EP0263519B1 - Mittel zur Verbesserung der Bedruckbarkeit von Papier und Karton - Google Patents
Mittel zur Verbesserung der Bedruckbarkeit von Papier und Karton Download PDFInfo
- Publication number
- EP0263519B1 EP0263519B1 EP87114697A EP87114697A EP0263519B1 EP 0263519 B1 EP0263519 B1 EP 0263519B1 EP 87114697 A EP87114697 A EP 87114697A EP 87114697 A EP87114697 A EP 87114697A EP 0263519 B1 EP0263519 B1 EP 0263519B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- weight
- denotes
- alkyl
- paper
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 24
- 239000011111 cardboard Substances 0.000 title description 10
- 239000011087 paperboard Substances 0.000 title description 6
- 239000000203 mixture Substances 0.000 claims abstract description 17
- 229920000642 polymer Polymers 0.000 claims abstract description 13
- 150000001412 amines Chemical class 0.000 claims abstract description 11
- 239000000194 fatty acid Substances 0.000 claims abstract description 10
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims abstract description 10
- 125000000129 anionic group Chemical group 0.000 claims abstract description 7
- 239000002253 acid Substances 0.000 claims abstract description 6
- 229920000151 polyglycol Polymers 0.000 claims abstract description 6
- 239000010695 polyglycol Substances 0.000 claims abstract description 6
- 229920006395 saturated elastomer Polymers 0.000 claims abstract description 6
- 229910052500 inorganic mineral Inorganic materials 0.000 claims abstract description 4
- 239000011707 mineral Substances 0.000 claims abstract description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000001257 hydrogen Substances 0.000 claims description 10
- 229910052739 hydrogen Inorganic materials 0.000 claims description 10
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims description 7
- 150000001875 compounds Chemical class 0.000 claims description 7
- 150000002431 hydrogen Chemical class 0.000 claims description 7
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 6
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 4
- 150000001450 anions Chemical class 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 239000005995 Aluminium silicate Substances 0.000 claims description 3
- 101000623895 Bos taurus Mucin-15 Proteins 0.000 claims description 3
- 235000012211 aluminium silicate Nutrition 0.000 claims description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 3
- 239000000049 pigment Substances 0.000 claims description 3
- 235000021355 Stearic acid Nutrition 0.000 claims description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 2
- 239000000463 material Substances 0.000 claims description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 2
- 239000008117 stearic acid Substances 0.000 claims description 2
- 239000004408 titanium dioxide Substances 0.000 claims description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- REYJJPSVUYRZGE-UHFFFAOYSA-N Octadecylamine Chemical compound CCCCCCCCCCCCCCCCCCN REYJJPSVUYRZGE-UHFFFAOYSA-N 0.000 claims 1
- 125000003342 alkenyl group Chemical group 0.000 claims 1
- REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 claims 1
- 239000004664 distearyldimethylammonium chloride (DHTDMAC) Substances 0.000 claims 1
- 238000007639 printing Methods 0.000 abstract description 19
- 238000000576 coating method Methods 0.000 abstract description 12
- 239000011248 coating agent Substances 0.000 abstract description 11
- 150000001735 carboxylic acids Chemical class 0.000 abstract description 2
- 239000000123 paper Substances 0.000 description 47
- 239000000976 ink Substances 0.000 description 12
- 238000007646 gravure printing Methods 0.000 description 10
- 238000007645 offset printing Methods 0.000 description 7
- 235000014113 dietary fatty acids Nutrition 0.000 description 6
- 229930195729 fatty acid Natural products 0.000 description 6
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 150000004665 fatty acids Chemical class 0.000 description 4
- 239000003960 organic solvent Substances 0.000 description 4
- 239000002023 wood Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 150000003863 ammonium salts Chemical class 0.000 description 3
- 239000002775 capsule Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 238000007644 letterpress printing Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 description 2
- 239000008199 coating composition Substances 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- ROBFUDYVXSDBQM-UHFFFAOYSA-N hydroxymalonic acid Chemical compound OC(=O)C(O)C(O)=O ROBFUDYVXSDBQM-UHFFFAOYSA-N 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 239000001254 oxidized starch Substances 0.000 description 2
- 235000013808 oxidized starch Nutrition 0.000 description 2
- 230000035515 penetration Effects 0.000 description 2
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 125000001424 substituent group Chemical group 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- QLAJNZSPVITUCQ-UHFFFAOYSA-N 1,3,2-dioxathietane 2,2-dioxide Chemical compound O=S1(=O)OCO1 QLAJNZSPVITUCQ-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- GJCOSYZMQJWQCA-UHFFFAOYSA-N 9H-xanthene Chemical compound C1=CC=C2CC3=CC=CC=C3OC2=C1 GJCOSYZMQJWQCA-UHFFFAOYSA-N 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- 244000007835 Cyamopsis tetragonoloba Species 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- 108010074506 Transfer Factor Proteins 0.000 description 1
