EP0108180A1 - Zusammensetzungen zum Spülen von Wäsche - Google Patents

Zusammensetzungen zum Spülen von Wäsche Download PDF

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Publication number
EP0108180A1
EP0108180A1 EP82402036A EP82402036A EP0108180A1 EP 0108180 A1 EP0108180 A1 EP 0108180A1 EP 82402036 A EP82402036 A EP 82402036A EP 82402036 A EP82402036 A EP 82402036A EP 0108180 A1 EP0108180 A1 EP 0108180A1
Authority
EP
European Patent Office
Prior art keywords
compound
composition according
rinsing
cationic
carbon atoms
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP82402036A
Other languages
English (en)
French (fr)
Other versions
EP0108180B1 (de
Inventor
Richard Weiss
Dominique Chauffour
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Reckitt Benckiser France SAS
Original Assignee
Reckitt and Colman SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=8189947&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EP0108180(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Reckitt and Colman SA filed Critical Reckitt and Colman SA
Priority to EP82402036A priority Critical patent/EP0108180B1/de
Priority to DE8282402036T priority patent/DE3274747D1/de
Priority to AT82402036T priority patent/ATE24333T1/de
Publication of EP0108180A1 publication Critical patent/EP0108180A1/de
Application granted granted Critical
Publication of EP0108180B1 publication Critical patent/EP0108180B1/de
Expired legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/40—Dyes ; Pigments
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/62—Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/40—Dyes ; Pigments
    • C11D3/42—Brightening agents ; Blueing agents

