EP0171788B1 - Bruleur d'allumage et de soutien de combustion pour combustible solide fossilé pulverisé, et chambre de combustion comportant de tels bruleurs - Google Patents
Bruleur d'allumage et de soutien de combustion pour combustible solide fossilé pulverisé, et chambre de combustion comportant de tels bruleurs Download PDFInfo
- Publication number
- EP0171788B1 EP0171788B1 EP85110126A EP85110126A EP0171788B1 EP 0171788 B1 EP0171788 B1 EP 0171788B1 EP 85110126 A EP85110126 A EP 85110126A EP 85110126 A EP85110126 A EP 85110126A EP 0171788 B1 EP0171788 B1 EP 0171788B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- ignition
- burner
- conduit
- fuel
- tap
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000002485 combustion reaction Methods 0.000 title claims abstract description 37
- 239000000446 fuel Substances 0.000 title claims abstract description 17
- 239000007787 solid Substances 0.000 title claims abstract description 11
- 239000002803 fossil fuel Substances 0.000 claims abstract description 13
- 239000004449 solid propellant Substances 0.000 claims description 12
- 238000010438 heat treatment Methods 0.000 claims description 11
- 238000001514 detection method Methods 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 2
- 230000000295 complement effect Effects 0.000 claims 2
- 239000007789 gas Substances 0.000 description 21
- 230000001590 oxidative effect Effects 0.000 description 17
- 239000003245 coal Substances 0.000 description 9
- 239000007800 oxidant agent Substances 0.000 description 5
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 3
- 239000003546 flue gas Substances 0.000 description 3
- 230000002093 peripheral effect Effects 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 239000003610 charcoal Substances 0.000 description 2
- 239000002737 fuel gas Substances 0.000 description 2
- 239000000295 fuel oil Substances 0.000 description 2
- 238000002309 gasification Methods 0.000 description 2
- 230000002035 prolonged effect Effects 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000010763 heavy fuel oil Substances 0.000 description 1
- 239000011872 intimate mixture Substances 0.000 description 1
- 239000003077 lignite Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23D—BURNERS
- F23D1/00—Burners for combustion of pulverulent fuel
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C7/00—Combustion apparatus characterised by arrangements for air supply
- F23C7/002—Combustion apparatus characterised by arrangements for air supply the air being submitted to a rotary or spinning motion
- F23C7/004—Combustion apparatus characterised by arrangements for air supply the air being submitted to a rotary or spinning motion using vanes
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C5/00—Disposition of burners with respect to the combustion chamber or to one another; Mounting of burners in combustion apparatus
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C5/00—Disposition of burners with respect to the combustion chamber or to one another; Mounting of burners in combustion apparatus
- F23C5/08—Disposition of burners
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C5/00—Disposition of burners with respect to the combustion chamber or to one another; Mounting of burners in combustion apparatus
- F23C5/08—Disposition of burners
- F23C5/32—Disposition of burners to obtain rotating flames, i.e. flames moving helically or spirally
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23D—BURNERS
- F23D1/00—Burners for combustion of pulverulent fuel
- F23D1/02—Vortex burners, e.g. for cyclone-type combustion apparatus
Definitions
- Combustion equipment for pulverized solid fuels of known boilers for thermal power stations, or possibly ovens comprises, in addition to the main burners, ignition and combustion support burners whose function is to ensure start-up operations at cold and assistance at low loads of the main burners.
- the document EP-A-0 057 895 describes a device for direct ignition of poor pulverized solid fuels in cold combustion chambers, and for supporting combustion at low loads. It comprises a make-up and ignition igniter operating with gas produced by the gasification of lean fuel and a main igniter operating with pulverized lean fuel. The combustion air sent to the igniter outlet is put into turbulence. This device requires that one has the gas produced by the gasification of the lean fuel. It does not provide means for translating the conduit for introducing pulverized solid fuel, or a flame detection device.
- Document DE-C-916 663 relates to a device for introducing solid fuel sprayed into a burner comprising an axial tube movable in translation inside an annular tube for introducing secondary air. But the burner does not have a refractory orifice, or a conduit for introducing tertiary oxidizing gas, neither an ignition member, nor a flame detection member.
- Document US-A-4 381 718 relates to a burner having in common with the present invention the members a), b), c), d), e) and f) above.
- the conduit for the introduction of pulverized solid fuel is fixed, and it does not include a flame detection device.
- the object of the present invention is to provide an ignition burner and support for combustion using pulverized fossil fuel, which has a lower operating cost than an ignition and support burner for fuel oil or gas, and easily adapts to frequent stops and prolonged operations at low load.
