EP0354344B1 - Wetting agent for mercerising and/or alcaline treatment - Google Patents
Wetting agent for mercerising and/or alcaline treatment Download PDFInfo
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- EP0354344B1 EP0354344B1 EP89112116A EP89112116A EP0354344B1 EP 0354344 B1 EP0354344 B1 EP 0354344B1 EP 89112116 A EP89112116 A EP 89112116A EP 89112116 A EP89112116 A EP 89112116A EP 0354344 B1 EP0354344 B1 EP 0354344B1
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- Prior art keywords
- alkyl
- weight
- radical
- wetting agents
- alkenyl
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Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/63—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing sulfur in the main chain, e.g. polysulfones
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic System
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S516/00—Colloid systems and wetting agents; subcombinations thereof; processes of
- Y10S516/01—Wetting, emulsifying, dispersing, or stabilizing agents
- Y10S516/03—Organic sulfoxy compound containing
Definitions
- the invention relates to mercerizing and / or lye wetting agents which contain alkali and / or ammonium salts of 2-ethylhexyl sulfate, end group-capped polyethers and optionally trialkyl phosphates.
- Mercerizing and leaching cotton i.e. H. the treatment of cellulose with lyes of different concentrations serves the purpose of giving the fibers better gloss effects, an increased absorption capacity for dyes, greater tear strengths and a softer, fuller feel.
- the concentrated sodium hydroxide solution used in practice does not have a large wetting power.
- wetting is made very difficult by the hydrophobic substances adhering to the cellulose fibers.
- wetting agents are therefore added to the mercerizing and / or leaching liquors in many cases (Chwala / Anger: "Handbook of Textile Aids" pages 347-350, 1977).
- the wetting agents should not cause foaming in the alkalis, should be stable within a large alkali concentration range and should be very well biodegraded.
- these known requirements are not satisfactorily met by most known mercerizing and / or lye wetting agents.
- the salts of 2-ethylhexyl sulfate that are frequently used as wetting agents tend to be in mercerising and / or lye liquors to excessive foaming.
- DE-A-12 45 898 describes mixtures of branched-chain carboxylic acid esters, phosphoric acid esters of aliphatic alcohols, fatty acids or soaps and alkoxylated compounds or alkylsulfuric acid esters as low-foaming wetting agents. From Chemical Abstract Unit CA 93 , 115887 g - (1980) it is also known that fatty alcohols, alkoxylated with 20 moles of ethylene oxide in combination with 2-ethylhexyl sodium sulfate, improve the wetting ability of mercerizing liquors and reduce the foaming in these liquors.
- DE-A-33 15 951, DE-A-37 27 378 and DE-A-38 00 490 end-capped alkyl alcohol ethoxylates are known as foam-suppressing additives in low-foam cleaning agents.
- the object of the invention was to develop low-foaming, alkali-stable and readily biodegradable mercerizing and / or lye wetting agents with very good shrink wetting properties.
- wetting agents which contain alkali and / or ammonium salts of 2-ethylhexyl sulfate, special end group-capped polyethers and optionally trialkyl phosphates largely meet the high demands placed on them.
- the mercerizing and / or lye wetting agents according to the invention preferably contain end-capped polyethers of the general formulas A and B in which the radicals R 1 are a straight-chain alkyl radical with 8 to 12 C atoms, R 2 is a straight-chain alkyl radical with 6 to 10 C atoms, R 3 Alkyl radical with 1 to 6 carbon atoms and R4 an alkyl or alkenyl radical with 12-18 C atoms and the indices n, the number 2 and x mean a number between 2 and 10.
- the weight ratio of the end group-capped polyethers A: B is preferably between 0.1 and 10, particularly preferably between 0.9 and 1.1.
- the end group-capped polyethers of the general formula A can be obtained by known processes: Guerbet alcohols, prepared by reacting saturated, primary alcohols with 1-20 C atoms in the presence of alkali (see, for example, in Angew. Chem.
- the end group-capped polyethers of the general formula B can also be prepared by processes known from the literature.
- the educts are aliphatic, saturated and / or unsaturated alcohols of natural and / or synthetic origin with 8-22 carbon atoms, for example octyl, decyl, dodecyl, myristyl, cetyl, stearyl, oleyl, linoleyl, behenyl -, Eruca alcohol or mixtures of these alcohols used.
- Alcohols with 12-18 C atoms for example lauryl, myristyl, cetyl, stearyl, oleyl alcohol and mixtures of these alcohols, are preferred.
