EP0193832A1 - Method for the manufacture of waterproof leather or fur - Google Patents

Method for the manufacture of waterproof leather or fur Download PDF

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Publication number
EP0193832A1
EP0193832A1 EP86102381A EP86102381A EP0193832A1 EP 0193832 A1 EP0193832 A1 EP 0193832A1 EP 86102381 A EP86102381 A EP 86102381A EP 86102381 A EP86102381 A EP 86102381A EP 0193832 A1 EP0193832 A1 EP 0193832A1
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Prior art keywords
impregnating
leather
sulfosuccinic acid
weight
acid monoester
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EP86102381A
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German (de)
French (fr)
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EP0193832B1 (en
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Hans-Herbert Dr. Friese
Uwe Dr. Ploog
Wolfgang Prinz
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Henkel AG and Co KGaA
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Henkel AG and Co KGaA
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    • C—CHEMISTRY; METALLURGY
    • C14—SKINS; HIDES; PELTS; LEATHER
    • C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
    • C14C9/00—Impregnating leather for preserving, waterproofing, making resistant to heat or similar purposes
    • C—CHEMISTRY; METALLURGY
    • C14—SKINS; HIDES; PELTS; LEATHER
    • C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
    • C14C9/00—Impregnating leather for preserving, waterproofing, making resistant to heat or similar purposes
    • C14C9/04—Fixing tanning agents in the leather

Definitions

  • Stabilizing the licker liquor with anionic and nonionic emulsifiers such as alkyl sulfates, alkylarylsulfonates or fatty alcohol ethoxylates, is out of the question because of the increase in water absorbency.
  • the invention thus relates to a process for the production of waterproof leather or furs using sulfosuccinic acid monoesters in combination with impregnating and / or hydrophobizing greasing agents, characterized in that the leather or furs are subsequently impregnated in an aqueous liquor with impregnating and / or hydrophobizing agents Fatting agents which contain sulfosuccinic acid monoester salts with C 12 -C 24 fat residues are treated and fixed after acidification by adding a chromium and / or aluminum salt.
  • the sulfosuccinic acid monoester salts are preferably used in combination with impregnating fatliquoring agents. These include, in particular, oxidized or oxidized and partly sulfonated C 18 -C 26 hydrocarbons or C 32 -C 40 waxes, C P hosphor Textremono- 12 - C 24 - alkyl esters, partial esters of polycarboxylic acids such as CitronenTalkremono-C 16 -C 24 alkyl esters, Partial ester of Polyalcohols, such as sorbitan, glycerol or pentaerythritol C16-C24 fatty acid esters.
  • the proportion of sulfosuccinic acid monoester salts in the fatliquor combination is 10 to 60, preferably 20 to 40 percent by weight.
  • greasing agents are used in licker lubrication, depending on the type of leather, in an amount of 5 to 20 percent by weight, based on the shaved weight of the leather.
  • the leather When using the sulfosuccinic acid monoesters in combinations with neutral oils, such as long-chain hydrocarbons, chlorinated paraffin, animal and vegetable oils and fats or their methyl esters and chlorinated fatty acid methyl esters, the leather also has a reduced water absorbency if acidified after greasing and then with chromium and / or aluminum salts is fixed.
  • neutral oils such as long-chain hydrocarbons, chlorinated paraffin, animal and vegetable oils and fats or their methyl esters and chlorinated fatty acid methyl esters
  • fatty agents containing sulfosuccinic acid monoester salts can also be used in part in normal leaching with sulfated, sulfited and / or synthetic fatliquors based on chloroparaffin sulfonates, depending on the proportion of impregnating and / or hydrophobizing fatliquoring, a more or less pronounced water resistance is achieved.
  • the sulfosuccinic acid monoester salts are prepared in a known manner by esterification of maleic anhydride with approximately one equivalent of the desired ester ester component and subsequent reaction with an approximately equivalent to the maleic anhydride Amount of a sulfite or bisulfite, for example according to DE-OS 16 69 347. Fat residues with 12 to 24 carbon atoms and compounds containing hydroxyl groups are suitable as esterification components. The fat residues can be saturated or unsaturated.
  • fatty alcohols or fatty acid mono- or diglycerides for example C 12 -C 18 coconut fatty alcohol, C 16 -C 18 tallow alcohol, C 16 -C 18 tallow fatty acid monoglyceride, or from adducts of 1 to 6 mol of alkylene oxide with the aforementioned Fatty alcohols or fatty acid glycerides or fatty acids, e.g. the adduct of 2 to 3 moles of ethylene oxide with C 16 -C 18 tallow fatty alcohol or from 4 to 6 moles of ethylene oxide to a C 16 -C 24 fatty acid mixture or of 2 moles of ethylene oxide to a C 12 - C 18 fatty acid mixture.
  • the sulfosuccinic acid monoester salts are preferably prepared as sodium or ammonium salts, but other alkalis or organic amines can also be used as cations.
  • Water-soluble chromium and / or aluminum salts are used to fix the sulfosuccinic acid monoester salts.
  • the application amount is 1 to 10 percent by weight in the liquor.
  • the claimed process is carried out in such a way that the sulfosuccinic acid monoester salts and, if appropriate, further fatliquoring agents are used as a licker after the retanning and, if appropriate, dyeing and subsequent washing out of excess tanning agent.
  • High temperatures over 50 ° C can be avoided here.
  • the aftertreatment is initially carried out in a customary manner by acidification, preferably with formic acid, it being possible, if appropriate, to precede a brief treatment with a polyacrylate tanning agent. Then fix with the chrome and / or aluminum salts at about nH 3.5.
  • the claimed Fatliquors be well received by the leather and spread very evenly over the entire leather q uerites. They have a remarkable resistance to water and give the leather excellent waterproofness, especially under dynamic loads. The result is soft, firm-grain leather with a pleasantly slim handle, which is particularly suitable for the production of upper leather, clothing velor and fur velor.
  • the sheepskins are worked up to the hair color as usual via switches, laundry, pimples / tanning, retanning and greasing.
  • the velor color is impregnated according to the following procedure.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Treatment And Processing Of Natural Fur Or Leather (AREA)
  • Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
  • Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
  • Gloves (AREA)
  • Insulated Conductors (AREA)

