EP0160616B1 - Verwendung eines Stahls in schwefelwasserstoffhaltiger Atmosphäre - Google Patents
Verwendung eines Stahls in schwefelwasserstoffhaltiger Atmosphäre Download PDFInfo
- Publication number
- EP0160616B1 EP0160616B1 EP85730016A EP85730016A EP0160616B1 EP 0160616 B1 EP0160616 B1 EP 0160616B1 EP 85730016 A EP85730016 A EP 85730016A EP 85730016 A EP85730016 A EP 85730016A EP 0160616 B1 EP0160616 B1 EP 0160616B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- cooled
- steel
- pipes
- temperature
- air
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 14
- 239000010959 steel Substances 0.000 title claims abstract description 14
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 title claims description 6
- 229910000037 hydrogen sulfide Inorganic materials 0.000 title description 4
- 238000005260 corrosion Methods 0.000 claims abstract description 8
- 230000007797 corrosion Effects 0.000 claims abstract description 8
- 238000005336 cracking Methods 0.000 claims abstract description 8
- 239000010955 niobium Substances 0.000 claims abstract 5
- 229910052758 niobium Inorganic materials 0.000 claims abstract 3
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims abstract 2
- 238000005096 rolling process Methods 0.000 claims description 9
- 229910052720 vanadium Inorganic materials 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 2
- 238000010606 normalization Methods 0.000 claims description 2
- 238000007493 shaping process Methods 0.000 claims 3
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 2
- 238000005275 alloying Methods 0.000 abstract 1
- 238000001816 cooling Methods 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 235000019362 perlite Nutrition 0.000 abstract 1
- 239000010451 perlite Substances 0.000 abstract 1
- 229910045601 alloy Inorganic materials 0.000 description 3
- 239000000956 alloy Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000005496 tempering Methods 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 239000008186 active pharmaceutical agent Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910000851 Alloy steel Inorganic materials 0.000 description 1
- QFGIVKNKFPCKAW-UHFFFAOYSA-N [Mn].[C] Chemical compound [Mn].[C] QFGIVKNKFPCKAW-UHFFFAOYSA-N 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000005098 hot rolling Methods 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/10—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of tubular bodies
Definitions
- a steel is known with alloy areas of the elements C, Mn, Si, Cr, V, N, of which the current one is a selection (DE-OS 31 27 373). From such steels it is known that the finished product has a yield strength between 480 and 650 N / mm2 with a special deformation and temperature control.
- the special feature is that during tube production the hollow body is cooled to a temperature between Ac1 and plus 500 ° C before the final longitudinal rolling and then heated to a temperature above Ar3 as the last rolling section to reduce the stretch.
- quality level N 80 is neither required nor guaranteed that the product, when used in media containing hydrogen sulfide, generally has sufficiently reliable resistance to stress corrosion cracking.
- quality level L 80 is prescribed for use under sour gas conditions according to API, which has limited technological properties compared to quality level N 80 and a limitation of hardness to a maximum of HRC 22 and a remuneration structure.
- the tempering consists of quench hardening and subsequent tempering. The high expenditure of energy and time for the treatment and reworking of the product is perceived as a disadvantage.
- the invention is based on the above steel alloy and the production of pipes therefrom. It has set itself the task of selecting alloy ranges and of carrying out the heat treatment in such a way that a fine-grained ferritic pearlitic structure is produced which has comparable stress corrosion cracking resistance as a tempered structure with comparable yield strengths.
- ferritic-pearlitic steels Due to a higher ratio of yield strength to tensile strength of tempered compared to ferritic-pearlitic steels, ferritic-pearlitic steels have a higher tensile strength and thus hardness with the same yield strength.
- the structures of the steels mentioned in claim 1 have a maximum hardness of HRC 26. At the same time, these steels have comparable resistance to stress corrosion cracking to tempered steels with HRC 22. However, this condition has not been practiced with the previously usual materials, which also achieve the required mechanical strength, and has also not become known in the literature.
- the current proposal avoids the subsequent tempering and specifies an alloy selection for a steel that cools in air from the hot forming heat and, if necessary, undergoes normalization treatment during the hot rolling process and fulfills requirements for a narrow yield strength range as well as for high resistance to hydrogen-induced stress corrosion cracking. This results in a simplified production of a product for use in an atmosphere containing hydrogen sulfide.
