EP0124213A1 - Procédé d'extraction - Google Patents

Procédé d'extraction Download PDF

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Publication number
EP0124213A1
EP0124213A1 EP84301172A EP84301172A EP0124213A1 EP 0124213 A1 EP0124213 A1 EP 0124213A1 EP 84301172 A EP84301172 A EP 84301172A EP 84301172 A EP84301172 A EP 84301172A EP 0124213 A1 EP0124213 A1 EP 0124213A1
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EP
European Patent Office
Prior art keywords
gold
process according
line
agent
leaching
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP84301172A
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German (de)
English (en)
Inventor
Lee Fisher Robinson
Angus William Morrison
Norman Owen Clark
John Hugo Nellmapius
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
HYDROMET MINERAL (UK) Ltd
Original Assignee
HYDROMET MINERAL (UK) Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GB838305232A external-priority patent/GB8305232D0/en
Priority claimed from GB838305871A external-priority patent/GB8305871D0/en
Priority claimed from GB838315241A external-priority patent/GB8315241D0/en
Priority claimed from GB838328151A external-priority patent/GB8328151D0/en
Application filed by HYDROMET MINERAL (UK) Ltd filed Critical HYDROMET MINERAL (UK) Ltd
Publication of EP0124213A1 publication Critical patent/EP0124213A1/fr
Withdrawn legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B11/00—Obtaining noble metals
    • C22B11/04—Obtaining noble metals by wet processes

