EP0277862A1 - Verfahren und Vorrichtung zur Vernichtung von festen Rückständen durch Pyrolyse - Google Patents
Verfahren und Vorrichtung zur Vernichtung von festen Rückständen durch Pyrolyse Download PDFInfo
- Publication number
- EP0277862A1 EP0277862A1 EP88400110A EP88400110A EP0277862A1 EP 0277862 A1 EP0277862 A1 EP 0277862A1 EP 88400110 A EP88400110 A EP 88400110A EP 88400110 A EP88400110 A EP 88400110A EP 0277862 A1 EP0277862 A1 EP 0277862A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- plasma
- waste
- column
- jet
- adjustable
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000197 pyrolysis Methods 0.000 title claims abstract description 18
- 239000002910 solid waste Substances 0.000 title claims abstract description 12
- 238000000034 method Methods 0.000 title claims abstract description 11
- 230000006378 damage Effects 0.000 title claims abstract description 8
- 239000002699 waste material Substances 0.000 claims abstract description 30
- 239000007789 gas Substances 0.000 claims description 24
- 239000002893 slag Substances 0.000 claims description 17
- 238000007664 blowing Methods 0.000 claims description 6
- 239000000463 material Substances 0.000 abstract description 6
- 235000010599 Verbascum thapsus Nutrition 0.000 description 33
- 238000002485 combustion reaction Methods 0.000 description 8
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 244000178289 Verbascum thapsus Species 0.000 description 2
- 239000002956 ash Substances 0.000 description 2
- 239000010882 bottom ash Substances 0.000 description 2
- 239000002803 fossil fuel Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000002906 medical waste Substances 0.000 description 2
- 235000011837 pasties Nutrition 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 235000002918 Fraxinus excelsior Nutrition 0.000 description 1
- 239000010953 base metal Substances 0.000 description 1
- 230000009194 climbing Effects 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000012809 cooling fluid Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000010891 electric arc Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 230000001717 pathogenic effect Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 125000006850 spacer group Chemical group 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000011345 viscous material Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B19/00—Heating of coke ovens by electrical means
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B49/00—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated
- C10B49/02—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with hot gases or vapours, e.g. hot gases obtained by partial combustion of the charge
Definitions
- the present invention relates to a method and a device for the destruction and treatment of solid waste, in particular waste of hospital and / or industrial origin.
- a pyrolysis oven is used for this purpose, which is generally in the form of a vertical cylinder (or several truncated cones).
- the waste is placed in the upper part and is heated and pyrolyzed, as it descends into the oven, by hot gases, originating from pyrolysis, which circulate against the current, that is to say climbing.
- the hot air wind is blown at the bottom of the oven. It provides part of the heat energy necessary for operation and the oxygen ensuring the combustion of part of the waste, thus producing additional heat energy.
- the object of the present invention is to remedy the drawbacks of known pyrolysis ovens. It makes it possible to solve the problem of unburnt materials contained in the residues originating from the destruction of solid waste and to improve the flow of these molten residues.
- the process for the destruction of solid waste by pyrolysis according to which a column of such waste is traversed at least partially, from bottom to top, by a hot gas stream blown at the base of said column , is remarkable in that said hot gas stream is generated by at least one plasma jet, and preferably by a plurality of plasma jets distributed at the periphery of said column of waste, in the vicinity of the base thereof.
- the hot gas blown at the base of the pyrolysis oven and passing through the waste column is no longer air, but a gas produced by one or more plasma generators (torches), which makes it possible to control the temperature molten residue.
- the plasma jet is preferably directed to the base of the waste column, where it enters the molten slag bath. It thus completes the fusion of the waste which has undergone pyrolysis and it increases the temperature of the slag, thus giving it the fluidity required for good flow.
- each plasma jet is inclined, from top to bottom, with respect to the horizontal, towards the base of said column.
- each plasma jet in order to allow greater efficiency and greater freedom in the choice of the point of impact of the darts of the plasma torches on the base of the waste column, provision is made for the direction of each plasma jet to be inclined relative to to the direction of the corresponding radius of the waste column and that this direction is adjustable.
- Any suitable plasma gas can be used.
- a device for the destruction of solid waste by pyrolysis comprising a vertical wall in which is guided a column of such waste, means for blowing a hot gas jet arranged at the lower part of said wall and means for the evacuation of hot gases arranged in the upper part of said wall, this device being remarkable in that said means for blowing hot gaseous jet consist of at least one plasma generator.
- said gas jet blowing means are constituted by a plurality of plasma generators distributed at the periphery of said lower part of said wall.
- said plasma generators are adjustable in orientation around a horizontal axis and / or around a vertical axis.
- said plasma generators are preferably individually adjustable.
