EP0195619A2 - Desinfektions-, Reinigungs- und Spülverfahren und Zusammensetzungen - Google Patents

Desinfektions-, Reinigungs- und Spülverfahren und Zusammensetzungen Download PDF

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Publication number
EP0195619A2
EP0195619A2 EP86301874A EP86301874A EP0195619A2 EP 0195619 A2 EP0195619 A2 EP 0195619A2 EP 86301874 A EP86301874 A EP 86301874A EP 86301874 A EP86301874 A EP 86301874A EP 0195619 A2 EP0195619 A2 EP 0195619A2
Authority
EP
European Patent Office
Prior art keywords
peroxy compound
surfactant
ppm
sanitising
rinse
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP86301874A
Other languages
English (en)
French (fr)
Other versions
EP0195619A3 (de
Inventor
Andrew Mark Sedgwick
Richard Andrew Paulson
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Diversey Corp Canada
Original Assignee
Diversey Corp Canada
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Diversey Corp Canada filed Critical Diversey Corp Canada
Publication of EP0195619A2 publication Critical patent/EP0195619A2/de
Publication of EP0195619A3 publication Critical patent/EP0195619A3/de
Withdrawn legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3942—Inorganic per-compounds

Definitions

  • This invention relates to a sanitising/destaining/ rinsing process and compositions, more particularly for use in rinsing in spray washing machines, such as dish and glass washers.
  • the wash programme conventionally comprises an alkaline wash, followed by a final rinse in hot water containing a rinse additive. There may be additional pre-washes or pre-rinses to these two basic operations and they may be sub-divided.
  • the wash temperature is 60-65°C and the rinse temperature is 80-85°C.
  • wash and rinse temperatures were recommended by the National Sanitation Foundation in America in 1948/49 and the N.S.F. currently specify wash and rinsing conditions, including wash and rinse volumes, wash and rinse temperatures, wash and rinse pressures, together with minimum residence times in the rinse and wash processes for dish and glass washing machines.
  • the recommendations on temperatures are based on the amount of heat required for thermal sanitisation. In America, the standards are often included in local regulations, but they have not per se been adopted outside North America. In many instances, the wash and rinse temperatures are alone specified in local regulations and the use of these temperatures has provided an acceptable level of sanitising.
  • the sanitising action required once the temperatures have been reduced has been provided by the use of chlorine-release agents which are accepted as being capable of providing the necessary sanitising action.
  • the use of available chlorine as a sanitiser in the final rinse water has, however several drawbacks.
  • the first drawback is that if not carefully regulated the residual chloride can cause an increased level of corrosion.
  • Other drawbacks include the residues left on glassware and the odour in use.
  • a further disadvantage is that chlorine-release agents cannot easily be included in the rinse additive that must in any case be injected into the rinse line and, therefore, two products are required to be injected into the final rinse water.
  • the concentration at which the quaternary compounds need to be used causes undesirable side effects in spray washing processes. These include generation of foam, poor rinsing effects, absorption onto the surfaces, followed by reaction with anionic materials, such as tannins, which causes staining, and reaction with food soils causing problems in the washing process.
  • anionic materials such as tannins
  • Iodine-based product cause problems due to the reaction thereof with starch, widely present in food soil, and the fact that iodine can vaporise when used at temperatures above 40-45°C.
  • peroxy compounds have been recognized as bactericides for over a century they have never been widely used because of the slow rate of bacterial kill thereof and the high concentrations required. It was only following the production, or in situ generation, of peracid compounds, such as peracetic acid, that this type of chemical has become useful economically. However, it was quite unexpected that peroxy compounds would be effective at the low concentrations and short exposure times required for use in the rinsing sections of spray washing machines.
  • the present invention provides a sanitising/ destaining/rinsing process for use in a spray washing machine characterised in that it comprises using a peroxy compound in rinse water.
  • the rinse water also comprises a surfactant.
  • the peroxy compound need not always be used with a surfactant.
  • the peroxy compound preferably hydrogen peroxide
  • the peroxy compound is generally used following one or more alkaline wash cycles.
  • Sufficient peroxy compound may be used to provide up to 500 ppm available oxygen, preferably up to 50 ppm available oxygen, typically about 20 ppm available oxygen.
  • the present invention also provides the use of a peroxy compound as a sanitising/destaining/rinsing agent in rinse water of a spray washing machine.
