7/085—Aggregate or filler materials therefor; Coloured reflecting or luminescent additives therefor
Definitions
- the present invention relates to road-surfacing material, and more particularly to a road-surface layer, so-called road-dressing, applied to asphalted road constructions.
- a Danish material designated synopal has been admixed with the road-dressing material in an amount corresponding to 8% by weight.
- the present invention relates to a road-surfacing material which will fulfill the desire for light-coloured road Burfaces.
- the present invention thus relates to road surfacing material which is intended to be laid as a road-surface dressing on asphalted roads and which comprises a crushed rock-material, such as quartzite (SiO 2 ), and a binder, such as pitch, and which is characterised in that it further comprises an additive material which will fluoresce when illuminated with ultraviolet light, said additive material having been produced by bringing a mineral substance to a molten state and doping said mineral substance with a doping agent whose presence will cause the mineral concerned to fluoresce, and which has been crushed and/or granulated to particle size which corresponds to the size of the quartzite particles.
- a crushed rock-material such as quartzite (SiO 2 )
- a binder such as pitch
- the inventive road-surfacing material comprises a conventional road Burface-dressing which has admixed therewith an additive material which will fluoresce when illuminated with ultraviolet light, said additive material being mixed with said road-dressing prior to applying the same.
- a very large number of mineral ⁇ which will fluoresce when irradiated with ultraviolet light are known to the art.
- the fluorescent effect of these minerals will vary in accordance with their place of origin, since the chemical composition of the minerals varies from place to place. Consequently, it is difficult, if not impossible, to locate a mineral mining or quarrying site from which the mineral extracted therefrom will have a considerable and fairly uniform fluorescent effect and which can be mined/quarried at reasonable, related costs.
- Typical minerals possessing fluorescent properties are fluorspar (CaF 2 ), limespar (CaCO 3 ), Scheelit (CaWO 4 ), Willemit (Zn 2 (SiO 2 ) and Autunit
- Limespar can be used to great advantage, since when manganese (Mn) is present, limespar will fluoresce with an orange light. Orange is namely a colour rich in contrast.
- the fluorescent additive material is not an untreated mineral, but a mineral which has been treated to provide a fluorescent effect.
- the treatment to which the mineral is subjected in accordance with the invention involves melting a mined or quarried mineral in a furnace of the kind used in the manufacture of mineral wool, i.e. a furnace of the electrosteel type. The molten material is then doped with a doping agent which will cause the mineral to fluoresce, by introducing said doping agent into the molten mineral-bath.
- the melt may then be granulated or cast. Subsequent hereto, the solidified material is crushed to a particle Bize which corresponds to the particle size of the quartzite present in the road-surfacing material, i.e. a particle size of about 10-20 mm.
- the additive material includes one of the minerals limespar or Scheelite doped with manganese or molybdenum respectively.
- the amount in which the mineral shall be added in order to provide a fluorescent effect will depend on the mineral concerned and also on the strength of fluorescence desired.
- the proportions in which the additive material is admixed with the road-surface material are also significant. A larger proportion will naturally result in a greater fluorescent effect.
- the additive material is present in the road-surfacing material in an amount which corresponds to 2-25% by weight, preferably about 10-15% by weight.
- the present invention is not limited to any particular mineral or doping agent. Those minerals which will fluoresce are well known, and the concentrations in which the fluorescent substance is contained in such minerals in order to achieve fluorescence is also known. Consequently, the skilled person is able to acquire this knowledge and is also capable of varying the proportion of the doping agent in the material, and also to vary the proportion in which the invented additive material is present in a road surface, so as to achieve the intended fluorescent effect.
- the present invention thus provides an additive material which, distinct from natural fluorescent materials, will produce a relatively smooth and uniform fluorescent effect.
- a fluorescent road-surface will greatly enhance road safety. It is namely found that a fluorescent road-surface will also provide improved road-vision and improved ability to discern objects on the road, even under daylight conditions.
- the natural light includes a large amount of ultraviolet light, which means that the light conditions of the inventive road-surface will be a considerable improvement on the light conditions afforded by a conventional road-dressing.
- the invention includes the concept of fitting automotive vehicles with lamps which emit a large proportion of ultraviolet light.
- lamps which emit white light together with a significant proportion of ultraviolet light can be used in conventional vehicle headlamps.
- the optical effect thus achieved is highly pronounced .
- the road surface will appear to glow in the dark, and objects present on the road will stand-out against the road surface, thereby enabling the objects to be discerned easily from a long way off.
- a mineral such as limespar for instance
- the resultant road-surface will obtain a wear-resistance which corresponds in all essentials to the wear-resistance of a conventional road surface.