Abstract

A process for leather tanning having the improvement of imparting waterproof properties to the leather by incorporating a sulfosuccinic monoester in the fatliquor.

Description

Zur Herstellung wasserdichter Leder oder Pelze sind insbesondere drei Verfahrensprinzipien bekannt:

  • 1) Imprägnierung durch Einlagerung wasserunlöslicher Substanzen, z.B. feste Fette, Wachse oder spezielle Polymere.
  • 2) Imprägnierung durch Einlagerung wasserquellender Substanzen, die bei Wasseraufnahme hochviskose Emulsionen bilden und die Faserzwischenräume des Leders verstopfen, z.B. spezielle Emulgatoren vom Wässer-in-öl-(W/O)-Typ.
  • 3) Behandlung mit hydrophobierend wirkenden Substanzen, z.B. Aluminium- und Chromkomplexe, Silikone oder organische Fluor-Verbindungen.
Three process principles are known in particular for producing waterproof leather or furs:
  • 1) Impregnation by storing water-insoluble substances, e.g. solid fats, waxes or special polymers.
  • 2) Impregnation by storing water-swelling substances that form highly viscous emulsions when water is absorbed and clog the interstices of the leather, eg special emulsifiers of the water-in-oil (W / O) type.
  • 3) Treatment with substances having a hydrophobic effect, for example aluminum and chromium complexes, silicones or organic fluorine compounds.

Diese Maßnahmen können auch im Zusammenhang mit einer üblichen Lickerung unter Verwendung gebräuchlicher Fettungsmittel durchgeführt, wobei die genannten Mittel in der Lickerflotte eingesetzt werden.These measures can also be carried out in connection with a conventional seepage using customary lubricants, the agents mentioned being used in the liquor fleet.

In der Praxis wird häufig eine Kombination der unter 2) und 3) genannten Maßnahmen angewandt, wobei aus wirtschaftlichen und ökologischen Gründen bevorzugt im Walkfaß in wäßriger Flotte gearbeitet wird. Dabei erfolgt eine Umwandlung der W/0-Emulgatoren in hydrophobierende Metallkomplexsalze durch eine Fixierung mit Chrom- bzw. Aluminiumsalzen. Dieses Verfahren weist aber Nachteile auf, da wegen der Instabilität der gebräuchlichen Lickeremulsionen die Imprägnierung bei relativ hohen pH-Werten (>6) durchgeführt werden muß, um ein oberflächliches Ausfallen der Fettungsmittel und damit Verschmierungen zu vermeiden. Außerdem ist bei diesem Verfahren in der Regel eine hohe Temperatur der Lickerflotte von ca. 60 °C erforderlich, was leicht zu einer Losnarbigkeit des Leders führt. Außerdem zeigen die in der Praxis erhaltenen Penetrometerwerte häufig starke Schwankungen infolge einer ungleichmäßigen Fettverteilung durch den Lederquerschnitt, so daß eine aufwendige Nachbehandlung des Leders durch Spritzen, Gießen oder Plüschen notwendig werden kann.In practice, a combination of the measures mentioned under 2) and 3) is often used, preference being given to working in a drum in an aqueous liquor for economic and ecological reasons. The W / 0 emulsifiers are converted into hydrophobizing metal complex salts by a fixation with Chrome or aluminum salts. However, this method has disadvantages, since, due to the instability of the usual licker emulsions, the impregnation must be carried out at relatively high pH values (> 6) in order to avoid superficial precipitation of the greasing agents and thus smearing. In addition, this process generally requires a high temperature of the licker liquor of approximately 60 ° C., which easily leads to a loose grain of the leather. In addition, the penetrometer values obtained in practice often show large fluctuations as a result of an uneven fat distribution through the leather cross section, so that an expensive aftertreatment of the leather by spraying, pouring or plushing may be necessary.

