EP0319836B1 - Verfahren zum Betrieb eines Einschmelzvergasers und Einschmelzvergaser zu dessen Durchführung - Google Patents
Verfahren zum Betrieb eines Einschmelzvergasers und Einschmelzvergaser zu dessen Durchführung Download PDFInfo
- Publication number
- EP0319836B1 EP0319836B1 EP88119930A EP88119930A EP0319836B1 EP 0319836 B1 EP0319836 B1 EP 0319836B1 EP 88119930 A EP88119930 A EP 88119930A EP 88119930 A EP88119930 A EP 88119930A EP 0319836 B1 EP0319836 B1 EP 0319836B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- oxygen
- inert gas
- supply
- nozzles
- flow
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title claims description 14
- 238000002844 melting Methods 0.000 title claims description 7
- 230000008018 melting Effects 0.000 title claims description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 48
- 239000001301 oxygen Substances 0.000 claims description 48
- 229910052760 oxygen Inorganic materials 0.000 claims description 48
- 239000007789 gas Substances 0.000 claims description 39
- 239000011261 inert gas Substances 0.000 claims description 25
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 24
- 229910052742 iron Inorganic materials 0.000 claims description 12
- 238000001816 cooling Methods 0.000 claims description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 7
- 229910052799 carbon Inorganic materials 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 229910000805 Pig iron Inorganic materials 0.000 claims description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 4
- 239000012530 fluid Substances 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 4
- 229910052757 nitrogen Inorganic materials 0.000 claims description 2
- 238000003723 Smelting Methods 0.000 claims 2
- 239000000945 filler Substances 0.000 claims 2
- 229910000831 Steel Inorganic materials 0.000 claims 1
- 239000007858 starting material Substances 0.000 claims 1
- 239000010959 steel Substances 0.000 claims 1
- 239000000498 cooling water Substances 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000003245 coal Substances 0.000 description 3
- 230000007257 malfunction Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 239000002826 coolant Substances 0.000 description 2
- 230000008646 thermal stress Effects 0.000 description 2
- 239000000654 additive Substances 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 235000011837 pasties Nutrition 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B13/00—Making spongy iron or liquid steel, by direct processes
- C21B13/02—Making spongy iron or liquid steel, by direct processes in shaft furnaces
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B13/00—Making spongy iron or liquid steel, by direct processes
- C21B13/0006—Making spongy iron or liquid steel, by direct processes obtaining iron or steel in a molten state
- C21B13/0013—Making spongy iron or liquid steel, by direct processes obtaining iron or steel in a molten state introduction of iron oxide into a bath of molten iron containing a carbon reductant
- C21B13/002—Reduction of iron ores by passing through a heated column of carbon
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B2100/00—Handling of exhaust gases produced during the manufacture of iron or steel
- C21B2100/40—Gas purification of exhaust gases to be recirculated or used in other metallurgical processes
- C21B2100/44—Removing particles, e.g. by scrubbing, dedusting
Definitions
- the invention relates to a method according to the preamble of claim 1 and a melter gasifier for carrying it out.
- a method for the direct production of molten pig iron from lumpy iron ore in which the iron ore is reduced to sponge iron in a reduction shaft furnace by means of a hot reducing gas and is then fed to a melter gasifier.
- the coal and injected oxygen-containing gas are used to generate the heat and the reducing gas required to melt the sponge iron.
- a fluidized bed is formed from the coal introduced from above and the oxygen-containing gas blown into the lower part of the carburetor, in which the iron sponge particles, which are also supplied above, are braked and be melted.
- radial oxygen nozzles distributed at the same height over the circumference of the melting gasifier are provided, which are fed from a ring line.
- the oxygen nozzles are inevitably water-cooled in order to be able to withstand the high temperatures which prevail inside the melter gasifier, in particular in front of these nozzles. In this area in front of the nozzles, the high temperature converts the fluidized bed into a doughy or liquid mass.
- cooling water supply for the nozzles fails, the nozzles are inevitably damaged. A failure of the cooling water supply also automatically leads to failure of the entire system, so that there is also the risk that the liquid or pasty fluid bed mass enters the nozzles and clogs them.
- the inert gas also serves as a cooling medium for the emergency cooling of the nozzles, and together with the water remaining in the nozzles, it solidifies the doughy fluid bed mass on the end faces of the nozzles, thereby additionally protecting the fluid bed mass that has not solidified will.