Definitions

  • This invention relates to the recovery of gold and other noble metal values from matter containing such values, such as ores or glacial deposits, and is particularly applicable to recovery from tailings slimes and other discarded materials from various previous methods for recovery of gold, silver and other noble metals.
  • the present invention seeks to overcome these problems. Furthermore, the present invention seeks to provide a process for the recovery of gold and/or other noble metal values which in comparison with current methods is less capital and labour intensive and which can give an effective extraction in a short period. It is also possible for the plant required to be mobile, skid mounted or easily moved and operable on a continuous basis. As the plant may be totally enclosed it is free of environmental objections to fumes and liquor pollution.
  • a process for the recovery of gold and/or other noble metals from matter containing such metals comprising contacting said matter in substantially finely divided form with an aqueous leaching agent comprising a source of halide ions and an oxidising agent capable of enhancing the leaching action of the halide ions and extracting the resulting soluble metal salts from the resulting pulp or leach liquor.
  • the metal-containing matter can be an ore which has been milled or screened, or otherwise treated, to remove or reduce bigger lumps of matter unlikely to be noble-metal bearing, e.g. lumps of granite.
  • the matter may be in the form of a waste sand or slime, freshly mined or which possibly has been lying for some considerable time and which was previously thought not be be of commercial significance.
  • the process of the invention preferably employs matter of comparatively low particle size, e.g. less than 0.5 mm.
  • the halide source preferably chloride may be provided by inorganic halides such as calcium and magnesium chloride or polar organic halides.
  • the halide component is preferably present in a concentration of from 3 to 15% by weight of the leach solution.
  • a mixture of materials may be used, such as waste halide liquors resulting from other processes.
  • a preferred halide is sodium chloride.
  • the oxidizing component of the leaching agent is preferably present in an amount of 2 to 15% by weight of the leaching agent and may be an acid such as nitric acid which is suitably used in a comparatively low concentration such as 5 to 12% by weight of the leaching agent, although it may be necessary to increase the nitric acid content, for example up to 25%, if the ore being treated has an alkalinity or carbonate content which will cause it to neutralise some of the nitric acid being used.
  • an acid such as nitric acid which is suitably used in a comparatively low concentration such as 5 to 12% by weight of the leaching agent, although it may be necessary to increase the nitric acid content, for example up to 25%, if the ore being treated has an alkalinity or carbonate content which will cause it to neutralise some of the nitric acid being used.
  • less corrosive oxidizing agents may be employed, preferably inorganic nitrates (such as sodium, potassium or ammonium nitrate), but also organic nitrates, organic or inorganic peroxides, oxides, sodium chlorate, sodium hypochlorite, permanganates, chromates, dichromates and persulphates or other conventional oxidizing agents including gaseous air, ozone and oxygen.
  • inorganic nitrates such as sodium, potassium or ammonium nitrate
  • organic nitrates organic or inorganic peroxides, oxides, sodium chlorate, sodium hypochlorite, permanganates, chromates, dichromates and persulphates or other conventional oxidizing agents including gaseous air, ozone and oxygen.
  • enhancement of the leaching action of the halide may be obtained by adding low concentrations (for example 2 to 5% by weight) of acid such as nitric acid, hydrochloric acid, sulphuric acid or organic acids or by adding low concentrations of other conventional oxidizing agents as mentioned above.
  • a mixture of acids gives an effective oxidising agent, especially a mixture of nitric acid plus sulphuric acid suitably with a halide such as sodium chloride as the other component of the leaching agent.
  • the leaching is preferably carried out at a pH not exceeding 3.5.
  • the leaching is preferably carried out at a temperature in the range of 45° to 95°C, for example about 90°C. It is desirable that the subsequent extraction of metal values is carried out at a lowered temperature, preferably in the range of 20°C to 45°C.
  • the metal values may be extracted from the pulp or liquor from the leaching step in several ways.
  • the metal values are preferably extracted from the leach liquor with a solvent which can be readily recovered for reuse.
  • the preferred solvent is methyl isobutyl ketone which can be distilled for reuse leaving a residue of high purity metal, preferably gold.
  • Other solvents such as diisobutyl ketone, amyl acetate, amyl chloride, diethyl ether, isopropyl ether, ethyl alcohol, acetone, chloroform, butyl acetate, methyl n-hexyl ketone, ethyl acetate and kerosene may be employed.
  • the most suitable solvents are those with minimum solubility in water, acid solutions, salt solutions or any other resultant leach solution.
  • the metal values may be extracted using an activated material such as cellulose chaff or activated carbon, which can be readily commercially obtained.