- the ignition and support burner for solid atomized fossil fuel according to the invention is characterized in that the conduit for introducing the solid atomized fuel is provided with translation means making it possible to adjust the length of the premix chamber of the solid fuel and of the first fraction of secondary oxidizing gas lying between the end of this duct and the inlet of the flue gas, and in that a flame detection device is arranged near its flue gas.
- the burner according to the invention is provided with means for adjusting the respective flow rates of the first and second fractions of secondary oxidizing gas in the annular conduits.
- the ignition and support burner according to the invention preferably comprises an additional igniter consisting of one or more injectors of liquid or gaseous fuel distributed in the wall of the flue.
- the invention further extends to combustion chambers with main burners and ignition and support burners for atomized fossil fuel.
- each ignition and support burner is arranged between two main burners, vertically or laterally with respect to a main burner and at the level thereof, but in this case, the third conduit for introducing tertiary oxidizing gas is concentric with the flue and surrounds it.
- each ignition and support burner is in the axis of a main burner, or placed in the arrival of secondary oxidant gas therefrom, or even laterally adjacent thereto, but in this case, the third conduit for introducing tertiary oxidant gas is concentric with the flue and surrounds it.
- the tertiary oxidant gas of the ignition and support burner can also be introduced in part by the main burner.
- the axial pipe or tube 1 provides a central supply of pulverized coal transported by primary air in relatively dense phase (several kg of coal pulverized per kg of air, and for example from 4 to 10 kg of coal per kg of air).
- This tube is surrounded by a first duct or annular tube 2 for secondary air inlet, coming from the duct 3, at a flow rate adjustable by a flap 4.
- the axial tube 1 can slide inside the annular tube 2, of which it crosses the wall by a seal 5 allowing its translation.
- the periphery of the end of the tube 1 is provided with fins 6 for rotating for the secondary air coming from the annular tube 2. These fins 6 make it possible to produce, at the outlet of the tube 1, by turbulence, an intimate mixture of the fuel and part of the air.
- the air arriving through the annular tube 2 can be preheated to promote the ignition of the fuel.
- the axial position of the end of the axial tube 1 is adjustable by means of a handle 21 for controlling the translation of this tube, which makes it possible to modify the length L, and consequently the volume of a premix chamber 10, between the end of the axial tube 1 and the bottom of the outlet 12, so as to adapt it to the flow rate and to the quality of the powdered coal admitted by the tube.
- the second duct or annular secondary air introduction tube 7 is supplied by the duct 8. It is provided with a flow adjustment flap 9, and is equipped at its end with rotation fins 11. L The air arriving through the annular tube can be preheated to promote ignition of the fuel.
- the flow rates and proportions of air passing through tubes 2 and 7 are adjusted according to the quality of the coal.
- the opening itself is provided with a refractory lining 13.
- This opening comprises an igniter 15 of low power (of the order of 1% of the total power of the burner), which can operate either with gas or with fuel oil domesticated. It can be replaced by an electric igniter, with arc periodically spouting between electrodes.
- an additional gas igniter is arranged in the quill. It consists of several injectors such as 16, 17 distributed in the wall of the flue in the ignition zone.
- a flame detector 20 which also monitors the flame of the pulverized fossil fuel.
- Tube 1 Primary air (tube 1) -15 to 30 Kg / h (charged with 4 to 10% of coal / Kg of air).
- First secondary air (tube 2) at 20 ° C to 300 ° C 50 to 300 Kg / h.
- Second secondary air (tube 7) at 20 ° C to 300 ° C - 50 to 300 Kg / h.
- the length of the premix chamber is adjustable between 100 and 500 mm depending on the flammability of the carbon.
- FIG. 2 represents an arrangement of an ignition and support burner with respect to the main burners, in the case of a boiler hearth with tangential heating.
- the ignition and support burner 22 is arranged between two main burners 23, 24 of rectangular section each of which is surrounded by a rectangular opening 25, 26 for introducing secondary air and framed between two rectangular orifices (27, 29 ; 28, 30) secondary air intake.
- the orifices 27, 28 are used both for the admission of secondary air to the main burner and of tertiary air to the ignition and support burner. In such a provision, admissions 18, 19, as mentioned in Figure 1, are deleted.
- FIG. 3 represents another possible arrangement of the ignition and support burners with respect to the main burners, in the case of a boiler hearth with tangential heating.
- the main burner 31 is arranged on an edge of the hearth, of rectangular cross section.
