EP0341071B2 - Compositions détergentes - Google Patents
Compositions détergentes Download PDFInfo
- Publication number
- EP0341071B2 EP0341071B2 EP89304522A EP89304522A EP0341071B2 EP 0341071 B2 EP0341071 B2 EP 0341071B2 EP 89304522 A EP89304522 A EP 89304522A EP 89304522 A EP89304522 A EP 89304522A EP 0341071 B2 EP0341071 B2 EP 0341071B2
- Authority
- EP
- European Patent Office
- Prior art keywords
- betaine
- alkyl
- active
- amine oxide
- ethanolamide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0094—High foaming compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/32—Amides; Substituted amides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/75—Amino oxides
Definitions
- the present invention relates to novel detergent compositions and especially, but not exclusively, to foaming liquid compositions useful for light-duty applications such as manual dishwashing.
- the compositions may also have use for fabric washing, cleaning carpets and as shampoos.
- Light-duty liquid detergent compositions such as are suitable for use in washing dishes are well known.
- Many commercially-available formulations are based on a sulphate - or sulphonate-type anionic detergent, especially alkyl sulphate, alkyl benzene sulphonate and alkane sulphonate, in conjunction with an alkyl polyethoxy sulphate (alkyl ether sulphate).
- the sulphonate-type detergent generally predominates.
- Alkyl mono- and poly-glycosides are known and have been disclosed in a number of prior art patents and literature publications.
- Boettner (US3219656) discusses the utility of alkyl mono-glycosides as foam stabilisers for anionic and nonionic surfactants.
- Lew (US 3772269) discloses that decyl glucoside containing less than 1.6 glucose units acts as a good foamer.
- Several Procter and Gamble disclosures eg EP 0 070 074, EP 0 070 075 and EP 0 070 076) discuss the utility of alkylpolyglucosides having greater than 1.5 glucose units in detergent compositions.
- Henkel (EP 216 301 A) disclose the beneficial use of alkyl glycosides having from 1 to 1.4 glucose units which are incorporated in dishwashing liquids comprising ether sulphate and ethanolamide.
- the present invention relates to safe, mild liquid detergents with a good foam stability and a good cleansing ability based upon alkyl polyglycosides.
- the invention aims to provide novel, high-foaming nonionic based liquid detergents comprising an alkyl polyglycoside. It is a further aim to provide a mild, ecologically safe liquid detergent.
- an aqueous liquid detergent composition comprising:
- Alkyl polyglycosides though nonionic in nature, differ from conventional ethoxylated nonionics such as alkyl ethoxylates or alkylphenol ethoxylates in having a different type of hydrophilic group and in consequence exhibit different physical, chemical and hence functional properties compared to conventional ethoxylated nonionics.
- ethoxylates are low melting solids or liquids at room temperature, are completely miscible in non-polar solvents and their aqueous solutions have cloud points.
- alkyl polyglycosides are high melting solids, sparingly soluble in non-polar solvents and their aqueous solutions do not show cloud points.
- Alkyl polyglycosides also generally give lower surface tensions and give a more stable foam compared to comparable, conventional nonionics.
- Alkyl polyglycosides are also prepared by different routes and can be produced entirely based on natural raw materials. Hence the compounds and compositions made therewith can be expected to be biologically safer and more acceptable than conventional nonionics and compositions containing them. Impurities present will also differ from conventional nonionics.
- Alkyl polyglycosides may be manufactured by the Fischer glycoxidation of a detergent alcohol, eg C 8 -C 18 Alcohol + "glucose” + catalyst ⁇ ROG x + H 2 O (ROH) + (G)
- ROG x product depends on control of the ratios of the reactants.
- a product will be a ratio of, eg ROG 1 :ROG 2 :ROG 3 .
- the alkyl polyglycosides used in the present invention have a hydrophobic group containing 8 to 20 carbon atoms, preferably about 10 to about 16, most preferably from 12 to 14, and a polysaccharide hydrophilic group containing from 1 to 1.4 preferably 1.2 to 1.4 saccharide units on average.
- the saccharide unit may be, for example, a galactoside, glucoside, fructoside or glycosyl. Mixtures thereof may be used.
- Preferred alkyl polyglycosides are APG 500 from Horizon (APG is a trademark).
- APG 500 has an average degree of polymerisation of 1.4.
- the alkyl polyglycoside is preferably the major active component and may, for example, be present at from 30 to 60 wt% of the total active.