Eine Stabilisierung der Lickerflotte mit anionischen und nichtionischen Emulgatoren, wie Alkylsulfaten, Alkylarylsulfonaten oder Fettalkoholethoxylaten kommt wegen der Erhöhung der Wasserzügigkeit nicht in Frage.Stabilizing the licker liquor with anionic and nonionic emulsifiers, such as alkyl sulfates, alkylarylsulfonates or fatty alcohol ethoxylates, is out of the question because of the increase in water absorbency.

Aus DE-OS 16 69 347 ist die Anwendung von in Nasser emul- gierbaren Sulfobernsteinsäureestern zum Fetten von Leder bekannt, wobei jedoch keine Wasserdichteffekte erzielt werden.DE-A 16 69 347 the use of emulsified g ierbaren in Nasser sulfosuccinic is known for oiling leather, although no waterproof effects.

In der älteren Anmeldung P 34 19 405.3 wird ein Verfahren zur Herstellung von Leder und Pelzen beschrieben, wobei als Fettungsmittel in der Gerbflotte eine Kombination von Sulfobernsteinsäureestern mit bestimmten anionischen oder nichtionischen Emulgatoren während der Chrom- oder Aluminiumgerbung bzw. -Machgerbung angewendet wird. Auch bei diesem Verfahren wird ein Wasserdichteffekt nicht erzielt.In the earlier application P 34 19 405.3, a process for the production of leather and furs is described, a combination of sulfosuccinic acid esters with certain anionic or nonionic emulsifiers during chrome or aluminum tanning or light tanning being used as the fatliquor in the tanning liquor. A waterproof effect is not achieved with this method either.

Es wurde nun die überraschende Feststellung gemacht, daß mit Sulfobernsteinsäuremonoestern gefettete Leder bei hoher Weichheit eine verminderte Wasserzügigkeit aufweisen, wenn nach dem Absäuern der Fettung eine Fixierung mit Chrom- und/oder Aluminiumsalzen vorgenommen wird.It has now been made the surprising finding that leather greased with sulfosuccinic acid monoesters, with high softness, has a reduced water absorbency if fixation with chromium and / or aluminum salts is carried out after acidification of the greasing.

Damit ist es möglich, unter Mitverwendung von Sulfobernsteinsäuremonoestern bei der imprägnierenden und/oder hydrophobierenden Fettung die Stabilität der Lickeremulsionen so zu verbessern, daß die beschriebenen Nachteile der bisherigen Verfahren nicht auftreten.It is thus possible, with the use of sulfosuccinic acid monoesters in the impregnating and / or hydrophobic greasing, to improve the stability of the licker emulsions in such a way that the disadvantages of the previous processes described do not occur.

Gegenstand der Erfindung ist somit ein Verfahren zur Herstellung wasserdichter Leder oder Pelze unter Verwendung von Sulfobernsteinsäuremonoestern in Kombination mit imprägnierenden und/oder hydrophobierenden Fettungsmitteln, dadurch gekennzeichnet, daß man die Leder oder Pelze im Anschluß an die Nachgerbung in wäßriger Flotte mit imprägnierenden und/oder hydrophobierenden Fettungsmitteln, die Sulfobernsteinsäuremonoester-Salze mit C12-C24-Fettresten enthalten, behandelt und nach Absäuern durch Zugabe eines Chrom-und/oder Aluminiumsalzes fixiert.The invention thus relates to a process for the production of waterproof leather or furs using sulfosuccinic acid monoesters in combination with impregnating and / or hydrophobizing greasing agents, characterized in that the leather or furs are subsequently impregnated in an aqueous liquor with impregnating and / or hydrophobizing agents Fatting agents which contain sulfosuccinic acid monoester salts with C 12 -C 24 fat residues are treated and fixed after acidification by adding a chromium and / or aluminum salt.

