EP0263785B1 - A flexible abrasive coated article and method of making it - Google Patents
A flexible abrasive coated article and method of making it Download PDFInfo
- Publication number
- EP0263785B1 EP0263785B1 EP87810529A EP87810529A EP0263785B1 EP 0263785 B1 EP0263785 B1 EP 0263785B1 EP 87810529 A EP87810529 A EP 87810529A EP 87810529 A EP87810529 A EP 87810529A EP 0263785 B1 EP0263785 B1 EP 0263785B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- fabric
- metal
- flexible
- conductive
- abrasive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000004519 manufacturing process Methods 0.000 title description 2
- 239000004744 fabric Substances 0.000 claims description 98
- 229910052751 metal Inorganic materials 0.000 claims description 62
- 239000002184 metal Substances 0.000 claims description 62
- 238000000034 method Methods 0.000 claims description 43
- 239000000463 material Substances 0.000 claims description 30
- 239000011248 coating agent Substances 0.000 claims description 27
- 238000000576 coating method Methods 0.000 claims description 27
- 239000003082 abrasive agent Substances 0.000 claims description 17
- 238000004070 electrodeposition Methods 0.000 claims description 13
- 239000002245 particle Substances 0.000 claims description 11
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 9
- 239000004800 polyvinyl chloride Substances 0.000 claims description 9
- 239000011888 foil Substances 0.000 claims description 8
- 239000002952 polymeric resin Substances 0.000 claims description 8
- 229920003235 aromatic polyamide Polymers 0.000 claims description 5
- 238000000151 deposition Methods 0.000 claims description 5
- 229920005570 flexible polymer Polymers 0.000 claims description 4
- 229920003002 synthetic resin Polymers 0.000 claims description 4
- 239000004020 conductor Substances 0.000 claims description 3
- 229920005989 resin Polymers 0.000 claims description 3
- 239000011347 resin Substances 0.000 claims description 3
- 238000001465 metallisation Methods 0.000 claims description 2
- 239000002759 woven fabric Substances 0.000 claims 2
- 239000004760 aramid Substances 0.000 claims 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 56
- 229910052759 nickel Inorganic materials 0.000 description 28
- 239000004761 kevlar Substances 0.000 description 20
- 229920000271 Kevlar® Polymers 0.000 description 18
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 15
- 229910052802 copper Inorganic materials 0.000 description 14
- 239000010949 copper Substances 0.000 description 14
- 239000000853 adhesive Substances 0.000 description 10
- 230000001070 adhesive effect Effects 0.000 description 10
- 229910003460 diamond Inorganic materials 0.000 description 8
- 239000010432 diamond Substances 0.000 description 8
- 229910001220 stainless steel Inorganic materials 0.000 description 6
- 239000010935 stainless steel Substances 0.000 description 6
- 238000010276 construction Methods 0.000 description 5
- 229920003023 plastic Polymers 0.000 description 5
- 239000004033 plastic Substances 0.000 description 5
- 239000007921 spray Substances 0.000 description 5
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Natural products CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 4
- 238000003475 lamination Methods 0.000 description 4
- KERTUBUCQCSNJU-UHFFFAOYSA-L nickel(2+);disulfamate Chemical compound [Ni+2].NS([O-])(=O)=O.NS([O-])(=O)=O KERTUBUCQCSNJU-UHFFFAOYSA-L 0.000 description 4
- 229920001225 polyester resin Polymers 0.000 description 4
- 229920001296 polysiloxane Polymers 0.000 description 4
- 230000008021 deposition Effects 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 230000005855 radiation Effects 0.000 description 3
- WRDNCFQZLUCIRH-UHFFFAOYSA-N 4-(7-azabicyclo[2.2.1]hepta-1,3,5-triene-7-carbonyl)benzamide Chemical compound C1=CC(C(=O)N)=CC=C1C(=O)N1C2=CC=C1C=C2 WRDNCFQZLUCIRH-UHFFFAOYSA-N 0.000 description 2
- 239000005041 Mylar™ Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 238000010030 laminating Methods 0.000 description 2
- 239000011140 metalized polyester Substances 0.000 description 2
- 230000035515 penetration Effects 0.000 description 2
- -1 poly(phenylene) Polymers 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 239000004645 polyester resin Substances 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 229910052582 BN Inorganic materials 0.000 description 1
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 229920001944 Plastisol Polymers 0.000 description 1
- 229920000265 Polyparaphenylene Polymers 0.000 description 1
- 229920004933 Terylene® Polymers 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000001464 adherent effect Effects 0.000 description 1
- 238000003486 chemical etching Methods 0.000 description 1