  • activated materials may be employed capable of acting as precipitants, such as oxalic acid.
  • Methods of subsequently recovering gold from an activated material such as charcoal are well known and include calcining, and non-destructive methods such as stripping with hydrogen cyanide or nitric acid or other concentrated acid or alkaline materials, deposition using zinc chips and electrolytic procedures such as the well known Zadra process.
  • the gold when the metal being extracted is gold, the gold may be extracted from the pulp or liquor from the leaching step using an organic complexing agent specific for gold and recovering the gold values from the complex so formed using an activated material capable of removing the gold values.
  • the organic complexing agent is preferably Rhodamine B which can be used in either oil-soluble or water-soluble form but can also be another organic complexing agent such as 5-(4-dimethylaminobenzylidene) (Rhodanine).
  • the activated material used to recover the gold from the organic complexing agent is suitably activated carbon or cellulose chaff, which may be regenerated for reuse as described above.
  • an extracting solvent such as methyl isobutyl ketone
  • a gold complexing agent such as Rhodamine B may be used together.
  • the extraction is preferably carried out by passing the pulp or leach liquor in cocurrent or countercurrent through a contactor in contact with a substantially immiscible liquid phase comprising an extractant for the metal values.
  • a preferred contactor is of the solids-liquid bucket contactor type, for example as described in G.B. Patent Specification No. 1,145,894 and U.S. Specification No. 3,649,209.
  • the process may be carried out by other methods, such as the use of a vertical stirred and heated leach tank or a horizontal leaching vessel fitted with a screw conveyor or using an Akins classifier.
  • Figures 1 to 4 are flow diagrams of processes for recovering gold values in accordance with different embodiments of the invention.
  • gold-containing material to be processed is introduced on line 2 to a mixer 4 with a suitably low particle size of less than 0.5 mm.
  • a mixer 4 with a suitably low particle size of less than 0.5 mm.
  • Dependent on the starting material which may for example be a sand, slime or newly mined ore, preliminary steps such as concentration, or steps to remove oversize material such as screening or the use of hydrocylones, may have been carried out.
  • Leaching agent suitably comprising nitric acid and a source of halide ions, is introduced to the mixer 4 on line 6.
  • the mixture in mixer 4 is subjected to continuous thorough stirring and heating.
  • Contactor 12 may suitably be of the solids-liquid bucket contactor type described in G.B. Patent No. 1,145,894 and U.S. Specification No. 3,649,209, but other contacting methods may be employed, such as a horizontal contactor with a screw conveyor or an Akins classifier.
  • Activated carbon, cellulose chaff, or other suitable activated material is introduced to contactor 12 on line 14 and preferably travels cocurrent with the mixture of leaching agent and gold-bearing material through the contactor.
  • the streams of activated material and the mixture may be introduced at opposite ends of the contactor 12 and flow in countercurrent.
  • the activated material suitably has a specific gravity of about 0.6 and not more than 1.2 when fully loaded.
  • the mixture of gold-bearing material and leaching agent initially will suitably have a specific gravity of about 1.3 to 1.8, the difference in specific gravities ensures that the activated material and ore/leaching agent mixture readily separate, so that each can be drawn separately from the contactor 12.
  • the activated material is unaffected by the concentrations of nitric acid used in the process.
  • the flow rate through contactor 12 can vary but a suitable residence time is from 2 to 6 hours.
  • the contacting is preferably carried out at a temperature of from 30°C (more preferably 50°C) to 95°C. Heating of contactor 12 can be carried out by any suitable means, for example by applying steam panels to the contactor 12.
  • two contactors could be employed in series, in the first of which the heating agent and gold-bearing material are contacted, while liquor freed at least partly from solids is passed to a second contactor for contact with the activated material.
  • the activated material bearing the extracted gold values leaves the contactor 12 on line 16 and passes via line 31 to screen and liquor tank unit 18.
  • the liquor passing through the screen is recycled on line 42 to the leaching agent feed to mixer 4.
  • the activated material and gold values pass on line 44 to treatment unit 46 where the gold values are recovered by any suitable means, such as calcining, stripping with hydrogen cyanide or nitric acid, deposition or electrolytic processes.
  • Gold values are withdrawn on line 20, while recovered activated material is recycled on line 22 to line 14.
  • unit 46 may simply act as a storage unit, gold recovery taking place off the plant.
  • Make-up activated carbon, cellulose chaff or other active material is supplied on line 24.
  • the use of activated material in contactor 12 is replaced by the use in processing unit 18 of oxalic acid, used in stoichiometric excess to the gold present in the separated liquor, to deposit the gold.