- the ignition and support burner 32 is disposed laterally, on the face 33 of the hearth adjacent to this edge, in a circular opening obtained by deforming at this location the tubes constituting the wall of the hearth.
- the ignition and support burner conforms to Figure 1.
- FIG. 4 shows a relative arrangement of the main burners and of the ignition and support burners in a front-heating boiler home.
- the main burners 41 are distributed in two rows on the face 40. They comprise an external tube 42 and an internal tube 43 which delimit a central inlet 45 for primary air and a peripheral inlet 46 for secondary air.
- the ignition and support burners 44 are arranged in the axis of the main burners 41. These ignition and support burners 44 conform to that of FIG. 1, but in this case the tertiary air intakes 18, 19 are deleted.
- Figure 5 shows another possible arrangement.
- the main burners 51 are distributed in two rows on the face 50. They comprise an external tube 52 and an internal tube 53 which provide a central inlet 55 for primary air and a peripheral inlet 56 for secondary air.
- the ignition and support burners 54 are arranged in the secondary air inlet of the main burners 51. In this case also the tertiary air inlets 18, 19 of the ignition and support burners 54 are eliminated.
- Figure 6 shows another possible arrangement.
- the burners 61 are distributed in two rows on the face 6 0 . They comprise an external tube 62 and an internal tube 63 which delimit a central inlet 65 of primary air and a peripheral inlet 66 of secondary air.
- the ignition and support burners 64 are each in an adjacent position relative to a main burner 61. In this case, the ignition and support burners 64 are in accordance with that of FIG. 1.
- the ignition and support burners can be supplied with the same charcoal as the main burners, or with charcoal of different nature and / or particle size.
- ignition and support burners can operate independently of the main burners.
- the invention can also be applied to burners or hearths burning lignite.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Combustion Of Fluid Fuel (AREA)
- Gas Burners (AREA)
- Pre-Mixing And Non-Premixing Gas Burner (AREA)
- Vertical, Hearth, Or Arc Furnaces (AREA)
- Pressure-Spray And Ultrasonic-Wave- Spray Burners (AREA)
- Disintegrating Or Milling (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT85110126T ATE40457T1 (de) | 1984-08-16 | 1985-08-13 | Zuendungs- und erhaltungsbrenner fuer festen, fossilen und zerstaeubten brennstoff und verbrennungskammer mit solchen brennern. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR8412855 | 1984-08-16 | ||
FR8412855A FR2569256B1 (fr) | 1984-08-16 | 1984-08-16 | Bruleur d'allumage et de soutien de combustion pour combustible solide fossile pulverise, et chambre de combustion comportant de tels bruleurs |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0171788A1 EP0171788A1 (fr) | 1986-02-19 |
EP0171788B1 true EP0171788B1 (fr) | 1989-01-25 |
Family
ID=9307063
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP85110126A Expired EP0171788B1 (fr) | 1984-08-16 | 1985-08-13 | Bruleur d'allumage et de soutien de combustion pour combustible solide fossilé pulverisé, et chambre de combustion comportant de tels bruleurs |
Country Status (14)
Country | Link |
---|---|
US (1) | US4690075A (pt) |
EP (1) | EP0171788B1 (pt) |
JP (1) | JPS6159109A (pt) |
KR (1) | KR940006903B1 (pt) |
AT (1) | ATE40457T1 (pt) |
