EP0139330B1 - Adjuvant pour le rinçage - Google Patents

Adjuvant pour le rinçage Download PDF

Info

Publication number
EP0139330B1
EP0139330B1 EP84201449A EP84201449A EP0139330B1 EP 0139330 B1 EP0139330 B1 EP 0139330B1 EP 84201449 A EP84201449 A EP 84201449A EP 84201449 A EP84201449 A EP 84201449A EP 0139330 B1 EP0139330 B1 EP 0139330B1
Authority
EP
European Patent Office
Prior art keywords
layered clay
composition according
rinse
aqueous
rinse aid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP84201449A
Other languages
German (de)
English (en)
Other versions
EP0139330A2 (fr
EP0139330A3 (en
Inventor
Machiel Goedhart
Franciscus Hermannus Gortemaker
Hermanus Christoffel Kemper
Hendrik Simon Kielman
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Unilever PLC
Unilever NV
Original Assignee
Unilever PLC
Unilever NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Unilever PLC, Unilever NV filed Critical Unilever PLC
Priority to AT84201449T priority Critical patent/ATE54326T1/de
Publication of EP0139330A2 publication Critical patent/EP0139330A2/fr
Publication of EP0139330A3 publication Critical patent/EP0139330A3/en
Application granted granted Critical
Publication of EP0139330B1 publication Critical patent/EP0139330B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246—Silicates, e.g. diatomaceous earth
    • C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
    • C11D3/126—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite in solid compositions

Definitions

  • the present invention relates to an improvement in the rinse step of machine dishwashing operations.
  • the articles to be cleaned are first cleaned in a main wash step, and subsequently rinsed several times to rinse away any adhering main wash product and remaining soil. It is customary to add to the rinsing water a rinse aid composition which causes the articles to dry more evenly and improves the visual appearance of the articles when dry. Although such rinse aid compositions improve said visual appearance in comparison with articles which have not been rinsed with a rinse aid containing rinse liquor, said visual appearance may still need improvement, as, despite the use of a rinse aid, some film- and spot-formation may still occur.
  • the present invention therefore relates to an improved rinse step in a machine dishwashing operation, wherein the improvement comprises the use, in the rinse liquor, of an effective amount of a layered clay.
  • Rinsing of the cleaned articles with a rinse liquor which comprises such an effective am6unt of a layered clay reduces the formation of spots on the articles when dry.
  • the layered clay minerals suitable for use in the present invention belong to the geological classes of the smectites, the kaolins, the illites, the chlorites, the attapulgites and the mixed layer clays.
  • Typical examples of specific clays belonging to these classes are:
  • the layered clay minerals may be either naturally occurring or synthetic.
  • Preferred clay minerals for use in the present invention are natural or synthetic hectorites, montmorillonites and bentonites, and of these the hectorites are especially preferred.
  • Many of the above clays are commercially available, and typical examples of commercial hectorites are the Laponites ex Laporte Industries Ltd, England; Veegum Pro and Veegum F ex R. T. Vanderbilt, U.S.A.; the Barasyms, Macaloids and Propaloids ex Baroid Division, National Read Comp., U.S.A. (The above means are trade marks of the companies concerned).
  • Laponite S Laponite S
  • Laponite XLS Laponite RD
  • Laponite RDS Trade Mark
  • This is a synthetic hectorite having the following characteristics: analysis (dry basis) Si0 2 59.8%, MgO 27.2%, Na 2 0 4.4%, Li 2 0 0.8%, structural H 2 0 7.7%, with the addition of tetrasodium pyrophosphate (6%); specific gravity 2.53; bulk density 1.0.
  • the layered clay may be added to the rinse water as such, or it may be added thereto in the form of a liquid dispersion of the clay in water or in the form of a composition in any suitable physical form comprising the clay and other suitable or desirable ingredients.
  • Such other suitable ingredients may be low levels of wetting or detergent surfactants, organic acids, hydrotropes, alcohols, perfumes, germicides, anticorrosion agents, etc.
  • Suitable physical forms are powders, liquids, tablets, blocks, granulates, etc.
  • the level of the layered clay in the rinse liquor should be such that the rinse liquor contains from 0.001-1 g of the clay per litre.
  • the rinse liquor with the layered clay is effective at both higher and lower rinsing temperatures.
  • the normal programme was used, at a temperature of 65°C.
  • the water hardness was 9° German hardness.
  • a commercially available machine dishwashing product was used at a dosage of 3 g/I.
  • Example 1 The procedure of Example 1 was repeated, using another machine dishwashing product in the main wash step, and using in the rinse step either no rinse aid at all, or a commercially available rinse aid, or a rinse aid of the following formulation:
  • the dosage of the rinse aid was 2.5 ml in the rinse water (corresponding to 0.015 g/l of Laponite XLS).
  • the spot-formation results were as follows:
  • compositions according to the invention are suitable rinse aid compositions according to the invention:

