EP0146184A2 - Waschmaschine mit Mittel zur Erzeugung einer oxydierenden Natriumhypochloritlösung - Google Patents

Waschmaschine mit Mittel zur Erzeugung einer oxydierenden Natriumhypochloritlösung Download PDF

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Publication number
EP0146184A2
EP0146184A2 EP84201808A EP84201808A EP0146184A2 EP 0146184 A2 EP0146184 A2 EP 0146184A2 EP 84201808 A EP84201808 A EP 84201808A EP 84201808 A EP84201808 A EP 84201808A EP 0146184 A2 EP0146184 A2 EP 0146184A2
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EP
European Patent Office
Prior art keywords
cell
water
machine
level
container
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP84201808A
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English (en)
French (fr)
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EP0146184B1 (de
EP0146184A3 (en
Inventor
Claudio Civanelli
Ambrogio Vanetti
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Whirlpool International BV
Original Assignee
Philips Gloeilampenfabrieken NV
Whirlpool International BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Philips Gloeilampenfabrieken NV, Whirlpool International BV filed Critical Philips Gloeilampenfabrieken NV
Publication of EP0146184A2 publication Critical patent/EP0146184A2/de
Publication of EP0146184A3 publication Critical patent/EP0146184A3/en
Application granted granted Critical
Publication of EP0146184B1 publication Critical patent/EP0146184B1/de
Expired legal-status Critical Current

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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06F—LAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
    • D06F35/00—Washing machines, apparatus, or methods not otherwise provided for
    • D06F35/003—Washing machines, apparatus, or methods not otherwise provided for using electrochemical cells
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06F—LAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
    • D06F35/00—Washing machines, apparatus, or methods not otherwise provided for
    • D06F35/004—Washing machines, apparatus, or methods not otherwise provided for using chlorine generators

