EP0181369A1 - Procede de teinture d'un substrat flexible polymere continu et produits obtenus a partir dudit procede. - Google Patents

Procede de teinture d'un substrat flexible polymere continu et produits obtenus a partir dudit procede.

Info

Publication number
EP0181369A1
EP0181369A1 EP85902282A EP85902282A EP0181369A1 EP 0181369 A1 EP0181369 A1 EP 0181369A1 EP 85902282 A EP85902282 A EP 85902282A EP 85902282 A EP85902282 A EP 85902282A EP 0181369 A1 EP0181369 A1 EP 0181369A1
Authority
EP
European Patent Office
Prior art keywords
film
substrate
transfer paper
paper
heating means
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP85902282A
Other languages
German (de)
English (en)
Other versions
EP0181369B1 (fr
Inventor
James Louis Joyce Jr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
TE Connectivity Corp
Original Assignee
AMP Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by AMP Inc filed Critical AMP Inc
Publication of EP0181369A1 publication Critical patent/EP0181369A1/fr
Application granted granted Critical
Publication of EP0181369B1 publication Critical patent/EP0181369B1/fr
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41F—PRINTING MACHINES OR PRESSES
    • B41F16/00—Transfer printing apparatus
    • B41F16/02—Transfer printing apparatus for textile material