  • the spent liquor and ore, sand or slime are withdrawn from contactor 12 on line 26. Any remaining carbon is drawn off via screen 28 and joined via line 30 with the carbon flow in line 16. Alternatively carbon on line 30 may be passed directly to treatment unit 46. The remaining material passes through desander 32. Spent pulp is withdrawn on line 34. Dependent on the nature of the waste and regulations governing its disposal, it may be desirable to add lime, or other neutralising agent, on line 36. The used leaching agent is recycled via line 38 to line 6. Make-up leaching agent is added on line 40.
  • gold-containing material to be processed is introduced, as ore or a slime slurry, on line 100 and passes through a 24 mesh screen 102 to give a suitably low particle size, e.g. less than 0.5 mm.
  • the screened material passes on line 103 to thickener unit 104 (provided with an overflow line 134 to remove excess slurry water or brine) and thence on line 105 to vertically arranged heated leach tank 106.
  • Recycled leaching agent suitably comprising nitric acid and a source of halide ions is mixed via line 107 with the thickened material in line 103 prior to entry to leach tank 106.
  • make up nitric acid and halide are introduced to tank 106 on lines 141 and 142.
  • the contents of leach tank 106 are subjected to intensive mixing and also heated, for example to about 90°C, by suitable means, such as the provision of a steam jacket (not shown) with steam introduced from boiler 108 on line 109.
  • suitable means such as the provision of a steam jacket (not shown) with steam introduced from boiler 108 on line 109.
  • the leach time is greatly reduced, for example in the range of 20 mins. to 3 hours.
  • the material from tank 106 passes via deaerator 110 (which may be dispensed with dependent on the materials employed) on line 111 to a horizontally arranged primary decanter 112, which is fitted with a plurality of weirs 113. Additional leaching agent and brine may be added to decanter 112 on line 114. Both line 114 and decanter 112 may also be heated by steam provided from boiler 108 via steam supply line 115 and condensate return line 116. Solids removed by the action of weirs 113 is combined and withdrawn on line 117 to a neutralisation and discharge tank 118 and finally discharged from tank 118 on line 119. Neutralisation may be with lime or other neutralising agent dependent on the nature of the waste and regulations governing its disposal.
  • leaching proceeds rapidly with rapid settling of the solids from the leach liquor, so that, in certain circumstances, it may be possible to dispense with decanter 112 and withdraw solids and leach liquor directly from tank 106.
  • the leach liquor from decanter 112 leaves on line 120 and passes to a solids-liquid separator 121 which is of the settling type or may be an alternative type of solids-liquid separator. Solids is withdrawn on line 122 to neutralisation and discharge tank 118 for final discharge on line 119.
  • the clear liquor from separator 121 passes on line 123 to heat exchanger 124 where it is cooled, for example to no hotter than 40°C for passage via line 125 to complexing vessel 126.
  • Vessel 126 may take the form of a mixer settler, column or a Graesser bucket contactor or other type of contactor.
  • the liquor is contacted in countercurrent fashion in vessel 126 with a supply of, for example, the commercially available oil soluble form of the complexing agent Rhodamine B, supplied from doser 127 via lines 128 and 129 in an organic carrier such as amyl acetate, methyl i-butylketone or the like, or a mixture thereof, which carrier is selected so as to have low solubility in aqueous-acid solution.
  • Rhodamine B complexes specifically with the gold values which are then withdrawn on line 130, while discarded liquor leaves on line 131 for recycle.
  • the organic complex phase then passes to a recovery station where a suitable activated material is used to recover the gold values.
  • a suitable activated material is used to recover the gold values.
  • two fixed beds 132 and 133 of activated carbon are used, alternatively or consecutively.
  • Recovered organic complexing agent is returned to complexing vessel 126 on line 129.
  • the activated carbon with adsorbed gold values may be treated in any suitable way to recover the gold. It is to be noted that only relatively pure liquor reaches the activated carbon adsorption stage and so the carbon does not become clogged and has a long useful life and can be used to greater efficiency to adsorb large amounts of gold . It is estimated that gold values can be adsorbed at a level of up to 500 oz gold per ton of carbon.
  • the activated carbon is not agitated, which aids clean separation after adsorption of the gold values.
  • the organic complexing agent readily separates therefrom.
  • the consumption of organic complexing agent is relatively low as it can be efficiently recycled.
  • Approximately 5 to 10 parts by weight of oil-soluble Rhodamine B per 1 part of gold chloride present in the liquor is suitably employed in the complexing stage.