- 239000011362 coarse particle Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000005137 deposition process Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000002659 electrodeposit Substances 0.000 description 1
- 238000007772 electroless plating Methods 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- QFXZANXYUCUTQH-UHFFFAOYSA-N ethynol Chemical group OC#C QFXZANXYUCUTQH-UHFFFAOYSA-N 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000009499 grossing Methods 0.000 description 1
- 239000002648 laminated material Substances 0.000 description 1
- 230000000873 masking effect Effects 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 239000011236 particulate material Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 229920002120 photoresistant polymer Polymers 0.000 description 1
- 239000004999 plastisol Substances 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 239000004588 polyurethane sealant Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- MHSKRLJMQQNJNC-UHFFFAOYSA-N terephthalamide Chemical compound NC(=O)C1=CC=C(C(N)=O)C=C1 MHSKRLJMQQNJNC-UHFFFAOYSA-N 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 238000007514 turning Methods 0.000 description 1
- 238000001771 vacuum deposition Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D15/00—Electrolytic or electrophoretic production of coatings containing embedded materials, e.g. particles, whiskers, wires
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
- B24D11/00—Constructional features of flexible abrasive materials; Special features in the manufacture of such materials
- B24D11/001—Manufacture of flexible abrasive materials
- B24D11/005—Making abrasive webs
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
- B24D11/00—Constructional features of flexible abrasive materials; Special features in the manufacture of such materials
- B24D11/06—Connecting the ends of materials, e.g. for making abrasive belts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
- B24D18/00—Manufacture of grinding tools or other grinding devices, e.g. wheels, not otherwise provided for
- B24D18/0018—Manufacture of grinding tools or other grinding devices, e.g. wheels, not otherwise provided for by electrolytic deposition
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
- B24D3/00—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents
- B24D3/001—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as supporting member
- B24D3/002—Flexible supporting members, e.g. paper, woven, plastic materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
- B24D3/00—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents
- B24D3/02—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent
- B24D3/04—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent and being essentially inorganic
- B24D3/06—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent and being essentially inorganic metallic or mixture of metals with ceramic materials, e.g. hard metals, "cermets", cements
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
- B24D3/00—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents
- B24D3/34—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents characterised by additives enhancing special physical properties, e.g. wear resistance, electric conductivity, self-cleaning properties
Definitions
- the present invention relates to abrasive members and in particular to flexible abrasive members incorporating abrasive particles.
- Such abrasive members are useful in grinding, smoothing and other operations on glass, stone, or other materials, and in particular for use as industrial abrasives as a longer-lasting alternative to conventional sanding products.
- U.S. Patent No. 4,256,467 issued August 17, 1981 to Ian Gorsuch discloses a flexible abrasive member comprising a flexible non-electrically conductive mesh material and a layer of electrodeposited metal adhering directly to and extending through the mesh material so that the mesh material is embedded in the metal layer. Abrasive material is embedded in the metal layer.
- the flexible abrasive member is manufactured by first laying a length of flexible non-electrically mesh material onto a conductive surface so that the mesh material is in immovable relationship with the conductive surface. A layer of metal is then electrodeposited onto the smooth surface through the mesh material in the presence of abrasive material so that the abrasive material becomes embedded in the metal layer and the metal layer adheres to the mesh. Finally, the mesh and the associated metal layer with the embedded abrasive material are stripped from the electrically conductive surface to constitute the abrasive member.