- alkoxylation of these alcohols with ethylene oxide, propylene oxide and / or butylene oxide, preferably with ethylene oxide is carried out by known industrial processes (See, for example, in "Chemical Technology" Volume 7, pages 131-132, Carl-Hanser Verlag, Kunststoff-Vienna (1986)).
- the alkoxylated alcohols are then reacted in a manner known per se, preferably with alkyl halides having 1 to 6 carbon atoms, for example methyl chloride, ethyl chloride, propyl chloride, butyl chloride, butyl bromide, pentyl chloride and / or hexyl chloride, to give the end group-capped polyethers.
- alkali and / or ammonium salts of 2-ethylhexyl sulfate contained in the wetting agents according to the invention are commercially available products, for example Texapon R EHS, Henkel KGaA.
- the trialkyl phosphates optionally contained in the wetting agents according to the invention are prepared in a manner known per se, for example by reacting phosphorus oxychloride with alkyl alcohols (Chem. And Ind. 1962 , 1032-1035).
- alkyl alcohols for example, methanol, ethanol, propanol, n-butanol, n-pentanol or n-hexanol are used.
- the wetting agents according to the invention preferably contain 0.5 to 5% by weight of trialkyl phosphates.
- the wetting agents according to the invention are prepared at 18 to 50 ° C. by stirring the individual components, if appropriate after melting, to give a homogeneous solution.
- the wetting agents according to the invention which are in the form of aqueous solutions, are notable for high shrink wetting capacity and low foaming. Furthermore, they are very easily biodegradable.
- the wetting agents according to the invention contain no or only small amounts of solvents such as polyalcohols, for example hexylene glycol and / or butylene glycol.
- the wetting agents according to the invention can be used Use both for mercerizing and for leaching, for example, cellulose-containing woven goods, knitwear and / or yarns.
- the content of the wetting agents according to the invention in the mercerizing and / or leaching liquors is between 2 and 12 g / l liquor.
- the shrink wetting capacity was determined according to DIN 53987 (Landolt method) at 18 ° C with a wetting agent amount of 5 g / l (indication of the shrinking capacity in%).
- the foaming power was determined according to the glass frit method described in Melliand textile reports 48 , 311-315 and 450-456 at 18 ° C. with a wetting agent amount of 5 g / l.
- the foam height is given in mm (200 mm is the maximum height under the test conditions).
Abstract
Description
Die Erfindung betrifft Mercerisier- und/oder Laugiernetzmittel, die Alkali- und/oder Ammoniumsalze von 2-Ethylhexylsulfat, endgruppenverschlossene Polyether und gegebenenfalls Trialkylphosphate enthalten.The invention relates to mercerizing and / or lye wetting agents which contain alkali and / or ammonium salts of 2-ethylhexyl sulfate, end group-capped polyethers and optionally trialkyl phosphates.
Das Mercerisieren und Laugieren von Baumwolle, d. h. die Behandlung von Zellulose mit Laugen unterschiedlicher Konzentrationen dient dem Zweck, den Fasern bessere Glanzeffekte, ein gesteigertes Aufnahmevermögen für Farbstoffe, größere Reißfestigkeiten und einen weicheren, fülligeren Griff zu verleihen. Die in der Praxis verwendete konzentrierte Natronlauge besitzt jedoch kein großes Netzvermögen. Außerdem wird das Netzen durch die an den Zellulosefasern anhaftenden hydrophoben Stoffe stark erschwert. Zur Erzielung einer raschen und gleichmäßigen Reaktion der Lauge mit der Zellulose werden daher in vielen Fällen den Mercerisier- und/oder Laugierflotten Netzmittel zugesetzt (Chwala/ Anger : "Handbuch der Textilhilfsmittel" Seiten 347 - 350, 1977).Mercerizing and leaching cotton, i.e. H. the treatment of cellulose with lyes of different concentrations serves the purpose of giving the fibers better gloss effects, an increased absorption capacity for dyes, greater tear strengths and a softer, fuller feel. However, the concentrated sodium hydroxide solution used in practice does not have a large wetting power. In addition, wetting is made very difficult by the hydrophobic substances adhering to the cellulose fibers. In order to achieve a rapid and uniform reaction of the lye with the cellulose, wetting agents are therefore added to the mercerizing and / or leaching liquors in many cases (Chwala / Anger: "Handbook of Textile Aids" pages 347-350, 1977).