Die Sulfobernsteinsäuremonoester-Salze werden vorzugsweise in Kombination mit imprägnierenden Fettungsmitteln angewendet. Hierzu zählen insbesondere oxidierte oder oxidierte und teilsulfierte C18-C26-Kohlenwasserstoffe oder C32-C40-wachse, Phosphorsäuremono-C 12-C 24- alkylester, Partialester von Polycarbonsäuren, wie Citronensäuremono-C16-C24-alkylester, Partialester von Polyalkoholen, wie Sorbitan-, Glyzerin- oder Pentaerythrit-C16-C24-fettsäureester.The sulfosuccinic acid monoester salts are preferably used in combination with impregnating fatliquoring agents. These include, in particular, oxidized or oxidized and partly sulfonated C 18 -C 26 hydrocarbons or C 32 -C 40 waxes, C P hosphorsäuremono- 12 - C 24 - alkyl esters, partial esters of polycarboxylic acids such as Citronensäuremono-C 16 -C 24 alkyl esters, Partial ester of Polyalcohols, such as sorbitan, glycerol or pentaerythritol C16-C24 fatty acid esters.

In der Fettungsmittel-Kombination beträgt der Anteil der Sulfobernsteinsäuremonoester-Salze 10 bis 60, vorzugsweise 20 bis 40 Gewichtsprozent. Derartige Fettungsmittel werden bei der Lickerfettung je nach Ledertyp in einer Menge von 5 bis 20 Gewichtsprozent, bezogen auf das Falzgewicht der Leder, eingesetzt.The proportion of sulfosuccinic acid monoester salts in the fatliquor combination is 10 to 60, preferably 20 to 40 percent by weight. Such greasing agents are used in licker lubrication, depending on the type of leather, in an amount of 5 to 20 percent by weight, based on the shaved weight of the leather.

Bei Verwendung der Sulfobernsteinsäuremonoester in Kombinationen mit Neutralölen, wie langkettige Kohlenwasserstoffe, Chlorparaffin, tierische und vegetabile öle und Fette bzw. deren Methylester und chlorierte Fettsäuremethylester, als Fettungsmittel tritt ebenfalls eine verminderte Wasserzügigkeit der Leder ein, wenn nach der Fettung abgesäuert und danach mit Chrom-und/oder Aluminiumsalzen fixiert wird.When using the sulfosuccinic acid monoesters in combinations with neutral oils, such as long-chain hydrocarbons, chlorinated paraffin, animal and vegetable oils and fats or their methyl esters and chlorinated fatty acid methyl esters, the leather also has a reduced water absorbency if acidified after greasing and then with chromium and / or aluminum salts is fixed.

Die genannten Sulfobernsteinsäuremonoester-Salze enthaltenden Fettungsmittel können auch anteilig in einer normalen Lickerfettung mit sulfatierten, sulfitierten und/oder synthetischen Fettungsmitteln auf Basis Chlorparaffinsulfonaten mitverwendet werden, wobei je nach Anteil der imprägnierenden und/oder hydrophobierenden Fettungsmittel eine mehr oder weniger stark ausgeprägte Wasserdichtigkeit erzielt wird.The above-mentioned fatty agents containing sulfosuccinic acid monoester salts can also be used in part in normal leaching with sulfated, sulfited and / or synthetic fatliquors based on chloroparaffin sulfonates, depending on the proportion of impregnating and / or hydrophobizing fatliquoring, a more or less pronounced water resistance is achieved.

Die Herstellung der Sulfobernsteinsäuremonoester-Salze erfolgt in bekannter Weise durch Veresterung von Maleinsäureanhydrid mit ca. einem Äquivalent der gewünschten Veresterunaskomponente und anschließende Umsetzung mit einer dem Maleinsäureanhydrid annähernd äquivalenten Menge eines Sulfits oder Bisulfits, z.B. entsprechend DE-OS 16 69 347. Als Veresterungskomponente kommen Fettreste mit 12 bis 24 C-Atomen sowie Hydroxygruppen enthaltende Verbindungen in Betracht. Die Fettreste können gesättigt oder ungesättigt sein. Sie können sich herleiten von Fettalkoholen oder Fettsäuremono- oder -diglyceriden, z.B. C12-C18-Kokosfettalkohol, C16-C18-Talgalkohol, C16-C18-Talgfettsäuremonoglycerid, oder von Addukten von 1 bis 6 Mol Alkylenoxid an die genannten Fettalkohole oder Fettsäureglyceride oder an Fettsäuren, z.B. das Addukt von 2 bis 3 Mol Ethylenoxid an C16-C18-Talgfettalkohol oder von 4 bis 6 Mol Ethylenoxid an ein C16-C24-Fettsäuregemisch oder von 2 Mol Ethylenoxid an ein C12-C18-Fettsäuregemisch. Die Sulfobernsteinsäuremonoester-Salze werden vorzugsweise als Natrium- oder Ammoniumsalze hergestellt, doch kommen als Kationen auch andere Alkalien oder organische Amine in Betracht.The sulfosuccinic acid monoester salts are prepared in a known manner by esterification of maleic anhydride with approximately one equivalent of the desired ester ester component and subsequent reaction with an approximately equivalent to the maleic anhydride Amount of a sulfite or bisulfite, for example according to DE-OS 16 69 347. Fat residues with 12 to 24 carbon atoms and compounds containing hydroxyl groups are suitable as esterification components. The fat residues can be saturated or unsaturated. They can be derived from fatty alcohols or fatty acid mono- or diglycerides, for example C 12 -C 18 coconut fatty alcohol, C 16 -C 18 tallow alcohol, C 16 -C 18 tallow fatty acid monoglyceride, or from adducts of 1 to 6 mol of alkylene oxide with the aforementioned Fatty alcohols or fatty acid glycerides or fatty acids, e.g. the adduct of 2 to 3 moles of ethylene oxide with C 16 -C 18 tallow fatty alcohol or from 4 to 6 moles of ethylene oxide to a C 16 -C 24 fatty acid mixture or of 2 moles of ethylene oxide to a C 12 - C 18 fatty acid mixture. The sulfosuccinic acid monoester salts are preferably prepared as sodium or ammonium salts, but other alkalis or organic amines can also be used as cations.