- the electrically conductive smooth surface is formed by a cylinder of stainless steel.
- the mesh material is attached under tension to the surface of the cylinder.
- the cylinder is prepared by a relatively complex procedure, which involves applying an electrically insulating acid photo resist to the stainless steel cylinder in the desired pattern to form a stencil.
- An object of the invention is to alleviate the aforementioned problem of the prior art.
- a method of forming a flexible abrasive member comprising providing a length of flexible fabric, applying a flexible mask of non-electrically conductive material having a multitude of discrete openings therein to one surface of said flexible fabric, placing the fabric with the mask applied thereto in a metal deposition bath, and depositing metal directly in said discrete openings onto said flexible fabric in the presence of particulate abrasive material such that the metal adheres directly to the fabric to form metal deposits in said openings and the abrasive material becomes embedded in the metal deposits.
- the deposition preferably takes place by electrodeposition and the discrete openings are preferably arranged in the form of a lattice.
- the fabric may be in the form of a mesh.
- the stainless steel cylinder may be eliminated when an electrically conductive flexible mesh is used, or if a cylinder is required, in the case of a non-electrically conductive flexible mesh, the cylinder can be of simple construction, e.g. a stainless steel cylinder coated with electrically conductive material, such as wax, to which the electrodeposited metal does not stick.
- the electrically conductive cylinder is not required and the method can be operated on a continuous basis to produce a flexible abrasive member at a much higher rate and much lower cost than in the process according to the U.S. Patent.
- the length of flexible mesh material is in the form of a wire mesh, e.g. a fine wire mesh, or metallized polyester resin mesh supplied under the trademark metalin MP E260 by B and SH Thompson Co. Ltd.
- the length of the flexible material may also be a flexible polymer resin mesh, such a polyester resin mesh, laminated on the side remote from the mask to a metal foil.
- the metal foil can be easily removed after electrodeposition.
- the mask By first forming the mask on the electrically conductive mesh material rather than on the electrically conductive surface, i.e. the surface of a cylinder, it is possible to operate the process by continuously passing the laminate through an electrodeposition bath, e.g. an electrolytic bath, where the length of flexible mesh material forms the cathode and metal to be deposited forms the anode.
- an electrodeposition bath e.g. an electrolytic bath
- the length of flexible mesh material is a non-electrically conducting flexible polymer resin mesh, such as a polyester resin mesh e.g. that supplied under the trademark Monotex by B and SH Thompson Co. Ltd., and which in the process is in immovable contact with a curved electrically conducting member treated to prevent adhesion of electrodeposited metal thereto.
- the electrically conducting member may be a cylinder to which the non-electrically conducting flexible polymer resin mesh is applied under tension.
- the cylinder may be formed of stainless steel or other electrically conductive metal having a smooth surface which may be coated with wax.
- the non-conducting flexible mesh may be, for example, formed of nylon or terylene.
- the mask is in the form of a very thin sheet, suitably a few thousandths, e.g. 3-4 thousandths of an inch (0,076-0,102 mm) thick, of a polymer resin, such as polyvinyl chloride.
- a polymer resin such as polyvinyl chloride.
- Such a mask defines a lattice with a large number of openings of, for example of 1/16 ⁇ (1,588 mm) diameter. Lamination takes place under heat and pressure.
- the abrasive material is a conventional abrasive such as diamond or cubic boron nitride, and in particular industrial diamond.
- the metal can be any metal which can be deposited from a suitable bath by electrodepositing or electroless plating, and is preferably nickel or copper, more preferably nickel.
- the length of electrically conductive flexible mesh material is continuously passed through an electrolytic bath to form a cathode, the anodes of which are formed by said metal, whereby the metal is continuously deposited in the discrete openings and the particulate abrasive during said electrodeposition is released into said bath.
- the length of flexible mesh material is present in the bath as a cathode, it is connected to a source of negative potential.
- the mesh material is preferably in contact with a smooth non-conductive surface, such as a plastic surface in the bath, which is suitably a nickel sulfamate bath.
