EP0128788B1 - Flüssige Sicherheitszusammensetzung für die Zündung von festen Brennstoffen - Google Patents
Flüssige Sicherheitszusammensetzung für die Zündung von festen Brennstoffen Download PDFInfo
- Publication number
- EP0128788B1 EP0128788B1 EP84400933A EP84400933A EP0128788B1 EP 0128788 B1 EP0128788 B1 EP 0128788B1 EP 84400933 A EP84400933 A EP 84400933A EP 84400933 A EP84400933 A EP 84400933A EP 0128788 B1 EP0128788 B1 EP 0128788B1
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- EP
- European Patent Office
- Prior art keywords
- composition
- accordance
- compound
- weight
- radical
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
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- 239000000203 mixture Substances 0.000 title claims abstract description 35
- 239000007788 liquid Substances 0.000 title claims abstract description 23
- 239000004449 solid propellant Substances 0.000 title claims abstract description 13
- 229910052500 inorganic mineral Chemical group 0.000 claims abstract description 15
- 239000011707 mineral Chemical group 0.000 claims abstract description 15
- 150000001875 compounds Chemical class 0.000 claims abstract description 12
- 150000003839 salts Chemical group 0.000 claims abstract description 10
- 229910052723 transition metal Inorganic materials 0.000 claims abstract description 5
- 150000003624 transition metals Chemical class 0.000 claims abstract description 5
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract 4
- 239000001257 hydrogen Substances 0.000 claims abstract 4
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims abstract 4
- 239000000654 additive Substances 0.000 claims description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- 229930195733 hydrocarbon Natural products 0.000 claims description 11
- 150000002430 hydrocarbons Chemical class 0.000 claims description 11
- 230000000996 additive effect Effects 0.000 claims description 8
- 229910052751 metal Inorganic materials 0.000 claims description 6
- 239000002184 metal Substances 0.000 claims description 6
- 239000004094 surface-active agent Substances 0.000 claims description 6
- 239000004215 Carbon black (E152) Substances 0.000 claims description 5
- 150000002739 metals Chemical class 0.000 claims description 4
- -1 organic peroxide compounds Chemical class 0.000 claims description 4
- 150000001451 organic peroxides Chemical class 0.000 claims description 4
- 125000002524 organometallic group Chemical group 0.000 claims description 3
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- 150000002902 organometallic compounds Chemical class 0.000 claims description 2
- 230000000737 periodic effect Effects 0.000 claims description 2
- 238000005191 phase separation Methods 0.000 claims description 2
- 229920001451 polypropylene glycol Polymers 0.000 claims description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- 229940126062 Compound A Drugs 0.000 claims 2
- NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 claims 2
- 239000006185 dispersion Substances 0.000 claims 1
- 230000001590 oxidative effect Effects 0.000 claims 1
- 238000010587 phase diagram Methods 0.000 claims 1
- 229920001223 polyethylene glycol Polymers 0.000 claims 1
- 229910020543 Cm H2m+1 Inorganic materials 0.000 abstract 1
- 239000007858 starting material Substances 0.000 description 48
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 17
- 239000000446 fuel Substances 0.000 description 15
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 12
- 235000010755 mineral Nutrition 0.000 description 10
- 239000007787 solid Substances 0.000 description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 238000002485 combustion reaction Methods 0.000 description 6
- 229960003280 cupric chloride Drugs 0.000 description 6
- 150000004683 dihydrates Chemical class 0.000 description 6
- 235000019441 ethanol Nutrition 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 239000000470 constituent Substances 0.000 description 3
- 239000012467 final product Substances 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 3
- 230000004580 weight loss Effects 0.000 description 3
- 229910002016 Aerosil® 200 Inorganic materials 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical class [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 150000001342 alkaline earth metals Chemical class 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- VNZQQAVATKSIBR-UHFFFAOYSA-L copper;octanoate Chemical compound [Cu+2].CCCCCCCC([O-])=O.CCCCCCCC([O-])=O VNZQQAVATKSIBR-UHFFFAOYSA-L 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 238000004880 explosion Methods 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 150000002823 nitrates Chemical class 0.000 description 2