Zur Fixierung der Sulfobernsteinsäuremonoester-Salze dienen wasserlösliche Chrom- un/oder Aluminiumsalze. Bevorzugt werden basische Chrom- oder Aluminiumsalze oder deren Mischungen, wie sie auch als Ledergerbstoffe verwendet werden. Die Anwendungsmenge beträgt 1 bis 10 Gewichtsprozent in der Flotte.Water-soluble chromium and / or aluminum salts are used to fix the sulfosuccinic acid monoester salts. Basic chromium or aluminum salts or mixtures thereof, as are also used as leather tanning agents, are preferred. The application amount is 1 to 10 percent by weight in the liquor.

Das beanspruchte Verfahren wird in der Weise durchgeführt, daß die Sulfobernsteinsäuremonoester-Salze und gegebenenfalls weiteren Fettungsmittel im Anschluß an die Nachgerbung und gegebenenfalls Färbung und nachfolgendes Auswaschen überschüssigen Gerbmittels als Licker angewendet werden. Hohe Temperaturen über 50 °C können hierbei vermieden werden. Die Nachbehandlung erfolgt zunächst in üblicher Weise durch Absäuern, vorzugsweise mit Ameisensäure, wobei gegebenenfalls eine kurze Behandlung mit einem Polyacrylat-Gerbstoff vorgeschaltet werden kann. Danach erfolgt Fixierung mit den Chrom- und/oder Aluminiumsalzen bei etwa nH 3,5.The claimed process is carried out in such a way that the sulfosuccinic acid monoester salts and, if appropriate, further fatliquoring agents are used as a licker after the retanning and, if appropriate, dyeing and subsequent washing out of excess tanning agent. High temperatures over 50 ° C can be avoided here. The aftertreatment is initially carried out in a customary manner by acidification, preferably with formic acid, it being possible, if appropriate, to precede a brief treatment with a polyacrylate tanning agent. Then fix with the chrome and / or aluminum salts at about nH 3.5.

Die beanspruchten Fettungsmittel werden vom Leder gut aufgenommen und verteilen sich sehr gleichmäßig über den gesamten Lederquerschnitt. Sie besitzen eine bemerkenswerte Beständigkeit gegen Wasser und verleihen dem Leder eine hervorragende Wasserdichtigkeit, insbesondere auch unter dynamischer Belastung. Man erhält weiche, festnarbige Leder mit angenehm schmalzigem Griff, die sich besonders zur Herstellung von Schuhoberleder, Bekleidungsvelour und Pelzvelour eignen.The claimed Fatliquors be well received by the leather and spread very evenly over the entire leather q uerschnitt. They have a remarkable resistance to water and give the leather excellent waterproofness, especially under dynamic loads. The result is soft, firm-grain leather with a pleasantly slim handle, which is particularly suitable for the production of upper leather, clothing velor and fur velor.