- the fabric When the fabric is in the form of a mesh, it is generally laminated onto a backing fabric for strength.
- An abrasive member reinforced in this way can be made into a sanding belt and similar abrasive articles.
- the backing fabric comprises a woven polyaramid fabric.
- the invention also provides a flexible abrasive member comprising a length of flexible fabric having applied to one surface thereof an electrically non-conductive mask layer having a multitude of discrete openings therein, and deposited metal adhering to said fabric in each of the openings, said deposited metal having particulate abrasive material embedded therein.
- the fabric is made of poly-p-phenyleneterephthalamide.
- a laminated abrasive member of this construction has been shown to have remarkable properties of longevity and strength. Such a member can even be used to cut edge on into glass, particularly if the backing material is coated on its underside with polyurethane adhesive.
- the flexible fabric can also be rendered at least partially conductive, with the metal being deposited directly on the fabric, using the conductive portion as an electrode, particulate abrasive material being embedded in the metal deposits during the formation thereof.
- a backing fabric can be coated with a vaporized metal such that the vaporized metal becomes firmly attached to the fabric to provide a conductive coating, the conductive coating masked to expose only the discrete locations, and the metal deposited on the coating at the discrete locations, using said coating as an electrode, in the presence of abrasive particles such that said particles become embedded therein.
- the above described method permits the complete elimination of the lamination stage and the fabrication of an abrasive belt directly onto the backing fabric.
- the backing fabric is preferably made of polyaramid yarn, such as p-poly(phenylene) terephthalamide and sold by Dupont under the trademark Kevlar.
- the fabric is preferably made of scoured 1500 denier yarn having a balanced weave.
- a laminate 20 comprising an electrically conductive flexible mesh material 21, such as a fine wire mesh material or a metallized polyester resin mesh supplied under the trademark METALIN MPE 260, and a polyvinyl chloride resin mask 22 having lattice of discrete openings distributed uniformly therein, is passed over idler roll 2 and between idler rolls 3 in a electrolytic nickel bath 4.
- the laminate 20 passes over the smooth non-electrically conductive upper surface of a plastic plate 5 and then out of the bath over idler rolls 6 and 7.
- the idler roll 2 is maintained at negative potential from an external source and thus makes the flexible laminate 20 passing over the smooth plastic plate 5 the cathode.
- the passage of the laminate 20 across the smooth member 5 is such that the mask 22 is uppermost.
- the plastic plate can also be in the form of a drum, with the laminate extending around part of its periphery.
- the electrolytic bath 4 is also provided with a plurality of titanium baskets 8 containing nickel turnings.
- the baskets are connected from an external source to a positive potential and thus form anodes.
- electrodeposition of nickel occurs in the discrete openings of the mask 22, forming in the openings deposits of nickel which intimately adhere to the mesh 21.
- particles of abrasive material 9 are shaken into the bath 4 from a shaker device 10 and become embedded in the metal deposits to form pellets 23 containing the abrasive.
- the laminate 20 is passed under idler roller 11 into a washing bath 12 where it is rinsed with water and passed to a collecting roll 13 for the continuous flexible abrasive member.
- the electrolytic bath is a commercial nickel sulfamate bath supplied under the trademark SNR 24 by Hanson Inc., operated at a 170 amps and 9 volts d.c. and at a temperature of 140° (60°C).
- the laminate is passed through the bath at the rate of 2 inches/minute.
- the laminate consists of a fine nickel or stainless steel silk screen mesh supplied under the trademark METALIN MPE 260 by B. & S.E. Thompson and Co. Ltd.
- the mask is made of polyvinyl chloride and has symmetrically disposed therein a lattice of a large number of openings (90/square inch (90/6,45 cm2) of about 1/16 ⁇ (1,588 mm) in diameter.
- the mask has a thickness of 3/4 thousandths of an inch (0,019 mm) and is laminated to the mesh from silicone release paper under heat and pressure at 350°F (176,7°C) and 85 psi (586,1 h Pa).
