EP0390157B1 - Cellule d'électrolyse et méthode d'utilisation - Google Patents

Cellule d'électrolyse et méthode d'utilisation Download PDF

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Publication number
EP0390157B1
EP0390157B1 EP90106050A EP90106050A EP0390157B1 EP 0390157 B1 EP0390157 B1 EP 0390157B1 EP 90106050 A EP90106050 A EP 90106050A EP 90106050 A EP90106050 A EP 90106050A EP 0390157 B1 EP0390157 B1 EP 0390157B1
Authority
EP
European Patent Office
Prior art keywords
cathode
electrolysis cell
carbon dioxide
phthalocyanine
metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP90106050A
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German (de)
English (en)
Other versions
EP0390157A3 (fr
EP0390157A2 (fr
Inventor
Trent M. Molter
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Raytheon Technologies Corp
Original Assignee
United Technologies Corp
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Filing date
Publication date
Application filed by United Technologies Corp filed Critical United Technologies Corp
Publication of EP0390157A2 publication Critical patent/EP0390157A2/fr
Publication of EP0390157A3 publication Critical patent/EP0390157A3/fr
Application granted granted Critical
Publication of EP0390157B1 publication Critical patent/EP0390157B1/fr
Anticipated expiration legal-status Critical
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    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00—Electrolytic production of organic compounds
    • C25B3/20—Processes
    • C25B3/25—Reduction
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/17—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
    • C25B9/19—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms
    • C25B9/23—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms comprising ion-exchange membranes in or on which electrode material is embedded

Definitions

  • Figure 1 depicts a cross-sectional view of one configuration of an electrolysis cell of the present invention.
  • the anodes useful in these cells are formed of conventional materials such as platinum, ruthenium or iridium. In addition, mixtures or alloys of these and other materials dispersed on a high surface area support may also be used. Conventional anodes which are particularly useful are described in commonly assigned U.S. Patent 4,294,608, as well as the aforementioned U.S. Patent 3,992,271.
  • the catalyst on the anode should be capable of high reactivity for the half cell reaction. 2H 2 O ⁇ 4H + 4e - + O 2 or H 2 ⁇ 2H + + 2e -

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Electrodes For Compound Or Non-Metal Manufacture (AREA)

Claims (10)

  1. Cellule d'électrolyse (2) pour la réduction de dioxyde de carbone, ayant une anode (4), une cathode (6, 18) et un électrolyte polymère solide (10), caractérisée en ce que la cathode comporte :
    (a) une cathode primaire de réduction de dioxyde de carbone (6) formée sous la forme d'une couche sur une surface dudit électrolyte polymère solide (10) et contenant au moins une phtalocyanine métallique ou une porphyrine métallique en tant que matériau catalytique
    (b) et une cathode secondaire de réduction de dioxyde de carbone (18) en contact électrique avec la cathode primaire (6), la cathode secondaire (18) ayant la forme d'un ou de plusieurs écrans revêtus d'un catalyseur de réduction de dioxyde de carbone ayant une surtension due à l'hydrogène plus grande que le platine.
  2. Cellule d'électrolyse selon la revendication 1, dans laquelle l'écran ou les écrans comportent de l'acier inoxydable, du cuivre, du laiton, du niobium, du zirconium ou du titane.
  3. Cellule d'électrolyse selon la revendication 1 ou 2, dans laquelle le revêtement de catalyseur est un métal.
  4. Cellule d'électrolyse selon l'une quelconque des revendications 1 à 3, dans laquelle le revêtement de catalyseur est formé à partir d'un matériau sélectionné parmi le groupe constitué d'étain, de plomb, de cuivre, de zinc, de cadmium, de gallium, d'argent, d'or, d'indium, de fer, de tungstène, de molybdène et de carbone.
  5. Cellule d'électrolyse selon la revendication 4, dans laquelle le revêtement de catalyseur est de l'indium.
  6. Cellule d'électrolyse selon la revendication 1 ou 2, dans laquelle le revêtement de catalyseur est une phtalocyanine métallique ou une porphyrine métallique.
  7. Cellule d'électrolyse selon la revendication 6, dans laquelle la phtalocyanine métallique est sélectionnée parmi le groupe constitué de la phtalocyanine de fer, de cuivre, de nickel et de cobalt.
  8. Cellule d'électrolyse selon la revendication 7, dans laquelle la phtalocyanine métallique est la phtalocyanine de nickel.
  9. Cellule d'électrolyse selon l'une quelconque des revendications 1 à 8, dans laquelle la cathode primaire est sélectionnée parmi le groupe constitué de la phtalocyanine de fer, de cuivre, de nickel et de cobalt.
  10. Cellule d'électrolyse selon la revendication 9, dans laquelle la phtalocyanine métallique est la phtalocyanine de nickel.
EP90106050A 1989-03-31 1990-03-29 Cellule d'électrolyse et méthode d'utilisation Expired - Lifetime EP0390157B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US33146489A 1989-03-31 1989-03-31
US331464 1989-03-31