Landscapes

  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Non-Silver Salt Photosensitive Materials And Non-Silver Salt Photography (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)

Claims (13)

1. Utilisation d'une argile feuilletée comme adjuvant de rinçage ou composant de rinçage dans le stade de rinçage aqueux d'un procédé de lavage de vaisselle en machine.
2. Utilisation selon la revendication 1, dans laquelle l'adjuvant au rinçage doit être ajouté à la liqueur de rinçage de façon à obtenir dans celle-ci une proportion d'argile de 0,001 g à 1 g par litre.
3. Utilisation selon la revendication 1 ou 2, dans laquelle l'argile fueilletée est une hectorite, une montmorillonite ou une bentonite.
4. Utilisation selon la revendication 3, dans laquelle l'argile fueilletée est une hectorite synthétique.
5. Composition solide d'adjuvant au rinçage pour utilisation dans le stade de rinçage aqueux d'un procédé de lavage de vaisselle en machine, caractérisée en ce qu'elle comprend une argile feuilletée en mélange avec une proportion relativement faible d'un surfactif mouillant ou détergent.
6. Composition solide selon la revendication 5, dans laquelle la couche feuilletée est en hectorite, montmorillonite ou bentonite.
7. Composition solide selon la revendication 6, dans laquelle la couche feuilletée est une hectorite synthétique.
8. Composition aqueuse liquide d'adjuvant au rinçage pour utilisation dans le stade de rinçage aqueux d'un procédé de lavage de vaisselle en machine, comprenant une faible proportion d'un surfactif mouillant ou détergent et au moins 74% en poids d'eau, caractérisée en ce qu'elle comprend une argile feuilletée présente en une proportion pondérale d'au moins 1,8 fois celle du surfactif.
9. Composition aqueuse selon la revendication 8, dans laquelle le surfactif est un surfactif non ionique.
10. Composition aqueuse selon la revendication 8 ou 9, qui comprend jusqu'à 20% en poids d'un alcool solvant.
11. Composition aqueuse selon l'une quelconque des revendications 8 à 10, dans laquelle l'argile feuilletée est une hectorite, une montmorillonite ou une bentonite.
12. Composition aqueuse selon la revendication 11, dans laquelle l'argile feuilletée est une hectorite synthétique.
13. Composition aqueuse selon l'une quelconque des revendications 8 à 12, dans laquelle la proportion des argiles feuilletées est d'au moins 3,6% en poids.
EP84201449A 1983-10-20 1984-10-10 Adjuvant pour le rinçage Expired - Lifetime EP0139330B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT84201449T ATE54326T1 (de) 1983-10-20 1984-10-10 Spuelhilfsmittel.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB8328077 1983-10-20
GB838328077A GB8328077D0 (en) 1983-10-20 1983-10-20 Rinse aid

Publications (3)