- 125000005474 octanoate group Chemical group 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical class OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 2
- 150000002978 peroxides Chemical class 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 239000001993 wax Substances 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- PCTMTFRHKVHKIS-BMFZQQSSSA-N (1s,3r,4e,6e,8e,10e,12e,14e,16e,18s,19r,20r,21s,25r,27r,30r,31r,33s,35r,37s,38r)-3-[(2r,3s,4s,5s,6r)-4-amino-3,5-dihydroxy-6-methyloxan-2-yl]oxy-19,25,27,30,31,33,35,37-octahydroxy-18,20,21-trimethyl-23-oxo-22,39-dioxabicyclo[33.3.1]nonatriaconta-4,6,8,10 Chemical compound C1C=C2C[C@@H](OS(O)(=O)=O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2.O[C@H]1[C@@H](N)[C@H](O)[C@@H](C)O[C@H]1O[C@H]1/C=C/C=C/C=C/C=C/C=C/C=C/C=C/[C@H](C)[C@@H](O)[C@@H](C)[C@H](C)OC(=O)C[C@H](O)C[C@H](O)CC[C@@H](O)[C@H](O)C[C@H](O)C[C@](O)(C[C@H](O)[C@H]2C(O)=O)O[C@H]2C1 PCTMTFRHKVHKIS-BMFZQQSSSA-N 0.000 description 1
- BGJSXRVXTHVRSN-UHFFFAOYSA-N 1,3,5-trioxane Chemical compound C1OCOCO1 BGJSXRVXTHVRSN-UHFFFAOYSA-N 0.000 description 1
- CGKQZIULZRXRRJ-UHFFFAOYSA-N Butylone Chemical compound CCC(NC)C(=O)C1=CC=C2OCOC2=C1 CGKQZIULZRXRRJ-UHFFFAOYSA-N 0.000 description 1
- UDHXJZHVNHGCEC-UHFFFAOYSA-N Chlorophacinone Chemical compound C1=CC(Cl)=CC=C1C(C=1C=CC=CC=1)C(=O)C1C(=O)C2=CC=CC=C2C1=O UDHXJZHVNHGCEC-UHFFFAOYSA-N 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- DUFKCOQISQKSAV-UHFFFAOYSA-N Polypropylene glycol (m w 1,200-3,000) Chemical compound CC(O)COC(C)CO DUFKCOQISQKSAV-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 125000003158 alcohol group Chemical group 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- RHZUVFJBSILHOK-UHFFFAOYSA-N anthracen-1-ylmethanolate Chemical compound C1=CC=C2C=C3C(C[O-])=CC=CC3=CC2=C1 RHZUVFJBSILHOK-UHFFFAOYSA-N 0.000 description 1
- 239000003830 anthracite Substances 0.000 description 1
- 235000021168 barbecue Nutrition 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- QUQFTIVBFKLPCL-UHFFFAOYSA-L copper;2-amino-3-[(2-amino-2-carboxylatoethyl)disulfanyl]propanoate Chemical compound [Cu+2].[O-]C(=O)C(N)CSSCC(N)C([O-])=O QUQFTIVBFKLPCL-UHFFFAOYSA-L 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 238000002372 labelling Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 125000005609 naphthenate group Chemical group 0.000 description 1
- 239000006259 organic additive Substances 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- ODGAOXROABLFNM-UHFFFAOYSA-N polynoxylin Chemical compound O=C.NC(N)=O ODGAOXROABLFNM-UHFFFAOYSA-N 0.000 description 1
- VKJKEPKFPUWCAS-UHFFFAOYSA-M potassium chlorate Chemical compound [K+].[O-]Cl(=O)=O VKJKEPKFPUWCAS-UHFFFAOYSA-M 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 229910001961 silver nitrate Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L11/00—Manufacture of firelighters
- C10L11/04—Manufacture of firelighters consisting of combustible material
Definitions
- Prepared fire starters can be classified into three categories according to whether they are in solid form, liquid form or gelled form.
- Solid fire starters are themselves separable into two classes according to whether they contain or do not contain liquid fuel.
- the porous substrates are most often cellulose, or wood agglomerates, the polymer matrices of urea-formaldehyde or phenol-formaldehyde resins.
- Liquid fuels are generally hydrocarbons, low molecular weight alcohols and their mixtures.
- solid fire starters do not contain liquid fuels, they simply consist of one or more solid fuels at room temperature. This is the case of metaformaldehyde cubes or even wax or paraffin bars.
- Liquid fire starters are most often formed by one or more hydrocarbons, by one or more alcohols or by mixtures of alcohols or hydrocarbons.
- Gelled fire starters are basically made up of one or more compounds with one or more alcohol functions, such as ethyl alcohol or butyl glycol, one or more hydrocarbons, or mixtures of these two classes of associated products. optionally with a solvent of very polar nature such as water. Gelation is generally obtained by the addition of long-chain organo-metallic salts, silica with high absorption power or organic polymers effective in very polar media.