- the co-active anionic surfactant used according to the present invention is a primary alkyl sulphate surfactant.
- the sulphates may be conventional anionic synthetic detergents, and are sulphuric acid half esters of alkanols. Suitable sulphates are from the linear, or branched, primary alcohols. Preferred alcohols are:
- Primary alcohols with substantial branching may be used.
- the preferred cations which neutralise the anionic surfactant are sodium and ammonium, and the latter sulphates can be an aid to hydrotroping of the liquid compositions of the invention.
- the third essential feature of the present invention is the presence of an amine oxide or a betaine as a lather booster.
- the amount of amine oxide is not more than 10% by weight of the active detergent mixture.
- the amount of betaine is not more than 30% by weight of this mixture.
- the total amount of amine oxide and betaine, and. if present, ethanolamide is from 12 to 30% by weight of the active detergent mixture.
- the lather booster is preferably present at from 2 to 6% by weight of the total composition. It is preferred to use betaines alone.
- Suitable betaines include simple betaines of formula: and amido betaines of formula:
- R is a C 8 to C 18 straight or branched alkyl group. It may be a lauryl group or a middle cut coconut alkyl group.
- R 6 and R 7 are each C 1 to C 3 alkyl or C 1 to C 3 hydroxyalkyl. Examples of sulphobetaines have the above formulae with -CH 2 CO - 2 replaced by:
- a suitable simple betaine is Empigen BB from Albright & Wilson. It has the formula quoted above in which R is C 12 to C 14 alkyl, derived from coconut, and R 6 and R 7 are both methyl. Also preferred is Tego L7 from Goldschmidt, which has a whole coconut alkyl group.
- Suitable amine oxides have the formula: R R 6 R 7 N ⁇ O wherein R is a straight- or branched-chain C 8 to C 18 alkyl group and R 6 and R 7 are each C 1 to C 3 alkyl, or C 1 to C 3 hydroxyalkyl.
- a suitable amine oxide is Empigen OB from Albright & Wilson. In it R is middle-cut coconut alkyl and R 6 and R 7 are both methyl.
- compositions according to the present invention may include other conventional ingredients such as minor amounts of builders, urea, sodium or ammonium chloride, corrosion inhibitors, colourings and perfumes.
- Conventional foam boosters such as ethanolamides may be included.
- ethanolamide is optional. If present, the total level of betaine and/or amine oxide and ethanolamide is from 12 to 30 wt% of the total active.
- a preferred ethanolamide is Empilan LME (Albright & Wilson).
- compositions according to the present invention are of particular use as light duty liquid detergent compositions for manual dishwashing.
- compositions for manual dishwashing comprise from about 5 to about 60 wt%, preferably about 10 to about 40 wt% of the mixture of active components hereinbefore described, the balance comprising water and solvents.
- compositions according to the present invention are mild and environmentally safe. They exhibit good foam characteristics.
- Foaming performance was assessed by means of a modified Schlachter-Dierkes test based on the principle described in Fette und Seifen 1951, 53 , 207.
- a 100 ml aqueous solution of each material tested, having a concentration of 0.04% active detergent in 24°H water (French hardness) at 45°C was rapidly oscillated using a vertically oscillating perforated disc within a graduated cylinder.
- increments (0.2 g) of soil 9.5 parts commercial cooking fat, 0.25 parts oleic acid, 0.25 parts stearic acid and 10 parts wheat starch in 120 parts water
- the result was recorded as the number of soil increments (NSI score): a score difference of 6 or less is generally regarded as insignificant.
- NAI score number of soil increments
- a comparison of wheatgerm acid phosphatase (WGAP) test and flex wash test results indicated that formulations giving less than 50% enzyme inhibition under the test conditions are substantially mild; any mildness differences between products giving ⁇ 40% inhibition do not show any detectable mildness differences in flex wash test, indicating that the enzyme test is very sensitive and that in a real life situation there is a threshold level of protein denaturation below which all actives and products are indistinguishably mild.
- the results of the WGAP test are expressed as percentage inhibition (ie, 100% minus percentage activity remaining). Water gave no inhibition at all, ie 100% of activity remained.
- compositions tested The varying amounts of ingredients used in the compositions tested are shown below as a percentage of the total weight of the composition.