- the flexible abrasive member taken from the roll 13 is suitable for use. It may be bonded to a heavy polyester cloth suitably supplied by Carborundum under the trademark NRE 5206. For its use as an abrasive the member may be attached to various substrates.
- the sanding belt comprises a flexible fine conductive mesh 31, for example a mesh supplied under the trade mark METALIN MP E260 by B & S.H. Thompson Co., Ltd., bearing a multitude of discrete island nickel deposits 32 in which the mesh 31 is embedded.
- the deposits 32 are formed by electrodeposition according to the process described above.
- Abrasive particulate material 33 for example diamond particles, is embedded in the nickel deposits 32 during the electrodeposition process.
- the mesh 31 be conductive, it is possible to employ a non-conductive mesh, with a mask applied thereto, in which the mesh should be placed on a conductive surface. If a conductive mesh is employed, the mesh has a polyvinyl chloride mask 34 defining the openings through which the electrodeposits are formed on its top surface.
- the mesh 31 is laminated onto a backing fabric 35 of 1500 denier Kevlar fabric (a trade mark for a yarn made from poly-p-phenyleneterephthalamide). This fabric is used for such applications as bullet proof vest and is sold by Barrday Inc. of Cambridge, Ontario under the trade designation 2160/175 F SC.
- the fabric Prior to lamination, the fabric is coated on both sides with a polyurethane sealant adhesive, such as Bostik 7070 TM . Once the adhesive has dried, the mesh 31 bearing the metal deposits 32 is laminated onto the coated fabric with the same adhesive, preferably under heat and pressure.
- a polyurethane sealant adhesive such as Bostik 7070 TM .
- the laminated material is cut into strips and the ends cut in a interlocking wavy fashion as shown at 36 in Figure 2.
- the two ends are joined together by means of a Mylar TM strip 37 applied by means of the same Bostik 7070 adhesive.
- Such a sanding belt has remarkable longevity and strength properties. It will last many times longer than a conventional sanding belt.
- the flexible mesh 31 may be desirable to laminate on both sides of the fabric 35.
- This sandwich construction is so strong that it can surprisingly cut edgewise into glass.
- the central fabric can be made quite rigid if the abrasive member is used as a cutting tool in this manner.
- the composite abrasive member including the flexible mesh 31 bearing the nickel deposits 32 and the backing fabric 35, possibly with a flexible mesh 31 on both surfaces, can be conveniently formed into other articles, such as abrasive disks, pads and the like.
- the abrasive member is formed directly onto the backing fabric, which is used as a substrate.
- the backing fabric 38 is made of 1500 denier Kevlar TM fabric of the same trade designation as the fabric referred to above.
- a metal foil 39 is laminated onto the Kevlar fabric 38 with a polyurethane adhesive, such as Bostik 7070 TM .
- a polyvinyl chloride mask 40 with a multitude of small openings forming a lattice is then laminated onto the metal foil 39.
- Nickel deposits 41 are then electrodeposited through the openings onto the metal foil, with the particulate diamond abrasive material being embedded in the nickel deposits.
- the polyvinyl chloride mask 40 can also be replaced by a second layer of a Kevlar fabric defining the openings, with which the backing material 38 and film 39 forms a strong sandwich construction.
- the metal foil 39 can be laminated on the underside of the backing fabric 38, which may have a looser weave to allow the fabric yarns to become embedded in the nickel deposits.
- the metal foil 39 can be replaced by a layer of metal that is deposited by vapour deposition onto either the front or rear surface of the backing fabric 38.
- the metal layer is formed onto a Mylar TM supporting sheet.
- the backing fabric 42 comprises a fabric woven from yarns 43 of the same 1500 denier Kevlar TM and conductive yarns, preferably wires, 44 shown by broken lines.
- the conductive yarns are interwoven in both the warp and weft directions every seven threads.
- the conductive yarns can be woven in the fabric in only one direction and can be woven in different groupings.