- solid fire starters when solid fire starters contain liquid fuels, they must be packaged in films ensuring an effective barrier against evaporation. This barrier is never perfect. storing these types of fire starters is not safe, especially during hot periods of the year.
- Liquid fire starters are most often made up of a single component.
- This component is either a hydrocarbon or a low molecular weight alcohol.
- mixtures of liquid fuels or solutions of a solid fuel such as wax or paraffin are often used in a fuel acting as a solvent.
- Liquid fire starters do not have the same technical drawbacks as solid fire starters because they can easily be distributed over a large area of solid fuel which is to be ignited. However, they still have major drawbacks. First of all, they are dangerous for the user due to the often very low flash points, further subjecting the marketing of these products to special labeling which is an important obstacle to their marketing.
- combustion improvement additives which is nevertheless particularly effective and therefore desirable in the case of a liquid fire starter, is made difficult because of the insolubility or very low solubility of the most effective additives. in the liquid compositions generally used. This is particularly the case for combustion catalysts based on heavy metals and peroxides mainly when they are in the form of mineral salts.
- Fire starters in gelled form are usually packaged in sachets or bottles so as to be poured onto the solid fuel to be ignited.
- sachets In the form of dose sachets, they have the same technical drawbacks as solids since they only allow one-off ignition of the fuel, while not presenting the same dangers during storage, their packaging being generally sealed.
- bottles can be distributed on solid fuel in the same way as liquids but then have the disadvantage of remaining on the surface of the fuel without penetrating it, thus making it possible to obtain a low efficiency.
- the present invention therefore relates to the production of an improved liquid fire starter for safety and usable for the ignition of all solid fuels.
- This fire starter is characterized in that it comprises at least two constituents A and B as defined below and that it can also contain at least one of the two additives C and D as also defined below , the assembly constituting a stable liquid under normal storage conditions.
- a / Component A comprises a compound or a mixture of compounds having the general formula: with n, a, b and m equal or different representing values between 1 and 12.
- the compounds which are particularly useful in the production of fire starters according to the invention are the methyl and ethyl, ethyl, propyl or butyl mono and di-ethers of mono- and polyethylenes and mono- and polypropylene glycols.
- This constituent A can contain organometallic additives among which mention may be made of fatty soaps of metals and organic complexes of metals.
- organic peroxides there may be mentioned, without this list being limiting, peroxides derived from aldehydes, ketones, esters, alkyl hydroperoxides and the like.
- mineral additives there may be mentioned, without this list being limiting, chlorates, perchlorates and nitrates of alkali or alkaline-earth metals.
- Component A can also contain surfactants.
- surfactants preference will be given to those which make it possible to obtain a final product in the form of a fluid solution, stable under normal conditions of storage and use.
- Component B comprises one or more mineral salts or complexes of the transition metals.
- the compounds particularly useful in the production of a fire starter of the invention are the salts and mineral complexes of the metals of column 1 b according to the periodic classification of the elements according to Mendeursev, namely the mineral salts and complexes of copper , silver and gold.
- Additive C mainly consists of water. It may also contain one or more mineral salts or complexes of the transition metals as defined above, within the limit of their solubility.
- This additive can also contain other mineral compounds such as chlorates, perchlorates and nitrates of alkali or alkaline earth metals. It can also contain one or more surfactants chosen so as to obtain a final product in the form of a stable fluid solution under normal conditions of storage and use.
- Additive D mainly consists of a hydrocarbon.
- This additive can also contain one or more organic additives or organic peroxides as defined under A. It can also contain one or more surfactants chosen to allow the production of a final product in the form of a fluid solution stable under normal conditions of storage and use.
- the weight proportions w, x, y, z in the various combinations AB, ABC, ABD, ABCD are easily determined in each case by those skilled in the art by establishing the corresponding binary, ternary or quaternary diagram delimiting the zones of stability of the composition.
- a liquid composition is considered to be stable when it does not exhibit phase separation in the formulation.
- a fire starter that can be used under normal lighting conditions at a temperature above its flash point must be considered dangerous.
- the AFNOR T 60-103 device was used with a Luchaire cutter with cover for the measurement of flash points.
- a regular shaped agglomerated charcoal ball weighing 39 ⁇ 1 g was chosen as fuel. It is weighed before and after immersion for 5 minutes in a fire starter solution. Note the amount of fire starter absorbed. The ball thus impregnated is then ignited and its weight loss is followed for 30 minutes from the time when the quantity of absorbed fire starter has theoretically burned.