Publications (3)

Publication Number Publication Date
EP0390157A2 EP0390157A2 (fr) 1990-10-03
EP0390157A3 EP0390157A3 (fr) 1991-04-17
EP0390157B1 true EP0390157B1 (fr) 2000-01-05

Family

ID=23294091

Family Applications (1)

Application Number Title Priority Date Filing Date
EP90106050A Expired - Lifetime EP0390157B1 (fr) 1989-03-31 1990-03-29 Cellule d'électrolyse et méthode d'utilisation

Country Status (4)

Country Link
EP (1) EP0390157B1 (fr)
JP (1) JPH03111586A (fr)
AT (1) ATE188514T1 (fr)
DE (1) DE69033409T2 (fr)

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8313634B2 (en) 2009-01-29 2012-11-20 Princeton University Conversion of carbon dioxide to organic products
US8500987B2 (en) 2010-03-19 2013-08-06 Liquid Light, Inc. Purification of carbon dioxide from a mixture of gases
US8524066B2 (en) 2010-07-29 2013-09-03 Liquid Light, Inc. Electrochemical production of urea from NOx and carbon dioxide
US8562811B2 (en) 2011-03-09 2013-10-22 Liquid Light, Inc. Process for making formic acid
US8568581B2 (en) 2010-11-30 2013-10-29 Liquid Light, Inc. Heterocycle catalyzed carbonylation and hydroformylation with carbon dioxide
US8592633B2 (en) 2010-07-29 2013-11-26 Liquid Light, Inc. Reduction of carbon dioxide to carboxylic acids, glycols, and carboxylates
US8658016B2 (en) 2011-07-06 2014-02-25 Liquid Light, Inc. Carbon dioxide capture and conversion to organic products
US8721866B2 (en) 2010-03-19 2014-05-13 Liquid Light, Inc. Electrochemical production of synthesis gas from carbon dioxide
US8845878B2 (en) 2010-07-29 2014-09-30 Liquid Light, Inc. Reducing carbon dioxide to products
US8845877B2 (en) 2010-03-19 2014-09-30 Liquid Light, Inc. Heterocycle catalyzed electrochemical process
US8961774B2 (en) 2010-11-30 2015-02-24 Liquid Light, Inc. Electrochemical production of butanol from carbon dioxide and water
US9090976B2 (en) 2010-12-30 2015-07-28 The Trustees Of Princeton University Advanced aromatic amine heterocyclic catalysts for carbon dioxide reduction

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2700052B2 (ja) * 1995-03-08 1998-01-19 工業技術院長 水素化物の製造方法
FR2747694B1 (fr) * 1996-04-18 1998-06-05 France Etat Cathode pour la reduction de dioxyde de carbone et procede de fabrication d'une telle cathode
US20110114502A1 (en) * 2009-12-21 2011-05-19 Emily Barton Cole Reducing carbon dioxide to products
WO2011135783A1 (fr) 2010-04-26 2011-11-03 パナソニック株式会社 Procédé de réduction du dioxyde de carbone
JP5624860B2 (ja) * 2010-11-25 2014-11-12 古河電気工業株式会社 電解セル、電解装置、炭化水素の生成方法
JP6083531B2 (ja) * 2011-03-18 2017-02-22 国立大学法人長岡技術科学大学 二酸化炭素の還元固定化システム、二酸化炭素の還元固定化方法、及び有用炭素資源の製造方法
JP6492676B2 (ja) * 2015-01-15 2019-04-03 株式会社豊田中央研究所 還元反応用電極及びそれを用いた反応デバイス