- VJHCJDRQFCCTHL-UHFFFAOYSA-N acetic acid 2,3,4,5,6-pentahydroxyhexanal Chemical compound CC(O)=O.OCC(O)C(O)C(O)C(O)C=O VJHCJDRQFCCTHL-UHFFFAOYSA-N 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000000740 bleeding effect Effects 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 235000015165 citric acid Nutrition 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000002761 deinking Substances 0.000 description 1
- -1 dimethophosphate Chemical compound 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 239000003094 microcapsule Substances 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 239000012875 nonionic emulsifier Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 150000003867 organic ammonium compounds Chemical group 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 125000000962 organic group Chemical group 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 235000011837 pasties Nutrition 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000011550 stock solution Substances 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- YNJBWRMUSHSURL-UHFFFAOYSA-N trichloroacetic acid Chemical compound OC(=O)C(Cl)(Cl)Cl YNJBWRMUSHSURL-UHFFFAOYSA-N 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/46—Non-macromolecular organic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/52—Macromolecular coatings
- B41M5/5245—Macromolecular coatings characterised by the use of polymers containing cationic or anionic groups, e.g. mordants
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
Definitions
- the invention has for its object to treat paper and cardboard so that all types of systems containing an organic solvent, for example the dispersed or dissolved in an organic solvent printing ink, coating material or a varnish, especially a low-viscosity gravure ink as little as possible to punch or punch through the paper or cardboard.
- an organic solvent for example the dispersed or dissolved in an organic solvent printing ink, coating material or a varnish
- a low-viscosity gravure ink as little as possible to punch or punch through the paper or cardboard.
- the less these colors penetrate the lower the consumption and the nicer the print gloss of the treated surface.
- the color depth also increases.
- This problem of knocking the printing ink into the paper is pronounced in all printing processes, but especially in gravure printing processes, since gravure printing inks have to have a significantly lower viscosity compared to other printing inks (high pressure, offset printing).
- Gravure printing is one of the most widespread types of printing for all types of mass printing. For economic and postal reasons, there has been
- the line of the coated varieties In order to have a good level of gravure ink on the paper surface, the line of the coated varieties must have a minimum thickness of about 6.5 - 7 g / m2 and page, for double-sided coated gravure paper this results in a coating at 50 g / m2 total weight.
- Base paper of around 36 g / m2. From today's perspective, this is a lower limit, since it is only the fibers of the coating base paper that contribute to the physical strength values of the printing paper.
- the uncoated rotogravure papers are neither in the whiteness nor in the gloss of those that can be produced Printed matter equivalent to coated gravure papers.
- the consumption of gravure printing ink is about 2 1/2 to 3 times that of the coated paper, because the porosity and thus the absorbency of the gravure printing paper is much greater.
- punching through and shining through the print on the back is a particular problem with these papers when the basis weight is further reduced.
- EP-A-016 465 a process for the production of coated paper and cardboard is known, in which an aqueous coating slip with particles of at least one aqueous plastic dispersion and inorganic pigments is applied to the coating paper or cardboard and dried.
- This coating slip should only penetrate to a small extent into the paper or the cardboard, thus preventing the coating slip from striking through and ensuring a smooth and trouble-free coating process.
- Suitable quaternary organic ammonium salts are, in particular, those of the following formulas (1) to (8) wherein R is C8-C22-alkyl, C8-C22-alkenyl or a group of the formula- (AO) y -C8-C22-alkyl, R1 C1-C4-alkyl or benzyl, R2 is hydrogen, C1-C22-alkyl, C1- C22-alkenyl or a group of the formula - (AO) y -B or the formula - (AO) y -C8-C22-alkyl, R3 is hydrogen, C1-C4-alkyl or a group of the formula - (AO) y -B , A is C1-C4 alkylene, B is hydrogen or a group of the formula -COR, y is a number from 1 to 25 and X is an anion; wherein X, R, R1 and R2 have the meanings given above; where
- Suitable organic amines for component Ic) are those amines on which the quaternary ammonium salts listed above are based. These amines have the following formulas (1 ⁇ ) to (8 ⁇ ), the individual substituents having the same meaning as in the formulas (1) to (8)
- the compounds of the formula 1 are preferred. Also preferred are the partially neutralized amines of the formula 1 ⁇ in a mixture with C12-C18 fatty acids as component Ic).