Neben einem guten Netzvermögen sollen die Netzmittel kein Schäumen in den Laugen verursachen, innerhalb eines großen Alkalikonzentrationsbereiches stabil sein und biologisch sehr gut abgebaut werden. Diese hohen Anforderungen werden jedoch von den meisten bekannten Mercerisier- und/oder Laugiernetzmitteln nicht in zufriedenstellender Weise erfüllt. So neigen beispielsweise die als Netzmittel häufig verwendeten Salze von 2-Ethylhexylsulfat in Mercerisier- und/oder Laugierflotten zu starker Schaumentwicklung.In addition to good wetting ability, the wetting agents should not cause foaming in the alkalis, should be stable within a large alkali concentration range and should be very well biodegraded. However, these known requirements are not satisfactorily met by most known mercerizing and / or lye wetting agents. For example, the salts of 2-ethylhexyl sulfate that are frequently used as wetting agents tend to be in mercerising and / or lye liquors to excessive foaming.
In DE-A-12 45 898 werden Gemische aus verzweigtkettigen Carbonsäureestern, Phosphorsäureestern von aliphatischen Alkoholen, Fettsäuren oder Seifen und alkoxylierte Verbindungen oder Alkylschwefelsäureester als schaumarme Netzmittel beschrieben. Aus dem Chemical Abstract Referat CA 93, 115887 g - (1980) ist ferner bekannt, daß Fettalkohole, alkoxyliert mit 20 Mol Ethylenoxid in Kombination mit 2-Ethylhexyl-Natriumsulfat das Netzvermögen von Mercerisierflotten verbessern und die Schaumentwicklung in diesen Flotten reduzieren.DE-A-12 45 898 describes mixtures of branched-chain carboxylic acid esters, phosphoric acid esters of aliphatic alcohols, fatty acids or soaps and alkoxylated compounds or alkylsulfuric acid esters as low-foaming wetting agents. From Chemical Abstract Unit CA 93 , 115887 g - (1980) it is also known that fatty alcohols, alkoxylated with 20 moles of ethylene oxide in combination with 2-ethylhexyl sodium sulfate, improve the wetting ability of mercerizing liquors and reduce the foaming in these liquors.
Aus DE-A-33 15 951, DE-A-37 27 378 und DE-A-38 00 490 sind endgruppenverschlossene Alkylalkoholethoxylate als schaumdrückende Zusätze in schaumarmen Reinigungsmitteln bekannt.DE-A-33 15 951, DE-A-37 27 378 and DE-A-38 00 490 end-capped alkyl alcohol ethoxylates are known as foam-suppressing additives in low-foam cleaning agents.
Die Aufgabe der Erfindung bestand in der Entwicklung von schaumarmen, alkalistabilen und biologisch gut abbaubaren Mercerisier- und/oder Laugiernetzmitteln mit sehr gutem Schrumpfnetzvermögen.The object of the invention was to develop low-foaming, alkali-stable and readily biodegradable mercerizing and / or lye wetting agents with very good shrink wetting properties.
Überraschenderweise wurde gefunden, daß Netzmittel, die Alkali-und /oder Ammoniumsalze von 2-Ethylhexylsulfat, spezielle endgruppenverschlossene Polyether und gegebenenfalls Trialkylphosphate enthalten, die an sie gestellten hohen Anforderungen weitgehend erfüllen.Surprisingly, it was found that wetting agents which contain alkali and / or ammonium salts of 2-ethylhexyl sulfate, special end group-capped polyethers and optionally trialkyl phosphates largely meet the high demands placed on them.