Claims (4)
- Composition détergente liquide aqueuse comprenant:(a) un tensioactif alkyl(en C8-18) polyglycoside ayant un degré moyen de polymérisation de 1 à 1,4,(b) un tensioactif alkylsulfate primaire,(c) une bétaïne et/ou un oxyde d'amine agent de surface; et éventuellement,(d) un éthanolamide,la quantité de tensioactif anionique n'est pas supérieure à 1,5 fois (sur une base molaire) le niveau de bétaïne et/ou d'oxyde d'amine, etle niveau de bétaïne et/ou d'oxyde d'amine et, le cas échéant, d'éthanolamide, représente de 12 à 30% en poids du total des ingrédients actifs.
- Composition selon la revendication 1 dans laquelle on utilise une bétaïne seule comme agent renforçateur de mousse.
- Composition selon l'une quelconque des revendications 1 ou 2 dans laquelle un ingrédient actif non ionique est aussi présent.
- Composition détergente liquide aqueuse selon la revendication 1 comprenant, par rapport à la quantité totale des ingrédients actifs,(a) de 50 à 60% en poids d'un tensioactif d'alkylpolyglycoside ayant un degré moyen de polymérisation de 1 à 1,4,(b) de 15 à 20% en poids d'un tensioactif alkylsulfate primaire,(c) de 10 à 15% en poids d'une bétaïne agent de surface, et(d) de 10 à 15% en poids d'un éthanolamide.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB888810820A GB8810820D0 (en) | 1988-05-06 | 1988-05-06 | Detergent compositions |
GB8810820 | 1988-05-06 |
Publications (4)
Publication Number | Publication Date |
---|---|
EP0341071A2 EP0341071A2 (fr) | 1989-11-08 |
EP0341071A3 EP0341071A3 (en) | 1990-07-11 |
EP0341071B1 EP0341071B1 (fr) | 1994-08-03 |
EP0341071B2 true EP0341071B2 (fr) | 2002-11-13 |
Family
ID=10636497
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP89304522A Expired - Lifetime EP0341071B2 (fr) | 1988-05-06 | 1989-05-05 | Compositions détergentes |
Country Status (9)
Country | Link |
---|---|
EP (1) | EP0341071B2 (fr) |
JP (1) | JP2664474B2 (fr) |
AU (1) | AU615740B2 (fr) |
BR (1) | BR8902111A (fr) |
CA (1) | CA1335876C (fr) |
DE (1) | DE68917195T3 (fr) |
ES (1) | ES2056215T5 (fr) |
GB (1) | GB8810820D0 (fr) |
ZA (1) | ZA893327B (fr) |
Families Citing this family (30)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0699711B2 (ja) * | 1989-07-25 | 1994-12-07 | 花王株式会社 | 液体洗浄剤組成物 |
DE4003098A1 (de) * | 1990-02-02 | 1991-08-08 | Henkel Kgaa | Waessriges fluessiges reinigungsmittel |
US5118440A (en) * | 1990-03-05 | 1992-06-02 | The Procter & Gamble Company | Light-duty liquid dishwashing detergent composition containing alkyl polysaccharide and alpha-sulfonated fatty acid alkyl ester surfactants |
DE4023334A1 (de) * | 1990-07-23 | 1992-01-30 | Henkel Kgaa | Fluessiges, giess- und pumpfaehiges tensidkonzentrat |
BR9106913A (pt) * | 1990-09-28 | 1993-07-20 | Procter & Gamble | Composicoes detergentes contendo amidas de acidos graxos poliidroxi e agente intensificador de espuma |
DE4039229A1 (de) * | 1990-12-08 | 1992-06-11 | Huels Chemische Werke Ag | Kosmetische reinigungsfluessigkeit |
SE468252B (sv) * | 1991-04-09 | 1992-11-30 | Berol Nobel Ab | Flytande diskmedelskomposition innehaallande ett anjoniskt ytaktivt medel och en kombination av amfotaera foereningar |
TR26609A (tr) * | 1991-11-21 | 1995-03-15 | Procter & Gamble | ANYONIK SüRFAKTANLARI, POLIHIDROKSI YAGLI ASIT AMIDLERI VE ÖNEM TASIYAN BIR SEKILDE SECILEN KÖPüK ARTTIRICI MADDEYI IHTIVA EDEN DETERJAN BILESIMLER. |
GB9201519D0 (en) * | 1992-01-24 | 1992-03-11 | Unilever Plc | Detergent compositions |
DE4234487A1 (de) * | 1992-10-14 | 1994-04-21 | Henkel Kgaa | Wäßrige Detergensgemische |
KR960700332A (ko) * | 1993-01-12 | 1996-01-19 | 웨인 씨. 제쉬크 | 손 설겆이 세정제(dishwashing detergent) |