- the non-conductive and conductive yarns could alternate or the conductive yarns can be arranged in groups of two or more.
- the whole fabric can then be placed in a commercial nickel sulfamate bath, for example the bath described above.
- the conductive wires are made the cathode and nickel deposits form around the conductive wires and adjacent non-conductive yarns where the former are exposed.
- Particulate diamond abrasive can be sprinkled into the bath and embedded in the forming nickel deposits in the same manner as described above.
- the partially conductive fabric described in Figure 6 enables the abrasive member to be formed directly onto the backing material without the need for the intermediate lamination step.
- the fabric is preferably made of Kevlar yarn, other yarns, such as polyester can be employed for certain applications.
- the wires 44 can have a non-conductive coating.
- the wires are generally woven closer together, for example alternating with the non-conductive yarns.
- the non-conductive coating can be removed by chemical etching or radiation, for example, with infrared radiation.
- chemical etching or radiation for example, with infrared radiation.
- a rigid mask having a multitude of holes is laid over the fabric to expose only those portions where nickel deposits are desired.
- the chemical etchant or radiation is applied to the mask to remove the non-conductive coating from the wires at these locations.
- the nickel deposits are only formed at locations where the non-conductive coating has been removed.
- the fabric can be plated through a rigid plastic mask, which is subsequently removed or in the alternative a chemical mask, such as a polyvinyl chloride mask, can be applied to the fabric.
- Fig. 7 shows a strip of Kevlar fabric 51 (Kevlar is a trade mark of Dupont for P-poly(phenyleneterephthalamide) yarn having deposited thereon, at discrete locations and in a uniform pattern, roughly circular deposits 52 of nickel, the deposits bearing abrasive particles formed of diamond grit.
- the deposits 52 can be seen more clearly in Figure 8, which shows in enlarged cross-section, a small length of the fabric shown in Figure 1.
- the diamond particles are referenced 53.
- the nickel deposits 52 are formed on a vaporized copper coating 54 firmly attached to the Kevlar fabric.
- the strip of Kevlar fabric is folded over to form a belt, with the two ends being lap jointed along a wavy line and held together by means of an overlying adhesive strip in a similar manner to the laminated belt shown in Figure 2.
- the nickel deposits 53 are formed, by means of the copper coating 4, directly onto the Kevlar backing fabric.
- the abrasive belt is made from a Barrday F-2160/175 Kevlar 29-1500 denier scoured fabric.
- the fabric is then coated with a layer of vaporized copper, which has good compatibility with nickel in the electrodeposition process.
- the copper should be firmly attached to the fibers making up the Kevlar fabric. This is achieved by spraying the vaporized copper onto the Kevlar fabric with a Metco type 12 4-arc all purpose metallizing spray gun.
- the arc spray gun forms an arc between a pair of copper electrodes and blows the vaporized copper onto the fabric by means of an air jet.
- a mask such as a polyvinyl chloride mask, having symmetrically disposed therein a very large number of holes (approximately 90 per square inch (90/6,45 cm2)) of about 1/16 inch (1,588 mm) in diameter, and the mask being of a thickness of about 3/4 of thousandth of an inch (0,019 mm), is applied to the copper coating.
- the mask can be laminated to the mesh from a silicone release paper, under a heat and pressure at 350 degrees F (176,7°C) and 85 PSI (586,1 h Pa).
- the mask is first formed on the silicone release paper by a silk screen or other suitable process.
- the mask is preferably applied to the silicone release paper in the form of a plastisol.
- the laminate is then placed in an electrolytic tank, for example the commercial nickel sulfamate bath described above.
- Nickel deposits build up on the portions of the copper coating exposed through the holes in the mask.
- the abrasive diamond particles are distributed over the fabric so as to become firmly embedded in the nickel deposits in a similar manner to the previous embodiments.
- the electrodeposition process can be carried out in a manner similar to the process described in the example with the coated Kevlar fabric in effect taking the place of the conductive mesh.