Erfindungsgegenstand sind dementsprechend Mercerisier- und/oder Laugiernetzmittel enthaltend
15 - 30 Gew.-% Alkali- und/oder Ammoniumsalze von 2-Ethylhexylsulfat
1 - 10 Gew.-% eines Gemisches aus endgruppenverschlossenen Polyethern der allgemeinen Formeln
- A)
- B) R⁴ - O -(CnH2nO)x- R³,
worin R⁴ einen Alkyl- oder Alkenylrest mit 8 bis 22 C-Atomen und R³ einen Alkyl-, Alkenyl-, Cycloalkyl-, Aryl-, Arylalkyl- oder Alkylarylrest mit 1 bis 22 C-Atomen bedeuten und n 2 und/oder 3 und/oder 4 und x eine Zahl zwischen 2 und 25 darstellt
0 - 5 Gew.-% Trialkylphosphate mit 1 bis 6 C-Atomen in den Alkylresten.Accordingly, the subject of the invention are mercerizing and / or lye wetting agents
15-30% by weight of alkali and / or ammonium salts of 2-ethylhexyl sulfate
1 - 10 wt .-% of a mixture of end-capped polyethers of the general formulas
- A)
- B) R⁴ - O - (C n H 2n O) x - R³,
wherein R⁴ is an alkyl or alkenyl radical with 8 to 22 C atoms and R³ is an alkyl, alkenyl, cycloalkyl, aryl, arylalkyl or alkylaryl radical with 1 to 22 C atoms and n is 2 and / or 3 and / or 4 and x represents a number between 2 and 25
0 - 5 wt .-% trialkyl phosphates with 1 to 6 carbon atoms in the alkyl radicals.
Vorzugsweise enthalten die erfindungsgemäßen Mercerisier- und/oder Laugiernetzmittel solche endgruppenverschlossenen Polyether der allgemeinen Formeln A und B, in denen die Reste R¹ einen geradkettigen Alkylrest mit 8 bis 12 C-Atomen, R² einen geradkettigen Alkylrest mit 6 bis 10 C-Atomen, R³ ein Alkylrest mit 1 bis 6 C-Atomen und R⁴ einen Alkyl- oder Alkenylrest mit 12 - 18 C-Atomen und die Indices n die Zahl 2 und x eine Zahl zwischen 2 und 10 bedeuten. Das Gewichtsverhältnis der endgruppenverschlossenen Polyether A : B liegt vorzugsweise zwischen 0,1 und 10, besonders bevorzugt zwischen 0,9 und 1,1.The mercerizing and / or lye wetting agents according to the invention preferably contain end-capped polyethers of the general formulas A and B in which the radicals R 1 are a straight-chain alkyl radical with 8 to 12 C atoms, R 2 is a straight-chain alkyl radical with 6 to 10 C atoms, R 3 Alkyl radical with 1 to 6 carbon atoms and R⁴ an alkyl or alkenyl radical with 12-18 C atoms and the indices n, the number 2 and x mean a number between 2 and 10. The weight ratio of the end group-capped polyethers A: B is preferably between 0.1 and 10, particularly preferably between 0.9 and 1.1.
Die endgruppenverschlossenen Polyether der allgemeinen Formel A sind nach bekannten Verfahren zugänglich: Guerbetalkohole, hergestellt durch Umsetzung von gesättigten, primären Alkoholen mit 1 - 20 C-Atomen in Gegenwart von Alkali (siehe beispielsweise in Angew. Chem. 64, 213 - 220 (1952)) werden einer Oxalkylierung mit Ethylenoxid, Propylenoxid und/oder Butylenoxid, vorzugsweise einer Ethoxylierung unterworfen ("Chemische Technologie" Band 7, Seite 131 - 132, Carl-Hanser Verlag, München-Wien (1986)) und anschließend vorzugsweise mit Alkylhalogeniden mit 1 bis 6 C-Atomen, beispielsweise Methylchlorid, Ethylchlorid, Propylchlorid, Butylchlorid, Butylbromid, Pentylchlorid und/oder Hexylchlorid bei Temperaturen zwischen 60 und 140 °C umgesetzt (DE-OS 37 44 525). Beispiele für die zur Herstellung von Guerbetalkoholen benötigten Alkohole sind Capryl-, Caprin-, Lauryl-, Myristyl-, Cetyl-, Stearylalkohol sowie Mischungen dieser Alkohole.The end group-capped polyethers of the general formula A can be obtained by known processes: Guerbet alcohols, prepared by reacting saturated, primary alcohols with 1-20 C atoms in the presence of alkali (see, for example, in Angew. Chem. 64 , 213-220 (1952) ) are subjected to an oxyalkylation with ethylene oxide, propylene oxide and / or butylene oxide, preferably ethoxylation ("Chemical Technology" Volume 7, pages 131-132, Carl-Hanser Verlag, Munich-Vienna (1986)) and then preferably with alkyl halides with 1 to 6 carbon atoms, for example methyl chloride, ethyl chloride, propyl chloride, butyl chloride, butyl bromide, pentyl chloride and / or hexyl chloride, are reacted at temperatures between 60 and 140 ° C. (DE-OS 37 44 525). Examples of the alcohols required for the production of Guerbet alcohols are caprylic, capric, lauryl, myristyl, cetyl, stearyl alcohol and mixtures of these alcohols.