Definitions

  • PROCESS FOR DYEING A CONTI NUOUS POLYMERIC FLEX I BLE SUBSTRATE AND PRODUCTS PRODUCED FROM SAID PROCESS This invention relates to the manufacture of conductor cables and in particular to the manufacture of multiconductor flat flexible cables.
  • Conductor cables typically are comprised of a number of longitudinally extended spaced-apart conductor elements encap ⁇ sulated within an insulating sheath.
  • the conductor elements may be composed of any suitable electroconductive material that exhibits the required qualities of flexibility and strength, such as copper and the like.
  • the insulating material is usually polyester, poly vinyl chloride or other plastic material .
  • the insulating materials used are generally manufactured as a trans ⁇ parent or translucent matte film. Generally these films must be heat stabilized to control shrinkage prior to being made into cable.
  • the cable is made by sandwiching the conductor elements between webs of adhesive coated insulating material and laminat ⁇ ing the layers by applying heat and pressure to the sandwich. Typical methods and apparatus for making flexible cables are disclosed in U . S. Patents 3 ,513 ,015 and 4,351 ,689.
  • Standard methods for coloring the plastic film prior to making flexible cable are unsatisfactory. Although it is possible to add pigment to the raw materials prior to extruding or form ⁇ ing the insulating film of material , this method is economically feasible only for very high volume production. Applying color to the surface of the film by means of dipping , spraying , or otherwise coating at least one surface of the film with a pigmented solution is also unsatisfactory. The colored coating is not sufficiently adhered to the surface or heat resistant to remain on the surfaces during the cable manufacturing process , particularly during lamination. Applying color to the finished cable by dipping , spraying , or other coating means is also unsatisfactory . The different coefficients of expansion of the insulating material and the conductive elements cause the cable layers to separate under the conditions required for the coloring process. Furthermore, a colored coating on the surface of the cable is subject to wear by abrasion and to attack by cleaning solvents.
  • Flexible cable can also be colored by adding dye to the adhesive layers or by adding a layer of colored insulating material between the outer dielectric web and the conducting elements. While these methods eliminate the problems associated with surface coating , they produce true vivid colors only when used with transparent film. These methods are generally unsat ⁇ isfactory for coloring translucent film because true vivid colors are unattainable due to the diffusion and refraction properties of the matte film.. Furthermore, these methods increase the number of manufacturing steps required to make a finished product.
  • the process as disclosed herein eliminates the aforemen ⁇ tioned problems.
  • the desired color or colors are imparted to the insulating film by means of sublimation dyeing.
  • This process also provides a means to impart a multicolored design and alpha ⁇ numeric characters as well as solid color to the film.
  • the process for dyeing a continuous flexible polymeric substrate such as a film uses a strip of transfer paper having one or more sublimabie dyes deposited on one surface.
  • the substrate and transfer paper are fed simultaneously into a heat transfer apparatus comprised of a heating means and a substrate retaining means.
  • the layers are fed into the apparatus so that the uncoated side of the transfer paper is proximate the heating means the coated side of the transfer paper is proximate one surface of the substrate and the other surface of the substrate is proximate the substrate retaining means.
  • the substrate retaining means is used to hold the transfer paper securely between the substrate and the heating means. Sufficient heat is applied to the transfer paper to cause the dye to sublime from the paper and diffuse into the intertices of the substrate as it is swelled during the heating process .
  • the colored substrate is removed from the heat transfer apparatus. Since the color is diffused into the intertices of the substrate by this process, it becomes an integral part of the substrate and is not merely a coating . The color remains stable during subsequent processing and is not affected by cleaning solvents or abrasion.
  • Products such as a flat ribbon-like flexible electrical cable dyed in accordance with this method are also disclosed.
  • the cable is comprised of one or more spaced apart, longitudinally extending conductor elements encapsulated between two layers of flexible insulating film wherein at least one of the film layers has been dyed in accordance with the process disclosed herein .
  • the process for making the cable is comprised of the steps of apply ⁇ ing adhesive to one surface of the film colored in accordance with the invention ; simultaneously feeding said adhesive coated film , at least one conductor element and a second layer of adhesive coated insulating film into a laminating means such that said at least one conductor element lies between the adhesive coated surfaces of the film layers and laminating said at least one conductor element between said two film layers thus encapsulating said at least one conductor with insulating film.
  • the textile industry has used sublimation dyeing of fabric for a number of years. Apparatus and methods for sublimation dyeing are disclosed in patents such as U. S.
  • Sublimation dyeing has also been used to print graphics on keyboards and the like for membrane switches. The printing takes place just prior to final assembly of the keyboard. It is new , however , to use sublimation dyeing to impart color into a continuous strip of flexible plastic film that is used for manufacturing flexible cable. Further, it is new to use sublimation dyeing as one of the initial steps in a cable man- ufacturing process. Using the method as disclosed herein also eliminates the necessity of prestabilizing film prior to making the cable. Sublimation dyeing requires a higher temperature than that normally used for stabilizing the material.
  • the film can be stabilized and colored at the same time. Furthermore, tests show that flexible cable that has been colored by sub ⁇ limation dyeing in accordance with the herein disclosed process surprisingly and unexpectedly exhibits greater resistance to being peeled apart than cable that has not been colored by this process. The method can be further understood by referring to the following drawings.
