EP0223573B1 - Verfahren zur Herstellung einer Kohle-Wasser-Suspension mit hohem Anteil feiner Teilchen - Google Patents
Verfahren zur Herstellung einer Kohle-Wasser-Suspension mit hohem Anteil feiner Teilchen Download PDFInfo
- Publication number
- EP0223573B1 EP0223573B1 EP19860308894 EP86308894A EP0223573B1 EP 0223573 B1 EP0223573 B1 EP 0223573B1 EP 19860308894 EP19860308894 EP 19860308894 EP 86308894 A EP86308894 A EP 86308894A EP 0223573 B1 EP0223573 B1 EP 0223573B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- slurry
- coal
- mill
- classifier
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000002002 slurry Substances 0.000 title claims description 114
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims description 57
- 238000000034 method Methods 0.000 title claims description 38
- 239000010419 fine particle Substances 0.000 title claims description 34
- 239000003245 coal Substances 0.000 claims description 44
- 239000002245 particle Substances 0.000 claims description 27
- 238000000227 grinding Methods 0.000 claims description 21
- 239000011362 coarse particle Substances 0.000 claims description 20
- 239000003795 chemical substances by application Substances 0.000 claims description 9
- 239000006185 dispersion Substances 0.000 claims description 8
- 238000010951 particle size reduction Methods 0.000 claims description 2
- 238000002485 combustion reaction Methods 0.000 description 19
- 238000009826 distribution Methods 0.000 description 9
- 239000000203 mixture Substances 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 5
- 239000002956 ash Substances 0.000 description 4
- 238000007796 conventional method Methods 0.000 description 4
- 230000001186 cumulative effect Effects 0.000 description 4
- 239000002270 dispersing agent Substances 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 230000009471 action Effects 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 239000011268 mixed slurry Substances 0.000 description 3
- 238000012216 screening Methods 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 239000010881 fly ash Substances 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000001737 promoting effect Effects 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 238000005303 weighing Methods 0.000 description 2
- 238000001238 wet grinding Methods 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000002802 bituminous coal Substances 0.000 description 1
- 239000000567 combustion gas Substances 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23K—FEEDING FUEL TO COMBUSTION APPARATUS
- F23K1/00—Preparation of lump or pulverulent fuel in readiness for delivery to combustion apparatus
- F23K1/02—Mixing solid fuel with a liquid, e.g. preparing slurries
Definitions
- Fig. 3 shows a conventional method of preparing fine-particle high-loaded coal-water slurry and conventional equipment for preparing the same.
- coal 1 which has been crushed previously, is supplied by a weighing feeder to a mill 3, for example a ball mill, together with water 4 and dispersion agent 5.
- the coal 1 is then ground and mixed into slurry within the mill 3 and flows out as fine-particle high loaded coal-water slurry 7, which is then transferred by means of a pump 6.
- the mill 3 has a length which is large compared to its diameter, the ratio of the length to the diameter being usually 4 to 8.
- the ratio of the length to the diameter of a mill employed in an ordinary method of preparing high-loaded coal-water slurry and ordinary equipment for preparing the same is 2 to 3.
- Increasing the ratio of length to diameter of the same makes it possible to increase the residence time of the coal-water mixture in the mill, thus promoting the grinding operation performed by the grinding medium, and thereby producing fine-particle high loaded coal-water slurry with
- Slurry 13 from the coal cleaner 11 is introduced into a dehydrating device 14 which removes water 15 therefrom, and the resulting slurry is made into cake having a coal content of not less than 60% by weight. Subsequently, the cake is made into a fluid in a device 16. In this way, fine-particle high-loaded coal-water slurry 7 is produced and is transferred by means of the pump 6.
- the underflow slurry should then be subjected to further tests in the particle size analyzer to determine what the particle size distribution of the underflow slurry is and its attendant surface area and porosity.
- the underflow slurry is passed through a third line to a final trim tank. If, however, the solids content or the viscosity or the specific surface area or the porosity of the underflow slurry is not as desired, then a portion of the underflow slurry is passed through the second line to a second mill. Depending on how badly the underflow slurry is out of specification, from 1 to 30 volume percent of the underflow slurry is passed to the second mill and the remainder is passed to the final trim tank.
- Water is fed into the second mill so that the solids concentration of the ground slurry fed through the second line is adjusted to 30 to 60 volume percent.
- the diluted slurry in the second mill is then ground in the second mill until at least 95 volume percent of the particles in the slurry have diameters less than 20 microns and preferably, less than 15 microns.
- the classifier may be a vibrating screen classifier, a cylinder-shaped classifier, or a horizontal disc-shaped classifier.
- Fig. 1 shows the embodiment of the present invention.
- a first stage mill 3a is supplied with coal 1, water 4, and a dispersion agent 5 under the operation of a weighing feeder 2 in such a manner that slurry having a predetermined coal content can be obtained.