Die endgruppenverschlossenen Polyether der allgemeinen Formel B lassen sich ebenfalls nach literaturbekannten Verfahren herstellen. Als Edukte werden aliphatische, gesättigte und/oder ungesättigte Alkohole natürlichen und/oder synthetischen Ursprungs mit 8 - 22 C-Atomen beispielsweise Octyl-, Decyl-, Dodecyl-, Myristyl-, Cetyl-, Stearyl-, Oleyl-, Linoleyl-, Behenyl-, Erucaalkohol oder Mischungen dieser Alkohole eingesetzt. Bevorzugt werden Alkohole mit 12 - 18 C-Atomen, beispielsweise Lauryl-, Myristyl-, Cetyl-, Stearyl-, Oleylalkohol sowie Mischungen dieser Alkohole. Die Oxalkylierung dieser Alkohole mit Ethylenoxid, Propylenoxid und/oder Butylenoxid, vorzugsweise mit Ethylenoxid werden nach bekannten großtechnischen Verfahren durchgeführt (siehe beispielsweise im "Chemischen Technologie" Band 7, Seite 131 - 132, Carl-Hanser Verlag, München-Wien (1986)). Anschliessend werden die oxalkylierten Alkohole in an sich bekannter Weise vorzugsweise mit Alkylhalogeniden mit 1 - 6 C-Atomen, beispielsweise Methylchlorid, Ethylchlorid, Propylchlorid, Butylchlorid, Butylbromid, Pentylchlorid und/oder Hexylchlorid zu den endgruppenverschlossenen Polyethern umgesetzt.The end group-capped polyethers of the general formula B can also be prepared by processes known from the literature. The educts are aliphatic, saturated and / or unsaturated alcohols of natural and / or synthetic origin with 8-22 carbon atoms, for example octyl, decyl, dodecyl, myristyl, cetyl, stearyl, oleyl, linoleyl, behenyl -, Eruca alcohol or mixtures of these alcohols used. Alcohols with 12-18 C atoms, for example lauryl, myristyl, cetyl, stearyl, oleyl alcohol and mixtures of these alcohols, are preferred. The alkoxylation of these alcohols with ethylene oxide, propylene oxide and / or butylene oxide, preferably with ethylene oxide, is carried out by known industrial processes (See, for example, in "Chemical Technology" Volume 7, pages 131-132, Carl-Hanser Verlag, Munich-Vienna (1986)). The alkoxylated alcohols are then reacted in a manner known per se, preferably with alkyl halides having 1 to 6 carbon atoms, for example methyl chloride, ethyl chloride, propyl chloride, butyl chloride, butyl bromide, pentyl chloride and / or hexyl chloride, to give the end group-capped polyethers.
Die in den erfindungsgemäßen Netzmitteln enthaltenen Alkali-und /oder Ammoniumsalze von 2-Ethylhexylsulfat sind handelsübliche Produkte, beispielsweise Texapon R EHS, Henkel KGaA.The alkali and / or ammonium salts of 2-ethylhexyl sulfate contained in the wetting agents according to the invention are commercially available products, for example Texapon R EHS, Henkel KGaA.
Die gewünschtenfalls in den erfindungsgemäßen Netzmitteln enthaltenen Trialkylphosphate werden in an sich bekannter Weise beispielsweise durch Umsetzung von Phosphoroxychlorid mit Alkylalkoholen hergestellt (Chem. and Ind. 1962, 1032 - 1035). Als Alkylalkohole werden beispielsweise Methanol, Ethanol, Propanol, n-Butanol, n-Pentanol oder n-Hexanol eingesetzt. Vorzugsweise enthalten die erfindungsgemäßen Netzmittel 0,5 bis 5 Gew.-% Trialkylphosphate.The trialkyl phosphates optionally contained in the wetting agents according to the invention are prepared in a manner known per se, for example by reacting phosphorus oxychloride with alkyl alcohols (Chem. And Ind. 1962 , 1032-1035). As alkyl alcohols, for example, methanol, ethanol, propanol, n-butanol, n-pentanol or n-hexanol are used. The wetting agents according to the invention preferably contain 0.5 to 5% by weight of trialkyl phosphates.