- substituents consist of C8-C22-alkyl or C8-C22-alkenyl groups
- substituents consist of C8-C22-alkyl or C8-C22-alkenyl groups
- groups which differ from natural fatty acids and their Derive mixtures such as tallow fatty acid, coconut fatty acid, oleic acid, palmitic acid, stearic acid.
- Possible anions are, for example, chloride, bromide, sulfate, methosulfate, dimethophosphate, phosphate or anions of organic acids such as acetic acid, propionic acid, trichloroacetic acid, lactic acid, citric acid, tartaric acid, tartronic acid, oxalic acid, malonic acid.
- the agent according to the invention preferably contains 15 to 25% by weight of the sum of the two components I and II.
- the preferred quantitative ratios of the two components I and II to one another are 5 to 15% by weight for component I and accordingly 85 to 95% by weight .-% for component II.
- Component Ib) preferably consists of 70% by weight of the quaternary ammonium salt and 30% by weight of the other portion (s). The same ratio is preferred for component Ic).
- 0.05 to 0.5 mol, preferably 0.1 mol, of an acid per 1 mol of organic amine are used. Suitable acids for this purpose are the customary mineral acids and organic carboxylic acids.
- component Ic) it has proven to be advantageous to use a non-ionic emulsifier. Instead of only one of the components Ia, b or c can also be used in various mixtures of these individual components.
- Suitable polymers include, for example, polysaccharide derivatives containing anionic groups, such as e.g. Carboxymethyl cellulose, carboxymethyl starch, carboxymethyl guar, xanthan or polymers containing synthetic anionic or polar groups, e.g. Polyacrylates, anionic polyacrylamides, copolymers of acrylic acid and maleic anhydride, of styrene and maleic anhydride or of styrene and acrylic acid or also polyvinyl alcohols and polyvinyl acetates.
- oxidized starch is preferred. Up to 70% by weight of these polymers can also be replaced by the white pigments commonly used in paper production, such as titanium dioxide, kaolin, calcium carbonate.
- the claimed agents are produced by simply stirring the base batches of the required components.
- the agent according to the invention can be added during the paper production in the mixing plant or material center and in an amount of 2 to 8, preferably 5 to 7% by weight, based on the finished paper.
- the addition can in particular also take place within the filler slurry by first stirring the polymer into the filler slurry and then adding the quaternary organic ammonium compound. This mixture is then added to the fabric.
- the agent according to the invention is preferably applied to the surface of the base paper. This is done with the help of suitable devices before calendering. If the paper machine is designed accordingly, the agent according to the invention can also be applied in the dryer section of the machine. After application to the surface, it is dried.
- the order quantities for the order on the surface are generally 0.1 to 10 g / m2, preferably 0.6 to 3 g / m2.
- the agent according to the invention is suitable for the treatment of all types of paper, such as are required in gravure printing, web offset printing, sheet-fed offset printing and letterpress printing.
- the agent according to the invention is particularly interesting for gravure and web offset papers.
- two types of paper are suitable for gravure printing, namely the highly filled, satin-coated, mostly wood-containing gravure printing paper in basis weights between 40 to about 80 g / m2 (SC paper) and the coated, wood-containing or wood-free, highly satined gravure printing paper in basis weights between 45 and approximately 135 g / m2.
- Web offset printing is usually wood-containing uncoated or coated, so-called LWC paper with basis weights between 40 and 80 g / m2.
- both wood-containing and wood-free papers with basis weights of 60 g / m 2 and up, which are sized or coated on the surface, are generally used.
- the compounds according to the invention are also of interest for the treatment of paper for letterpress printing (letterpress printing, newspaper printing). It is particularly important here that papers which are treated with the agent according to the invention require less color when printing.
- the organic groups in the quaternary ammonium salts and amines prevent further penetration of the printing ink by adsorption of the organic solvent or mineral oil contained in the printing inks and thus penetration of the back of the paper. At the same time, the affinity of the printing ink for paper is improved.