Definitions

  • This invention relates to an automatic laundry washing machine comprising a washing environment, a container for the salt (NaCl), a water reservoir connectable to a water source, and a cell for the electrochemical production of sodium hypochlorite (NaCIO) and hydraulically connected both to the water reservoir by way of the salt container and to the washing environment.
  • Automatic washing machines incorporating means for the in-situ production, in accordance with the wash cycle requirements, of given quantities of an oxidising agent which can be sodium hypochlorite, chlorine and the like, are already known.
  • European patent application 80810403.8 (publication number 31308) describes a washing machine comprising a reservoir containing a concentrated sodium chloride solution, a dispenser constituted by an electromagnetically controlled piston, and an electrochemical cell to which the dispenser supplies a given quantity of concentrated solution withdrawn from the reservoir.
  • the main drawback is the fact that salt deposits form on the dispenser and hinder its movement.
  • a further European patent application (publication number 83740) describes an automatic washing machine which produces gaseous chlorine and comprises a reservoir arranged to contain a metered quantity of water and hydraulically connected by way of a valve and the concentrated sodium chloride solution receptacle to an electrochemical cell in which the anode compartment is separated from the cathode compartment by a diaphragm.
  • the serious drawback of the machine in question is its constructional complexity, partly deriving from the need to make the water absorb the gaseous chlorine evolved in the anode compartment, this being done by using a bubble column.
  • a further drawback is the danger of the gaseous chlorine.
  • the main object of the present invention is to provide an automatic washing machine comprising a washing environment, a container for the salt (NaCl), a water reservoir connectable to a water source, and a cell for the electrochemical production of sodium hypochlorite (NaOCI) and hydraulically connected both to the water reservoir by way of the salt container and to the washing environment, which with regard to the production of the oxidising agent, i.e. the NaOCI starting from NaCl, is simple, safe and of reliable operation.
  • the oxidising agent i.e. the NaOCI starting from NaCl
  • an automatic washing machine characterised essentially in that the water reservoir and the electrochemical cell are also hydraulically connected together by way of a further path, and said cell is provided with level determination means to enable it to be filled to a predetermined level, in such a manner that said cell becomes filled with water as far as said level by way of said further path.
  • the reference numeral 1 indicates overall the housing of a laundry wasliing machine, which in known manner comprises a conduit or pipe 2 for its connection to a cock 3 of the water mains, a wash tub 4, a drum 5 mounted rotatably in the tub and driven byan electric motor (not shown), a discharge pump 6 with its suction side connected to the tub 4 and with its delivery side connected to a discharge pipe 7, a drawer or the like 8 with several compartments 61, 62 to receive the necessary wash product (detergents, witheners and the like ), a timer not shown, for -controlling the various stages of the wash programmes, and means, shown by way of example as a swivel-mounted nozzle 9 controlled by the timer, which selectively feed water to different points or compartments of the drawer 8 in accordance with the programme.
  • the drawer 8 comprises various compartments 61, 62 for the wash products.
  • the timer directs the nozzle 9 towards each of them in accordance with the requirements of the particular programme, in order to supply them with a stream of water which transfers said products through passages 63 into a receptacle 64 which is connected to the wash tub 4 by way of a conduit 65.
  • the washing machine also comprises a container 10 for the salt (NaCl) which is provided with a pipe 11 through which the user loads the salt.
  • the pipe is surrounded at a distance by a sleeve of lesser height 12, the upurpose of which is to discharge (see the arrow A') into a surrounding vessel 13 the liquid which, originating from the container 10, necessarily overflows when the salt is loaded.
  • the .pipe and sleeve are closed upperly by a plug 14 screwed on in a sealed manner.
  • the container 10, in which at least part of the salt is dissolved in water, is associated with a container 15 containing an ion exchange resin, the purpose of which is to soften the water used in at least one stage of the wash programmes.
  • the two containers 10, 15 can be connected together by way of a unidirectional solenoid valve EV4 controlled by the timer.
  • the salt container 10 is hydraulically connected by means of a conduit 16 and a solenoid valve EV3 (also controlled by the timer) to a water reservoir 17, which is positioned in the washing machine at a higher level than the container 10.
  • a dip pipe 18 By means of a dip pipe 18, the container 10 is connected to a rising pipe 19 extending into an electrochemical cell 20.
  • said cell comprises an anode 71 and a cathode 21, which are not separated by a diaphragm, and which can be. connected to a direct current electricity supply source by the timer.
  • the cell also comprises a discharge syphon 22 and, in one wall 26, a level determination port 23 of predetermined cross-section which determines the liquid level in the cell.
  • the cell 20 comprises a conduit 24 arranged to receive the water which is fed to it by the swivel-mounted nozzle 9 when this latter faces a cup 25 situated at the drawer 8.
  • the syphon 22 discharges the cell liquid into a collection receptacle 27, which is connected by the pipes 28, 29 and 30 both to the tub 4 and to the suction side of the pump 6.
  • the water reservoir 17 is disposed to the ⁇ de of the collection receptacle 27, and upperly comprises a side overflow 31 which enables part of the excess water overflowing from said reservoir to be discharged into the cell 20.