- said device comprises a pouring orifice for molten slag provided in the bottom of said device, there is at least one of said plasma generators at least substantially perpendicular to said pouring orifice.
- the plasma jet participates, on the one hand, in the vertical stability of the charge and, on the other hand, in the clearance of the pouring orifice (thus avoiding the passage of non-pyrolyzed material).
- the pyrolysis oven according to the invention and shown in Figures 1 and 2, comprises a refractory crucible 1, surmounted by a vertical envelope in two parts 2 and 3, the upper part 3 of said envelope being itself surmounted through a hopper 4.
- an airlock 5 is provided, delimited between an upper register 6 and a lower register 7.
- a pipe 8 for the evacuation of the gases is provided at the junction of the two envelope parts 2 and 3.
- Plasma torches 9 are arranged at the periphery of the crucible 1 and directed towards the interior thereof.
- the waste to be destroyed is loaded into the oven through the hopper 4 and passes through the airlock 5, which seals with the outside.
- the upper part 3 of the envelope the cross section of which advantageously goes downwards in order to avoid jams, guides the waste column 10 in its descent by gravity.
- the upper part 10a of the waste column contained in the upper part 3 of the envelope (under the register 7) protects the airlock from direct contact of the gases leaving the oven through the pipe 8.
- the combustion of these gases in a post-combustion, their cooling and their treatment are not described below, because outside the scope of the present invention.
- the lower part 2 of the envelope advantageously cooled by a water jacket 11, guides the downward descent of the middle part 10b of the waste column 10.
- the section of the envelope 2 also increases in a downward direction in order to avoid jams.
- the waste contained in this zone 10b is gradually dried, decomposed and pyrolyzed by the hot gases which come from the lower part of the oven.
- the crucible 1 constituting the base of the furnace, is entirely coated with refractory elements resistant to very high temperatures.
- the waste enters there through the upper part and comes to rest on the bottom 12 in the slag 13.
- the liquid slag 13 flows through an orifice 15 passing through the bottom 12 of the crucible 1, falls into a well 16 and cools in a tank 17 filled with water.
- the point of impact 14 of the plasma jets of the torches 9 on the base 10c of the waste column 10 can be adjusted by adjusting the angle a of the torches 9 with the horizontal. If we decrease a , point 14 moves to the still solid waste; on the other hand, if the angle a increases, the point 14 moves towards the slag 13.
- angles a may be different for each torch 9, thus making it possible to distribute the energy supplied horizontally as well as possible, which promotes stirring movements.
- One of the torches 9 is advantageously in the vertical plane of the taphole 15 so as to release the latter.
- the torches 9 are not directed towards the axis 18 of the crucible 1, but form with the corresponding radius 20 an angle b which can be adjusted according to the intended application and even vary in order to give a rotational movement to the molten slag and thus homogenize its temperature.
- the torches 9 are supplied with electric current and with plasmogenic gas in a known manner and not shown. Under the effect of the stabilized electric arc in the torches, the gas is transformed into plasma (for example between 3000 ° C and 7000 ° C) and constitutes a dart 19 at very high temperature.
- the temperature in the crucible is increased and therefore the temperature of the slag which thus becomes more fluid.
- Part of the thermal energy is brought to the system by the enthalpy of the plasma.
- the other part is provided by the combustion of a fraction of the waste in contact with the oxygen brought in by the plasma; by increasing the flow of gas supplied to the torches, the quantity of waste oxidized by the oxygen in the plasma is increased, therefore the thermal energy released by the combustion of the waste is increased. It is then possible to use in return the corresponding energy of the plasma to raise the temperature of the slag, for example by increasing the angle a .
- FIG 3 there is shown the adjustable mounting of a torch 9.
- said adjustable mounting is of the ball joint type.
- each torch 9 is secured to a frame 25, by means of fixing means 26.
- the nozzle 27 of said torch 9 passes through the frame 25 and an internal seal 28 ensures the seal between the latter and said nozzle.
- the mount 25, by means of a seal 29, can rotate in a spherical bearing 30 in order to pivot around a center of rotation 31.
- the spherical bearing 30 is formed in a flange 32, for example hollow to form a channel 33 for circulation of a cooling fluid, which is fixed to the periphery of an orifice 34, passing through the side wall 35 of the crucible 1.
- a rear support 36 secured to the flange 32 by spacers 37, has a spherical bearing surface 38 in contact with a stud 39, integral with the rear of the torch 9 and provided with a spherical end capable of sliding on the bearing surface 38.
- Elastic means 40 provided between the frame 25 and the torch 9 allow to apply the seal 29 against the spherical bearing 30 and the stud 39 against the spherical bearing 38.