- the invention thus fulfills the aforesaid objects.
- the invention is not limited to any particular additive material, and the choice of a suitable mineral for the purposes intended is therefore left to the person skilled in this art.
Landscapes
- Engineering & Computer Science (AREA)
- Architecture (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Road Paving Structures (AREA)
- Radiation-Therapy Devices (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT89909635T ATE87681T1 (de) | 1988-08-26 | 1989-08-25 | Fluoressierendes strassenbelagmaterial. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
SE8802996 | 1988-08-26 | ||
SE8802996A SE462109B (sv) | 1988-08-26 | 1988-08-26 | Fluorecerande vaegbelaeggning |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0426760A1 true EP0426760A1 (de) | 1991-05-15 |
EP0426760B1 EP0426760B1 (de) | 1993-03-31 |
Family
ID=20373135
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP89909635A Expired - Lifetime EP0426760B1 (de) | 1988-08-26 | 1989-08-25 | Fluoressierendes strassenbelagmaterial |
Country Status (7)
Country | Link |
---|---|
EP (1) | EP0426760B1 (de) |
JP (1) | JPH03501040A (de) |
DE (1) | DE68905813T2 (de) |
DK (1) | DK165598C (de) |
FI (1) | FI93889C (de) |
SE (1) | SE462109B (de) |
WO (1) | WO1990002226A1 (de) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2684398B1 (fr) * | 1991-12-03 | 1993-12-31 | Dubois Jean Noel | Composition bitumineuse phosphorescente. |
SE502005C2 (sv) * | 1993-11-15 | 1995-07-10 | Cleanosol Int Ab | Fluorescerande beläggning för vägar, parkeringsplatser etc som fluorescerar vid belysning med ultraviolett ljus |
US5853615A (en) * | 1993-11-15 | 1998-12-29 | Cleanosol International Ab | Fluorescent covering for roads, parking areas etc, which fluoresces upon illumination with ultraviolet light |
FR2811663B1 (fr) | 2000-07-13 | 2003-05-02 | Commenplus | Materiau luminescent de ragreage et procede de mise en place d'un tel materiau |
US8562864B2 (en) * | 2008-06-24 | 2013-10-22 | Shell Oil Company | Asphalt mixture |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3253146A (en) * | 1962-08-16 | 1966-05-24 | Prismo Safety Corp | Fluorescent marker pigment for roadways |
CH419210A (de) * | 1965-03-10 | 1966-08-31 | Alusuisse | Verfahren zum Aufhellen der Decke von Bitumen- oder Teerstrassen und -plätzen |
GB1401271A (en) * | 1971-06-17 | 1975-07-16 | Kroyer K K K | Aggregate for road construction and method for the production of said aggregate |
US4208300A (en) * | 1973-07-11 | 1980-06-17 | Gravisse Philippe E | Photoluminescent materials and method of manufacturing same |
-
1988
- 1988-08-26 SE SE8802996A patent/SE462109B/sv not_active IP Right Cessation
-
1989
- 1989-08-25 EP EP89909635A patent/EP0426760B1/de not_active Expired - Lifetime
- 1989-08-25 JP JP1509034A patent/JPH03501040A/ja active Pending
- 1989-08-25 DE DE89909635T patent/DE68905813T2/de not_active Expired - Fee Related
- 1989-08-25 WO PCT/SE1989/000447 patent/WO1990002226A1/en active IP Right Grant
-
1990
- 1990-04-25 FI FI902084A patent/FI93889C/fi not_active IP Right Cessation
- 1990-04-25 DK DK102090A patent/DK165598C/da not_active IP Right Cessation
Non-Patent Citations (1)
Title |
---|
See references of WO9002226A1 * |
Also Published As
Publication number | Publication date |
---|---|
DE68905813D1 (de) | 1993-05-06 |
SE462109B (sv) | 1990-05-07 |
DK102090D0 (da) | 1990-04-25 |
FI902084A0 (fi) | 1990-04-25 |
DK165598B (da) | 1992-12-21 |
DK165598C (da) | 1993-05-03 |
SE8802996L (sv) | 1990-02-27 |
JPH03501040A (ja) | 1991-03-07 |
SE8802996D0 (sv) | 1988-08-26 |
EP0426760B1 (de) | 1993-03-31 |
WO1990002226A1 (en) | 1990-03-08 |
DK102090A (da) | 1990-04-25 |
FI93889B (fi) | 1995-02-28 |
FI93889C (fi) | 1995-06-12 |
DE68905813T2 (de) | 1993-10-21 |
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