US5518647A (en) * | 1993-12-20 | 1996-05-21 | Colgate-Palmolive Company | Foaming liquid emulsion composition |
ZA951012B (en) * | 1994-02-14 | 1996-08-08 | Colgate Palmolive Co | Composition |
DE4435495C2 (de) * | 1994-10-04 | 1997-08-14 | Henkel Kgaa | Pumpfähige wäßrige Tensidkonzentrate |
DE4435387C2 (de) * | 1994-10-04 | 1997-08-14 | Henkel Kgaa | Pumpfähige wäßrige Tensidkonzentrate |
GB9509452D0 (en) * | 1995-05-10 | 1995-07-05 | Unilever Plc | Light duty cleaning composititon |
US5932535A (en) * | 1995-12-21 | 1999-08-03 | Henkel Kommanditgesellschaft Auf Aktien | Process for the production of light-colored, low-viscosity surfactant concentrates |
DE19548068C1 (de) | 1995-12-21 | 1997-06-19 | Henkel Kgaa | Verfahren zur Herstellung hellfarbiger, niedrigviskoser Tensidkonzentrate |
DE19714369A1 (de) * | 1997-04-08 | 1998-10-15 | Henkel Kgaa | Mittel für die Reinigung harter Oberflächen |
EP1003605A4 (fr) * | 1997-06-12 | 2001-04-18 | Henkel Corp | Emploi de polyglycosides d'alkyle ameliorant la stabilisation des mousses des amphoacetates |
US6673760B1 (en) * | 2000-06-29 | 2004-01-06 | Ecolab Inc. | Rinse agent composition and method for rinsing a substrate surface |
FR2826017B1 (fr) * | 2001-06-15 | 2004-06-11 | Cognis France Sa | Melanges de tensioactifs |
KR100494626B1 (ko) * | 2002-04-19 | 2005-06-13 | 주식회사 엘지생활건강 | 헹굼성이 우수한 주방용 세제 조성물 |
JP2005255708A (ja) * | 2004-03-09 | 2005-09-22 | Teepol Diversey Kk | 濃縮中性洗浄剤組成物 |
FR2913351B1 (fr) | 2007-03-08 | 2010-11-26 | Rhodia Recherches Et Tech | Utilisation d'une betaine a titre d'agent de reduction du drainage de la mousse |
DE102007032110A1 (de) * | 2007-07-09 | 2009-01-15 | Henkel Ag & Co. Kgaa | Wasch- oder Reinigungsmittel mit Tensiden auf Basis nachwachsender Rohstoffe |
JP5367243B2 (ja) * | 2007-09-13 | 2013-12-11 | ディバーシー株式会社 | 家庭用業務用兼用濃縮中性洗浄剤組成物 |
EP3146032B1 (fr) | 2014-05-21 | 2018-10-31 | Colgate-Palmolive Company | Composition aqueuse de liquide vaisselle |
WO2017209708A1 (fr) | 2016-05-30 | 2017-12-07 | Hayat Kimya San. A. Ş. | Composition non irritante pour le lavage de la vaisselle à la main |
JP7414896B2 (ja) * | 2021-07-16 | 2024-01-16 | ザ プロクター アンド ギャンブル カンパニー | 液体食器手洗い用洗浄組成物 |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0070076B2 (fr) * | 1981-07-13 | 1992-11-04 | THE PROCTER & GAMBLE COMPANY | Compositions liquides moussantes de rinçage pour la vaisselle |
JPS58132100A (ja) * | 1981-09-28 | 1983-08-06 | ザ・プロクタ−・エンド・ギヤンブル・カンパニ− | 洗剤組成物 |
US4554098A (en) | 1982-02-19 | 1985-11-19 | Colgate-Palmolive Company | Mild liquid detergent compositions |
JPS58186429A (ja) * | 1982-04-26 | 1983-10-31 | ザ・プロクタ−・エンド・ギヤンブル・カンパニ− | 起泡性界面活性剤組成物 |
JPS60197614A (ja) * | 1984-03-21 | 1985-10-07 | Shionogi & Co Ltd | 低刺激性シヤンプ−組成物 |
US4668422A (en) * | 1985-05-31 | 1987-05-26 | A. E. Staley Manufacturing Company | Liquid hand-soap or bubble bath composition |
DE3534082A1 (de) * | 1985-09-25 | 1987-04-02 | Henkel Kgaa | Fluessiges reinigungsmittel |
JP2585032B2 (ja) * | 1987-11-30 | 1997-02-26 | 株式会社資生堂 | 洗浄剤組成物 |
-
1988
- 1988-05-06 GB GB888810820A patent/GB8810820D0/en active Pending
-
1989
- 1989-05-01 CA CA000598304A patent/CA1335876C/fr not_active Expired - Fee Related
- 1989-05-02 JP JP1113612A patent/JP2664474B2/ja not_active Expired - Lifetime
- 1989-05-04 AU AU33989/89A patent/AU615740B2/en not_active Ceased
- 1989-05-05 DE DE68917195T patent/DE68917195T3/de not_active Expired - Fee Related
- 1989-05-05 ZA ZA893327A patent/ZA893327B/xx unknown
- 1989-05-05 EP EP89304522A patent/EP0341071B2/fr not_active Expired - Lifetime
- 1989-05-05 ES ES89304522T patent/ES2056215T5/es not_active Expired - Lifetime
- 1989-05-05 BR BR898902111A patent/BR8902111A/pt not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