- the seals 28 and 29 are for example made of copper or stainless steel.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Gasification And Melting Of Waste (AREA)
- Processing Of Solid Wastes (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR8700726A FR2610087B1 (fr) | 1987-01-22 | 1987-01-22 | Procede et dispositif pour la destruction de dechets solides par pyrolyse |
FR8700726 | 1987-01-22 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0277862A1 true EP0277862A1 (de) | 1988-08-10 |
EP0277862B1 EP0277862B1 (de) | 1991-12-04 |
Family
ID=9347162
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP88400110A Expired - Lifetime EP0277862B1 (de) | 1987-01-22 | 1988-01-19 | Verfahren und Vorrichtung zur Vernichtung von festen Rückständen durch Pyrolyse |
Country Status (7)
Country | Link |
---|---|
US (1) | US4831944A (de) |
EP (1) | EP0277862B1 (de) |
JP (1) | JPH0743104B2 (de) |
CA (1) | CA1297345C (de) |
DE (1) | DE3866551D1 (de) |
ES (1) | ES2027769T3 (de) |
FR (1) | FR2610087B1 (de) |
Cited By (4)
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GB2287471A (en) * | 1994-03-17 | 1995-09-20 | Wrc Plc | Aqueous sludge treatment |
DE20120189U1 (de) * | 2001-12-14 | 2003-04-24 | Umweltkontor Renewable Energy AG, 04158 Leipzig | Gleichstrom-Schacht-Reaktor |
EP2262872A1 (de) * | 2008-04-10 | 2010-12-22 | The Crucible Group Pty Ltd | Verarbeitung von organischen materialien |
US9708540B2 (en) | 2008-04-10 | 2017-07-18 | The Crucible Group Pty Ltd | Processing organic materials |
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FR2630529B1 (fr) * | 1988-04-22 | 1990-08-10 | Aerospatiale | Procede et dispositif pour la destruction de dechets chimiquement stables |
DE3922383C2 (de) * | 1988-08-11 | 1994-06-09 | Grimma Masch Anlagen Gmbh | Verfahren zur Vernichtung toxischer Abprodukte und Vorrichtung zur Durchführung des Verfahrens |
US4998486A (en) * | 1989-04-27 | 1991-03-12 | Westinghouse Electric Corp. | Process and apparatus for treatment of excavated landfill material in a plasma fired cupola |
CA2036581C (en) * | 1990-02-23 | 1998-09-22 | Gunter H. Kiss | Method of transporting, intermediate storage and energetic and material utilization of waste goods of all kinds and device for implementing said method |
US5158449A (en) * | 1991-01-08 | 1992-10-27 | Institute Of Gas Technology | Thermal ash agglomeration process |
US5143000A (en) * | 1991-05-13 | 1992-09-01 | Plasma Energy Corporation | Refuse converting apparatus using a plasma torch |
US5090340A (en) * | 1991-08-02 | 1992-02-25 | Burgess Donald A | Plasma disintegration for waste material |
US5279234A (en) * | 1992-10-05 | 1994-01-18 | Chiptec Wood Energy Systems | Controlled clean-emission biomass gasification heating system/method |
US5534659A (en) * | 1994-04-18 | 1996-07-09 | Plasma Energy Applied Technology Incorporated | Apparatus and method for treating hazardous waste |
US5611947A (en) * | 1994-09-07 | 1997-03-18 | Alliant Techsystems, Inc. | Induction steam plasma torch for generating a steam plasma for treating a feed slurry |
US5653183A (en) * | 1994-09-22 | 1997-08-05 | Balboa Pacific Corporation | Pyrolytic waste treatment system |
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US6355904B1 (en) | 1996-06-07 | 2002-03-12 | Science Applications International Corporation | Method and system for high-temperature waste treatment |
US5902915A (en) * | 1997-03-20 | 1999-05-11 | Lawrence Plasma Research Laboratory Inc. | Process for producing liquid hydrocarbons |
DE19735153C2 (de) * | 1997-08-13 | 2003-10-16 | Linde Kca Dresden Gmbh | Verfahren und Vorrichtung zur Vergasung von Abfallstoffen |
IT1313272B1 (it) * | 1999-07-29 | 2002-07-17 | Rgr Ambiente Reattori Gassific | Procedimento e dispositivo per la pirolisi e gassificazione di rifiuti |
DE10007115C2 (de) * | 2000-02-17 | 2002-06-27 | Masch Und Stahlbau Gmbh Rolan | Verfahren und Reaktor zum Vergasen und Schmelzen von Einsatzstoffen mit absteigender Gasführung |
