EP0191707B1 - Procédé d'obtention par la métallurgie des poudres d'un matériau à base d'alliage d'aluminium et d'au moins une céramique destiné à la confection de pièces soumises à frottement - Google Patents
Procédé d'obtention par la métallurgie des poudres d'un matériau à base d'alliage d'aluminium et d'au moins une céramique destiné à la confection de pièces soumises à frottement Download PDFInfo
- Publication number
- EP0191707B1 EP0191707B1 EP86420032A EP86420032A EP0191707B1 EP 0191707 B1 EP0191707 B1 EP 0191707B1 EP 86420032 A EP86420032 A EP 86420032A EP 86420032 A EP86420032 A EP 86420032A EP 0191707 B1 EP0191707 B1 EP 0191707B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- ceramic
- friction
- powder
- process according
- solid lubricant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000919 ceramic Substances 0.000 title claims description 17
- 239000000463 material Substances 0.000 title claims description 17
- 238000000034 method Methods 0.000 title claims description 11
- 238000004519 manufacturing process Methods 0.000 title claims description 9
- 229910052782 aluminium Inorganic materials 0.000 title description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title description 4
- 239000004411 aluminium Substances 0.000 title description 2
- 229910045601 alloy Inorganic materials 0.000 claims description 12
- 239000000956 alloy Substances 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 10
- 229910000838 Al alloy Inorganic materials 0.000 claims description 9
- 239000000843 powder Substances 0.000 claims description 9
- 239000007787 solid Substances 0.000 claims description 9
- 239000000314 lubricant Substances 0.000 claims description 8
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 6
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 6
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 5
- 229910052593 corundum Inorganic materials 0.000 claims description 5
- 239000010431 corundum Substances 0.000 claims description 5
- 229910002804 graphite Inorganic materials 0.000 claims description 5
- 239000010439 graphite Substances 0.000 claims description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- 238000000889 atomisation Methods 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 3
- 238000004663 powder metallurgy Methods 0.000 claims description 3
- 238000005245 sintering Methods 0.000 claims description 3
- 229910052582 BN Inorganic materials 0.000 claims description 2
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 claims description 2
- 239000011261 inert gas Substances 0.000 claims description 2
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 claims description 2
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- 238000003756 stirring Methods 0.000 claims description 2
- 238000001033 granulometry Methods 0.000 claims 3
- 235000012438 extruded product Nutrition 0.000 claims 1
- 238000002156 mixing Methods 0.000 claims 1
- 239000002245 particle Substances 0.000 description 13
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 5
- 229910052710 silicon Inorganic materials 0.000 description 5
- 239000010703 silicon Substances 0.000 description 5
- 230000008901 benefit Effects 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- 229910000676 Si alloy Inorganic materials 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- CSDREXVUYHZDNP-UHFFFAOYSA-N alumanylidynesilicon Chemical compound [Al].[Si] CSDREXVUYHZDNP-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 239000011133 lead Substances 0.000 description 2
- 238000005461 lubrication Methods 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 150000004767 nitrides Chemical class 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 239000011856 silicon-based particle Substances 0.000 description 2
- 238000005496 tempering Methods 0.000 description 2
- 229910052718 tin Inorganic materials 0.000 description 2
- 239000011135 tin Substances 0.000 description 2
- -1 AI 2 0 3 Inorganic materials 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229910000365 copper sulfate Inorganic materials 0.000 description 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 230000001050 lubricating effect Effects 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 229910052982 molybdenum disulfide Inorganic materials 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
- ITRNXVSDJBHYNJ-UHFFFAOYSA-N tungsten disulfide Chemical compound S=[W]=S ITRNXVSDJBHYNJ-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C32/00—Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ
- C22C32/001—Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with only oxides
- C22C32/0015—Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with only oxides with only single oxides as main non-metallic constituents
- C22C32/0036—Matrix based on Al, Mg, Be or alloys thereof
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C32/00—Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ
- C22C32/0089—Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with other, not previously mentioned inorganic compounds as the main non-metallic constituent, e.g. sulfides, glass
Definitions
- the present invention relates to a process for obtaining, by powder metallurgy, a material based on aluminum alloy, a solid lubricant and at least one ceramic intended for making parts subjected to friction. , such as for example the liners of internal combustion engines.
- these alloys have the advantage, when they contain silicon in a hypereutective amount, of leading, during their manufacture by casting, to the formation of primary hard silicon crystals distributed in a softer aluminum matrix, which strengthens their resistance to wear and seizure.
- This technique is also favorable for the incorporation into the alloy of solid lubricating products such as graphite, tin or even hardening agents such as silicon carbide for example.
- the mechanical strength of such alloys can be increased by adding other addition elements such as copper, magnesium, etc.
- the particle size does not exceed 7 wm.