  • FIGURE 1 is a schematic view of the apparatus used to transfer color to a continuous flexible polymeric substrate.
  • FIGURE 2 is an enlarged cross-sectional view taken at circle A of Figure 1 .
  • FIGURE 3 is a flow chart giving a schematic method for making flexible conductor cables in accordance with the in ⁇ vention .
  • FIGURE 1 shows a schematic view of the apparatus used for sublimating dyeing in the disclosed method.
  • Apparatus 10 is comprised of a rotating heatable drum 30 and a continuous belt 32 which is held against the rotating drum 30.
  • a continuous strip of dyed transfer paper 18 and a continuous polymeric substrate 12 are passed between the rotating drum 30 and belt 32.
  • Figure 1 also shows the use of blotting paper 24 which may be used between the polymeric substrate 12 and the belt 32 to absorb any excess dye that penetrates through the substrate during the sublimation process.
  • the transfer paper 18 , the polymeric substrate 12 and the blotting paper 24 are fed into the apparatus 10 by use of supply reels 20 , 14 and 26 respectively.
  • the spent transfer paper 18 1 , the colored film 12' and the spent blotting paper 24' are wound on take-up reels 22 , 16 and 28 respectively.
  • Figure 2 is an enlarged cross-sectional view of a portion of apparatus 10 , showing the drum 30 and the belt 32 with the transfer paper 18 , the film 12 and the optional blotting paper 24 situated between the drum 30 and the belt 32.
  • the belt 32 and the layers of paper 18 , 24 and film 12 are held securely against the drum 30 by the tension means 34 as shown in Figure 1 .
  • Figure 3 is a schematic representation of the steps used in producing flexible cable in accordance with the disclosed method.
  • the polymeric substrate is a plastic film commonly used for electrical cables.
  • the insulating film is dyed by sublimation and coated with an appropriate adhesive.
  • Flexible cable is made by laminating conductor elements between tw ⁇ layers of adhesive coated film.
  • Figure 3 also shows the use of a slitter which can be used to slit a wide strip of colored film into multiple strips.
  • the film can be slit before or after adhesive is applied.
  • the transfer paper is made by printing sublimable dye having the desired color and in the desired design onto transfer paper.
  • the dye or ink and transfer paper used are the same as those used by the fabric industry . Paper can be obtained from commercial printing paper suppliers such as Crown Zeller Corp.
  • Sublimable dyestuffs are available from manufacturers such as C ⁇ ba-Geigy , Ardsley , New York 10502 and Gotham Ink and Color Co. Inc. , Long Island City , New York 11101 .
  • the blotting paper if used , is also standard paper avail- able and commonly used by the fabric industry. Blotting paper is necessary if the apparatus is operated under conditions that cause the dye to be sublimed through the film and onto the belt.
  • the belt is a seamless fiber belt as is used in the fabric indus ⁇ try.
  • cable is made from biaxially oriente"d polyester film. Biaxially oriented film has greater dielectric strength , physical strength and flex life than non- oriented film. In order to have cable that is dimensionally stable the film must be normally stabilized by heating prior to being made into cable. Biaxially oriented film can be obtained from companies such as E. I . DuPont de Nemours & Co. Inc. , Wilmington , Delaware 19898; ICI Americas Inc. , Wilmington , Delaware 19897 and American Hoechst Corp. , Somerville, New Jersey 08876.
  • the apparatus used is a modification of standard equipment commonly used by the textile industry. Additional heaters and temperature control devices were added so that uniform heat could be maintained throughout the drum.
  • the temperature necessary for dyeing the film depends upon factors such as the dyestuff used , the speed of the drum and the thickness of the paper and film layers. It was found that polyester film dyed best when subjected to temperatures in the range of 350-450° F (177-232° C) . The temperature and time relationship is extreme- ly important. The tim required for the dye to sublime and penetrate the plastic film is significantly longer than the time required to dye textile.
  • the tension on the film must be carefully controlled at all stages of the dyeing process , as the film is fed into the heat transfer apparatus, during the time the film re ⁇ mains in contact with the heat and after the film exits the appa ⁇ ratus.
  • the tension on the continuous belt must be controlled.
  • the take-up drive was also modified so that a constant tension could be maintained on the film despite the number of layers on the take-up reel.
  • the film begins to cool as soon as it is no longer in contact with the drum. If the tension on the exiting film is not controlled precisely, the film will buckle, wrinkle and have varying degrees of shrinkage across the web as the film cools.
  • Colored cable was made in accordance with the invention . Continuous strips of transfer paper and film were fed from reels onto the rotating drum.
  • the drum was kept at a constant temperature throughout the dyeing process. By carefully con- trolling the temperature and speed of the drum the amount of dye sublimed into the film was optimized and the amount of wasted dye was minimized. The majority of the sublimed dye thus became part of the structure of the film.
  • the film was maintained under constant tension as it exited from the drum and was wound onto the take-up reel . Adhesive was then applied to one surface of the colored film. In the preferred embodiment adhesive was applied to the surface of film that was against the transfer paper to ensure that any dye on that surface of the film was encased within the laminated cable. The film was then slit into the desired widths . In the preferred cable embodiment, conductor elements were sandwiched between two layers of the colored film and laminated.
  • the sublimation method can be used to impart a solid color a plurality of colors , alphanumeric characters , and designs to flexible polymeric substrate.
  • the design on the transfer paper is imparted to the substrate.
  • otherwise solidly colored substrate when used for electrical cables can be color coded to indicate specific conductors. If color coding is desired this method can be used to color code the film , the cable can be made with one color coded layer of film and one uncoded layer of film.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Thermal Transfer Or Thermal Recording In General (AREA)
  • Coloring (AREA)