- the amount of inert gas required depends on the operating pressure of the melter gasifier at the time of the event triggering the introduction of the inert gas. Since a certain operating pressure can be assigned to each of these events, the amount of inert gas introduced is expediently controlled as a function of the type of event triggering the introduction.
- the iron sponge formed by reducing the iron ore passes through downpipes 3 into a melter gasifier 4, into which a solid carbon carrier, for example coal or coke, is also introduced via a line 5 and an oxygen-containing gas is blown in via nozzles 6.
- a solid carbon carrier for example coal or coke
- the rising oxygen-containing gas and the particles of the carbon carrier sinking in the opposite direction form a fluidized bed in the melting gasifier 4, which first slows down the falling iron sponge particles and in which these are then melted by the heat generated during the reaction of the carbon carrier with the oxygen.
- the molten pig iron collecting at the bottom of the melter gasifier 4 and the liquid slag floating thereon are periodically tapped by means of a tap 7.
- the gas formed in the reaction of the carbon carrier with the oxygen is led out of the melter gasifier 4 via a line 8 and cleaned in a cyclone 9, before possibly reaching the shaft furnace 1 as a reducing gas through line 2 after cooling to a suitable temperature.
- the nozzles 6 arranged at equal intervals over the circumference of the melter gasifier 4 are connected to a ring line 10, to which the oxygen-containing gas is supplied via a line 11.
- a control valve 12 and a flow rate measuring device 13 are located in this line 11. The supplied amount of oxygen-containing gas is thus measured by the measuring device 13 and adjusted using the control valve 12.
- An inert gas in particular nitrogen, can be fed into the line 11 through a line 14 which opens into the line 11.
- a control valve 15 and a flow rate measuring device 16 are also used.
- the control valve 12 for the oxygen-containing gas is automatically closed and the control valve 15 is opened for the inert gas when the flow rate determined by the measuring device 13 falls below a predetermined value, so that this now instead of the oxygen-containing gas by Nozzles 6 flows into the melter 4.
- the inert gas can simultaneously act as a cooling medium for the nozzles and protect them from damage caused by excessive thermal stress if the cooling water supply to them fails.
- the supply of the inert gas is preferably controlled as a function of time, in such a way that first the maximum amount of gas for the respective event is passed through the nozzles 6 and then a controlled throttling takes place via the control valve 15.
- the initial amount of the inert gas depends on the type of event triggering the supply of this gas or on the Operating pressure in the melter gasifier 4 at the time of this event.
- another line 17 also opens into the line 14 for the supply of inert gas, in which a control valve 18 is inserted.
- the inert gas can thus be supplied via two parallel lines, with a larger amount of gas being supplied via line 14 than via line 17.
- the control valves 15 and 18 are controlled in such a way that at the start of feeding in inert gas both Fittings are opened and after a predetermined period of time the control valve 15 is closed, so that only a relatively small amount of inert gas is supplied via line 17.
- This training has the advantage that the control valve 15 does not require continuous control, but can be designed as a simple open-close valve. This also leads to greater plant security.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Vertical, Hearth, Or Arc Furnaces (AREA)
- Manufacture Of Iron (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Fluidized-Bed Combustion And Resonant Combustion (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE3742156A DE3742156C1 (de) | 1987-12-10 | 1987-12-10 | Verfahren zum Betrieb eines Einschmelzvergasers und Einschmelzvergaser zu dessen Durchfuehrung |