Beispiel 1example 1 RindoberlederCowhide

In üblicher Weise, jedoch ohne Zusätze anionischer Tenside, chromgegerbte Rind-Wet-blue, pH 3,8, Falzstärke 1,8 mm, werden wie folgend weiterbehandelt:

Figure imgb0001
Figure imgb0002
Figure imgb0003
Figure imgb0004
 In a conventional manner, but without the addition of anionic surfactants, chrome-tanned beef wet blue, pH 3.8, fold thickness 1.8 mm, the treatment is continued as follows:
Figure imgb0001
Figure imgb0002
Figure imgb0003
Figure imgb0004

Beispiel 2Example 2 Rindoberleder, WaterproofCowhide leather, waterproof

Figure imgb0005
Figure imgb0005
Figure imgb0006
Figure imgb0006
Figure imgb0007
Figure imgb0007

Beispiel 3Example 3 Modischer Rindoberleder-SoftytypFashionable cowhide softy type

Figure imgb0008
Figure imgb0008
Figure imgb0009
Figure imgb0009
Figure imgb0010
Figure imgb0010

Beispiel 4Example 4 SchafbekleidungsvelourSheep clothing velor

Figure imgb0011
Figure imgb0011
Figure imgb0012
Figure imgb0012
Figure imgb0013
Figure imgb0013

Beisiel 5Example 5 PelzvelourFur velor Ausgangsmaterial: Luftgetrocknete SchaffelleStarting material: air-dried sheepskins

Die Schaffelle werden bis zur Haarfarbe wie üblich über Weiche, Wäsche, Pickel/Gerbung, Nachgerbung und Fettung gearbeitet. In der Velourfarbe erfolgt nach nachstehender Arbeitsweise die Imprägnierung.

Figure imgb0014
The sheepskins are worked up to the hair color as usual via switches, laundry, pimples / tanning, retanning and greasing. The velor color is impregnated according to the following procedure.
Figure imgb0014

Claims (7)

1. Verfahren zur Herstellung wasserdichter Leder oder Pelze unter Verwendung von Sulfobernsteinsäuremonoestern in Kombination mit imprägnierenden und/oder hydrophobierenden Fettungsmitteln, dadurch gekennzeichnet, daß man die Leder oder Pelze im Anschluß an die Nachgerbung in wäßriger Flotte mit imprägnierenden und/oder hydrophobierenden Fettungsmitteln, die Sulfobernsteinsäuremonoester-Salze mit C12-C24-Fettresten enthalten, behandelt und nach Absäuern durch Zugabe eines Chrom- und/oder Aluminiumsalzes fixiert.1. A process for the production of waterproof leathers or skins using sulfosuccinic acid monoesters in combination with impregnating and / or hydrophobicizing fat-liquoring agents, characterized in that the leather or pelts subsequent to retanning in an aqueous liquor with impregnating and / or hydro-p hobierenden fatliquors one, containing the sulfosuccinic acid monoester salts with C12-C24 fat residues, treated and fixed after acidification by adding a chromium and / or aluminum salt. 2. Verfahren nach Anspruch 1, dadurch gekennzeichnet, daß die Sulfobernsteinsäuremonoester-Salze in Kombination mit imprägnierenden Fettungsmitteln angewendet werden.2. The method according to claim 1, characterized in that the sulfosuccinic acid monoester salts are used in combination with impregnating fatliquoring agents. 3. Verfahren nach Anspruch 2, dadurch gekennzeichnet, daß die imprägnierenden Fettungsmittel ausgewählt sind aus der Gruppe oxidierte oder oxidierte und teilsulfierte C18-C26-Kohlenwasserstoffe oder C32-C40-Wachse, Phosphorsäuremono-C12-C24-alkylester, Citronensäuremono-C16-C24-alkylester, Sorbitan-, Glyzerin- oder Pentaerythrit-C16-C24-fettsäureester.3. The method according to claim 2, characterized in that the impregnating fatliquors are selected from the group of oxidized or oxidized and partially sulfonated C 18 -C 26 hydrocarbons or C 32 -C 40 waxes, phosphoric acid mono-C 12 -C 24 alkyl esters, Citric acid mono-C 16 -C 24 alkyl esters, sorbitan, glycerol or pentaerythritol C 16 -C 24 fatty acid esters. 4. Verfahren nach Anspruch 2 oder 3, dadurch gekennzeichnet, daß der Anteil der Sulfobernsteinsäuremonoester-Salze an der gesamten Fettungsmittel-Kombination 10 bis 60,.vorzugsweise 20 bis 40 Gewichtsprozent beträgt.4. The method according to claim 2 or 3, characterized in that the proportion of sulfosuccinic acid monoester salts in the total fatliquor combination is 10 to 60, preferably 20 to 40 percent by weight. 5. Verfahren nach Anspruch 1 bis 4, dadurch gekennzeichnet, daß das Fettungsmittel in einer Menge von 5 bis 20 Gewichtsprozent, bezogen auf das Falzgewicht der Leder oder Pelze, angewendet wird.5. The method according to claim 1 to 4, characterized in that the fatliquor is used in an amount of 5 to 20 percent by weight, based on the shaved weight of the leather or fur. 6. Verfahren nach Anspruch 1 bis 5, dadurch gekennzeichnet, daß die Fixierung mit basischen Chrom-und/oder Aluminiumgerbstoffen in einer Menge von 1 bis 10 Gewichtsprozent, bezogen auf die Flotte, durchgeführt wird.6. The method according to claim 1 to 5, characterized in that the fixation with basic chromium and / or aluminum tannins in an amount of 1 to 10 percent by weight, based on the liquor, is carried out. 7. Verfahren nach Anspruch 1 bis 6, dadurch gekennzeichnet, daß die imprägnierenden, Sulfobernsteinsäuremonoester-Salze enthaltenden Fettungsmittel mit üblichen sulfatierten, sulfitierten und/oder synthetischen Fettungsmitteln kombiniert werden.7. The method according to claim 1 to 6, characterized in that the impregnating, sulfosuccinic acid monoester salts containing fatliquor are combined with conventional sulfated, sulfited and / or synthetic fatliquoring agents.
EP86102381A 1985-03-01 1986-02-24 Method for the manufacture of waterproof leather or fur Expired EP0193832B1 (en)