Publication Number Publication Date
EP0139330A2 EP0139330A2 (fr) 1985-05-02
EP0139330A3 EP0139330A3 (en) 1987-08-05
EP0139330B1 true EP0139330B1 (fr) 1990-07-04

Family

ID=10550501

Family Applications (1)

Application Number Title Priority Date Filing Date
EP84201449A Expired - Lifetime EP0139330B1 (fr) 1983-10-20 1984-10-10 Adjuvant pour le rinçage

Country Status (9)

Country Link
EP (1) EP0139330B1 (fr)
JP (1) JPS60110792A (fr)
AT (1) ATE54326T1 (fr)
AU (1) AU566578B2 (fr)
DE (1) DE3482635D1 (fr)
GB (1) GB8328077D0 (fr)
NO (1) NO163963C (fr)
PT (1) PT79379B (fr)
ZA (1) ZA848108B (fr)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB8616615D0 (en) * 1986-07-08 1986-08-13 Unilever Plc Rinse aid
ZA885894B (en) * 1987-08-21 1990-04-25 Colgate Palmolive Co Thixotropic clay aqueous suspensions containing polycarboxylic acids and metal salts thereof stabilizers
US4828750A (en) * 1987-12-02 1989-05-09 Colgate-Polmolive Company Fabric rinse composition to remove surfactant residues
DE3934675C1 (fr) * 1989-10-18 1991-05-23 Joh. A. Benckiser Gmbh, 6700 Ludwigshafen, De
JP2004518786A (ja) * 2001-01-30 2004-06-24 ザ、プロクター、エンド、ギャンブル、カンパニー 食器表面を改質するためのすすぎを助ける表面コーティング組成物
US8689599B2 (en) 2003-08-28 2014-04-08 Timberline Tool, L.L.C. Clamp and repair tool
US8316684B2 (en) 2003-08-28 2012-11-27 Timberline Tool, L.L.C. Clamp and repair tool
CA2536064C (fr) 2003-08-28 2013-01-08 Timberline Tool & Casting, Inc. Pince et outil de reparation
US9109740B2 (en) 2005-01-31 2015-08-18 Timberline Tool, L.L.C. Multi-layered patch system and method
CN105002000B (zh) * 2015-07-03 2018-02-02 承德人和矿业有限责任公司 一种去污粉及其制备方法和用途

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1303810A (fr) * 1969-05-02 1973-01-24
US4005027A (en) * 1973-07-10 1977-01-25 The Procter & Gamble Company Scouring compositions
DE2539733C2 (de) * 1974-09-09 1986-08-21 The Procter & Gamble Co., Cincinnati, Ohio Flüssiges Reinigungsmittel mit Schmirgelwirkung
JPS5311480A (en) * 1976-07-15 1978-02-01 Ishikawajima Harima Heavy Ind Co Ltd Sea freight transporting process
DE3138425A1 (de) * 1981-09-26 1983-04-14 Henkel KGaA, 4000 Düsseldorf "verwendung eines pastoesen reinigers in geschirrspuelmaschinen"
JPS606794A (ja) * 1983-06-27 1985-01-14 ライオン株式会社 硬表面用液体洗浄剤
GB8328076D0 (en) * 1983-10-20 1983-11-23 Unilever Plc Dishwashing compositions

Also Published As

Publication number Publication date
PT79379A (en) 1984-11-01
DE3482635D1 (de) 1990-08-09
AU3442884A (en) 1985-04-26
EP0139330A2 (fr) 1985-05-02
NO844170L (no) 1985-04-22
NO163963B (no) 1990-05-07
NO163963C (no) 1990-08-15
JPH0321600B2 (fr) 1991-03-25
AU566578B2 (en) 1987-10-22
EP0139330A3 (en) 1987-08-05
PT79379B (en) 1987-02-09
ATE54326T1 (de) 1990-07-15
JPS60110792A (ja) 1985-06-17
ZA848108B (en) 1986-06-25
GB8328077D0 (en) 1983-11-23

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