AU615740B2 (en) | 1991-10-10 |
DE68917195T2 (de) | 1994-12-01 |
GB8810820D0 (en) | 1988-06-08 |
ES2056215T3 (es) | 1994-10-01 |
EP0341071B1 (fr) | 1994-08-03 |
CA1335876C (fr) | 1995-06-13 |
AU3398989A (en) | 1989-11-09 |
ZA893327B (en) | 1991-01-30 |
JP2664474B2 (ja) | 1997-10-15 |
DE68917195D1 (de) | 1994-09-08 |
JPH01318089A (ja) | 1989-12-22 |
DE68917195T3 (de) | 2003-04-03 |
ES2056215T5 (es) | 2003-05-01 |
EP0341071A3 (en) | 1990-07-11 |
BR8902111A (pt) | 1990-01-02 |
EP0341071A2 (fr) | 1989-11-08 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP0341071B2 (fr) | Compositions détergentes | |
US5387373A (en) | Detergent compositions | |
EP0232153B1 (fr) | Compositions détérgentes | |
US4839098A (en) | Liquid detergent | |
HU212050B (en) | Protective liquid dishwashing detergent compositions | |
AU687780B2 (en) | Dishwashing detergent | |
US5480586A (en) | Light duty liquid detergent compostion comprising a sulfosuccinamate-containing surfactant blend | |
US5578560A (en) | Water-containing detergent mixtures comprising oligoglycoside surfactants | |
EP0071411A2 (fr) | Compositions détergentes | |
AU634489B2 (en) | Light duty liquid detergent compositions | |
EP0387063B1 (fr) | Compositions détergentes | |
JP2571117B2 (ja) | 洗浄剤組成物 | |
JP2530215B2 (ja) | 洗浄剤組成物 | |
JP2582626B2 (ja) | 洗浄剤組成物 | |
JPH0699710B2 (ja) | 洗浄剤組成物 | |
JP2566821B2 (ja) | 洗浄剤組成物 | |
JP2566816B2 (ja) | 洗浄剤組成物 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
AK | Designated contracting states |
Kind code of ref document: A2 Designated state(s): CH DE ES FR GB IT LI NL SE |
|
PUAL | Search report despatched |
Free format text: ORIGINAL CODE: 0009013 |
|
AK | Designated contracting states |
Kind code of ref document: A3 Designated state(s): CH DE ES FR GB IT LI NL SE |
|
17P | Request for examination filed |
Effective date: 19900616 |
|
RAP3 | Party data changed (applicant data changed or rights of an application transferred) |
Owner name: UNILEVER PLC Owner name: UNILEVER N.V. |
|
17Q | First examination report despatched |
Effective date: 19930521 |
|
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): CH DE ES FR GB IT LI NL SE |
|
REF | Corresponds to: |
Ref document number: 68917195 Country of ref document: DE Date of ref document: 19940908 |
|
REG | Reference to a national code |
Ref country code: ES Ref legal event code: FG2A Ref document number: 2056215 Country of ref document: ES Kind code of ref document: T3 |
|
ET | Fr: translation filed | ||
ITF | It: translation for a ep patent filed |
Owner name: JACOBACCI CASETTA & PERANI S.P.A. |
|
EAL | Se: european patent in force in sweden |
Ref document number: 89304522.9 |
|
PLBI | Opposition filed |
Free format text: ORIGINAL CODE: 0009260 |
|
PLBI | Opposition filed |
Free format text: ORIGINAL CODE: 0009260 |
|
26 | Opposition filed |
Opponent name: HENKEL KOMMANDITGESELLSCHAFT AUF AKTIEN Effective date: 19950411 |
|
26 | Opposition filed |
Opponent name: HENKEL KOMMANDITGESELLSCHAFT AUF AKTIEN Effective date: 19950411 Opponent name: COLGATE-PALMOLIVE COMPANY Effective date: 19950501 |
|
NLR1 | Nl: opposition has been filed with the epo |
Opponent name: HENKEL KOMMANDITGESELLSCHAFT AUF AKTIEN Opponent name: COLGATE-PALMOLIVE COMPANY |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: CH Payment date: 19960502 Year of fee payment: 8 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: CH Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 19970531 Ref country code: LI Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 19970531 |
|
PLBQ | Unpublished change to opponent data |
Free format text: ORIGINAL CODE: EPIDOS OPPO |
|