  • the remainder of the overflowing water falls from the sides of the bent overflow plate and into the underlying collection receptacle 27, and from here flows into the said pipe 28.
  • the water reservoir 17 is fed by the pipe 32, which is connected to the cock 3 by way of the solenoid valve EV2.
  • the pipe 32 opens above the level M, which the water can reach in the reservoir 17 and is at a higher level than the lever determination port 23 of the cell 20.
  • the resin container 15 is connected to the cock 3 by way of the pipe 33, the solenoid valve EV5 and a conventional pipe interruptor 34 which, in the limit, can be represented by a hole provided in the pipe wall.
  • the water from the solenoid valve EV5 is collected by the vessel 35 and is conveyed by the pipe 36 to the collection receptacle 27.
  • the resin container 15 is also connected to the nozzle 9 by way of the pipes 37 and 73 and the pipe interruptor 38.
  • the water leaving the interruptor 38 flows into the vessel 39 and from here to the pipe 29 through the connection 70.
  • the nozzle 9 is connected to the cock 3 by way of a solenoid valve EV1 and a pipe interruptor 40.
  • the water leaving this latter discharges into the collection receptacle 27 by way of the vessel 41 and the pipe 42.
  • the nozzle 9 can supply water to a vessel 43 connected to the .pipe 30 by way of the connection 72.
  • the container 10 contains brine (a saturated solution of NaCl in water) and undissolved salt, which have previously been loaded by the user.
  • the timer causes the valve EV2 to open so that mains water enters the reservoir 17.
  • this water reaches the level M, it discharges through the side overflow 31 into the underlying cell 20. In this latter, the water rises until it attains the level A-A set by the port 23, but without priming the syphon 22.
  • the valve EV2 is then closed when the water is at the level M in the reservoir 17 and at the level A-A in the cell 20.
  • the level B-B is lower than the level M but higher than the level A-A, because of the difference in density between brine and water.
  • the timer controls the solenoid valve EV5 so that mains water passes along the pipe 33 and into the container 15. This water pushes the brine (which, as will be more apparent hereinafter, is present from the end of the preceding laundry wash programme together with a large quantity of calcium ions) along the pipes 73, 37 until it reaches the nozzle 9. This latter is positioned above the vessel 43 so that the said brine becomes discharged from the machine through the pipes 73, 37, 7 the pump 6 being in operation. On termination of this brine discharge, the timer stops the pump 6, directs the nozzle towards one of the compartments 61, 62 containing the wash agents and keeps the valve EV5 open.
  • the mains water is softened in the container 15, is fed to the nozzle 9 through the pipes 73 and 37, and is finally mixed with detergent in order to flow through the pipe 65 to the wash tub 4, where it is used in the manner well known to the experts of the art.
  • the brine is electrolysed in the cell 20 to form NaClO.
  • the timer breaks the circuit of the electrodes 21 and 71, displaces the nozzle 9 in order to direct it (as shown in the figure) towards the cup 25, and simultaneously opens the valve EV1. Consequently mains water reaches the cell 20 through the pipe 24.
  • the throughput of the valve EV1 is greater than the throughput which can be discharged through the port 23, the level of the liquid contained in the cell 20 rises until it climbs the syphon 22.
  • the water overflows from the upper edge 60 of the wall 26 and into the receptacle 27, and from here passes through the pipes 28 and 29 and into the tub 4 (as the pump 6 is at rest), said tub partly being at a level less than the cell 20.
  • the timer closes the valve EV1 because of which, by virtue of the syphon 22 and without the need for using bottom solenoid valves, the entire contents of the cell 20 (i.e. NaCLO in aqueous solution) are discharged into the wash tub.
  • the laundry bleaching stage is then effected, as scheduled by the wash programme.
  • the last stage of the wash programme provides for the regeneration of the ion exchange resins.
  • the timer starts the pump 6 and opens the valves EV3, EV4.
  • the brine contained in this latter is then transferred through the va ve EV4 and into the resin container 15.
  • the water present in the container 15 is thus forced to rise under a modest thrust pressure through the pipe 71 until it reaches the vessel 39. From here the water falls through the pipes 70, 29, 30 to the pump 6, which expels it from the machine through the discharge pipe 7.
  • the machine When the wash programme finishes, the machine is in the same state as the commencement of the operation heretofore described, i.e. the valves EV1 etc. are all closed, the pump 6 is at rest, the electrode circuit 71, 21 is broken, the cell 20 and the reservoir 17 are empty, the container 10 contains brine with undissolved NaCl, and the container 15 contains the resins together with brine and a large quantity of calcium ions originating from the softening of the mains water.
  • the secondary advantages of the present invention include the fact that the syphon 22 effectively replaces a discharge valve at lesser cost, and that the rising pipe 19 is provided in order to prevent excessive dilution of the brine contained in the container 10.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Detail Structures Of Washing Machines And Dryers (AREA)
  • Filling, Topping-Up Batteries (AREA)
  • Detergent Compositions (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
EP84201808A 1983-12-16 1984-12-05 Waschmaschine mit Mittel zur Erzeugung einer oxydierenden Natriumhypochloritlösung Expired EP0146184B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IT24213/83A IT1169700B (it) 1983-12-16 1983-12-16 Macchina lavabiancheria con mezzi per produrre una soluzione ossidante di ipoclorito sodico
IT2421383 1983-12-16