  • the peroxy compound is used together with a surfactant- containing rinse aid following an alkaline wash.
  • the present invention further provides an aqueous sanitising/destaining/rinsing composition characterised in that it comprises a peroxy compound and a surfactant suitable for use in a rinse aid.
  • the peroxy compound will generally be used in the form of a combined composition which includes a surfactant together with the peroxy compound.
  • Such compositions when added to the rinse water of spray washing machines may provide effective rinsing and drying properties, together with effective biocidal activity even when the machine is operated at reduced temperatures.
  • the combination is preferably formulated as a liquid composition and the peroxy compound is preferably hydrogen peroxide.
  • peroxy compounds may be used, although for practical reasons they should be in a liquid form, and to prevent subsequent problems on rinsing should not include high levels or inorganic salts.
  • a stabiliser for the peroxy compound in the liquid composition will generally buffer the composition to a pH at which the peroxy compound is stable'(generally 2-to 5) and will also scavenge for metal ions which tend to destabilise the peroxy compound.
  • Suitable stabilisers include organic and inorganic acids, alkali metal pyrophosphates and salts of tin alone or together with compounds of magnesium or phosphorus. Any stabiliser is generally used in a conventional amount.
  • the peroxy compound is used in the combined composition together with a surfactant.
  • Preferred surfactants are weakly foaming non-ionic wetting agents which are, for example, ethylene oxide adducts to fatty alcohols or alkyl phenols or ethylene oxide adducts to polypropylene oxides of molecular weight from 500 to 2000, commonly called the "PLURONICS", or adducts of ethylene oxide and propylene oxide with mono- or multifunctional initiators, commonly alcohols or amines as described in the book “Non-ionic Surfactants” by SCHICK (published by Marcel Dekker, 1966) or adducts of ethylene oxide, propylene oxide and/or butylene oxide with fatty alcohols or alkyl phenols.
  • solubilisers which may be used in conventional amounts, include the low molecular weight alcohols typified by methanol, ethanol, isopropanol, propylene glycol, hexylene glycol and low molecular weight adducts of ethylene oxide and propylene oxide with mono- or multi- functional initiators, low molecular weight anionic compounds typified by the xylene, toluene and cumene sulphonates and low molecular weight alcohol phosphate esters or the phosphate esters of alcohol/ethylene oxide adducts.
  • compositions according to the present invention may contain sufficient peroxy compound to provide up to 20% available oxygen, preferably from 1 to 10% available oxygen, typically about 5% available oxygen.
  • the surfactant component may be present in amounts of up to 60% w/w, preferably from 10 to 50% w/w, typically about 20% w/w.
  • compositions may be produced by conventional means involving mixing the components in an appropriate order.
  • compositions are added to the rinse water of spray washing machines, thus providing in-use solutions.
  • up to 500 ppm preferably about 20 ppm, available oxygen, would commonly be present.
  • 500 ppm preferably about 75 ppm, surfactant would be provided.
  • the machine was used to wash plates artificially soiled with the bacteria Micrococcus caseolyticus (NCIB 3251) in a starch-based soil and conditioned overnight. This ensured that the soil was not completely removed by the washing process.
  • An unwashed control had a level of 10 5 to 10 6 bacteria.
  • the washed plates were swabbed to measure residual bacteria and the log decimal reduction in the number of bacteria was calculated following each rinsing process.
  • the following rinsing processes were used, the surfactant being Eth y lan CPG 660:-(1) Surfactant alone, at a concentration of 80 ppm, used at a wash temperature of 60°C and a rinse temperature of 80°C. These are the standard conditions referred to above and it is to be assumed that they provide adequate sanitising.
  • a value of at least 4 is desirable.
  • composition according to the present invention was evaluated:
  • This composition was evaluated at an in-use concentration of 400 ppm, generating 30 ppm AvO 2 , and its ability for rinsing, drying and sanitising measured and compared to a conventional system using the machine and wash programme detailed in Example 1.
  • compositions according to the present invention are provided.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)
EP86301874A 1985-03-15 1986-03-14 Desinfektions-, Reinigungs- und Spülverfahren und Zusammensetzungen Withdrawn EP0195619A3 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB858506735A GB8506735D0 (en) 1985-03-15 1985-03-15 Sanitising & rinsing process
GB8506735 1985-03-15

Publications (2)

Publication Number Publication Date
EP0195619A2 true EP0195619A2 (de) 1986-09-24
EP0195619A3 EP0195619A3 (de) 1988-09-07

Family

ID=10576042

Family Applications (1)