- This particular particle size can be obtained by any known means of spraying and / or grinding and sieving the ceramic used.
- This ceramic may in particular be corundum, silicon carbide, zirconia and silica.
- the amount of ceramic having given the best results is in the range of 5 to 25% by weight relative to the final material and preferably between 7 and 15%. Above 25%, there is a deterioration in the mechanical properties which can or could be remedied by carrying out a special sintering treatment under load in the presence of a liquid phase, but the price of the material thus produced is considerably increased. Below 5%, the ceramic does not have a sufficient effect.
- the materials of the invention also contain a solid lubricant such as, for example, molybdenum disulfide, graphite, boron nitride.
- a solid lubricant such as, for example, molybdenum disulfide, graphite, boron nitride.
- the aluminum alloy with which the solid lubricant and the ceramic are mixed may be any alloy available in the form of a pre-alloyed or premixed powder.
- the compression can be done either in a uniaxial press or in an isostatic press and the tablets obtained are either hot-spun in an extrusion press in the form of slabs or billets which are machined at the sides of the desired part or hot sintered from a blank with suitable dimensions.
- the parts thus obtained are subjected to heat treatments such as dissolution, quenching and tempering.
- seizure tests were carried out using an alternative PLINT tribometer based on the following principle: a metallic segment animated by an alternating rectilinear movement is rubbed on a horizontal and lubricated flat face of the piece. whether there is seizure or not.
- the present invention finds its application in the production of parts subject to friction, such as engine liners in order to obtain an optimum compromise between the values of the coefficient of friction and of the resistance to seizing and wear.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Powder Metallurgy (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR8501856A FR2576913B1 (fr) | 1985-02-01 | 1985-02-01 | Procede d'obtention par la metallurgie des poudres d'un materiau a base d'alliage d'aluminium et d'au moins une ceramique destine a la confection de pieces soumises a frottement |
FR8501856 | 1985-02-01 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0191707A1 EP0191707A1 (fr) | 1986-08-20 |
EP0191707B1 true EP0191707B1 (fr) | 1988-09-28 |
Family
ID=9316104
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP86420032A Expired EP0191707B1 (fr) | 1985-02-01 | 1986-01-30 | Procédé d'obtention par la métallurgie des poudres d'un matériau à base d'alliage d'aluminium et d'au moins une céramique destiné à la confection de pièces soumises à frottement |
Country Status (9)
Country | Link |
---|---|
US (1) | US4661154A (enrdf_load_stackoverflow) |
EP (1) | EP0191707B1 (enrdf_load_stackoverflow) |
DE (1) | DE3660816D1 (enrdf_load_stackoverflow) |
DK (1) | DK43486A (enrdf_load_stackoverflow) |
ES (1) | ES8705527A1 (enrdf_load_stackoverflow) |
FR (1) | FR2576913B1 (enrdf_load_stackoverflow) |
GR (1) | GR860255B (enrdf_load_stackoverflow) |
IE (1) | IE860278L (enrdf_load_stackoverflow) |
PT (1) | PT81947B (enrdf_load_stackoverflow) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6030577A (en) * | 1995-09-01 | 2000-02-29 | Erbsloh Aktiengesellschaft | Process for manufacturing thin pipes |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0213113B1 (de) * | 1985-07-25 | 1990-12-12 | Miba Sintermetall Aktiengesellschaft | Verfahren zum Herstellen von Sinterformkörpern aus einer Aluminium-Sintermischung |
FR2607741B1 (fr) * | 1986-12-04 | 1990-01-05 | Cegedur | Procede d'obtention de materiaux composites, notamment a matrice en alliage d'aluminium, par metallurgie des poudres |
JP2987704B2 (ja) * | 1988-07-15 | 1999-12-06 | 財団法人鉄道総合技術研究所 | 高速鉄道車両用ブレーキディスク材 |
US4989556A (en) * | 1988-10-07 | 1991-02-05 | Honda Giken Kogyo Kabushiki Kaisha | Valve spring retainer for valve operating mechanism for internal combustion engine |
JPH0621309B2 (ja) * | 1988-10-31 | 1994-03-23 | 本田技研工業株式会社 | 耐熱性、耐摩耗性、高靭性Al−Si系合金及びそれを使用したシリンダ−ライナ− |