- the coarseness of the coating is important. As mentioned above, the arc spray gives a reasonably uniform coating, in which the mask can be attached. If the coating is too coarse, the coarse particles will tend to penetrate the mask causing nickel to be deposited on them at unwanted locations during the deposition process.
- the treated fabric when it emerges from the bath, can be cut to size and is ready for use as an abrasive without the need to have it laminated onto a backing material.
- the Kevlar fabric is extremely strong and well suited to most industrial applications.
- the fabric is preferably coated on the back with an adhesive, such as Bostik 7070 adhesive, to reduce fraying at the edges.
- an adhesive such as Bostik 7070 adhesive
- the two ends are preferably joined together in a wavy lap joint, as illustrated in Figure 1, and overlaid on the inside with a strip of fabric.
- Bostik 7070 adhesive can be employed.
- the strip can be stitched to the fabric with Kevlar thread.
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Ceramic Engineering (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Polishing Bodies And Polishing Tools (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT87810529T ATE61268T1 (de) | 1986-09-15 | 1987-09-15 | Flexibles ueberzogenes schleifmittel und verfahren zu dessen herstellung. |
Applications Claiming Priority (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA000518201A CA1280896C (en) | 1986-09-15 | 1986-09-15 | Flexible abrasive coated article and method of making it |
CA518201 | 1986-09-15 | ||
CA530811 | 1987-02-27 | ||
CA530811 | 1987-02-27 | ||
CA000542562A CA1317465C (en) | 1987-07-21 | 1987-07-21 | Method of making abrasive articles with metallized backing fabric and articles made thereby |
CA542562 | 1987-07-21 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0263785A1 EP0263785A1 (en) | 1988-04-13 |
EP0263785B1 true EP0263785B1 (en) | 1991-03-06 |
Family
ID=27167633
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP87810529A Expired - Lifetime EP0263785B1 (en) | 1986-09-15 | 1987-09-15 | A flexible abrasive coated article and method of making it |
Country Status (8)
Country | Link |
---|---|
EP (1) | EP0263785B1 (pt) |
CN (1) | CN87106418A (pt) |
AU (1) | AU613584B2 (pt) |
BR (1) | BR8705173A (pt) |
DE (1) | DE3768408D1 (pt) |
DK (1) | DK484887A (pt) |
FI (1) | FI873967A (pt) |
NO (1) | NO873745L (pt) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6096107A (en) * | 2000-01-03 | 2000-08-01 | Norton Company | Superabrasive products |
Families Citing this family (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB8701553D0 (en) * | 1987-01-24 | 1987-02-25 | Interface Developments Ltd | Abrasive article |
US5127197A (en) * | 1991-04-25 | 1992-07-07 | Brukvoort Wesley J | Abrasive article and processes for producing it |
EP0558869A1 (de) * | 1992-03-02 | 1993-09-08 | Gebrüder Sulzer Aktiengesellschaft | Gegenstand mit einer Abrasionsfläche und Verfahren zum Herstellen des Gegenstandes |
DE4235281C1 (de) * | 1992-10-20 | 1993-11-04 | Otmar Horl | Schleifwerkzeug aus flexiblem grundmaterial, insbesondere zum schleifen von unebenen flaechen, welches als schuh oder handschuh ausgebildet ist |
NL9300661A (nl) * | 1993-04-19 | 1994-11-16 | K G S Diamind Holding B V | Schuurvoorwerp omvattende een niet-geweven vezelmateriaal en een werkwijze voor het vervaardigen van een dergelijk schuurvoorwerp. |
