DE734509C - Process for mercerizing - Google Patents
Process for mercerizingInfo
- Publication number
- DE734509C DE734509C DEI61723D DEI0061723D DE734509C DE 734509 C DE734509 C DE 734509C DE I61723 D DEI61723 D DE I61723D DE I0061723 D DEI0061723 D DE I0061723D DE 734509 C DE734509 C DE 734509C
- Authority
- DE
- Germany
- Prior art keywords
- fatty acids
- mercerizing
- carbon atoms
- liquors
- molecule
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic System
Description
Verfahren zum Mercerisieren Es wurde gefunden, daß lösliche Mono-oder Dioxäthylamide von Fettsäuren mit y bis 9 Kohlenstoffatomen im Molekül, die keine verätherte Hydroxylgruppe aufweisen, ausgezeichnete Netzmittel für Mercerisierlaugen sind.Process for mercerizing It has been found that soluble mono- or Dioxäthylamides of fatty acids with y to 9 carbon atoms in the molecule, which are none have etherified hydroxyl groups, excellent wetting agents for mercerising liquors are.
Die erwähnten Fettsäuren mit 5 bis 9 Kohlenstoffatomen im Molekül können aus Naturprodukten gewonnen werden. Zwangsläufig fallen sie bei der Oxydation von Paraffin zu Seifenfettsäuren als Nebenprodukte an, weshalb ihre Verwendung von erheblicher technischer Bedeutung ist. Außerdem können auch Fettsäuren mit verzweigter Kette Verwendung finden, die aus den bei der Methylalkoholsynthese anfallendenhöherenAlkoholen durch Oxydation gewonnen werden.The mentioned fatty acids with 5 to 9 carbon atoms in the molecule can be obtained from natural products. Inevitably they fall with the oxidation from paraffin to soap fatty acids as by-products, which is why their use of is of considerable technical importance. In addition, fatty acids can also be branched with Chain use, those from the higher alcohols obtained in the methyl alcohol synthesis can be obtained by oxidation.
Die Heratelluni# der Oxalkylamide aus den Fettsäuren oder deren funktionellen Abkömmlingen erfolgt in bekannter Weise. Aus der französischen Patentschrift 751 6,41 ist u.a. ein Verfahren zur Herstellung von Einwirkungsprodukten von Alkylenoxyden auf Fett-23 sowie deren Verwendung als N etzmittel für Mercerisierlaugen bekannt Nach diesem bekannten Verfahren werden aber nur Gemische erhalten, die stets noch weitere Einwirkungsprodukte auf die primär gebildeten Oxäthylamide enthalten. Die vorliegenden Mono- und Dioxalkylamide sind diesen Gemischen sowohl in der Löslichkeit in Mercerisierlaugen als auch in der Wirksamkeit der mit ihnen versetzten Mercerisierlaugen überlegen. Beispiel r Das bei der Paraffino2#,vdation anfallende Fettsäuregemisch aus Fettsäuren mit 7 bis 9 Kohlenstoffatomen im Molekül wird in bekannter Weise in das Fettsäuredioxäthylamidgemisch übergeführt. Dieses stellt eine dicke Flüssigkeit dar, die in Natronlauge von 3o°Be klar löslich ist. Lösungen von 5 bis zog im Liter netzen rohe Baumwolle fast augenblicklich.The Heratelluni # of the oxalkylamides from the fatty acids or their functional derivatives takes place in a known manner. From the French patent specification 751 6.41, among other things, a process for the production of products of the action of alkylene oxides on fatty 23 and their use as wetting agents for mercerising liquors are known Contain Oxäthylamide. The present mono- and dioxalkylamides are superior to these mixtures both in their solubility in mercerizing liquors and in the effectiveness of the mercerizing liquors to which they are added. EXAMPLE The fatty acid mixture of fatty acids with 7 to 9 carbon atoms in the molecule resulting from paraffination is converted into the fatty acid dioxäthylamide mixture in a known manner. This is a thick liquid that is clearly soluble in sodium hydroxide solution at 30 ° Be. Solutions from 5 to 1 liter of netting of raw cotton drew almost instantly.
Beispiel z An Stelle des Gemisches aus Fettsäuren mit 7 bis 9 Kohlenstoffatomen
im Molekül
Claims (1)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEI61723D DE734509C (en) | 1938-06-24 | 1938-06-25 | Process for mercerizing |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE2257183X | 1938-06-24 | ||
DEI61723D DE734509C (en) | 1938-06-24 | 1938-06-25 | Process for mercerizing |
Publications (1)
Publication Number | Publication Date |
---|---|
DE734509C true DE734509C (en) | 1943-04-17 |
Family
ID=25982082
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DEI61723D Expired DE734509C (en) | 1938-06-24 | 1938-06-25 | Process for mercerizing |
Country Status (1)
Country | Link |
---|---|
DE (1) | DE734509C (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0638685A1 (en) * | 1993-08-10 | 1995-02-15 | Ciba-Geigy Ag | Welling agent for mercerising |
-
1938
- 1938-06-25 DE DEI61723D patent/DE734509C/en not_active Expired
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0638685A1 (en) * | 1993-08-10 | 1995-02-15 | Ciba-Geigy Ag | Welling agent for mercerising |
US5464547A (en) * | 1993-08-10 | 1995-11-07 | Ciba-Geigy Corporation | Mercerization wetting composition |
US5494486A (en) * | 1993-08-10 | 1996-02-27 | Ciba-Geigy Corporation | Mercerization wetting composition |
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