- the use of the polymer such as oxidized starch is necessary because the organic quaternary ammonium salts alone exert a softening effect on the paper fibers and thus significantly reduce the tear length of the paper. This undesired effect of the quaternary ammonium compound is prevented by salt formation between the quaternary ammonium compound and the polymer. The softening effect and thus the reduction of the tear length is missing.
- the advantages which can be achieved with the agent according to the invention on printing papers can be represented as follows: reduction of bleeding through and translucency, increase in color depth or blackness, reduced ink consumption, increase in gloss, reduction of missing dots, increase in conductivity. Web offset printing also showed an improvement in pick resistance.
- the reduction in ink consumption also makes it easier to deink a paper treated with an agent according to the invention and then printed.
- the fiber obtained during deinking has a much better whiteness.
- the described agent also has advantages for carbonless carbonless papers that work with microcapsules. The problem with all of these capsule papers is that approximately half of the capsule content released is sucked back into the dispensing sheet and does not contribute to the color reaction at all. By treating the paper with the agent according to the invention, this sucking back of the capsule contents is reduced and the transfer factor is increased significantly.
Landscapes
- Paper (AREA)
- Measuring Volume Flow (AREA)
- Air Bags (AREA)
- Vehicle Body Suspensions (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT87114697T ATE87045T1 (de) | 1986-10-08 | 1987-10-08 | Mittel zur verbesserung der bedruckbarkeit von papier und karton. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19863634277 DE3634277A1 (de) | 1986-10-08 | 1986-10-08 | Mittel zur verbesserung der bedruckbarkeit von papier und karton |
DE3634277 | 1986-10-08 |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0263519A2 EP0263519A2 (de) | 1988-04-13 |
EP0263519A3 EP0263519A3 (en) | 1988-09-07 |
EP0263519B1 true EP0263519B1 (de) | 1993-03-17 |
Family
ID=6311312
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP87114697A Expired - Lifetime EP0263519B1 (de) | 1986-10-08 | 1987-10-08 | Mittel zur Verbesserung der Bedruckbarkeit von Papier und Karton |
Country Status (11)
Country | Link |
---|---|
US (1) | US4857110A (da) |
EP (1) | EP0263519B1 (da) |
JP (1) | JPS6452899A (da) |
AT (1) | ATE87045T1 (da) |
AU (1) | AU592470B2 (da) |
BR (1) | BR8705311A (da) |
CA (1) | CA1289702C (da) |
DE (2) | DE3634277A1 (da) |
DK (1) | DK169588B1 (da) |
FI (1) | FI89527C (da) |
NO (1) | NO170814C (da) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5302249A (en) * | 1990-01-25 | 1994-04-12 | Xerox Corporation | Treated papers |
DE4015252A1 (de) * | 1990-05-12 | 1991-11-21 | Hoechst Ag | Verfahren zur einbindung eines binders in ein in der masse gefuelltes papier |
GB2310216A (en) * | 1995-10-13 | 1997-08-20 | Ecc Int Ltd | Coating composition |
GB2310215A (en) * | 1995-10-13 | 1997-08-20 | Ecc Int Ltd | Coating composition |
AU7309296A (en) * | 1995-10-13 | 1997-04-30 | Ecc International Limited | Paper coating |
WO2011071156A1 (ja) * | 2009-12-11 | 2011-06-16 | 花王株式会社 | 複合材料 |
EP3007968B1 (en) | 2013-06-12 | 2020-04-01 | Alfred Marcum | Aerostat anchoring, deployment, extended duration and recovery apparatus |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2514131A (en) * | 1945-11-08 | 1950-07-04 | Gen Aniline & Film Corp | Process of producing sheetings of a water-soluble film-forming material |
US2666038A (en) * | 1950-08-08 | 1954-01-12 | American Viscose Corp | Textile-finishing compositions, finished articles, and methods of producing them |
DE2314060A1 (de) * | 1973-03-21 | 1974-10-10 | Honshu Paper Co Ltd | Oberflaechenaktive substanz |
DE2911679C3 (de) * | 1979-03-24 | 1987-04-16 | Feldmühle AG, 4000 Düsseldorf | Verfahren zum Herstellen von gestrichenem Papier und Karton und Streichmasse zur Durchführung des Verfahrens |