AU (1) | AU587392B2 (pt) |
BR (1) | BR8503889A (pt) |
CA (1) | CA1268996A (pt) |
DE (1) | DE3567956D1 (pt) |
ES (1) | ES8700413A1 (pt) |
FR (1) | FR2569256B1 (pt) |
GR (1) | GR851990B (pt) |
IN (1) | IN164006B (pt) |
ZA (1) | ZA856236B (pt) |
Families Citing this family (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2202234B (en) * | 1987-03-16 | 1991-09-18 | Shell Int Research | Method for starting up a partial combustion process |
US4801261A (en) * | 1987-03-19 | 1989-01-31 | Eagleair, Inc. | Apparatus and method for delivery of combustion air in multiple zones |
US5211705A (en) * | 1987-03-19 | 1993-05-18 | Damper Design, Inc. | Apparatus and method for delivery of combustion air in multiple zones |
US5183646A (en) * | 1989-04-12 | 1993-02-02 | Custom Engineered Materials, Inc. | Incinerator for complete oxidation of impurities in a gas stream |
DE19514615C2 (de) * | 1995-04-25 | 2001-05-17 | Alstom Power Boiler Gmbh | Brenner, insbesondere Strahlbrenner, zum Verbrennen von staubförmigem Brennstoff, insbesondere staubförmiger Kohle, und einem brennbaren Fluid |
FR2869672A1 (fr) * | 2004-10-15 | 2005-11-04 | Alstom Sa | Dispositif d'injection de gaz dans un foyer |
FR2880410B1 (fr) * | 2005-01-03 | 2007-03-16 | Air Liquide | Procede de combustion etagee produisant des flammes asymetriques |
EP2304316A2 (de) * | 2008-07-11 | 2011-04-06 | Rheinkalk GmbH | Brennereinheit und brenneranordnung für staubförmigen festbrennstoff |
CN102788347B (zh) * | 2012-06-07 | 2014-11-12 | 上海锅炉厂有限公司 | 一种微油量点火煤粉燃烧系统 |
US9909755B2 (en) * | 2013-03-15 | 2018-03-06 | Fives North American Combustion, Inc. | Low NOx combustion method and apparatus |
GB2513389A (en) * | 2013-04-25 | 2014-10-29 | Rjm Corp Ec Ltd | Nozzle for power station burner and method for the use thereof |
EP3130851B1 (en) * | 2015-08-13 | 2021-03-24 | General Electric Technology GmbH | System and method for providing combustion in a boiler |
CN107606607A (zh) * | 2017-09-21 | 2018-01-19 | 哈尔滨工业大学 | 一种燃尽风环形布置的中心给粉稳燃型燃烧装置 |
CN107504480A (zh) * | 2017-09-21 | 2017-12-22 | 哈尔滨工业大学 | 一种带有中心给粉旋流煤粉燃烧装置的工业煤粉锅炉 |
CN107559818A (zh) * | 2017-09-21 | 2018-01-09 | 哈尔滨工业大学 | 采用预燃室及双层射流分离二次风的中心给粉旋流煤粉燃烧装置 |
CN107559819A (zh) * | 2017-09-21 | 2018-01-09 | 哈尔滨工业大学 | 一种用于工业锅炉带有渐扩形预燃室的旋流煤粉燃烧机构 |
CN107559822B (zh) * | 2017-09-21 | 2020-06-09 | 哈尔滨工业大学 | 中心给粉旋流煤粉燃器和燃尽风布置结构 |
CN107477572A (zh) * | 2017-09-21 | 2017-12-15 | 哈尔滨工业大学 | 采用分离二次风双层射流的中心给粉旋流煤粉燃烧装置 |
CN109631018A (zh) * | 2018-12-18 | 2019-04-16 | 哈尔滨工业大学 | 一种用于工业煤粉锅炉的渐扩式防结渣燃烧器 |
CN113007698B (zh) * | 2021-02-07 | 2021-12-03 | 哈尔滨工业大学 | 一种用于对冲燃烧锅炉下层的燃烧系统及使用方法 |
CN112902147B (zh) * | 2021-02-07 | 2022-03-01 | 哈尔滨工业大学 | 一种混烧低挥发分固体燃料的预燃室燃烧装置 |
CN114017796A (zh) * | 2021-11-03 | 2022-02-08 | 北京优稳昌盛科技有限公司 | 一种基于煤粉锅炉的自动点火控制系统 |
Family Cites Families (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3123027A (en) * | 1964-03-03 | Apparatus and method of flame or combustion rate | ||
US1600724A (en) * | 1923-11-22 | 1926-09-21 | Fitch William Henry | Burner |
US2096946A (en) * | 1932-12-27 | 1937-10-26 | Powderco Inc | Apparatus for burning powdered fuel |
FR870016A (fr) * | 1940-02-08 | 1942-02-27 | Kohlenscheidungs Gmbh | Foyer à combustible pulvérisé |
DE881717C (de) * | 1940-03-28 | 1953-07-02 | Steinmueller Gmbh L & C | Mit Kohlenstaub betriebener Zuendbrenner fuer Kohlenstaubfeuerungen |
US2485656A (en) * | 1944-03-25 | 1949-10-25 | Franz J M Raskin | Hydroxylating fuel burner |