  • While the drawing illustrates the provision of steam heating for leach tank 106 and decanter 112 from steam boiler 108, it may also be expedient to heat thickener unit 104 and/or to insulate all three vessels. Further, to minimise the energy requirements of the system, the brine and/or water overflow from thickener unit 104 is withdrawn on line 134 and passes to heat exchanger 124 where the liquid is heated by exchange with the gold-bearing liquor flow in line 123. The heated brine and/or water passes on line 135 to a further heat exchanger 136 and is returned to slurry vessel 104 on line 140. Line 140 has a bleed-off stream 144 which may be used if there is need to reduce the volume of slimes in the system.
  • Spent liquor on line 131 acquires some heat by passage through heat exchanger 136 and then passes via line 137 to heat exchanger 138 which is heated from boiler 108 and serves to heat the return liquor to the desired temperature for recycle on line 107 to the incoming thickened feed in line 105.
  • Condensed steam leaves on line 139.
  • Lines 135, 137 and 107 may be insulated to minimise heat loss.
  • gold bearing material having been subjected to suitable preprocessing as described above in connection with Figures 1 and 2, and suitably in the form of a pulp with brine, is introduced on line 220 to a stirred leaching vessel 222 to which is supplied an oxidising agent on line 224, suitably nitric acid.
  • an oxidising agent on line 224 suitably nitric acid.
  • other oxidising agents or mixtures of oxidising agents may be employed as described above. It may be possible to add gold bearing material, brine and acid directly to leach vessel 222 without preprocessing for easily leachable ores where problems in releasing the gold are not encountered.
  • Leaching vessel 222 may suitably be lined with silicone elastomer or other materials to resist corrosion. It may be heated by any suitable means, such as by heating coils with steam or oil as heating fluid, to a temperature such as about 90°C so as to give a satisfactory leach time, for example from 20 mins. to 3 hours.
  • concentration of brine and oxidizing agent in leaching vessel 222 can vary widely.
  • a suitable content of nitric acid is from 5 to 12% by weight of the aqueous medium, although this may be increased, for example up to 25%, if the ore being treated has an alkalinity or carbonate content which will cause it to neutralise some of the nitric acid being used.
  • the brine content may vary from very dilute to saturated, but is preferably in the range of from 5 to 30%.
  • leach tank 222 may contain a solution of soluble inorganic chlorides (e.g. sodium, magnesium and potassium) in up to 15% nitric acid. The ore and leaching agent may be stirred for about 30 mins with a stirrer shaft speed of 5000 rpm.
  • Analyses of nitric acid and chloride contents in tank 222 may be carried out and previous analysis of the carbonate and sulphide content of the ore enable adjustment of the acid added to give a final leach acidity of 15% HN0 3 .
  • a typical mix in tank 222 is ore (dry) 6 kg, sodium chloride 2.5 kg and 15% nitric acid 18 litres.
  • the leached slurry passes from vessel 222 on line 226 to cooling tanks 228 where the slurry is cooled, suitably by heat exchange.
  • Cooling tanks 228 may be lined with corrosion resistant materials such as polythene and polybutadiene and may be stirred.
  • the slurry is cooled to a temperature of 45°C or less before being passed on line 230 to a contactor 232.
  • Tanks 228 may act as settling tanks so that the material passed on line 230 is a rich liquor separated from residual ore.
  • Contactor 232 is preferably a bucket contactor, for example, as described in G.B. Patent Specification No. 1145894 and U.S. Specification No. 3649209. However the contacting may be carried out by other equipment, such as an Akins classifier.
  • the leach liquor is contacted in countercurrent with a stream of solvent entering the contactor on line 234.
  • a 6" bucket contactor may be used with a flow rate of 60 litres per hour and a rotation speed of 6 to 8 rpm.
  • Extra cooling may be supplied by heat exchange with cold brine.
  • Solvent may be supplied to the contactor at about 6 to 15 litres per hour.
  • the preferred solvent is methyl isobutyl ketone, although other solvents may be employed, with or without the addition of a gold complexing agent, as described above.
  • the rate of liquid flow through the contactor may be of the order of 120 litres per hour with a volume ratio of leach liquor to solvent of about 10:1 and a retention time in the contactor of about 10 minutes.
  • the methyl isobutyl ketone carrying extracted gold values leaves contactor 232 on line 236 and passes to solvent still 238 where the methyl isobutyl ketone is distilled by heating to its boiling point of 103 to 106°C. After addition of alkali to neutralise the acid content, gold precipitates as a powdered product.
  • the gold can be extracted with a non-polar solvent from still 238. We have found the gold to be of high purity of at least 80% and usually of 95 to 100% purity.
  • residual organic impurities or inorganic salts can be removed, for example by washing and/or calcining.
  • the solvent may be heated, for examnle up to 90°C, at which temperature the gold is precipitated as a high purity fine powder.
  • the distilled methyl isobutyl ketone is liquified in condenser 240 and collects in solvent tank 242 for recycle to contactor 232 on line 234. This simple recovery of solvent by distillation is efficient and gives a low loss of solvent.
  • the methyl isobutyl ketone can be cleaned before recycle by any suitable means, for example using zeolites, activated carbon, or exchange resins.