US6617538B1 (en) | 2000-03-31 | 2003-09-09 | Imad Mahawili | Rotating arc plasma jet and method of use for chemical synthesis and chemical by-products abatements |
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Citations (5)
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US3841239A (en) * | 1972-06-17 | 1974-10-15 | Shin Meiwa Ind Co Ltd | Method and apparatus for thermally decomposing refuse |
US3894573A (en) * | 1972-06-05 | 1975-07-15 | Paton Boris E | Installation and method for plasma arc remelting of metal |
EP0105866A1 (de) * | 1982-10-05 | 1984-04-18 | VOEST-ALPINE Aktiengesellschaft | Plasmaschmelzofen |
EP0112325A2 (de) * | 1982-12-22 | 1984-06-27 | VOEST-ALPINE Aktiengesellschaft | Anlage zur Erzeugung von Calciumcarbid |
GB2213815A (en) * | 1987-12-17 | 1989-08-23 | Takeda Chemical Industries Ltd | Process for producing nucleosides |
Family Cites Families (6)
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JPS5139646A (ja) * | 1974-09-27 | 1976-04-02 | Kojin Kk | 22shikuropentenn11onruino seizohoho |
JPS51132669A (en) * | 1975-05-13 | 1976-11-17 | Nippon Kokan Kk <Nkk> | Method for dry distillation of garbage |
JPS5664699A (en) * | 1979-11-01 | 1981-06-01 | Daido Steel Co Ltd | Oven for melting radioactive material*etc* |
JPS58800A (ja) * | 1981-06-25 | 1983-01-05 | 大同特殊鋼株式会社 | 放射性廃棄物の処理炉 |
SE451033B (sv) * | 1982-01-18 | 1987-08-24 | Skf Steel Eng Ab | Sett och anordning for omvandling av avfallsmaterial med plasmagenerator |
DE3611429A1 (de) * | 1985-02-15 | 1986-11-06 | SKF Steel Engineering AB, Hofors | Verfahren zur abfallzersetzung |
-
1987
- 1987-01-22 FR FR8700726A patent/FR2610087B1/fr not_active Expired
-
1988
- 1988-01-14 JP JP63005021A patent/JPH0743104B2/ja not_active Expired - Fee Related
- 1988-01-19 DE DE8888400110T patent/DE3866551D1/de not_active Expired - Lifetime
- 1988-01-19 ES ES198888400110T patent/ES2027769T3/es not_active Expired - Lifetime
- 1988-01-19 EP EP88400110A patent/EP0277862B1/de not_active Expired - Lifetime
- 1988-01-22 US US07/147,205 patent/US4831944A/en not_active Expired - Lifetime
- 1988-01-22 CA CA000557212A patent/CA1297345C/fr not_active Expired - Lifetime
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3894573A (en) * | 1972-06-05 | 1975-07-15 | Paton Boris E | Installation and method for plasma arc remelting of metal |
US3841239A (en) * | 1972-06-17 | 1974-10-15 | Shin Meiwa Ind Co Ltd | Method and apparatus for thermally decomposing refuse |
EP0105866A1 (de) * | 1982-10-05 | 1984-04-18 | VOEST-ALPINE Aktiengesellschaft | Plasmaschmelzofen |
EP0112325A2 (de) * | 1982-12-22 | 1984-06-27 | VOEST-ALPINE Aktiengesellschaft | Anlage zur Erzeugung von Calciumcarbid |
GB2213815A (en) * | 1987-12-17 | 1989-08-23 | Takeda Chemical Industries Ltd | Process for producing nucleosides |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2287471A (en) * | 1994-03-17 | 1995-09-20 | Wrc Plc | Aqueous sludge treatment |
GB2287471B (en) * | 1994-03-17 | 1997-11-26 | Wrc Plc | Aqueous sludge treatment |
DE20120189U1 (de) * | 2001-12-14 | 2003-04-24 | Umweltkontor Renewable Energy AG, 04158 Leipzig | Gleichstrom-Schacht-Reaktor |
EP2262872A1 (de) * | 2008-04-10 | 2010-12-22 | The Crucible Group Pty Ltd | Verarbeitung von organischen materialien |
EP2262872A4 (de) * | 2008-04-10 | 2011-10-12 | Crucible Group Pty Ltd | Verarbeitung von organischen materialien |
US8888962B2 (en) | 2008-04-10 | 2014-11-18 | The Crucible Group Pty Ltd | Processing organic materials |
US9708540B2 (en) | 2008-04-10 | 2017-07-18 | The Crucible Group Pty Ltd | Processing organic materials |
Also Published As
Publication number | Publication date |
---|---|
US4831944A (en) | 1989-05-23 |
DE3866551D1 (de) | 1992-01-16 |
ES2027769T3 (es) | 1992-06-16 |
JPH0743104B2 (ja) | 1995-05-15 |
FR2610087A1 (fr) | 1988-07-29 |
EP0277862B1 (de) | 1991-12-04 |
FR2610087B1 (fr) | 1989-11-24 |
JPS63183307A (ja) | 1988-07-28 |
CA1297345C (fr) | 1992-03-17 |
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