EP0125170B1 - Procédé de blanchiment des textiles en présence de particules de fer ou de rouille - Google Patents
Procédé de blanchiment des textiles en présence de particules de fer ou de rouille Download PDFInfo
- Publication number
- EP0125170B1 EP0125170B1 EP84400861A EP84400861A EP0125170B1 EP 0125170 B1 EP0125170 B1 EP 0125170B1 EP 84400861 A EP84400861 A EP 84400861A EP 84400861 A EP84400861 A EP 84400861A EP 0125170 B1 EP0125170 B1 EP 0125170B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- bleaching
- bath
- iron
- sodium
- process according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000004061 bleaching Methods 0.000 title claims description 23
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 title claims description 16
- 238000000034 method Methods 0.000 title claims description 11
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 title claims description 10
- 229910052742 iron Inorganic materials 0.000 title claims description 8
- 239000002245 particle Substances 0.000 title claims description 8
- 239000004753 textile Substances 0.000 title claims description 8
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical group OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 8
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 8
- 239000007800 oxidant agent Substances 0.000 claims description 6
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical group [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 claims description 5
- 229910000397 disodium phosphate Inorganic materials 0.000 claims description 5
- 235000019800 disodium phosphate Nutrition 0.000 claims description 5
- 239000001488 sodium phosphate Substances 0.000 claims description 5
- KEZYHIPQRGTUDU-UHFFFAOYSA-N 2-[dithiocarboxy(methyl)amino]acetic acid Chemical compound SC(=S)N(C)CC(O)=O KEZYHIPQRGTUDU-UHFFFAOYSA-N 0.000 claims description 3
- 239000008139 complexing agent Substances 0.000 claims description 3
- PFUVRDFDKPNGAV-UHFFFAOYSA-N sodium peroxide Chemical compound [Na+].[Na+].[O-][O-] PFUVRDFDKPNGAV-UHFFFAOYSA-N 0.000 claims description 3
- 239000000080 wetting agent Substances 0.000 claims description 3
- 230000006866 deterioration Effects 0.000 claims description 2
- 229910000318 alkali metal phosphate Inorganic materials 0.000 claims 2
- STNGULMWFPMOCE-UHFFFAOYSA-N ethyl 4-butyl-3,5-dimethyl-1h-pyrrole-2-carboxylate Chemical compound CCCCC1=C(C)NC(C(=O)OCC)=C1C STNGULMWFPMOCE-UHFFFAOYSA-N 0.000 claims 1
- 239000004744 fabric Substances 0.000 description 12
- 210000001519 tissue Anatomy 0.000 description 10
- 239000000835 fiber Substances 0.000 description 6
- 229910019142 PO4 Inorganic materials 0.000 description 4
- 230000015556 catabolic process Effects 0.000 description 4
- 238000006731 degradation reaction Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 4
- 239000010452 phosphate Substances 0.000 description 4
- 238000004513 sizing Methods 0.000 description 4
- 229920000742 Cotton Polymers 0.000 description 3
- 229920002472 Starch Polymers 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 239000008107 starch Substances 0.000 description 3
- 235000019698 starch Nutrition 0.000 description 3
- 239000004382 Amylase Substances 0.000 description 2
- 102000013142 Amylases Human genes 0.000 description 2
- 108010065511 Amylases Proteins 0.000 description 2
- 229920006051 Capron® Polymers 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 235000019418 amylase Nutrition 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- CDMADVZSLOHIFP-UHFFFAOYSA-N disodium;3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane;decahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].O1B([O-])OB2OB([O-])OB1O2 CDMADVZSLOHIFP-UHFFFAOYSA-N 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000004043 dyeing Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 2
- 238000005470 impregnation Methods 0.000 description 2
- 239000013528 metallic particle Substances 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 235000010339 sodium tetraborate Nutrition 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 229920002994 synthetic fiber Polymers 0.000 description 2
- 239000012209 synthetic fiber Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- ZMZDMBWJUHKJPS-UHFFFAOYSA-M Thiocyanate anion Chemical compound [S-]C#N ZMZDMBWJUHKJPS-UHFFFAOYSA-M 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000003929 acidic solution Substances 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 210000001520 comb Anatomy 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000009990 desizing Methods 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- ZMZDMBWJUHKJPS-UHFFFAOYSA-N hydrogen thiocyanate Natural products SC#N ZMZDMBWJUHKJPS-UHFFFAOYSA-N 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002923 metal particle Substances 0.000 description 1
- 238000009896 oxidative bleaching Methods 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- -1 persalts Chemical compound 0.000 description 1
- 235000020004 porter Nutrition 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- VGTPCRGMBIAPIM-UHFFFAOYSA-M sodium thiocyanate Chemical compound [Na+].[S-]C#N VGTPCRGMBIAPIM-UHFFFAOYSA-M 0.000 description 1
- HQAITFAUVZBHNB-UHFFFAOYSA-N sodium;pentahydrate Chemical compound O.O.O.O.O.[Na] HQAITFAUVZBHNB-UHFFFAOYSA-N 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000009988 textile finishing Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3937—Stabilising agents
- C11D3/394—Organic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
- D06L4/10—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen
- D06L4/12—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen combined with specific additives
Definitions
- the present invention relates to a process for bleaching cellulosic or cellulosic-synthetic fibers by means of oxidizing agents such as hydrogen peroxide, persalts, sodium peroxide in the presence of particles of iron or rust.