Die Herstellung der erfindungsgemäßen Netzmittel erfolgt bei 18 bis 50 °C, indem man die einzelnen Komponenten, gegebenenfalls nach Aufschmelzen, zu einer homogenen Lösung verrührt.The wetting agents according to the invention are prepared at 18 to 50 ° C. by stirring the individual components, if appropriate after melting, to give a homogeneous solution.
Die erfindungsgemäßen Netzmittel, die in Form wäßriger Lösungen vorliegen, zeichnen sich durch ein hohes Schrumpfnetzvermögen bei gleichzeitiger Schaumarmut aus. Des weiteren sind sie sehr gut biologisch abbaubar. Die erfindungsgemäßen Netzmittel enthalten keine oder nur geringe Mengen an Lösungsmitteln wie Polyalkohole, beispielsweise Hexylenglycol und/oder Butylenglycol.The wetting agents according to the invention, which are in the form of aqueous solutions, are notable for high shrink wetting capacity and low foaming. Furthermore, they are very easily biodegradable. The wetting agents according to the invention contain no or only small amounts of solvents such as polyalcohols, for example hexylene glycol and / or butylene glycol.
Aufgrund ihrer Stabilität in einem weiten Alkalikonzentrationsbereich lassen sich die erfindungsgemäßen Netzmittel sowohl zum Mercerisieren als auch zum Laugieren von beispielsweise zellulosehaltigen Webwaren, Wirkwaren und/oder Garnen verwenden. In den Mercerisier- und/oder Laugierflotten liegt der Gehalt der erfindungsgemäßen Netzmittel zwischen 2 und 12 g/l Flotte.Because of their stability in a wide range of alkali concentrations, the wetting agents according to the invention can be used Use both for mercerizing and for leaching, for example, cellulose-containing woven goods, knitwear and / or yarns. The content of the wetting agents according to the invention in the mercerizing and / or leaching liquors is between 2 and 12 g / l liquor.
-
a)
- 81 Gew.-%
- 2-Ethylhexylsulfat-Natriumsalz (Aktivsubstanzgehalt: 30 Gew.-%, Wassergehalt: 70 Gew.-%)
- 2,5 Gew.-%
- C₁₂₋₁₈-Fettalkohol x 5 Mol Ethylenoxid-Butylether
- 2,5 Gew.-%
- 2-Hexyldecanol-1 x 6 Mol Ethylenoxid-Butylether
- 2 Gew.-%
- n-Tributylphosphat
- 4 Gew.-%
- Hexylenglycol
- 8 Gew.-%
- Wasser
- 81% by weight
- 2-ethylhexyl sulfate sodium salt (active substance content: 30% by weight, water content: 70% by weight)
- 2.5% by weight
- C₁₂₋₁₈ fatty alcohol x 5 moles of ethylene oxide butyl ether
- 2.5% by weight
- 2-Hexyldecanol-1 x 6 mol ethylene oxide butyl ether
- 2% by weight
- n-tributyl phosphate
- 4% by weight
- Hexylene glycol
- 8% by weight
- water
-
b)
- 81 Gew.-%
- 2-Ethylhexylsulfat-Natriumsalz (Aktivsubstanzgehalt = 30 Gew.-%, Wassergehalt = 70 Gew.-%)
- 2,5 Gew.-%
- C₁₂₋₁₈-Fettalkohol x 5 Mol Ethylenoxid-Butylether
- 2,5 Gew.-%
- 2-Octyldodecanol-1 x 8 Mol Ethylenoxid-Butylether
- 2 Gew.-%
- n-Tributylphosphat
- 4 Gew.-%
- Hexylenglycol
- 8 Gew.-%
- Wasser
- 81% by weight
- 2-ethylhexyl sulfate sodium salt (active substance content = 30% by weight, water content = 70% by weight)
- 2.5% by weight
- C₁₂₋₁₈ fatty alcohol x 5 moles of ethylene oxide butyl ether
- 2.5% by weight
- 2-octyldodecanol-1 x 8 moles of ethylene oxide butyl ether
- 2% by weight
- n-tributyl phosphate
- 4% by weight
- Hexylene glycol
- 8% by weight
- water
-
c)
- 81 Gew.-%
- 2-Ethylhexylsulfat-Natriumsalz (Aktivsubstanzgehalt = 30 Gew.-%, Wassergehalt = 70 Gew.-%)
- 2,5 Gew.-%
- C₁₂₋₁₈-Fettalkohol x 7 Mol Ethylenoxid-Butylether
- 2,5 Gew.-%
- 2-Octyldodecanol-1 x 8 Mol Ethylenoxid-Butylether
- 2 Gew.-%
- n-Tributylphosphat
- 4 Gew.-%
- Hexylenglycol
- 8 Gew.-%
- Wasser
- 81% by weight
- 2-ethylhexyl sulfate sodium salt (active substance content = 30% by weight, water content = 70% by weight)
- 2.5% by weight
- C₁₂₋₁₈ fatty alcohol x 7 moles of ethylene oxide butyl ether
- 2.5% by weight
- 2-octyldodecanol-1 x 8 moles of ethylene oxide butyl ether
- 2% by weight
- n-tributyl phosphate
- 4% by weight
- Hexylene glycol
- 8% by weight
- water
Das Schrumpfnetzvermögen wurde nach DIN 53987 (Landolt-methode) bei 18 °C mit einer Netzmittelmenge von 5 g/l bestimmt (Angabe des Schrumpfvermögens in %).