JPS60199998A (ja) * | 1984-03-26 | 1985-10-09 | ジェイエスアール株式会社 | 紙被覆用組成物 |
US4707189A (en) * | 1984-11-07 | 1987-11-17 | Hercules Incorporated | Biostable compositions and the aqueous solutions thereof as thickeners for aqueous-based systems |
-
1986
- 1986-10-08 DE DE19863634277 patent/DE3634277A1/de not_active Withdrawn
-
1987
- 1987-10-06 US US07/106,562 patent/US4857110A/en not_active Expired - Lifetime
- 1987-10-06 FI FI874378A patent/FI89527C/fi not_active IP Right Cessation
- 1987-10-07 JP JP62251744A patent/JPS6452899A/ja active Pending
- 1987-10-07 DK DK525587A patent/DK169588B1/da not_active IP Right Cessation
- 1987-10-07 BR BR8705311A patent/BR8705311A/pt not_active IP Right Cessation
- 1987-10-07 NO NO874204A patent/NO170814C/no not_active IP Right Cessation
- 1987-10-07 CA CA000548734A patent/CA1289702C/en not_active Expired - Lifetime
- 1987-10-08 DE DE8787114697T patent/DE3784828D1/de not_active Expired - Fee Related
- 1987-10-08 AT AT87114697T patent/ATE87045T1/de not_active IP Right Cessation
- 1987-10-08 EP EP87114697A patent/EP0263519B1/de not_active Expired - Lifetime
- 1987-10-08 AU AU79458/87A patent/AU592470B2/en not_active Ceased
Also Published As
Publication number | Publication date |
---|---|
FI89527B (fi) | 1993-06-30 |
JPS6452899A (en) | 1989-02-28 |
BR8705311A (pt) | 1988-05-24 |
DE3634277A1 (de) | 1988-04-21 |
NO170814B (no) | 1992-08-31 |
EP0263519A3 (en) | 1988-09-07 |
NO170814C (no) | 1992-12-09 |
ATE87045T1 (de) | 1993-04-15 |
AU592470B2 (en) | 1990-01-11 |
FI89527C (fi) | 1993-10-11 |
FI874378A0 (fi) | 1987-10-06 |
NO874204L (no) | 1988-04-11 |
DK525587D0 (da) | 1987-10-07 |
DK525587A (da) | 1988-04-09 |
NO874204D0 (no) | 1987-10-07 |
FI874378A (fi) | 1988-04-09 |
CA1289702C (en) | 1991-10-01 |
EP0263519A2 (de) | 1988-04-13 |
US4857110A (en) | 1989-08-15 |
DE3784828D1 (de) | 1993-04-22 |
AU7945887A (en) | 1988-04-14 |
DK169588B1 (da) | 1994-12-12 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
DE69307113T3 (de) | Aufzeichnungsmaterial für Tintenstrahlaufzeichnung | |
EP0192252B1 (de) | Verfahren zur Verbesserung des Holdouts von Druckfarben, Lacken und Beschichtungsmassen auf Flächengebilden aus Fasern sowie zur Verbesserung des De-Inkings der Fasern sowie Masse zur Durchführung des Verfahrens und damit erzeugte Flächengebilde | |
DE3730887A1 (de) | Verfahren zur verbesserung der bedruckbarkeit von papier | |
EP0835906B1 (de) | Dispersionen von optischen Aufhellern | |
DE3707221A1 (de) | Kationisch eingestellte pigmentdispersion und streichfarbe | |
DE2357165B2 (de) | Oberflächenleim- und -streichmasse für Papier | |
EP0279313B1 (de) | Verfahren zur Herstellung eines für die Papier- und Kartonindustrie geeigneten, die Bedruckbarkeit von Papier und Karton verbessernden Mittels auf Pigmentbasis, das Mittel und seine Verwendung | |
EP0263519B1 (de) | Mittel zur Verbesserung der Bedruckbarkeit von Papier und Karton | |
DE1264944B (de) | Waessrige Streichmasse fuer Papier, Pappe od. dgl. | |
DE69804514T2 (de) | Verfahren zur herstellung von beschichtetem papier für die verpackung von flüssigkeiten | |
DE2522306C3 (de) | Cyclische, substituierte Dicarbonsäureanhydride enthaltendes Papierleimungsgemisch und dessen Verwendung | |
EP0016465B1 (de) | Verfahren zum Herstellen von gestrichenem Papier und Karton und Streichmasse zur Durchführung des Verfahrens | |
DE69728285T2 (de) | Stärkederivat enthaltende kolophoniumemulsion zur papierleimung | |
DE4137091C2 (de) | Wäßrige Feindispersion eines organophilen Schichtsilikates | |
EP0307795A2 (de) | Kationisch eingestellte Pigmentdispersion und Streichfarbe | |
DE1546415A1 (de) | Verfahren zur Erhoehung der Nassfestigkeit von Papier | |
DE1812416C3 (de) | Verfahren zur Oberflächen- und/oder Masseleimung von Papier | |
DE69202176T2 (de) | Verfahren zur Beschichtung von Papier und Pappe und seine Verwendung zur Herstellung von Papier mit guter Glätte. | |
DE4141860A1 (de) | Beschichtungsmasse fuer zeitungspapier | |
DE69814733T2 (de) | Verwendung von Wasserglas in einer Papierbeschichtung | |
DE1922038A1 (de) | Verfahren zur Herstellung eines Leimungs- und Hydrophobierungsmittels | |