Abstract

Le procédé de teinture d'un substrat flexible polymère continu (12), par exemple un film, utilise une bande de papier de transfert (18) comportant des colorants sublimables déposés sur une surface. Le substrat (12) et le papier de transfert (18) sont introduits simultanément dans un appareil de transfert thermique (10) formé d'un dispositif de chauffage (30) et d'un dispositif de retenue du substrat (32). Les couches sont introduites dans l'appareil (10) de telle manière que le côté non enduit du papier de transfert (18) est à proximité du dispositif de chauffage (30) et que le substrat se trouve près du dispositif de retenue (32). Les couches sont maintenues contre le dispositif de chauffage (30) alors qu'une chaleur suffisante est appliquée sur le papier de transfert (18) pour mener la sublimation du colorant à partir du papier (18) et sa diffusion dans les interstices du substrat (12).
EP85902282A 1984-05-11 1985-04-15 Procede de teinture d'un substrat flexible polymere continu et produits obtenus a partir dudit procede Expired EP0181369B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US60915884A 1984-05-11 1984-05-11
US609158 1990-11-02

Publications (2)

Publication Number Publication Date
EP0181369A1 true EP0181369A1 (fr) 1986-05-21
EP0181369B1 EP0181369B1 (fr) 1988-10-26

Family

ID=24439582

Family Applications (1)

Application Number Title Priority Date Filing Date
EP85902282A Expired EP0181369B1 (fr) 1984-05-11 1985-04-15 Procede de teinture d'un substrat flexible polymere continu et produits obtenus a partir dudit procede

Country Status (5)

Country Link
EP (1) EP0181369B1 (fr)
JP (1) JPS61502109A (fr)
DE (1) DE3565799D1 (fr)
ES (1) ES8703672A1 (fr)
WO (1) WO1985005324A1 (fr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2224974A (en) * 1988-10-04 1990-05-23 Robert William Wilson Method and means for decorating a substrate
FR2764238B1 (fr) * 1997-06-04 1999-08-13 Glace Controle Procede de transfert d'image sur un film de polyester et produit ainsi obtenu
CN102285209B (zh) * 2011-07-08 2015-06-24 长胜纺织科技发展(上海)有限公司 自动控制型转移印花装置

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2086941A6 (fr) * 1970-04-14 1971-12-31 Lemaire & Cie
GB1355856A (en) * 1971-10-07 1974-06-05 Basford Dyers Ltd Printing and bonding machines
FR2318742A1 (fr) * 1975-07-21 1977-02-18 Rejto Thomas Procede d'impression par transfert avec gaufrage simultane et installation pour la mise en oeuvre du procede
NL7608721A (nl) * 1975-09-01 1977-03-03 Kleinewefers Ind Co Gmbh Inrichting voor het bedrukken van textielbanen.
US4351689A (en) * 1979-12-26 1982-09-28 Western Electric Company, Inc. Apparatus for the manufacture of multi-conductor flat cable

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO8505324A1 *

Also Published As

Publication number Publication date
JPS61502109A (ja) 1986-09-25
EP0181369B1 (fr) 1988-10-26
DE3565799D1 (en) 1988-12-01
WO1985005324A1 (fr) 1985-12-05
ES8703672A1 (es) 1987-02-16
ES543010A0 (es) 1987-02-16

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