Das Schaumvermögen wurde nach der in Melliand Textilberichte 48, 311 - 315 und 450 - 456 beschriebenen Glasfrittenmethode bei 18 °C mit einer Netzmittelmenge von 5 g/l bestimmt. Die Schaumhöhe ist in mm angegeben (200 mm ist unter den Testbedingungen die maximale Höhe).
Claims (4)
- The use of mixtures containing
15 to 30% by weight alkali metal and/or ammonium salts of 2-ethyl hexyl sulfate,
1 to 10% by weight of a mixture of end-capped polyethers corresponding to the following general formulaeA)B) R⁴ - O -(CnH2nO)x- R³0 to 5% by weight trialkyl phosphates containing 1 to 6 carbon atoms in the alkyl groups,
in which R⁴ is a C₈₋₂₂ alkyl or alkenyl radical and R³ is a C₁₋₂₂ alkyl, alkenyl, cycloalkyl, aryl, arylalkyl or alkylaryl radical and n is the number and 2 and/or 3 and/or 4 and x is a number of 2 to 25,
as mercerizing and/or causticizing wetting agents. - The use claimed in claim 1, characterized in that, in general formulae A and B, R¹ is a linear C₈₋₁₂ alkyl radical, R² is a linear C₆₋₁₀ alkyl radical, R³ is a C₁₋₅ alkyl radical and R⁴ is a C₁₂₋₁₈ alkyl or alkenyl radical, n is the number 2 and x is a number of 2 to 10.
- The use claimed in one or both of claims 1 - 2, characterized in that the ratio by weight of A to B is between 0.1 and 10 and preferably between 0.9 and 1.1.
- The use claimed in one or more of claims 1 to 3, characterized in that the trialkyl phosphate content is from 0.5 to 5% by weight.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT89112116T ATE82778T1 (en) | 1988-07-11 | 1989-07-03 | MERCERISING AND/OR BASED NETTING AGENTS. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE3823454A DE3823454A1 (en) | 1988-07-11 | 1988-07-11 | MERCERIZING AND / OR LYING AGENT |
DE3823454 | 1988-07-11 |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0354344A2 EP0354344A2 (en) | 1990-02-14 |
EP0354344A3 EP0354344A3 (en) | 1990-07-18 |
EP0354344B1 true EP0354344B1 (en) | 1992-11-25 |
Family
ID=6358427
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP89112116A Expired - Lifetime EP0354344B1 (en) | 1988-07-11 | 1989-07-03 | Wetting agent for mercerising and/or alcaline treatment |
Country Status (12)
Country | Link |
---|---|
US (1) | US5013327A (en) |
EP (1) | EP0354344B1 (en) |
JP (1) | JP2738959B2 (en) |
KR (1) | KR900001918A (en) |
AT (1) | ATE82778T1 (en) |
BR (1) | BR8903381A (en) |
CA (1) | CA1323468C (en) |
DE (2) | DE3823454A1 (en) |
ES (1) | ES2043971T3 (en) |
GR (1) | GR3006359T3 (en) |
HK (1) | HK134694A (en) |
TR (1) | TR23864A (en) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0420802B1 (en) * | 1989-09-26 | 1995-08-09 | Ciba-Geigy Ag | Aqueous, storage stable, low foaming wetting agent |
AU1228192A (en) * | 1991-03-04 | 1992-10-06 | Ciba-Geigy Ag | Aqueous textile auxiliary composition |
DE19502514A1 (en) * | 1994-02-03 | 1995-08-10 | Sandoz Ag | New finishing agent for textile fibres |
ES2182880T3 (en) * | 1994-08-11 | 2003-03-16 | Ciba Sc Holding Ag | COMPOSITIONS OF MULTIFUNCTIONAL TEXTILE AGENTS. |