  • zeolites, activated carbon, or exchange resins for example, some acid may have been taken up by the methyl isobutyl ketone. This may be removed by distilling over an alkali such as dilute caustic soda or calcium hydroxide or by other suitable means. Other washing procedures may be necessary to clean the solvent from contaminants such as iron chlorides. Washing may be carried out in a second small contactor.
  • Stripped leach liquor leaves contactor 232 on line 244 and passes to leach residue settling tanks 246, or any alternative type of solids-liquid separator or settling ponds. Solids residue is withdrawn on line 248 to residue neutralisation tank 250 and final discharge on line 252. The recovered leach liquor from tanks 246 is recycled on line 254 to line 224 which supplies acid to leach tank 222. Make up acid is supplied from reservoir 256.
  • FIG 4 illustrates an alternative process for use with feedstock ores from which it is particularly difficult to release the gold values.
  • gold bearing feedstock in brine passes on line 268 to leach tank 270 where acid such as nitric acid is added on line 272 to give leaching conditions within tank 270.
  • Tank 270 is heated by suitable means (not shown).
  • Leached pulp is withdrawn on line 274 to cooling tanks 276 where the temperature is reduced by suitable means such as heat exchange prior to passage of the pulp on line 278 to contactor 280 similar to contactor 232 shown in Figure 3.
  • the leached pulp is brought into contact in contactor 280 with a stream of solvent, preferably methyl isobutyl ketone fed to the contactor on line 282.
  • the solvent carrying extracted gold values is withdrawn on line 284 and the solvent distilled off in still 284 leaving gold product. Alternatively the gold is precipitated by heating the solvent below its boiling point. Solvent is condensed in condenser 288, and stored in vessel 290 for recycle on line 282.
  • the pulp is led on line 292 to further reaction tanks 294, where it is further extracted with an additional solvent under alkaline conditions, suitably alcohol and sodium hydroxide. Separated liquor is recycled on line 296 to leach tank 270. Alcohol/water extract passes via lines 298 to distillation column 300 where the alcohol/water azeotrope distils leaving further residual gold.
  • the solvent is condensed in condenser 302 and stored in tank 304 prior to its recycle (not shown).
  • vessels in which the leaching agent is employed are advantageously made of materials such as titanium which are resistant to the concentrations of leaching agent such as halide and nitric acid being conventionally used. If higher concentrations of leaching agent are employed, it is possible to employ vessels carrying a corrosion resistant ptfe coating or synthetic rubber at modest cost.
  • the highly oxidising leach is particularly suitable for the processing of metal-containing ore bodies where there is contamination with refractory materials, such as non-oxidised arsenic. Being in a totally enclosed vessel the oxidation does not release poisonous materials and these can be subsequently precipitated by known methods.
  • All or part of the apparatus is preferably enclosed to minimise problems with any potentially corrosive reactants.
  • the recycling of leaching agent reduces these problems and minimises the cost of reagents.
  • the process can be successfully operated on a continuous basis.
  • gold recoveries of greater than 80%, preferably greater than 90%, are achieved.
  • the process of the invention can be carried out on a scale to suit a particular mining operation.
  • apparatus for carrying out the process may be scaled so that it can be mounted on a lorry.
  • Such an apparatus can then be readily transported to the scene of operations and used, for example,-to process slime heaps along a previously worked riverbed.
  • Such an apparatus could process, for example, some 100,000 tons of ore per annum, dependent of course on the type of ore and residence times employed.
  • Larger apparatus may be constructed on site, on the surface or in a mine cavern, having a contactor of for example, 2 to 3 metres diameter and a throughput of 250,000 to 800,000 tons of ore per annum, again dependent on the ore being processed and the conditions of processing.
  • the throughput can also be increased, for example, by a factor of 5 to 1, or even 10 to 1, by suitable pre-processing of the feedstock ore, for example by separation and concentration processes.
  • halide and nitric acid as leaching agent.
  • the oxidising agent comprises a mixture of acids such as a mixture of nitric acid and sulphuric acid, especially in conjunction with methyl isobutyl ketone as an extractant. This is illustrated in the following examples.
  • the starting material used was an ore of head grade 2.21g of gold per tonne (assayed by neutron activation) and 2.5g per tonne (by aqua regia assay). 100g of ore were mixed with 300g of an aqueous solution containing 10% by weight sulphuric acid, 5% by weight nitric acid, 17.7% by weight potassium chloride and 13.3% by weight sodium chloride. The mixture was vigorously stirred at 95°C for 30 minutes, allowed to cool and filtered. The residue was washed three times with water and the washings combined with the initial filtrate.
EP84301172A 1983-02-25 1984-02-23 Procédé d'extraction Withdrawn EP0124213A1 (fr)