Application Number Title Priority Date Filing Date
EP86301874A Withdrawn EP0195619A3 (de) 1985-03-15 1986-03-14 Desinfektions-, Reinigungs- und Spülverfahren und Zusammensetzungen

Country Status (5)

Country Link
EP (1) EP0195619A3 (de)
AU (1) AU5469986A (de)
DK (1) DK118686A (de)
ES (1) ES8800339A1 (de)
GB (1) GB8506735D0 (de)

Cited By (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1991000044A1 (de) * 1989-06-24 1991-01-10 Henkel Kommanditgesellschaft Auf Aktien Verfahren zum betrieb einer geschirrspülmaschine und vorrichtung zum durchführen des verfahrens
US5122538A (en) * 1990-07-23 1992-06-16 Ecolab Inc. Peroxy acid generator
DE4124372C1 (en) * 1991-07-23 1992-10-29 Domex Aquatec Gmbh, 4600 Dortmund, De Chlorine-free rinsing compsn. for dishwashers - comprises low iron content potassium tri:phosphate, potassium hydroxide, sodium water glass, hydrogen peroxide and hydrated magnesium sulphate (-borax)
US5200189A (en) * 1991-07-23 1993-04-06 Ecolab Inc. Peroxyacid antimicrobial composition
US5437868A (en) * 1991-07-23 1995-08-01 Ecolab Inc. Peroxyacid antimicrobial composition
EP1026226A1 (de) * 1999-01-14 2000-08-09 Ecolab Inc. Säurische Sanitärwaschmittel
WO2001025388A1 (en) * 1999-09-30 2001-04-12 The Procter & Gamble Company Process for promoting sanitization of articles during post-wash stage of automatic dishwashing
US6326032B1 (en) 1998-11-18 2001-12-04 Ecolab Inc. Beverage manufacture and cold aseptic bottling using peroxyacid antimicrobial composition
US6545047B2 (en) 1998-08-20 2003-04-08 Ecolab Inc. Treatment of animal carcasses
US6627593B2 (en) 2001-07-13 2003-09-30 Ecolab Inc. High concentration monoester peroxy dicarboxylic acid compositions, use solutions, and methods employing them
US7754670B2 (en) 2005-07-06 2010-07-13 Ecolab Inc. Surfactant peroxycarboxylic acid compositions
US7771737B2 (en) 2004-01-09 2010-08-10 Ecolab Inc. Medium chain peroxycarboxylic acid compositions
US7816555B2 (en) 2003-01-17 2010-10-19 Ecolab Inc. Peroxycarboxylic acid compositions with reduced odor
US7832360B2 (en) 2000-12-15 2010-11-16 Ecolab Usa Inc. Method and composition for washing poultry during processing
US7887641B2 (en) 2004-01-09 2011-02-15 Ecolab Usa Inc. Neutral or alkaline medium chain peroxycarboxylic acid compositions and methods employing them
US8124132B2 (en) 2000-07-12 2012-02-28 Ecolab Usa Inc. Method and composition for inhibition of microbial growth in aqueous food transport and process streams
US8128976B2 (en) 2004-01-09 2012-03-06 Ecolab Usa Inc. Methods for washing poultry during processing with medium chain peroxycarboxylic acid compositions
US8187652B2 (en) 2004-01-09 2012-05-29 Ecolab Usa Inc. Methods for washing carcasses, meat, or meat products with medium chain peroxycarboxlyic acid compositions
US8246906B2 (en) 2000-04-28 2012-08-21 Ecolab Usa Inc. Antimicrobial composition
US8999175B2 (en) 2004-01-09 2015-04-07 Ecolab Usa Inc. Methods for washing and processing fruits, vegetables, and other produce with medium chain peroxycarboxylic acid compositions
US9511161B2 (en) 2004-01-09 2016-12-06 Ecolab Usa Inc. Methods for reducing the population of arthropods with medium chain peroxycarboxylic acid compositions
US9708256B2 (en) 2006-10-18 2017-07-18 Ecolab Usa Inc. Method for making a peroxycarboxylic acid
US11241658B2 (en) 2018-02-14 2022-02-08 Ecolab Usa Inc. Compositions and methods for the reduction of biofilm and spores from membranes

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6479454B1 (en) 2000-10-05 2002-11-12 Ecolab Inc. Antimicrobial compositions and methods containing hydrogen peroxide and octyl amine oxide
US7547421B2 (en) 2006-10-18 2009-06-16 Ecolab Inc. Apparatus and method for making a peroxycarboxylic acid