US5384087A (en) * | 1992-04-06 | 1995-01-24 | Ametek, Specialty Metal Products Division | Aluminum-silicon carbide composite and process for making the same |
CA2094369C (en) * | 1992-04-21 | 2001-04-10 | Pradeep Kumar Rohatgi | Aluminum-base metal matrix composite |
JP2914076B2 (ja) * | 1993-03-18 | 1999-06-28 | 株式会社日立製作所 | セラミックス粒子分散金属部材とその製法及びその用途 |
US5561829A (en) * | 1993-07-22 | 1996-10-01 | Aluminum Company Of America | Method of producing structural metal matrix composite products from a blend of powders |
US5980602A (en) * | 1994-01-19 | 1999-11-09 | Alyn Corporation | Metal matrix composite |
US5669059A (en) * | 1994-01-19 | 1997-09-16 | Alyn Corporation | Metal matrix compositions and method of manufacturing thereof |
US5722033A (en) * | 1994-01-19 | 1998-02-24 | Alyn Corporation | Fabrication methods for metal matrix composites |
AUPN273695A0 (en) * | 1995-05-02 | 1995-05-25 | University Of Queensland, The | Aluminium alloy powder blends and sintered aluminium alloys |
DE19532252C2 (de) * | 1995-09-01 | 1999-12-02 | Erbsloeh Ag | Verfahren zur Herstellung von Laufbuchsen |
FR2840969B1 (fr) * | 2002-06-14 | 2004-09-03 | Snecma Moteurs | Materiau dense autolubrifiant a sec; piece mecanique en ledit materiau; procede d'elaboration dudit materiau |
US6837915B2 (en) * | 2002-09-20 | 2005-01-04 | Scm Metal Products, Inc. | High density, metal-based materials having low coefficients of friction and wear rates |
CN114045417A (zh) * | 2021-11-16 | 2022-02-15 | 玉林师范学院 | 一种轻量化铝合金复合材料、压缩机滚子及其制备方法 |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1296805B (de) * | 1965-05-25 | 1969-06-04 | Schneider Reinhard | Verfahren zur pulvermetallurgischen Herstellung von Formkoerpern mit selbstschmierenden Eigenschaften |
US3885959A (en) * | 1968-03-25 | 1975-05-27 | Int Nickel Co | Composite metal bodies |
FR2343895A1 (fr) * | 1976-03-10 | 1977-10-07 | Pechiney Aluminium | Procede de fabrication de corps creux en alliages d'aluminium au silicium par filage de grenailles |
US4297136A (en) * | 1978-10-16 | 1981-10-27 | The International Nickel Co., Inc. | High strength aluminum alloy and process |
US4315777A (en) * | 1979-08-07 | 1982-02-16 | Scm Corporation | Metal mass adapted for internal oxidation to generate dispersion strengthening |
US4463058A (en) * | 1981-06-16 | 1984-07-31 | Atlantic Richfield Company | Silicon carbide whisker composites |
JPS58110652A (ja) * | 1981-12-25 | 1983-07-01 | Nissan Motor Co Ltd | 耐摩耗性アルミニウム複合材料およびその製造方法 |
US4557893A (en) * | 1983-06-24 | 1985-12-10 | Inco Selective Surfaces, Inc. | Process for producing composite material by milling the metal to 50% saturation hardness then co-milling with the hard phase |
US4579587A (en) * | 1983-08-15 | 1986-04-01 | Massachusetts Institute Of Technology | Method for producing high strength metal-ceramic composition |
-
1985
- 1985-02-01 FR FR8501856A patent/FR2576913B1/fr not_active Expired
-
1986
- 1986-01-27 US US06/822,523 patent/US4661154A/en not_active Expired - Fee Related
- 1986-01-28 GR GR860100255A patent/GR860255B/el unknown
- 1986-01-29 DK DK43486A patent/DK43486A/da not_active Application Discontinuation
- 1986-01-30 PT PT81947A patent/PT81947B/pt not_active IP Right Cessation
- 1986-01-30 DE DE8686420032T patent/DE3660816D1/de not_active Expired
- 1986-01-30 EP EP86420032A patent/EP0191707B1/fr not_active Expired
- 1986-01-31 ES ES551511A patent/ES8705527A1/es not_active Expired
- 1986-01-31 IE IE860278A patent/IE860278L/xx unknown
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6030577A (en) * | 1995-09-01 | 2000-02-29 | Erbsloh Aktiengesellschaft | Process for manufacturing thin pipes |
Also Published As
Publication number | Publication date |
---|---|
PT81947A (fr) | 1986-02-01 |
ES8705527A1 (es) | 1987-05-01 |
PT81947B (pt) | 1988-02-17 |
FR2576913A1 (fr) | 1986-08-08 |
GR860255B (enrdf_load_stackoverflow) | 1986-05-15 |
IE860278L (en) | 1986-08-01 |
DE3660816D1 (en) | 1988-11-03 |
EP0191707A1 (fr) | 1986-08-20 |
US4661154A (en) | 1987-04-28 |
DK43486A (da) | 1986-08-02 |
DK43486D0 (da) | 1986-01-29 |
FR2576913B1 (fr) | 1987-02-27 |
ES551511A0 (es) | 1987-05-01 |
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