Applications Claiming Priority (8)

Application Number Priority Date Filing Date Title
GB8305232 1983-02-25
GB838305232A GB8305232D0 (en) 1983-02-25 1983-02-25 Extraction process
GB838305871A GB8305871D0 (en) 1983-03-03 1983-03-03 Extraction process
GB8305871 1983-03-03
GB8315421 1983-06-03
GB838315241A GB8315241D0 (en) 1983-06-03 1983-06-03 Extraction process
GB8328151 1983-10-21
GB838328151A GB8328151D0 (en) 1983-10-21 1983-10-21 Extraction process

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Publication Number Publication Date
EP0124213A1 true EP0124213A1 (fr) 1984-11-07

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EP84301172A Withdrawn EP0124213A1 (fr) 1983-02-25 1984-02-23 Procédé d'extraction

Country Status (2)

Country Link
EP (1) EP0124213A1 (fr)
ES (1) ES8504955A1 (fr)

Cited By (16)

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EP0232380A1 (fr) * 1985-08-26 1987-08-19 Asarco Inc Procede de purification des boues de raffinage d'argent.
FR2672304A1 (fr) * 1991-01-03 1992-08-07 Chevron Res & Tech Recovery of gold from refractory ores and concentrates.
US5137700A (en) * 1987-07-02 1992-08-11 Nelson H. Shapiro Processes employing iodine-iodide etching solutions
US5516355A (en) * 1991-11-13 1996-05-14 Radhakrishnan; Subramaniam Method of preparation of compositions for an amalgam
WO1999045159A1 (fr) * 1998-03-02 1999-09-10 Lee Fisher Robinson Extraction de metal utile par lixiviation par cyanuration acide
WO2011100821A1 (fr) * 2010-02-18 2011-08-25 Neomet Technologies Inc. Procédé pour la récupération d'or à partir d'un minerai dans un milieu de chlorures avec une espèce azotée
RU2502813C1 (ru) * 2012-05-22 2013-12-27 Общество с ограниченной ответственностью "Компания "ОРИЯ" Способ переработки отходов электронной и электротехнической промышленности
WO2015130607A1 (fr) * 2014-02-25 2015-09-03 Advanced Technology Materials, Inc. Formulations à base humide pour l'élimination sélective de métaux nobles
RU2572938C2 (ru) * 2014-06-11 2016-01-20 Федеральное государственное автономное образовательное учреждение высшего профессионального образования "Уральский федеральный университет имени первого Президента России Б.Н. Ельцина" Способ переработки электронного лома, преимущественно электронных плат
RU2618588C1 (ru) * 2016-02-19 2017-05-04 Общество с ограниченной ответственностью "Опытно-демонстрационная площадка "Элмус" Способ переработки лома радиоэлектронных изделий с выделением драгоценных металлов высокой чистоты
US9649712B2 (en) 2011-12-15 2017-05-16 Entegris, Inc. Apparatus and method for stripping solder metals during the recycling of waste electrical and electronic equipment
RU2625156C1 (ru) * 2016-05-11 2017-07-11 Акционерное общество "Ведущий научно-исследовательский институт химической технологии" (АО "ВНИИХТ") Способ извлечения олова из отходов электронной и электротехнической промышленности
US9889421B2 (en) 2010-02-18 2018-02-13 Brav Metal Technologies Inc. Process for the recovery of metals and hydrochloric acid
RU2644719C2 (ru) * 2016-06-29 2018-02-13 Акционерное общество "Ведущий научно-исследовательский институт химической технологии" (АО "ВНИИХТ") Способ переработки отходов электронной и электротехнической промышленности
US10034387B2 (en) 2010-04-15 2018-07-24 Entegris, Inc. Method for recycling of obsolete printed circuit boards
US11408053B2 (en) 2015-04-21 2022-08-09 Excir Works Corp. Methods for selective leaching and extraction of precious metals in organic solvents

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US2835569A (en) * 1956-04-19 1958-05-20 Electro Chimie Metal Process of extracting gold and other metals from ores, concentrates, residues and the like containing principally cobalt, nickel, iron, arsenic and gold
DE1189720B (de) * 1963-04-23 1965-03-25 Aux De La Ind S A Empresa Verfahren zur Auslaugung von Pyritabbraenden
GB1145894A (en) * 1966-05-12 1969-03-19 Graesser Ltd R Improvements in treatment of solids with liquids
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DE2418441A1 (de) * 1974-04-17 1975-10-30 Helmut Dipl Ing Cronjaeger Verfahren zur extraktion von ne- und edelmetallen aus erzen
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Cited By (24)