PLAB | Opposition data, opponent's data or that of the opponent's representative modified |
Free format text: ORIGINAL CODE: 0009299OPPO |
|
R26 | Opposition filed (corrected) |
Opponent name: HENKEL KOMMANDITGESELLSCHAFT AUF AKTIEN * 950501 C Effective date: 19950411 |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: PL |
|
PLAW | Interlocutory decision in opposition |
Free format text: ORIGINAL CODE: EPIDOS IDOP |
|
NLR1 | Nl: opposition has been filed with the epo |
Opponent name: COLGATE-PALMOLIVE COMPANY Opponent name: HENKEL KOMMANDITGESELLSCHAFT AUF AKTIEN |
|
APAC | Appeal dossier modified |
Free format text: ORIGINAL CODE: EPIDOS NOAPO |
|
APAE | Appeal reference modified |
Free format text: ORIGINAL CODE: EPIDOS REFNO |
|
APAC | Appeal dossier modified |
Free format text: ORIGINAL CODE: EPIDOS NOAPO |
|
APAE | Appeal reference modified |
Free format text: ORIGINAL CODE: EPIDOS REFNO |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: SE Payment date: 20000417 Year of fee payment: 12 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: NL Payment date: 20000524 Year of fee payment: 12 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20010506 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: NL Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20011201 |
|
REG | Reference to a national code |
Ref country code: GB Ref legal event code: IF02 |
|
NLV4 | Nl: lapsed or anulled due to non-payment of the annual fee |
Effective date: 20011201 |
|
APAC | Appeal dossier modified |
Free format text: ORIGINAL CODE: EPIDOS NOAPO |
|
PLAW | Interlocutory decision in opposition |
Free format text: ORIGINAL CODE: EPIDOS IDOP |
|
PUAH | Patent maintained in amended form |
Free format text: ORIGINAL CODE: 0009272 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: PATENT MAINTAINED AS AMENDED |
|
27A | Patent maintained in amended form |
Effective date: 20021113 |
|
AK | Designated contracting states |
Kind code of ref document: B2 Designated state(s): CH DE ES FR GB IT LI NL SE |
|
ET3 | Fr: translation filed ** decision concerning opposition | ||
REG | Reference to a national code |
Ref country code: ES Ref legal event code: DC2A Date of ref document: 20030127 Kind code of ref document: T5 |
|
APAH | Appeal reference modified |
Free format text: ORIGINAL CODE: EPIDOSCREFNO |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: ES Payment date: 20070528 Year of fee payment: 19 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: DE Payment date: 20070702 Year of fee payment: 19 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: GB Payment date: 20070525 Year of fee payment: 19 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: IT Payment date: 20070526 Year of fee payment: 19 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: FR Payment date: 20070517 Year of fee payment: 19 |
|
GBPC | Gb: european patent ceased through non-payment of renewal fee |
Effective date: 20080505 |
|
REG | Reference to a national code |
Ref country code: FR Ref legal event code: ST Effective date: 20090119 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: FR Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20080602 Ref country code: DE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20081202 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: GB Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20080505 |
|
REG | Reference to a national code |
Ref country code: ES Ref legal event code: FD2A Effective date: 20080506 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20080505 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: ES Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20080506 |