DE3742156 | 1987-12-10 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0319836A1 EP0319836A1 (de) | 1989-06-14 |
EP0319836B1 true EP0319836B1 (de) | 1991-07-24 |
Family
ID=6342448
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP88119930A Expired - Lifetime EP0319836B1 (de) | 1987-12-10 | 1988-11-30 | Verfahren zum Betrieb eines Einschmelzvergasers und Einschmelzvergaser zu dessen Durchführung |
Country Status (12)
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AT395435B (de) * | 1991-02-19 | 1992-12-28 | Voest Alpine Ind Anlagen | Verfahren zur inbetriebnahme einer anlage zur herstellung von roheisen oder stahlvormaterial, sowie anlage zur durchfuehrung des verfahrens |
US5320676A (en) * | 1992-10-06 | 1994-06-14 | Bechtel Group, Inc. | Low slag iron making process with injecting coolant |
US6197088B1 (en) | 1992-10-06 | 2001-03-06 | Bechtel Group, Inc. | Producing liquid iron having a low sulfur content |
US5397376A (en) * | 1992-10-06 | 1995-03-14 | Bechtel Group, Inc. | Method of providing fuel for an iron making process |
US5354356A (en) * | 1992-10-06 | 1994-10-11 | Bechtel Group Inc. | Method of providing fuel for an iron making process |
US5958107A (en) * | 1993-12-15 | 1999-09-28 | Bechtel Croup, Inc. | Shift conversion for the preparation of reducing gas |
AT407994B (de) * | 1999-08-24 | 2001-07-25 | Voest Alpine Ind Anlagen | Verfahren zum betreiben eines einschmelzvergasers |
US8118085B2 (en) * | 2008-02-06 | 2012-02-21 | Leprino Foods Company | Heat exchanger |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3499638A (en) * | 1967-11-13 | 1970-03-10 | John E Allen | Method of cooling damaged blast furnace cooling elements |
US4047937A (en) * | 1972-12-04 | 1977-09-13 | United States Steel Corporation | Method for controlling the operation of a steel refining converter |
JPS54152615A (en) * | 1978-05-24 | 1979-12-01 | Ishikawajima Harima Heavy Ind Co Ltd | Suspended layer type direct reduction iron making process |
AT367453B (de) * | 1980-04-03 | 1982-07-12 | Voest Alpine Ag | Verfahren und vorrichtung zur herstellung von fluessigem roheisen oder stahlvormaterial |
DE3034539C2 (de) * | 1980-09-12 | 1982-07-22 | Korf-Stahl Ag, 7570 Baden-Baden | Verfahren und Vorrichtung zur direkten Erzeugung von flüssigem Roheisen aus stückigem Eisenerz |
JPS5757817A (en) * | 1980-09-19 | 1982-04-07 | Kawasaki Steel Corp | Method for controlling bottom blowing gas in steel making by composite top and bottom blown converter |
DE3318005C2 (de) * | 1983-05-18 | 1986-02-20 | Klöckner CRA Technologie GmbH, 4100 Duisburg | Verfahren zur Eisenherstellung |
-
1987
- 1987-12-10 DE DE3742156A patent/DE3742156C1/de not_active Expired
-
1988
- 1988-11-02 AU AU24598/88A patent/AU611215B2/en not_active Ceased
- 1988-11-30 EP EP88119930A patent/EP0319836B1/de not_active Expired - Lifetime
- 1988-11-30 KR KR1019880015894A patent/KR960001709B1/ko not_active Expired - Fee Related
- 1988-12-06 RU SU884356948A patent/RU1838428C/ru active
- 1988-12-06 UA UA4356948A patent/UA12803A/uk unknown
- 1988-12-06 US US07/280,596 patent/US4891062A/en not_active Expired - Lifetime
- 1988-12-07 ZA ZA889147A patent/ZA889147B/xx unknown
- 1988-12-08 DD DD88322867A patent/DD283651A5/de not_active IP Right Cessation
- 1988-12-09 CA CA000585491A patent/CA1310826C/en not_active Expired - Lifetime
- 1988-12-09 BR BR888806514A patent/BR8806514A/pt not_active IP Right Cessation
- 1988-12-09 JP JP63311795A patent/JPH01283308A/ja active Granted
Also Published As
Publication number | Publication date |
---|---|
AU611215B2 (en) | 1991-06-06 |
JPH0368081B2 (enrdf_load_html_response) | 1991-10-25 |
RU1838428C (ru) | 1993-08-30 |
ZA889147B (en) | 1989-11-29 |
BR8806514A (pt) | 1989-08-22 |
KR890010215A (ko) | 1989-08-07 |
UA12803A (uk) | 1997-02-28 |
DE3742156C1 (de) | 1988-10-13 |
EP0319836A1 (de) | 1989-06-14 |
DD283651A5 (de) | 1990-10-17 |
JPH01283308A (ja) | 1989-11-14 |
AU2459888A (en) | 1989-06-15 |
CA1310826C (en) | 1992-12-01 |
KR960001709B1 (ko) | 1996-02-03 |
US4891062A (en) | 1990-01-02 |
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