Publications (3)

Publication Number Publication Date
EP0146184A2 true EP0146184A2 (de) 1985-06-26
EP0146184A3 EP0146184A3 (en) 1987-04-15
EP0146184B1 EP0146184B1 (de) 1989-06-07

Family

ID=11212573

Family Applications (1)

Application Number Title Priority Date Filing Date
EP84201808A Expired EP0146184B1 (de) 1983-12-16 1984-12-05 Waschmaschine mit Mittel zur Erzeugung einer oxydierenden Natriumhypochloritlösung

Country Status (4)

Country Link
EP (1) EP0146184B1 (de)
DE (1) DE3478622D1 (de)
ES (1) ES538566A0 (de)
IT (1) IT1169700B (de)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2113602A1 (de) * 2008-04-29 2009-11-04 Haier Group Corporation Waschmaschine mit Wasserlaufsystem
WO2013017476A1 (de) * 2011-07-29 2013-02-07 Henkel Ag & Co. Kgaa Wasch- oder reinigungsmittel mit elektrochemisch aktivierbarer mediatorverbindung
WO2019068337A1 (en) 2017-10-05 2019-04-11 Electrolux Appliances Aktiebolag WASHING MACHINE

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0031308A2 (de) * 1979-12-20 1981-07-01 Battelle Memorial Institute Automatische Wasch- oder Geschirrspülmaschine
EP0083740A1 (de) * 1981-12-14 1983-07-20 INDUSTRIE ZANUSSI S.p.A. Waschmaschine mit elektrochemischem Element

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0031308A2 (de) * 1979-12-20 1981-07-01 Battelle Memorial Institute Automatische Wasch- oder Geschirrspülmaschine
EP0083740A1 (de) * 1981-12-14 1983-07-20 INDUSTRIE ZANUSSI S.p.A. Waschmaschine mit elektrochemischem Element

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2113602A1 (de) * 2008-04-29 2009-11-04 Haier Group Corporation Waschmaschine mit Wasserlaufsystem
WO2013017476A1 (de) * 2011-07-29 2013-02-07 Henkel Ag & Co. Kgaa Wasch- oder reinigungsmittel mit elektrochemisch aktivierbarer mediatorverbindung
KR20140060506A (ko) * 2011-07-29 2014-05-20 헨켈 아게 운트 코. 카게아아 전기화학적으로 활성화가능한 매개체 화합물을 갖는 세척제 또는 세정제
US10435649B2 (en) 2011-07-29 2019-10-08 Henkel Ag & Co. Kgaa Washing or cleaning agent with electrochemically activatable mediator compound
WO2019068337A1 (en) 2017-10-05 2019-04-11 Electrolux Appliances Aktiebolag WASHING MACHINE
CN111164253A (zh) * 2017-10-05 2020-05-15 伊莱克斯家用电器股份公司 洗衣机

Also Published As

Publication number Publication date
EP0146184B1 (de) 1989-06-07
IT8324213A0 (it) 1983-12-16
ES8600439A1 (es) 1985-09-16
DE3478622D1 (en) 1989-07-13
IT1169700B (it) 1987-06-03
EP0146184A3 (en) 1987-04-15
ES538566A0 (es) 1985-09-16

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