- oxidizing agents such as hydrogen peroxide, persalts, sodium peroxide in the presence of particles of iron or rust.
- the metal particles catalyze the decomposition of the oxidant used for bleaching, causing damage to the fibers by the formation of oxycellulose. These alterations are located at the places where the catalyst adheres to the fiber. They are manifested by the formation of holes in the form of dots or lines, the rest of the fabric can be absolutely correct.
- the oxidizer of the bleaching bath can, for example, be chosen from hydrogen peroxide, persalts and sodium peroxide.
- the present invention is surprising in view of the state of the art in the field of bleaching. Indeed, the Belgian patent n ° 789 699 of LAPORTE concerning bleaching compositions based on hydrogen peroxide indicates that the baths are less effective when added disodium phosphate. There was therefore a prejudice to overcome in order to carry out the present invention.
- the process of the invention makes it possible to bleach fabrics made of cellulosic or mixed cellulose-synthetic fibers without any degradation in the presence of particles of iron and rust.
- the method of the invention also makes it possible to carry out desizing-bleaching simultaneously in the presence of amylase.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Cosmetics (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR838307766A FR2545854B1 (fr) | 1983-05-10 | 1983-05-10 | Procede de blanchiment des textiles en presence de particules de fer ou de metaux ferreux |
| FR8307766 | 1983-05-10 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0125170A1 EP0125170A1 (fr) | 1984-11-14 |
| EP0125170B1 true EP0125170B1 (fr) | 1987-02-04 |
Family
ID=9288737
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP84400861A Expired EP0125170B1 (fr) | 1983-05-10 | 1984-04-27 | Procédé de blanchiment des textiles en présence de particules de fer ou de rouille |
Country Status (13)
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0517996B1 (en) * | 1991-06-14 | 1993-12-15 | The Procter & Gamble Company | Stable, hydrogen peroxide-containing bleaching compositions |
| EP0584710A3 (de) * | 1992-08-22 | 1995-02-01 | Hoechst Ag | Verfahren zum Bleichen von Textilien. |
| US5645688A (en) * | 1995-01-30 | 1997-07-08 | Vinings Industries, Inc. | Bleaching compositions and processes employing sulfamates and polyaminocarboxylic acids |
| US5639348A (en) * | 1995-01-30 | 1997-06-17 | Vinings Industries, Inc. | Bleaching compositions comprising sulfamates and borates or gluconates and processes |
| CA2213633C (en) * | 1995-02-28 | 2002-01-22 | The Procter & Gamble Company | Laundry pretreatment with peroxide bleaches containing chelators for iron, copper or manganese for reduced fabric damage |
| DE19638569A1 (de) * | 1996-09-20 | 1998-04-02 | Bayer Ag | Bleichregulatoren und Bleichverfahren damit |
| RU2162907C1 (ru) * | 1999-07-06 | 2001-02-10 | ООО "Русь-Агрос" | Состав жидкого отбеливателя |
| RU2191859C2 (ru) * | 2000-06-13 | 2002-10-27 | Центральный научно-исследовательский институт хлопчатобумажной промышленности | Способ беления текстильного материала (варианты) |
| US8138106B2 (en) | 2005-09-30 | 2012-03-20 | Rayonier Trs Holdings Inc. | Cellulosic fibers with odor control characteristics |
| US9512563B2 (en) | 2009-05-28 | 2016-12-06 | Gp Cellulose Gmbh | Surface treated modified cellulose from chemical kraft fiber and methods of making and using same |
| BRPI1012052A2 (pt) * | 2009-05-28 | 2017-12-26 | Gp Cellulose Gmbh | fibras kraft hidrolisadas e quimicamente modificadas e métodos de produção e de branqueamento de fibras kraft |
| US9512237B2 (en) | 2009-05-28 | 2016-12-06 | Gp Cellulose Gmbh | Method for inhibiting the growth of microbes with a modified cellulose fiber |