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AT86102381T ATE36349T1 (en) 1985-03-01 1986-02-24 PROCESS FOR MAKING WATERPROOF LEATHER OR FUR.

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DE3507241 1985-03-01
DE19853507241 DE3507241A1 (en) 1985-03-01 1985-03-01 METHOD FOR PRODUCING WATERPROOF LEATHER OR FUR

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EP (1) EP0193832B1 (en)
JP (1) JPS61211399A (en)
AT (1) ATE36349T1 (en)
BR (1) BR8600857A (en)
CA (1) CA1256655A (en)
DE (2) DE3507241A1 (en)
ES (1) ES8706211A1 (en)
IN (1) IN166295B (en)
MX (1) MX164625B (en)
TR (1) TR22674A (en)

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EP0324536A1 (en) * 1988-01-07 1989-07-19 Exxon Chemical Patents Inc. Improved leather
EP0362134A2 (en) * 1988-09-28 1990-04-04 Ciba-Geigy Ag Leather treating agent
WO1993005188A1 (en) * 1991-09-03 1993-03-18 Henkel Kommanditgesellschaft Auf Aktien Aqueous dispersions of novel amphiphilic co-oligomers for imparting a washing and cleaning-resistant finish to leather and pelts and their use
WO1995019452A1 (en) * 1994-01-12 1995-07-20 Henkel Kommanditgesellschaft Auf Aktien Use of aminopropionic acid derivatives for the fatty treatment of leather
US5489389A (en) * 1992-07-14 1996-02-06 Henkel Kommanditgesellschaft Auf Aktien New leather oiling preparations and their use
US5567343A (en) * 1992-07-14 1996-10-22 Henkel Kommanditgesellschaft Auf Aktien New leather oiling preparations and their use
WO1997002240A1 (en) * 1995-07-04 1997-01-23 Henkel Kommanditgesellschaft Auf Aktien Sulfosuccinates used as leather-stuffing agents and as cleaning agents
EP0761823A1 (en) * 1995-07-26 1997-03-12 Hans J. Scheen Leather tanning processes and the products thereof
US5683611A (en) * 1994-01-12 1997-11-04 Henkel Kommanditgesellschaft Auf Aktien Preparations for the oiling of leather
US5728313A (en) * 1994-02-18 1998-03-17 Henkel Corporation Leather oiling compositions and their use
WO2002085845A2 (en) * 2001-03-08 2002-10-31 Basf Aktiengesellschaft Mixtures of sulfogroup-containing esters of polybasic organic acids with long-chain alkanols
US10947605B2 (en) 2016-01-12 2021-03-16 Fraunhofer-Gesellschaft Zur Forderung Der Angewand Method for hydrophobising leather, and leather produced by means of same