- the coal 1 is ground within the first stage mill 3a and the mixture flows out as slurry 8.
- the slurry 8 is then led to a classifier 9 wherein coarser particles 9b contained in the slurry 8 are removed from the mixture.
- a lower flow 9a is directly supplied to a second stage mill 3b wherein it is successively ground, flows out from the second stage mill 3b as fine-particle high loaded coal-water slurry 7 containing minimal coarse particles, and then is transferred by means of a pump 6.
- the coarser particles 9b may be sent back to the first stage mill 3a through suitable means and may be ground together with coal 1, water 4, and a dispersion agent 5.
- the slurry 8, the lower flow 9a, and the fine-particle high loaded coal-water slurry 7 have practically the same coal content which is not less than 60% by weight.
- the lower flow 9a containing lesser amount of coarse particles is supplied to the mill 3b where it is ground again. Therefore, since the coarse particles are substantially low in this stage of grinding, the coal particles can be adequately subjected to grinding action without any disturbance, thus promoting the grinding operation and thereby producing fine-particle high loaded coal-water slurry 7 which contains minimal coarse particles.
- first stage mill 3a and the second stage mill 3b a ball mill which is so dimensioned that the ratio of length to diameter is 2 to 4 is used. Therefore, within the first stage and second stage mills 3a and 3b, grinding can so proceed in the state of high loaded coal-water slurry with adequately long residence time to prepare fine-particle high loaded coal-water slurry having a (specified) particle size distribution. This arrangement achieves a remarkably finer particle size distribution or arrangement in comparison to that of the case of a single mill having the length to diameter ratio of approximately 3.
- Each of the curve groups collectively indicates the data values of a number of experiments.
- ordinate value (cumulative oversize of 150 ⁇ m corresponding to a abscissa value 85% (cumulative undersize of 74 ⁇ m) is much lower in curve group a (the present invention) than in curve groups b and c (prior arts).
- the present invention makes it possible to prepare fine-particle high loaded coal-water slurry containing minimal coarse particles, and also possible, when the slurry is supplied to combustion equipment to be burned therein, to reduce the amount of the unburnt carbon in the combustion residue, and to lower the NOx concentration in the exhaust gases.
- the second stage mill is supplied with slurry from the first stage mill after coarser particles have been removed from the slurry by means of the classifier, and the slurry is then ground in the second stage mill, and also because the grinding is performed for an adequate period, fine-particle high loaded coal-water slurry containing minimal coarse particles can be prepared by relatively simple method and equipment without any complicated equipment or operation, and in addition, when the slurry is supplied to combustion equipment to be burnt therein, the amount of unburnt carbon in the combustion residue can be reduced and also the NOx concentration in the exhaust gases can be lowered.
- the capability of the classifier can be increased, various advantages are attainable, such as the possibility of mass production of fine-particle high loaded coal-water slurry, and the possibility of excellent grinding efficiency (reduced power consumption) and grindability.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Liquid Carbonaceous Fuels (AREA)
- Crushing And Grinding (AREA)
Claims (6)
- Verfahren zu Herstellung einer Kohle-Wasser-Suspension mit hohem Anteil feiner Teilchen, umfassend
Zuführen von Kohle (1), Wasser (4) und eines Dispergiermittels (5) an eine Mühle (3a) der ersten Stufe, in der das Gut gemahlen wird, wobei der Gewichts-Prozentanteil an Zugeführter Kohle (1) größer ist als 60% des Gesamtgewichts der zugeführten Mengen an Kohle (1), Wasser (4) und Dispergiermittel (6),
Klassieren der Suspension (8) in einem Klassierer (9) und Entfernen derjenigen groben Teilchen (9b) aus der von der Mühle (3a) der ersten Stufe abgegebenen Suspension (8), die größer sind als die mittlere Teilchengröße der besagten Kohle-Wasser-Aufschlemmung mit hohem Anteil feiner Teilchen,
Rückführen dieser groben Teilchen (9b) an die Mühle (3a) der ersten Stufe zum weiteren Mahlen, und
Zuführen der klassierten Suspension (8), aus der die groben Teilchen (9b) entfernt worden sind, an eine Mühle (3b) der zweiten Stufe, in der sie gemahlen wird,
wobei die Suspension in der zweiten Mühle (3b) einen Gewichts-Prozentanteil an Kohle (1) aufweist, der größer ist als 60% des Gesamtgewichts der Suspension (9a), und
wobei die aufbereitete Suspension (7) aus feinen Teilchen, die einen Gewichts-Prozentanteil an Kohle (1) größer als 60% des Gesamtgewichts der Suspension (7) aufweist, von der Mühle (3b) der zweiten Stufe abgenommen wird. - Verfahren nach Anspruch 1, wobei das Mahlen in der Mühle (3b) der zweiten Stufe so erfolgt, daß eine Verringerung der Teilchengröße in der Suspension (9a) auf wesentlich weniger als 150 µm erfolgt und darin eine wesentliche Menge an feinen Teilchen mit weniger als 74 µm erhalten wird.