- a fire starter is prepared according to the formula: Monoethyl ether of monoethylene glycol: 90 parts by weight said below butyl glycol
- Cupric chloride (dihydrate) 10 parts by weight
- This fire starter is compared to those of butylglycol alone.
- the results show the excellent ignition performance obtained.
- the 70 ° C flash point guarantees safety in use under normal conditions.
- This fire starter is compared to those of "Shellsol K” alone, butylglycolseul and the mixture of these two solvents (50% / 50%).
- the flash point of 64 ° C maintains a sufficient degree of security for normal conditions of use.
- the performance obtained is greatly improved compared to the products used alone and to their mixture.
- This fire starter is compared with those of butylglycol alone, Shellsol K alone and the mixture of the two solvents (50% / 50%).
- This table illustrates the excellent results obtained, both in terms of safety since the flash point no longer exists, thus eliminating any explosion explosion of the product vapors when sprayed on embers for example, as in terms of ignition efficiency since the performance obtained is superior to that of a conventional additive.
- Viscosity (Brookfield RVT viscometer; needle No. 3; 20 revolutions per minute) 1,200 mPas (centipoises)
- Weight loss 1 g (burning of the ball erred after 5 minutes).
- This fire starter is compared to those of a butylglycol / water / "Shellsol K" (47.5 / 5 / 47.5) mixture without additives.
- the results show the excellent performance obtained with the composition according to the invention.
- the flash point is higher than normal temperatures for using a fire starter.
- This fire starter is compared to those of a butylglycol / water / "Shellsol K" (47.5 / 5 / 47.5) mixture without additives.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Manufacturing & Machinery (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Fire-Extinguishing Compositions (AREA)
- Liquid Carbonaceous Fuels (AREA)
- Solid Fuels And Fuel-Associated Substances (AREA)
- Non-Portable Lighting Devices Or Systems Thereof (AREA)
- Fire-Extinguishing By Fire Departments, And Fire-Extinguishing Equipment And Control Thereof (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Compounds Of Unknown Constitution (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Claims (7)
- Flüssiges Sicherheitszündmittel für brennbare Feststoffe dadurch gekennzeichnet, daß es mindestens eine Verbindung der allgemeinen FormelR3 ein Rest CmH2m+1 oder Wasserstoff ist, a, b, n und m, die gleich oder verschieden sein können, Werte zwischen 1 und 12 darstellen, und eine Verbindung B mit einem Gehalt an mindestens einem Salz oder einem mineralischen Komplex eines Übergangsmetalls enthält.
- 2. Mittel nach Anspruch 1, dadurch gekennzeichnet, daß die Verbindung A ausgewählt ist aus den Methyl-, Propyl- und Butylmono- und -diäthern von Mono- und Polyäthylenglykolen und Mono- und Polypropylenglykolen.
- 3. Mittel nach Anspruch 1 oder Anspruch 2, dadurch gekennzeichnet, daß die Verbindung A ein Additiv ausgewählt entsprechend seiner Löslichkeit aus den Organometallverbindungen, den organischen Peroxidverbindungen, den oxidierenden Alkali- oder Erdalkalimineralsalzen, den oberflächenaktiven Mitteln und den verträglichen Mischungen hievon enthält.
- 4. Mittel nach einem der Ansprüche 1 bis 3, dadurch gekennzeichnet, daß das Übergangsmetall der Verbindung B ausgewählt ist aus den Elementen der Gruppe 1b des Periodischen Systems der Elemente von Mendelejew.
- 5. Mittel nach einem der Ansprüche 1 bis 4, dadurch gekennzeichnet, daß es mindestens eines der beiden Additive (C, D) in den durch die Diagramme der Phase (A, B, C), (A, B, D) oder (A, B, C, D) gegebenen Gewichtsverhältnissen (y, z) entsprechend einer stabilen Zusammensetzung, die unter den normalen Lagerungsbedingungen keine Phasentrennung aufweist, wobei Additiv C hauptsächlich Wasser und das Additiv D hauptsächlich mindestens ein Kohlenwasserstoff ist.
- 6. Mittel nach Anspruch 5, dadurch gekennzeichnet, daß das genannte Wasser in Dispersion einen Anteil mindestens eines Salzes oder eines mineralischen Komplexes eines Übergangsmetalls der Gruppe 1b des Periodischen Systems der Elemente von Mendelejew, einer mineralischen Sauerstoffverbindung, eines oberflächenaktiven Mittels oder einer verträglichen Mischung hievon aufweist.