DE1946471C3 (de) | Verfahren zur Herstellung von holzschliffhaltigen Druckpapieren | |
DE1696168C3 (de) | Verfahren zum Leimen von Papier | |
AT202436B (de) | Überzugsmasse für Papier | |
DE1696162A1 (de) | Verfahren zur Herstellung von gestrichenen Papieren mit verbesserten Oberflaecheneigenschaften |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
AK | Designated contracting states |
Kind code of ref document: A2 Designated state(s): AT BE CH DE FR GB IT LI NL SE |
|
PUAL | Search report despatched |
Free format text: ORIGINAL CODE: 0009013 |
|
AK | Designated contracting states |
Kind code of ref document: A3 Designated state(s): AT BE CH DE FR GB IT LI NL SE |
|
17P | Request for examination filed |
Effective date: 19890302 |
|
17Q | First examination report despatched |
Effective date: 19910214 |
|
RTI1 | Title (correction) | ||
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AT BE CH DE FR GB IT LI NL SE |
|
REF | Corresponds to: |
Ref document number: 87045 Country of ref document: AT Date of ref document: 19930415 Kind code of ref document: T |
|
ITF | It: translation for a ep patent filed | ||
REF | Corresponds to: |
Ref document number: 3784828 Country of ref document: DE Date of ref document: 19930422 |
|
GBT | Gb: translation of ep patent filed (gb section 77(6)(a)/1977) |
Effective date: 19930520 |
|
ET | Fr: translation filed | ||
PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
26N | No opposition filed | ||
EAL | Se: european patent in force in sweden |
Ref document number: 87114697.3 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: FR Payment date: 20010816 Year of fee payment: 15 Ref country code: DE Payment date: 20010816 Year of fee payment: 15 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: AT Payment date: 20010822 Year of fee payment: 15 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: GB Payment date: 20010823 Year of fee payment: 15 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: SE Payment date: 20010824 Year of fee payment: 15 Ref country code: CH Payment date: 20010824 Year of fee payment: 15 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: NL Payment date: 20010907 Year of fee payment: 15 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: BE Payment date: 20011011 Year of fee payment: 15 |
|
REG | Reference to a national code |
Ref country code: GB Ref legal event code: IF02 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: GB Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20021008 Ref country code: AT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20021008 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20021009 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LI Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20021031 Ref country code: CH Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20021031 Ref country code: BE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20021031 |
|
BERE | Be: lapsed |
Owner name: *HOECHST A.G. Effective date: 20021031 Owner name: *INSTITUT FUR PAPIER- ZELLSTOFF-UND FASERTECHNIK D Effective date: 20021031 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: NL Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20030501 Ref country code: DE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20030501 |
|
GBPC | Gb: european patent ceased through non-payment of renewal fee |
Effective date: 20021008 |
|
EUG | Se: european patent has lapsed | ||
REG | Reference to a national code |
Ref country code: CH Ref legal event code: PL |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: FR Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20030630 |
|
NLV4 | Nl: lapsed or anulled due to non-payment of the annual fee |
Effective date: 20030501 |
|
REG | Reference to a national code |
Ref country code: FR Ref legal event code: ST |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES;WARNING: LAPSES OF ITALIAN PATENTS WITH EFFECTIVE DATE BEFORE 2007 MAY HAVE OCCURRED AT ANY TIME BEFORE 2007. THE CORRECT EFFECTIVE DATE MAY BE DIFFERENT FROM THE ONE RECORDED. Effective date: 20051008 |