- Verfahren nach Anspruch 1 oder 2, wobei jede der Mühlen (3a, 3b) der ersten und der zweiten Stufe eine Kugelmühle (3a, 3b) umfaßt, die so dimensioniert ist, daß das Verhältnis ihrer Länge zu ihrem Durchmesser 2 bis 4 beträgt.
- Verfahren nach einem der Ansprüche 1 bis 3, wobei der Klassierer (9) ein Schwingsieb-Klassierer ist.
- Verfahren nach einem der Ansprüche 1 bis 3, wobei der Klassierer (9) ein zylindrischer Klassierer ist.
- Verfahren nach einem der Ansprüche 1 bis 3, wobei der Klassierer (9) ein horizontaler scheibenförmiger Klassierer ist.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP256900/85 | 1985-11-16 | ||
JP25690085A JPS62116692A (ja) | 1985-11-16 | 1985-11-16 | 微粒高濃度石炭水スラリ−の製造方法および装置 |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0223573A2 EP0223573A2 (de) | 1987-05-27 |
EP0223573A3 EP0223573A3 (en) | 1988-09-21 |
EP0223573B1 true EP0223573B1 (de) | 1991-08-28 |
Family
ID=17298951
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP19860308894 Expired EP0223573B1 (de) | 1985-11-16 | 1986-11-14 | Verfahren zur Herstellung einer Kohle-Wasser-Suspension mit hohem Anteil feiner Teilchen |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP0223573B1 (de) |
JP (1) | JPS62116692A (de) |
AU (1) | AU572410B2 (de) |
CA (1) | CA1279477C (de) |
DE (1) | DE3681123D1 (de) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10287522B2 (en) | 2013-01-31 | 2019-05-14 | General Electric Company | System and method for preparing coal water slurry |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AU612127B2 (en) * | 1986-12-26 | 1991-07-04 | Ube Industries, Ltd. | Solid fuel-water slurry composition and process for the preparation of the same |
DE3718568C1 (de) * | 1987-06-03 | 1988-06-30 | Steinmueller Gmbh L & C | Verfahren zur Herstellung einer Kohle-Wasser-Mischung fuer die Verbrennung in einer Wirbelschichtfeuerung und Vorrichtung zur Durchfuehrung des Verfahrens |
JP2001190974A (ja) * | 2000-01-07 | 2001-07-17 | Masumi Kusunoki | 粉体分散機用解砕フィルタ装置 |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4391702A (en) * | 1977-10-07 | 1983-07-05 | Nippon Steel Corporation | Method for classification of coals for coke production |
DE2919914A1 (de) * | 1979-05-17 | 1980-11-20 | Stotz Ag A | Siebrost, insbesondere vibrationssiebrost |
AU545527B2 (en) * | 1981-12-03 | 1985-07-18 | Electric Power Development Co. Ltd. | Production of high concentration of coal |
US4477259A (en) * | 1982-05-05 | 1984-10-16 | Alfred University Research Foundation, Inc. | Grinding mixture and process for preparing a slurry therefrom |
US4477260A (en) * | 1982-05-05 | 1984-10-16 | Alfred University Research Foundation, Inc. | Process for preparing a carbonaceous slurry |
GB2121819B (en) * | 1982-06-14 | 1985-03-27 | Smidth & Co As F L | Method of manufacturing a pumpable coal/liquid mixture |
-
1985
- 1985-11-16 JP JP25690085A patent/JPS62116692A/ja active Granted
-
1986
- 1986-11-13 AU AU65106/86A patent/AU572410B2/en not_active Ceased
- 1986-11-14 EP EP19860308894 patent/EP0223573B1/de not_active Expired
- 1986-11-14 DE DE8686308894T patent/DE3681123D1/de not_active Expired - Lifetime
- 1986-11-14 CA CA000523028A patent/CA1279477C/en not_active Expired - Lifetime
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10287522B2 (en) | 2013-01-31 | 2019-05-14 | General Electric Company | System and method for preparing coal water slurry |
Also Published As
Publication number | Publication date |
---|---|
AU572410B2 (en) | 1988-05-05 |
EP0223573A2 (de) | 1987-05-27 |
EP0223573A3 (en) | 1988-09-21 |
JPH0329275B2 (de) | 1991-04-23 |
JPS62116692A (ja) | 1987-05-28 |
CA1279477C (en) | 1991-01-29 |
AU6510686A (en) | 1987-05-21 |
DE3681123D1 (de) | 1991-10-02 |
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