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DE3620780A1 (en) * 1986-06-20 1987-12-23 Henkel Kgaa LUBRICANTS BASED ON SULPHONIC ACID MONOAMIDES
DE3909614A1 (en) * 1989-03-23 1990-09-27 Zschimmer & Schwarz Gmbh & Co Process for fatliquoring and hydrophobicising leather and fur skins
US5069935A (en) * 1990-11-07 1991-12-03 Wilson Sporting Goods Co. Method of making water-repellent leather game ball
DE4214150A1 (en) * 1992-04-29 1993-11-11 Stockhausen Chem Fab Gmbh Process for the hydrophobization of materials of fibrous structure and means for carrying out the process
DE4240159A1 (en) * 1992-11-30 1994-06-01 Henkel Kgaa Sulphited fatty substances with a reduced content of free hydrogen sulphite
US6123632A (en) * 1998-11-02 2000-09-26 Spalding Sports Worldwide, Inc. Game ball with improved moisture resistance
US7066852B1 (en) 1998-11-02 2006-06-27 Callaway Golf Company Game ball with improved moisture resistance
US6726582B1 (en) * 2000-01-11 2004-04-27 Classic Sport Companies, Inc. Sport ball having improved surface and method for manufacture thereof
DE10012722A1 (en) * 2000-03-16 2001-09-20 Basf Ag Mixtures of di- or tri-basic carboxylic acid monoesters with OH group free 18-45 C ethers and esters, useful for leather treatment, contain up to 85 wt.% ether groups and up to 16 wt.% ester groups
KR100469808B1 (en) * 2002-07-27 2005-02-02 김홍립 manufacture method of a section dyeing leather
KR100617978B1 (en) * 2006-03-08 2006-08-28 한국신발피혁연구소 The development of cow like split leather by steer hide
CN103060483B (en) * 2013-01-08 2015-01-28 四川大学 Double waterproof chromium-free tanned sheep fur and its making method
CN114622043B (en) * 2022-04-13 2023-12-01 瑞泰(漳浦)皮业有限公司 Manufacturing method of waterproof leather with head layer

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Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0324536A1 (en) * 1988-01-07 1989-07-19 Exxon Chemical Patents Inc. Improved leather
US5457835A (en) * 1988-01-07 1995-10-17 Exxon Chemical Patents Inc. Leather
EP0362134A2 (en) * 1988-09-28 1990-04-04 Ciba-Geigy Ag Leather treating agent
EP0362134A3 (en) * 1988-09-28 1992-01-08 Ciba-Geigy Ag Leather treating agent
WO1993005188A1 (en) * 1991-09-03 1993-03-18 Henkel Kommanditgesellschaft Auf Aktien Aqueous dispersions of novel amphiphilic co-oligomers for imparting a washing and cleaning-resistant finish to leather and pelts and their use
US5501707A (en) * 1991-09-03 1996-03-26 Henkel Kommanditgesellschaft Auf Aktien Aqueous dispersions of new amphiphilic co-oligomers for the washing- and cleaning-resistant oiling of leather and skins and their use
US5741434A (en) * 1992-07-14 1998-04-21 Henkel Kommanditgesellschaft Auf Aktien Leather oiling preparations and their use
US5489389A (en) * 1992-07-14 1996-02-06 Henkel Kommanditgesellschaft Auf Aktien New leather oiling preparations and their use
US5567343A (en) * 1992-07-14 1996-10-22 Henkel Kommanditgesellschaft Auf Aktien New leather oiling preparations and their use
WO1995019452A1 (en) * 1994-01-12 1995-07-20 Henkel Kommanditgesellschaft Auf Aktien Use of aminopropionic acid derivatives for the fatty treatment of leather
US5683611A (en) * 1994-01-12 1997-11-04 Henkel Kommanditgesellschaft Auf Aktien Preparations for the oiling of leather
US5728313A (en) * 1994-02-18 1998-03-17 Henkel Corporation Leather oiling compositions and their use
WO1997002240A1 (en) * 1995-07-04 1997-01-23 Henkel Kommanditgesellschaft Auf Aktien Sulfosuccinates used as leather-stuffing agents and as cleaning agents
EP0761823A1 (en) * 1995-07-26 1997-03-12 Hans J. Scheen Leather tanning processes and the products thereof
WO2002085845A2 (en) * 2001-03-08 2002-10-31 Basf Aktiengesellschaft Mixtures of sulfogroup-containing esters of polybasic organic acids with long-chain alkanols
WO2002085845A3 (en) * 2001-03-08 2003-12-04 Basf Ag Mixtures of sulfogroup-containing esters of polybasic organic acids with long-chain alkanols
US10947605B2 (en) 2016-01-12 2021-03-16 Fraunhofer-Gesellschaft Zur Forderung Der Angewand Method for hydrophobising leather, and leather produced by means of same

Also Published As

Publication number Publication date
DE3507241A1 (en) 1986-09-04
US4755187A (en) 1988-07-05
IN166295B (en) 1990-04-07
ES552548A0 (en) 1987-05-16
ES8706211A1 (en) 1987-05-16
BR8600857A (en) 1986-11-11
ATE36349T1 (en) 1988-08-15
EP0193832B1 (en) 1988-08-10
DE3660494D1 (en) 1988-09-15
CA1256655A (en) 1989-07-04
JPH0574640B2 (en) 1993-10-18
TR22674A (en) 1988-02-26
JPS61211399A (en) 1986-09-19
MX164625B (en) 1992-09-10

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