EP0716180A1 (en) * | 1994-12-08 | 1996-06-12 | Ciba-Geigy Ag | Wetting agent for mercerizing |
DE59508783D1 (en) * | 1994-12-22 | 2000-11-16 | Ciba Sc Holding Ag | N-cyanomethylated chitosans and their hydrolysis products |
US6017887A (en) * | 1995-01-06 | 2000-01-25 | Sibia Neurosciences, Inc. | Peptide, peptide analog and amino acid analog protease inhibitors |
JP3475596B2 (en) * | 1995-08-01 | 2003-12-08 | チッソ株式会社 | Durable hydrophilic fibers, cloths and moldings |
DE59912401D1 (en) * | 1999-10-16 | 2005-09-15 | Ciba Sc Pfersee Gmbh | Composition for the pretreatment of fiber materials |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR949934A (en) * | 1949-09-14 | |||
CH287464A (en) * | 1948-12-15 | 1952-11-30 | Ciba Geigy | Process for increasing the wetting ability of mercerising liquors. |
SU732427A1 (en) * | 1977-12-19 | 1980-05-05 | Предприятие П/Я А-7568 | Composition for mercerization of textile articles |
CH671668B5 (en) * | 1981-08-22 | 1990-03-30 | Sandoz Ag | |
DE3315951A1 (en) * | 1983-05-02 | 1984-11-08 | Henkel KGaA, 4000 Düsseldorf | USE OF POLYGLYCOLETHERS AS FOAM-PRESSING ADDITIVES IN LOW-FOAM CLEANERS |
DE3727378A1 (en) * | 1987-08-17 | 1989-03-02 | Henkel Kgaa | FOAM-PRESSING ADDITIVES IN LOW-FOAM CLEANING AGENTS |
DE3800490A1 (en) * | 1988-01-11 | 1989-07-20 | Henkel Kgaa | USE OF SELECTED END-GROUP-CONTAINED FAT ALCOHOL ETHHOXYLATES FOR FOAM ARMS, COLD-FRYABLE CLEANING AGENTS |
-
1988
- 1988-07-11 DE DE3823454A patent/DE3823454A1/en not_active Withdrawn
-
1989
- 1989-07-03 AT AT89112116T patent/ATE82778T1/en active
- 1989-07-03 ES ES89112116T patent/ES2043971T3/en not_active Expired - Lifetime
- 1989-07-03 DE DE8989112116T patent/DE58902808D1/en not_active Expired - Fee Related
- 1989-07-03 TR TR89/0542A patent/TR23864A/en unknown
- 1989-07-03 EP EP89112116A patent/EP0354344B1/en not_active Expired - Lifetime
- 1989-07-06 US US07/376,089 patent/US5013327A/en not_active Expired - Fee Related
- 1989-07-10 BR BR898903381A patent/BR8903381A/en not_active Application Discontinuation
- 1989-07-11 KR KR1019890009879A patent/KR900001918A/en not_active Application Discontinuation
- 1989-07-11 JP JP1178887A patent/JP2738959B2/en not_active Expired - Lifetime
- 1989-07-11 CA CA000605374A patent/CA1323468C/en not_active Expired - Fee Related
-
1992
- 1992-11-26 GR GR920402717T patent/GR3006359T3/el unknown
-
1994
- 1994-12-01 HK HK134694A patent/HK134694A/en not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
GR3006359T3 (en) | 1993-06-21 |
CA1323468C (en) | 1993-10-26 |
KR900001918A (en) | 1990-02-27 |
JP2738959B2 (en) | 1998-04-08 |
JPH0280662A (en) | 1990-03-20 |
EP0354344A3 (en) | 1990-07-18 |
ES2043971T3 (en) | 1994-01-01 |
BR8903381A (en) | 1990-02-13 |
US5013327A (en) | 1991-05-07 |
TR23864A (en) | 1990-10-16 |
EP0354344A2 (en) | 1990-02-14 |
ATE82778T1 (en) | 1992-12-15 |
DE3823454A1 (en) | 1990-01-25 |
DE58902808D1 (en) | 1993-01-07 |
HK134694A (en) | 1994-12-09 |
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