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB976511A (en) * 1960-05-02 1964-11-25 Henkel & Cie Gmbh Production of stable liquid concentrates containing active oxygen
DE1198800B (de) * 1963-01-12 1965-08-19 Henkel & Cie Gmbh Fluessige, lagerbestaendige, Aktivsauerstoff enthaltende Konzentrate
DE1279877B (de) * 1962-04-26 1968-10-10 Unilever Nv Verfahren zum mechanischen Geschirrspuelen
DE1617100A1 (de) * 1966-08-18 1971-02-18 Giulini Gmbh Geb Nachspuelmittel fuer Geschirr
US4130501A (en) * 1976-09-20 1978-12-19 Fmc Corporation Stable viscous hydrogen peroxide solutions containing a surfactant and a method of preparing the same
DE2744457A1 (de) * 1977-10-03 1979-04-12 Henkel Kgaa Verfahren zum bleichen von textilien im waeschetrockner
GB2072643A (en) * 1980-04-01 1981-10-07 Interox Chemicals Ltd Aqueous H2O2 bleach compositions
EP0086423A2 (de) * 1982-02-15 1983-08-24 Henkel Kommanditgesellschaft auf Aktien Mittel und Verfahren um Nachbehandeln gewaschener Wäsche
EP0087049A1 (de) * 1982-02-15 1983-08-31 Henkel Kommanditgesellschaft auf Aktien Desinfektionsmittelkonzentrat
EP0092932A1 (de) * 1982-04-27 1983-11-02 Interox Chemicals Limited Wasserstoffperoxid-Zusammensetzungen

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB976511A (en) * 1960-05-02 1964-11-25 Henkel & Cie Gmbh Production of stable liquid concentrates containing active oxygen
DE1279877B (de) * 1962-04-26 1968-10-10 Unilever Nv Verfahren zum mechanischen Geschirrspuelen
DE1198800B (de) * 1963-01-12 1965-08-19 Henkel & Cie Gmbh Fluessige, lagerbestaendige, Aktivsauerstoff enthaltende Konzentrate
DE1617100A1 (de) * 1966-08-18 1971-02-18 Giulini Gmbh Geb Nachspuelmittel fuer Geschirr
US4130501A (en) * 1976-09-20 1978-12-19 Fmc Corporation Stable viscous hydrogen peroxide solutions containing a surfactant and a method of preparing the same
DE2744457A1 (de) * 1977-10-03 1979-04-12 Henkel Kgaa Verfahren zum bleichen von textilien im waeschetrockner
GB2072643A (en) * 1980-04-01 1981-10-07 Interox Chemicals Ltd Aqueous H2O2 bleach compositions
EP0086423A2 (de) * 1982-02-15 1983-08-24 Henkel Kommanditgesellschaft auf Aktien Mittel und Verfahren um Nachbehandeln gewaschener Wäsche
EP0087049A1 (de) * 1982-02-15 1983-08-31 Henkel Kommanditgesellschaft auf Aktien Desinfektionsmittelkonzentrat
EP0092932A1 (de) * 1982-04-27 1983-11-02 Interox Chemicals Limited Wasserstoffperoxid-Zusammensetzungen