| AU2015255155B2 (en) * | 2009-05-28 | 2017-01-12 | Gp Cellulose Gmbh | Modified cellulose from chemical kraft fiber and methods of making and using the same |
| US9511167B2 (en) | 2009-05-28 | 2016-12-06 | Gp Cellulose Gmbh | Modified cellulose from chemical kraft fiber and methods of making and using the same |
| CA2901665A1 (en) | 2013-03-14 | 2014-09-18 | Gp Cellulose Gmbh | A method of making highly functional, low viscosity kraft fiber using an acidic bleaching sequence and a fiber made by the process |
| CN105143547B (zh) | 2013-03-15 | 2018-05-01 | Gp 纤维素股份有限公司 | 具有增高羧基含量的低粘度牛皮纸纤维及其制造和使用方法 |
| US10865519B2 (en) | 2016-11-16 | 2020-12-15 | Gp Cellulose Gmbh | Modified cellulose from chemical fiber and methods of making and using the same |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB784538A (en) * | 1955-03-17 | 1957-10-09 | Alcock Peroxide Ltd | Improvements in or relating to sodium metasilicate compositions |
| US3640885A (en) * | 1968-09-24 | 1972-02-08 | Ken Mcgee Chemical Corp | Dry free flowing peroxygen composition with an organic acid anhydride and alkali metal hydrate |
| US3671439A (en) * | 1969-07-22 | 1972-06-20 | American Home Prod | Oxygen bleach-activator systems stabilized with puffed borax |
| US3919102A (en) * | 1971-03-16 | 1975-11-11 | Henkel & Cie Gmbh | Composition and method for activating oxygen utilizing N-acylated tetraaza-bicyclo-nonandiones |
| BE789699A (fr) * | 1971-10-06 | 1973-04-05 | Laporte Industries Ltd | Composition de blanchiment a base de peroxyde |
| US4107065A (en) * | 1975-11-05 | 1978-08-15 | Colgate-Palmolive Company | Activated peroxy compound bleaching compositions and bleaching detergent compositions |
| JPS5331871A (en) * | 1976-09-02 | 1978-03-25 | Kao Corp | Bleaching agent composition safe to color of textile goods |
| DE2735816C3 (de) * | 1977-08-09 | 1981-08-13 | Basf Ag, 6700 Ludwigshafen | Verfahren zum Entschlichten und Bleichen von Textilgut |
| US4230591A (en) * | 1979-07-30 | 1980-10-28 | Fmc Corporation | Peroxygen bleaching and compositions therefor |
| US4450089A (en) * | 1982-10-21 | 1984-05-22 | Colgate-Palmolive Company | Stabilized bleaching and laundering composition |
-
1983
- 1983-05-10 FR FR838307766A patent/FR2545854B1/fr not_active Expired
- 1983-06-06 BE BE0/210939A patent/BE896968A/fr not_active IP Right Cessation
-
1984
- 1984-04-23 MA MA20320A patent/MA20099A1/fr unknown
- 1984-04-25 US US06/603,708 patent/US4619663A/en not_active Expired - Fee Related
- 1984-04-27 EP EP84400861A patent/EP0125170B1/fr not_active Expired
- 1984-04-27 DE DE198484400861T patent/DE125170T1/de active Pending
- 1984-04-27 DE DE8484400861T patent/DE3462346D1/de not_active Expired
- 1984-05-07 KR KR1019840002473A patent/KR840009346A/ko not_active Withdrawn
- 1984-05-08 GR GR74636A patent/GR79863B/el unknown
- 1984-05-08 BR BR8402152A patent/BR8402152A/pt unknown
- 1984-05-09 CA CA000453930A patent/CA1225801A/fr not_active Expired
- 1984-05-09 ES ES532327A patent/ES8505749A1/es not_active Expired
- 1984-05-10 OA OA58295A patent/OA07781A/xx unknown
- 1984-05-10 JP JP59091979A patent/JPS59211674A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| OA07781A (fr) | 1985-08-30 |
| ES532327A0 (es) | 1985-06-01 |
| JPS6220303B2 (enrdf_load_stackoverflow) | 1987-05-06 |
| CA1225801A (fr) | 1987-08-25 |
| BR8402152A (pt) | 1984-12-18 |
| JPS59211674A (ja) | 1984-11-30 |
| FR2545854A1 (fr) | 1984-11-16 |
| GR79863B (enrdf_load_stackoverflow) | 1984-10-31 |
| KR840009346A (ko) | 1984-12-26 |
| MA20099A1 (fr) | 1984-12-31 |
| DE3462346D1 (en) | 1987-03-12 |
| US4619663A (en) | 1986-10-28 |
| FR2545854B1 (fr) | 1985-07-26 |
| BE896968A (fr) | 1983-12-06 |
| ES8505749A1 (es) | 1985-06-01 |
| EP0125170A1 (fr) | 1984-11-14 |
| DE125170T1 (de) | 1985-06-05 |
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