DE916663C (de) * | 1951-02-03 | 1954-08-16 | Ruhrgas Ag | Duese fuer Vorrichtungen zur Verbrennung oder Vergasung von Brennstoffstaub |
GB809148A (en) * | 1956-11-20 | 1959-02-18 | Prvni Brnenska Strojirna Zd Y | A furnace for burning pulverised coal |
FR1347777A (fr) * | 1962-11-19 | 1964-01-04 | O C C R Organisation Conceptio | Brûleur à poussières de déchets végétaux |
FR2375544A2 (fr) * | 1976-12-22 | 1978-07-21 | Colmant Cuvelier | Bruleur pour carburant pulverulent |
US4173189A (en) * | 1977-01-21 | 1979-11-06 | Combustion Engineering, Inc. | Boiler cold start using pulverized coal in ignitor burners |
DE2806363C2 (de) * | 1977-02-18 | 1985-06-27 | Combustion Engineering, Inc., Windsor, Conn. | Verfahren zum Zünden der Verbrennung von Kohlenstaub |
DE2933060B1 (de) * | 1979-08-16 | 1980-10-30 | Steinmueller Gmbh L & C | Brenner zur Verbrennung von staubfoermigen Brennstoffen |
US4381718A (en) * | 1980-11-17 | 1983-05-03 | Carver George P | Low emissions process and burner |
DE3048201A1 (de) * | 1980-12-20 | 1982-07-08 | L. & C. Steinmüller GmbH, 5270 Gummersbach | "brenner zur verminderung der no(pfeil abwaerts)x(pfeil abwaerts)-emission" |
FR2499681A1 (fr) * | 1981-02-06 | 1982-08-13 | Stein Industrie | Dispositif d'allumage direct de combustibles solides pulverises pauvres dans des chambres de combustion froides |
DE3107649A1 (de) * | 1981-02-27 | 1982-11-11 | Steag Ag, 4300 Essen | Verfahren zum mindestens zweistufigen zuenden einer brennstaubleistungsbrennerflamme und brennsystem zur durchfuehrung des verfahrens |
US4523530A (en) * | 1982-02-26 | 1985-06-18 | Sumitomo Metal Industries, Ltd. | Powdery coal burner |
US4531461A (en) * | 1982-05-14 | 1985-07-30 | T.A.S., Inc. | Solid fuel pulverizing and burning system and method and pulverizer and burner therefor |
JPS60226609A (ja) * | 1984-04-23 | 1985-11-11 | Babcock Hitachi Kk | 燃焼装置 |
-
1984
- 1984-08-16 FR FR8412855A patent/FR2569256B1/fr not_active Expired
-
1985
- 1985-08-08 IN IN653/DEL/85A patent/IN164006B/en unknown
- 1985-08-13 AT AT85110126T patent/ATE40457T1/de not_active IP Right Cessation
- 1985-08-13 DE DE8585110126T patent/DE3567956D1/de not_active Expired
- 1985-08-13 EP EP85110126A patent/EP0171788B1/fr not_active Expired
- 1985-08-13 ES ES546120A patent/ES8700413A1/es not_active Expired
- 1985-08-14 GR GR851990A patent/GR851990B/el unknown
- 1985-08-15 AU AU46223/85A patent/AU587392B2/en not_active Ceased
- 1985-08-15 BR BR8503889A patent/BR8503889A/pt not_active IP Right Cessation
- 1985-08-15 JP JP60180006A patent/JPS6159109A/ja active Granted
- 1985-08-15 CA CA000488743A patent/CA1268996A/fr not_active Expired - Fee Related
- 1985-08-16 KR KR1019850005906A patent/KR940006903B1/ko not_active IP Right Cessation
- 1985-08-16 ZA ZA856236A patent/ZA856236B/xx unknown
-
1986
- 1986-08-04 US US06/891,429 patent/US4690075A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
JPS6159109A (ja) | 1986-03-26 |
DE3567956D1 (en) | 1989-03-02 |
JPH0240923B2 (pt) | 1990-09-13 |
ES546120A0 (es) | 1986-10-16 |
FR2569256B1 (fr) | 1989-04-07 |
FR2569256A1 (fr) | 1986-02-21 |
AU4622385A (en) | 1986-02-20 |
EP0171788A1 (fr) | 1986-02-19 |
BR8503889A (pt) | 1986-05-27 |
CA1268996A (fr) | 1990-05-15 |
KR940006903B1 (ko) | 1994-07-29 |
ATE40457T1 (de) | 1989-02-15 |
AU587392B2 (en) | 1989-08-17 |
GR851990B (pt) | 1985-12-17 |
ES8700413A1 (es) | 1986-10-16 |
US4690075A (en) | 1987-09-01 |
KR860001981A (ko) | 1986-03-24 |
ZA856236B (en) | 1986-04-30 |
IN164006B (pt) | 1988-12-24 |
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