Cited By (36)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1991000044A1 (de) * 1989-06-24 1991-01-10 Henkel Kommanditgesellschaft Auf Aktien Verfahren zum betrieb einer geschirrspülmaschine und vorrichtung zum durchführen des verfahrens
US5122538A (en) * 1990-07-23 1992-06-16 Ecolab Inc. Peroxy acid generator
DE4124372C1 (en) * 1991-07-23 1992-10-29 Domex Aquatec Gmbh, 4600 Dortmund, De Chlorine-free rinsing compsn. for dishwashers - comprises low iron content potassium tri:phosphate, potassium hydroxide, sodium water glass, hydrogen peroxide and hydrated magnesium sulphate (-borax)
US5200189A (en) * 1991-07-23 1993-04-06 Ecolab Inc. Peroxyacid antimicrobial composition
US5314687A (en) * 1991-07-23 1994-05-24 Ecolab Inc. Peroxyacid antimicrobial composition
US5437868A (en) * 1991-07-23 1995-08-01 Ecolab Inc. Peroxyacid antimicrobial composition
US5489434A (en) * 1991-07-23 1996-02-06 Ecolab Inc. Peroxyacid antimicrobail composition
US6545047B2 (en) 1998-08-20 2003-04-08 Ecolab Inc. Treatment of animal carcasses
US9770040B2 (en) 1998-08-20 2017-09-26 Ecolab Usa Inc. Treatment of animal carcasses
US8043650B2 (en) 1998-08-20 2011-10-25 Ecolab Inc. Treatment of animal carcasses
US6326032B1 (en) 1998-11-18 2001-12-04 Ecolab Inc. Beverage manufacture and cold aseptic bottling using peroxyacid antimicrobial composition
EP1026226A1 (de) * 1999-01-14 2000-08-09 Ecolab Inc. Säurische Sanitärwaschmittel
WO2001025388A1 (en) * 1999-09-30 2001-04-12 The Procter & Gamble Company Process for promoting sanitization of articles during post-wash stage of automatic dishwashing
US8246906B2 (en) 2000-04-28 2012-08-21 Ecolab Usa Inc. Antimicrobial composition
US10342231B2 (en) 2000-07-12 2019-07-09 Ecolab Usa Inc. Method and composition for inhibition of microbial growth in aqueous food transport and process streams
US9247738B2 (en) 2000-07-12 2016-02-02 Ecolab Usa Inc. Method and composition for inhibition of microbial growth in aqueous food transport and process streams
US8124132B2 (en) 2000-07-12 2012-02-28 Ecolab Usa Inc. Method and composition for inhibition of microbial growth in aqueous food transport and process streams
US8020520B2 (en) 2000-12-15 2011-09-20 Ecolab Usa Inc. Method and composition for washing poultry during processing
US7832360B2 (en) 2000-12-15 2010-11-16 Ecolab Usa Inc. Method and composition for washing poultry during processing
US6627593B2 (en) 2001-07-13 2003-09-30 Ecolab Inc. High concentration monoester peroxy dicarboxylic acid compositions, use solutions, and methods employing them
US7816555B2 (en) 2003-01-17 2010-10-19 Ecolab Inc. Peroxycarboxylic acid compositions with reduced odor
US8999175B2 (en) 2004-01-09 2015-04-07 Ecolab Usa Inc. Methods for washing and processing fruits, vegetables, and other produce with medium chain peroxycarboxylic acid compositions
US9491965B2 (en) 2004-01-09 2016-11-15 Ecolab Usa Inc. Medium chain peroxycarboxylic acid compositions
US8128976B2 (en) 2004-01-09 2012-03-06 Ecolab Usa Inc. Methods for washing poultry during processing with medium chain peroxycarboxylic acid compositions
US8318188B2 (en) 2004-01-09 2012-11-27 Ecolab Usa Inc. Medium chain peroxycarboxylic acid compositions
US8758789B2 (en) 2004-01-09 2014-06-24 Ecolab Usa Inc. Medium chain peroxycarboxylic acid compositions
US7887641B2 (en) 2004-01-09 2011-02-15 Ecolab Usa Inc. Neutral or alkaline medium chain peroxycarboxylic acid compositions and methods employing them
US8057812B2 (en) 2004-01-09 2011-11-15 Ecolab Usa Inc. Medium chain peroxycarboxylic acid compositions
US8187652B2 (en) 2004-01-09 2012-05-29 Ecolab Usa Inc. Methods for washing carcasses, meat, or meat products with medium chain peroxycarboxlyic acid compositions
US9511161B2 (en) 2004-01-09 2016-12-06 Ecolab Usa Inc. Methods for reducing the population of arthropods with medium chain peroxycarboxylic acid compositions
US10568322B2 (en) 2004-01-09 2020-02-25 Ecolab Usa Inc. Medium chain peroxycarboxylic acid compositions
US7771737B2 (en) 2004-01-09 2010-08-10 Ecolab Inc. Medium chain peroxycarboxylic acid compositions
US9888684B2 (en) 2004-01-09 2018-02-13 Ecolab Usa Inc. Medium chain perosycarboxylic acid compositions
US7754670B2 (en) 2005-07-06 2010-07-13 Ecolab Inc. Surfactant peroxycarboxylic acid compositions
US9708256B2 (en) 2006-10-18 2017-07-18 Ecolab Usa Inc. Method for making a peroxycarboxylic acid
US11241658B2 (en) 2018-02-14 2022-02-08 Ecolab Usa Inc. Compositions and methods for the reduction of biofilm and spores from membranes

Also Published As

Publication number Publication date
ES8800339A1 (es) 1987-10-16
EP0195619A3 (de) 1988-09-07
DK118686D0 (da) 1986-03-14
DK118686A (da) 1986-09-16
AU5469986A (en) 1986-10-23
ES553053A0 (es) 1987-10-16
GB8506735D0 (en) 1985-04-17

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