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0081982A1 (fr) * 1981-12-11 1983-06-22 The British Petroleum Company p.l.c. Synthèse organique électrochimique
US4595465A (en) * 1984-12-24 1986-06-17 Texaco Inc. Means and method for reducing carbn dioxide to provide an oxalate product

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3176766D1 (en) * 1980-10-21 1988-07-07 Oronzio De Nora Sa Electrolysis cell and method of generating halogen
US4673473A (en) * 1985-06-06 1987-06-16 Peter G. Pa Ang Means and method for reducing carbon dioxide to a product

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0081982A1 (fr) * 1981-12-11 1983-06-22 The British Petroleum Company p.l.c. Synthèse organique électrochimique
US4595465A (en) * 1984-12-24 1986-06-17 Texaco Inc. Means and method for reducing carbn dioxide to provide an oxalate product

Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8663447B2 (en) 2009-01-29 2014-03-04 Princeton University Conversion of carbon dioxide to organic products
US8986533B2 (en) 2009-01-29 2015-03-24 Princeton University Conversion of carbon dioxide to organic products
US8313634B2 (en) 2009-01-29 2012-11-20 Princeton University Conversion of carbon dioxide to organic products
US8721866B2 (en) 2010-03-19 2014-05-13 Liquid Light, Inc. Electrochemical production of synthesis gas from carbon dioxide
US10119196B2 (en) 2010-03-19 2018-11-06 Avantium Knowledge Centre B.V. Electrochemical production of synthesis gas from carbon dioxide
US9970117B2 (en) 2010-03-19 2018-05-15 Princeton University Heterocycle catalyzed electrochemical process
US8845877B2 (en) 2010-03-19 2014-09-30 Liquid Light, Inc. Heterocycle catalyzed electrochemical process
US8500987B2 (en) 2010-03-19 2013-08-06 Liquid Light, Inc. Purification of carbon dioxide from a mixture of gases
US9222179B2 (en) 2010-03-19 2015-12-29 Liquid Light, Inc. Purification of carbon dioxide from a mixture of gases
US8592633B2 (en) 2010-07-29 2013-11-26 Liquid Light, Inc. Reduction of carbon dioxide to carboxylic acids, glycols, and carboxylates
US8524066B2 (en) 2010-07-29 2013-09-03 Liquid Light, Inc. Electrochemical production of urea from NOx and carbon dioxide
US8845878B2 (en) 2010-07-29 2014-09-30 Liquid Light, Inc. Reducing carbon dioxide to products
US9309599B2 (en) 2010-11-30 2016-04-12 Liquid Light, Inc. Heterocycle catalyzed carbonylation and hydroformylation with carbon dioxide
US8961774B2 (en) 2010-11-30 2015-02-24 Liquid Light, Inc. Electrochemical production of butanol from carbon dioxide and water
US8568581B2 (en) 2010-11-30 2013-10-29 Liquid Light, Inc. Heterocycle catalyzed carbonylation and hydroformylation with carbon dioxide
US9090976B2 (en) 2010-12-30 2015-07-28 The Trustees Of Princeton University Advanced aromatic amine heterocyclic catalysts for carbon dioxide reduction
US8562811B2 (en) 2011-03-09 2013-10-22 Liquid Light, Inc. Process for making formic acid
US8658016B2 (en) 2011-07-06 2014-02-25 Liquid Light, Inc. Carbon dioxide capture and conversion to organic products

Also Published As

Publication number Publication date
EP0390157A3 (fr) 1991-04-17
DE69033409D1 (de) 2000-02-10
DE69033409T2 (de) 2000-08-03
ATE188514T1 (de) 2000-01-15
EP0390157A2 (fr) 1990-10-03
JPH03111586A (ja) 1991-05-13

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