- the hardness was HRC 23 and the average grain size was ASTM 10.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Heat Treatment Of Steel (AREA)
- Heat Treatment Of Articles (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Heat Treatment Of Sheet Steel (AREA)
- Rigid Pipes And Flexible Pipes (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT85730016T ATE38059T1 (de) | 1984-04-24 | 1985-02-01 | Verwendung eines stahls in schwefelwasserstoffhaltiger atmosphaere. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE3415590 | 1984-04-24 | ||
DE19843415590 DE3415590A1 (de) | 1984-04-24 | 1984-04-24 | Verwendung eines stahls in schwefelwasserstoffhaltigen medien |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0160616A2 EP0160616A2 (de) | 1985-11-06 |
EP0160616A3 EP0160616A3 (en) | 1986-12-30 |
EP0160616B1 true EP0160616B1 (de) | 1988-10-19 |
Family
ID=6234444
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP85730016A Expired EP0160616B1 (de) | 1984-04-24 | 1985-02-01 | Verwendung eines Stahls in schwefelwasserstoffhaltiger Atmosphäre |
Country Status (7)
Country | Link |
---|---|
US (1) | US4631095A (enrdf_load_stackoverflow) |
EP (1) | EP0160616B1 (enrdf_load_stackoverflow) |
JP (1) | JPS60234952A (enrdf_load_stackoverflow) |
AT (1) | ATE38059T1 (enrdf_load_stackoverflow) |
BR (1) | BR8501925A (enrdf_load_stackoverflow) |
CA (1) | CA1239332A (enrdf_load_stackoverflow) |
DE (1) | DE3415590A1 (enrdf_load_stackoverflow) |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3909675A1 (de) * | 1989-03-23 | 1990-09-27 | Siemens Ag | Sperren von mfv-teilnehmernummern |
DE4019118C1 (enrdf_load_stackoverflow) * | 1990-06-12 | 1991-04-18 | Mannesmann Ag, 4000 Duesseldorf, De | |
DE4439059A1 (de) * | 1994-11-02 | 1996-05-09 | Teves Gmbh Alfred | Verschlußvorrichtung zum Verschließen von Druckmittel führenden Kanälen in einem Gehäuse |
EP0940476B1 (en) * | 1997-04-30 | 2005-06-29 | JFE Steel Corporation | Process for producing steel pipe having high ductility and strength |
US5993570A (en) * | 1997-06-20 | 1999-11-30 | American Cast Iron Pipe Company | Linepipe and structural steel produced by high speed continuous casting |
WO1999000525A1 (fr) * | 1997-06-26 | 1999-01-07 | Kawasaki Steel Corporation | Tuyau en acier a grains ultrafins et procede de fabrication dudit tuyau |
ATE312208T1 (de) * | 1997-06-26 | 2005-12-15 | Jfe Steel Corp | Verfahren zur herstellung von stahlrohr mit ultrafeinem gefüge |
US6149862A (en) * | 1999-05-18 | 2000-11-21 | The Atri Group Ltd. | Iron-silicon alloy and alloy product, exhibiting improved resistance to hydrogen embrittlement and method of making the same |
RU2153011C1 (ru) * | 1999-10-18 | 2000-07-20 | Открытое акционерное общество "Синарский трубный завод" | Способ изготовления труб из углеродистых и низколегированных сталей |
JP2006083963A (ja) * | 2004-09-16 | 2006-03-30 | Ntn Corp | 中空状動力伝達シャフト |
CN102400057B (zh) * | 2011-11-28 | 2014-12-03 | 宝山钢铁股份有限公司 | 抗二氧化碳腐蚀油井管用低合金钢及其制造方法 |
DE102015217399A1 (de) * | 2015-09-11 | 2017-03-16 | Thyssenkrupp Ag | Rohrfeder für Kraftfahrzeuge und ein Verfahren zum Herstellen einer Rohrfeder |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB839063A (en) * | 1957-02-11 | 1960-06-29 | Fagersta Bruks Ab | Improvements relating to steel for welding or cold working |
US3741822A (en) * | 1971-07-14 | 1973-06-26 | North Star Steel Co | High strength steel |
US4256517A (en) * | 1978-01-09 | 1981-03-17 | Republic Steel Corporation | Welded alloy casing |
DE2900022C3 (de) * | 1979-01-02 | 1981-12-03 | Estel Hoesch Werke Ag, 4600 Dortmund | Verfahren zum Herstellen von Profilen |
US4282047A (en) * | 1979-08-29 | 1981-08-04 | Kawasaki Steel Corporation | Method of producing steel pipe material for oil well |
JPS5937328B2 (ja) * | 1980-09-05 | 1984-09-08 | 新日本製鐵株式会社 | 耐サワ−特性のすぐれた鋼管用熱延鋼材の製造方法 |
US4354882A (en) * | 1981-05-08 | 1982-10-19 | Lone Star Steel Company | High performance tubulars for critical oil country applications and process for their preparation |
US4394189A (en) * | 1981-05-08 | 1983-07-19 | Lone Star Steel Company | High performance tubulars for critical oil country applications and improved process for their preparation |
US4370178A (en) * | 1981-06-30 | 1983-01-25 | Republic Steel Corporation | Method of making as-pierced tubular products |
DE3127373C2 (de) * | 1981-07-09 | 1985-08-29 | Mannesmann AG, 4000 Düsseldorf | Verfahren zum Herstellen von nahtlosen Stahlrohren für die Erdölindustrie |
CS330783A2 (en) * | 1982-07-09 | 1984-06-18 | Mannesmann Ag | Zpusob vyroby plechu s jemnozrnnou strukturou z nizce legovane oceli pro vyrobu trub velkeho prumeru |
-
1984
- 1984-04-24 DE DE19843415590 patent/DE3415590A1/de active Granted
-
1985
- 1985-02-01 EP EP85730016A patent/EP0160616B1/de not_active Expired
- 1985-02-01 AT AT85730016T patent/ATE38059T1/de not_active IP Right Cessation
- 1985-04-19 JP JP60084369A patent/JPS60234952A/ja active Pending
- 1985-04-23 BR BR8501925A patent/BR8501925A/pt unknown
- 1985-04-23 CA CA000479760A patent/CA1239332A/en not_active Expired
- 1985-04-24 US US06/726,799 patent/US4631095A/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
ATE38059T1 (de) | 1988-11-15 |
CA1239332A (en) | 1988-07-19 |
DE3415590C2 (enrdf_load_stackoverflow) | 1987-11-12 |
US4631095A (en) | 1986-12-23 |
EP0160616A3 (en) | 1986-12-30 |
JPS60234952A (ja) | 1985-11-21 |
BR8501925A (pt) | 1985-12-24 |
DE3415590A1 (de) | 1985-10-31 |
EP0160616A2 (de) | 1985-11-06 |
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