- 7. Mittel nach Anspruch 5 oder 6, dadurch gekennzeichnet, daß der genannte Kohlenwasserstoff dispergiert mindestens ein Organometallderivat, ein organisches Peroxid, ein oberflächenaktives Mittel oder eine verträgliche Mischung entsprechend der Löslichkeit hievon aufweist.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT84400933T ATE23358T1 (de) | 1983-05-10 | 1984-05-09 | Fluessige sicherheitszusammensetzung fuer die zuendung von festen brennstoffen. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR8307773A FR2545833B1 (fr) | 1983-05-10 | 1983-05-10 | Composition liquide de securite pour l'allumage de combustibles solides |
FR8307773 | 1983-05-10 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0128788A1 EP0128788A1 (de) | 1984-12-19 |
EP0128788B1 true EP0128788B1 (de) | 1986-11-05 |
Family
ID=9288743
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP84400933A Expired EP0128788B1 (de) | 1983-05-10 | 1984-05-09 | Flüssige Sicherheitszusammensetzung für die Zündung von festen Brennstoffen |
Country Status (11)
Country | Link |
---|---|
EP (1) | EP0128788B1 (de) |
AT (1) | ATE23358T1 (de) |
AU (1) | AU564262B2 (de) |
DE (1) | DE3461198D1 (de) |
DK (1) | DK165122C (de) |
FR (1) | FR2545833B1 (de) |
GR (1) | GR82090B (de) |
IE (1) | IE57371B1 (de) |
NZ (1) | NZ208115A (de) |
PT (1) | PT78560B (de) |
ZA (1) | ZA843206B (de) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2727688B1 (fr) * | 1995-12-04 | 1997-05-09 | Jacquelin Guy | Produits combustibles liquides, brulant avec des flammes de couleurs variees. dispositifs d'eclairage decoratifs simplifies mettant en oeuvre ces produits |
DE202007009186U1 (de) * | 2007-06-29 | 2007-09-06 | Schiller, Alfons | Brennstoff zum Beheizen einer Einrichtung zum Grillen |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1494234A (fr) * | 1966-07-26 | 1967-09-08 | Sinnova Ou Sadic | Agent de combustion |
CH492010A (de) * | 1967-05-25 | 1970-06-15 | Chiswick Products Ltd | Feueranzünder |
GB1256264A (en) * | 1969-05-21 | 1971-12-08 | Reckitt And Coleman Products L | Improvements in or relating to firelighters |
NL7610483A (nl) * | 1975-09-23 | 1977-03-25 | Hansruedi Zahner | Vast lichaam voor het opwekken van vuur door verbranding en werkwijze ter vervaardiging van een dergelijk vast lichaam. |
-
1983
- 1983-05-10 FR FR8307773A patent/FR2545833B1/fr not_active Expired
-
1984
- 1984-04-30 ZA ZA843206A patent/ZA843206B/xx unknown
- 1984-05-08 GR GR74642A patent/GR82090B/el unknown
- 1984-05-08 PT PT78560A patent/PT78560B/pt not_active IP Right Cessation
- 1984-05-09 IE IE1148/84A patent/IE57371B1/en not_active IP Right Cessation
- 1984-05-09 DK DK229784A patent/DK165122C/da not_active IP Right Cessation
- 1984-05-09 NZ NZ208115A patent/NZ208115A/en unknown
- 1984-05-09 EP EP84400933A patent/EP0128788B1/de not_active Expired
- 1984-05-09 AU AU27832/84A patent/AU564262B2/en not_active Ceased
- 1984-05-09 AT AT84400933T patent/ATE23358T1/de not_active IP Right Cessation
- 1984-05-09 DE DE8484400933T patent/DE3461198D1/de not_active Expired
Also Published As
Publication number | Publication date |
---|---|
DK165122B (da) | 1992-10-12 |
EP0128788A1 (de) | 1984-12-19 |
NZ208115A (en) | 1986-10-08 |
DK229784D0 (da) | 1984-05-09 |
AU2783284A (en) | 1984-11-15 |
FR2545833A1 (fr) | 1984-11-16 |
AU564262B2 (en) | 1987-08-06 |
FR2545833B1 (fr) | 1985-08-23 |
PT78560A (fr) | 1984-06-01 |
DK165122C (da) | 1993-11-08 |
DK229784A (da) | 1984-11-11 |
DE3461198D1 (en) | 1986-12-11 |
IE841148L (en) | 1984-11-10 |
ATE23358T1 (de) | 1986-11-15 |
IE57371B1 (en) | 1992-08-12 |
PT78560B (fr) | 1986-07-14 |
GR82090B (de) | 1984-12-13 |
ZA843206B (en) | 1984-12-24 |
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