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EP0232380A1 (fr) * 1985-08-26 1987-08-19 Asarco Inc Procede de purification des boues de raffinage d'argent.
EP0232380A4 (fr) * 1985-08-26 1988-01-21 Asarco Inc Procede de purification des boues de raffinage d'argent.
US5137700A (en) * 1987-07-02 1992-08-11 Nelson H. Shapiro Processes employing iodine-iodide etching solutions
FR2672304A1 (fr) * 1991-01-03 1992-08-07 Chevron Res & Tech Recovery of gold from refractory ores and concentrates.
US5516355A (en) * 1991-11-13 1996-05-14 Radhakrishnan; Subramaniam Method of preparation of compositions for an amalgam
WO1999045159A1 (fr) * 1998-03-02 1999-09-10 Lee Fisher Robinson Extraction de metal utile par lixiviation par cyanuration acide
AU734238B2 (en) * 1998-03-02 2001-06-07 H.M.C. Technology Limited Extraction of valuable metal by acid cyanide leach
US6423117B1 (en) * 1998-03-02 2002-07-23 Lee Fisher Robinson Extraction of valuable metal by acid cyanide leach
US9889421B2 (en) 2010-02-18 2018-02-13 Brav Metal Technologies Inc. Process for the recovery of metals and hydrochloric acid
WO2011100821A1 (fr) * 2010-02-18 2011-08-25 Neomet Technologies Inc. Procédé pour la récupération d'or à partir d'un minerai dans un milieu de chlorures avec une espèce azotée
US8894740B2 (en) 2010-02-18 2014-11-25 Neomet Technologies Inc. Process for the recovery of gold from an ore in chloride medium with a nitrogen species
US10034387B2 (en) 2010-04-15 2018-07-24 Entegris, Inc. Method for recycling of obsolete printed circuit boards
US9649712B2 (en) 2011-12-15 2017-05-16 Entegris, Inc. Apparatus and method for stripping solder metals during the recycling of waste electrical and electronic equipment
US9731368B2 (en) 2011-12-15 2017-08-15 Entegris, Inc. Apparatus and method for stripping solder metals during the recycling of waste electrical and electronic equipment
RU2502813C1 (ru) * 2012-05-22 2013-12-27 Общество с ограниченной ответственностью "Компания "ОРИЯ" Способ переработки отходов электронной и электротехнической промышленности
CN106661663A (zh) * 2014-02-25 2017-05-10 恩特格里斯公司 用于选择性去除贵金属的湿基制剂
WO2015130607A1 (fr) * 2014-02-25 2015-09-03 Advanced Technology Materials, Inc. Formulations à base humide pour l'élimination sélective de métaux nobles
RU2572938C2 (ru) * 2014-06-11 2016-01-20 Федеральное государственное автономное образовательное учреждение высшего профессионального образования "Уральский федеральный университет имени первого Президента России Б.Н. Ельцина" Способ переработки электронного лома, преимущественно электронных плат
US11408053B2 (en) 2015-04-21 2022-08-09 Excir Works Corp. Methods for selective leaching and extraction of precious metals in organic solvents
US11427886B2 (en) 2015-04-21 2022-08-30 Excir Works Corp. Methods for simultaneous leaching and extraction of precious metals
US11814698B2 (en) 2015-04-21 2023-11-14 Excir Works Corp. Methods for simultaneous leaching and extraction of precious metals
RU2618588C1 (ru) * 2016-02-19 2017-05-04 Общество с ограниченной ответственностью "Опытно-демонстрационная площадка "Элмус" Способ переработки лома радиоэлектронных изделий с выделением драгоценных металлов высокой чистоты
RU2625156C1 (ru) * 2016-05-11 2017-07-11 Акционерное общество "Ведущий научно-исследовательский институт химической технологии" (АО "ВНИИХТ") Способ извлечения олова из отходов электронной и электротехнической промышленности
RU2644719C2 (ru) * 2016-06-29 2018-02-13 Акционерное общество "Ведущий научно-исследовательский институт химической технологии" (АО "ВНИИХТ") Способ переработки отходов электронной и электротехнической промышленности

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