NL9401528A (nl) * | 1994-09-21 | 1996-05-01 | Sandro Giovanni Guiseppe Ferro | Schuurvoorwerp en werkwijze voor het maken daarvan |
DE19727104C2 (de) | 1997-06-26 | 2000-07-20 | Ver Schmirgel & Maschf | Flexibler Schleifkörper und Verfahren zu seiner Herstellung |
FR2860743B1 (fr) | 2003-10-14 | 2006-01-13 | Snecma Moteurs | Procede de polissage automatise de pieces mecaniques en titane ou alliage de titane |
WO2007137453A1 (fr) * | 2006-05-29 | 2007-12-06 | Kerong Ruan | Toile de ponçage contenant du diamant et procédé de fabrication correspondant |
CN101602231B (zh) * | 2009-06-26 | 2011-08-03 | 江苏锋菱超硬工具有限公司 | 电镀钻石线锯的制备方法 |
CN101879707B (zh) * | 2010-06-10 | 2011-12-21 | 江苏锋菱超硬工具有限公司 | 连续生产电镀钻石砂布的方法及其装置 |
EP2895298B1 (en) | 2012-09-05 | 2021-10-20 | Mirka Oy | Flexible grinding product with flattened surface and method for manufacturing the same |
CN103203692B (zh) * | 2013-04-19 | 2016-01-27 | 韦勇荣 | 一种电镀金刚石砂带及其制造方法 |
US10888973B2 (en) * | 2015-06-25 | 2021-01-12 | 3M Innovative Properties Company | Methods of making metal bond abrasive articles and metal bond abrasive articles |
EP3397428A1 (en) * | 2015-12-29 | 2018-11-07 | 3M Innovative Properties Company | Abrasive article and a process for preparation thereof |
CN109420990B (zh) * | 2017-08-21 | 2022-05-06 | 凯吉斯金刚石(广州)有限公司 | 具有细长沉积物的柔性磨料构件 |
CN108588799B (zh) * | 2018-06-06 | 2020-04-14 | 郑州磨料磨具磨削研究所有限公司 | 一种电镀砂轮的上砂装置及制备方法 |
WO2023130059A1 (en) | 2021-12-30 | 2023-07-06 | Saint-Gobain Abrasives, Inc. | Abrasive articles and methods for forming same |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3660400A (en) * | 1966-11-17 | 1972-05-02 | Merck & Co Inc | Lower alkyl 3-hydroxy and 3-mercaptopyrazinoates |
USRE30494E (en) * | 1974-07-17 | 1981-01-27 | Buckbee-Mears Company | Cutting teeth for etched abrasives |
US4047902A (en) * | 1975-04-01 | 1977-09-13 | Wiand Richard K | Metal-plated abrasive product and method of manufacturing the product |
EP0013486B1 (en) * | 1978-12-12 | 1983-08-03 | Interface Developments Limited | Flexible abrasive member and method of making same |
JPS56116166U (pt) * | 1980-02-01 | 1981-09-05 |
-
1987
- 1987-09-08 AU AU78154/87A patent/AU613584B2/en not_active Ceased
- 1987-09-08 NO NO873745A patent/NO873745L/no unknown
- 1987-09-11 FI FI873967A patent/FI873967A/fi not_active IP Right Cessation
- 1987-09-15 DK DK484887A patent/DK484887A/da not_active Application Discontinuation
- 1987-09-15 BR BR8705173A patent/BR8705173A/pt unknown
- 1987-09-15 DE DE8787810529T patent/DE3768408D1/de not_active Expired - Lifetime
- 1987-09-15 CN CN198787106418A patent/CN87106418A/zh active Pending
- 1987-09-15 EP EP87810529A patent/EP0263785B1/en not_active Expired - Lifetime
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6096107A (en) * | 2000-01-03 | 2000-08-01 | Norton Company | Superabrasive products |
Also Published As
Publication number | Publication date |
---|---|
FI873967A0 (fi) | 1987-09-11 |
CN87106418A (zh) | 1988-03-30 |
AU613584B2 (en) | 1991-08-08 |
DE3768408D1 (de) | 1991-04-11 |
EP0263785A1 (en) | 1988-04-13 |
NO873745L (no) | 1988-03-16 |
FI873967A (fi) | 1988-03-16 |
AU7815487A (en) | 1988-03-17 |
BR8705173A (pt) | 1988-05-24 |
DK484887A (da) | 1988-03-16 |
DK484887D0 (da) | 1987-09-15 |
NO873745D0 (no) | 1987-09-08 |
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