Definitions

  • the brighteners that can be used in a washing machine are in the form of a powder which is added to the main detergent, or in the form of a liquid which is added during the last rinsing cycle.
  • the main element of these brighteners is overseas blue.
  • the pigment is diluted in a mineral filler, generally baking soda.
  • the pigment is suspended in water, the suspension being stabilized either by water-soluble thickeners, or even by hydrophilic silicas such as bentonites,
  • the rinsing liquids for curtains and curtains contain as main elements polymers similar to those used in starchy products. However, preference is given in this case to polymers having good water solubility. Among these, mention may be made of polymers derived from cellulose, polymers or copolymers of acrylic or methacrylic acid or of their esters and polyvinyl alcohols.
  • the products for curtains and curtains contain anti-static agents as secondary active principles; use is made, in general, of quaternary ammonium salts or phosphoric esters or alternatively of combinations of these two types of products.
  • These products contain, apart from these main components, secondary additives such as perfumes and optical brighteners. They therefore suffer from the same disadvantages as those already reported for rinsing liquids, the greatest disadvantage being, for this type of product, the poor resistance to daylight of optical brighteners, which represents a major drawback in the treatment of curtains and net curtains that are exposed to sunlight for long hours.
  • Rinsing products with a bactericidal effect use active ingredients used alone or in combination for the search for synergistic effects such as quaternary ammonium salts, organochlorine products, aldehydes, etc. They also contain as secondary components perfumes and optical brighteners. They therefore suffer from the same drawbacks as other laundry rinses.
  • the object of the present invention is to make available to the housewife rinsing products for laundry with a brightening effect which do not have the disadvantages of existing rinsing products nor those of the old techniques of blueing by ultramarine blue. .
  • the Applicant has in fact unexpectedly found that it is essentially the presence of the cationic character which makes it possible to obtain the results observed.
  • the object of the present invention is therefore to provide compositions for rinsing the laundry capable of giving it one or more properties such as flexibility, softness, whiteness, odor, sterility, rigidity, wrinkle-resistant together with an azure appearance. and this in a single treatment either in a washing machine or during a rinsing treatment by hand.
  • the invention covers a composition, in solid or liquid form, suitable for rinsing laundry, essentially characterized in that it contains at least 0.05% by weight of at least one pigment of whitening and at least .0.05% by weight of at least one organic compound of catalytic nature.
  • a composition will contain from 0.05 to 5% by weight and, preferably, from 0.1 to 2% of said pigment and from 0.05 to 50% of said compound with a cationic nature.
  • the whitening pigment (s) can be chosen from the class comprising natural or synthetic overseas blue or overseas violet.
  • the compound or compounds with a cationic character can be chosen from the compounds chemically known to have this character and belonging for example to the class of quaternary ammonium salts having at least one alkyl chain of at least 8 carbon atoms and preferably of 12 to 18 carbon atoms; imidazoline salts having at least one alkyl chain of at least 8 carbon atoms and preferably from 12 to 18 carbon atoms; ethoxylated or propoxylated tertiary amines having at least one alkyl chain of at least 8 carbon atoms and preferably from 12 to 18 carbon atoms; natural or synthetic polymers or copolymers containing groups of a cationic nature with a degree of substitution at least equal to 0.01;
  • composition according to the invention can also comprise at least 0.01% by weight, advantageously from 0.01 to 3% by weight of a water-soluble perfume.
  • the composition contains at least one known bactericidal agent of a cationic nature.
  • Cotton terry cloth samples weighing 4 grams are washed and then rinsed in 600 ml of a 1.5 g / l solution of the rinsing composition, at a temperature of 25 ° C. and for 10 minutes.
  • the device used is an AHIBA TEXOMAT and the dilution used corresponds to the recommended dose for use in a standard washing machine (50 g of rinsing liquid for a volume of approximately 30 liters of water).
  • a fabric softener liquid is prepared for rinsing the laundry according to the formula: - Deionized water complement to 100 parts by weight.
  • the degrees of brightening obtained are measured and organoleptic tests are carried out to assess the retention of the perfume on the treated fabrics.
  • the results show the excellent whitening performance obtained with the softener containing ultramarine blue compared to the softener which does not contain it and compared with the brightening rinsing liquid containing no cationic derivative, as well as the excellent retention of fragrance from a fragrant fabric softener compared to a fragrant brightener that does not contain. cationic derivative.
  • a fabric softening liquid is produced for rinsing the laundry according to the formula:
  • a white cotton terry cloth is treated with a 1.4 g / l solution of the rinsing liquid.
  • this same fabric is treated under the same conditions with the above rinsing product which does not contain ultramarine blue.
  • the degrees of brightening obtained are measured and organoleptic tests are carried out to assess the retention of the perfume on the treated fabrics.
  • a fabric softener liquid is prepared for rinsing the laundry according to the formula:
  • a white cotton terry cloth is treated with a 1.4 g / l solution of the rinsing liquid.
  • this same fabric is treated under the same conditions with said rinsing product. Which does not contain ultramarine blue.
  • the degrees of brightening obtained are measured and organoleptic tests are carried out to assess the retention of perfume on the treated fabrics.
  • the results show the excellent whitening performance obtained with the softener containing ultramarine blue compared to the softener which does not contain it and compared to the brightening rinsing liquid containing no cationic derivative, as well as the good perfume retention of a perfumed softener compared to a perfumed brightener but containing no cationic derivative.
  • a curtain rinse product having the following composition:
  • White fabrics made of polyester / linen fibers are treated with a 1.4 g / l solution of the rinsing product.
  • these same fabrics are treated under the same conditions with said rinsing product not containing ultramarine blue.
  • the degrees of brightening obtained are measured and organoleptic tests are carried out to assess the retention of perfume on the treated fabrics.
  • the results show the excellent performances obtained with the product for curtains containing ultramarine blue and a cationic derivative compared to the product which does not contain -blue and that containing no cationic derivative as well as the perfume retention of a scented curtain product containing a cationic derivative compared to a product not containing it.
  • a rinsing product is prepared which is suitable for starching the laundry according to the form:
  • a white cotton fabric is treated with a 1.4 g / l solution of this heavy rinsing product.
  • this same tissue is treated under the same conditions with the above rinsing product not containing ultramarine blue and with a starchy product without ultramarine blue and in which the cationic starch has been replaced. by native starch.
  • the degrees of brightening obtained are measured and organoleptic tests are carried out to assess the retention of perfume on the treated fabric.
  • the results show the excellent whitening performance obtained with the cationic starch product containing ultramarine blue compared to the product which does not contain it as well as the excellent perfume retention of a perfumed starch product containing a cationic derivative. compared to a product not containing it.
  • a rinsing liquid for brightening the laundry is produced according to the formula:
  • a white terry cloth is treated with a solution of 1.4 g / l of brightening product.
  • this same tissue is treated under the same conditions with the above brightening liquid containing no cationic derivative.
  • the degrees of brightening obtained are measured and organoleptic tests are carried out to assess the retention of perfume on the treated fabric.
  • the results show the excellent whitening performance obtained with the brightening liquid containing ultramarine blue compared to the product which does not contain it as well as the excellent perfume retention of a scented brightening liquid containing a cationic derivative compared to a brightening liquid that does not contain it.
  • a disinfectant rinsing liquid is produced according to the formula:
  • a white terry cloth is treated with a solution of 1.4 g / l of disinfectant rinse aid.
  • this same tissue is treated under the same conditions with the above disinfectant rinse product not containing ultramarine blue.
  • the degrees of brightening obtained are measured and organoleptic tests are carried out to assess the retention of perfume on the treated fabric.
  • the results show the excellent whitening performance obtained with the disinfectant rinse product containing ultramarine blue compared to the product which does not contain it as well as the retention of perfume of a perfumed disinfectant product containing a cationic derivative.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
EP82402036A 1982-11-05 1982-11-05 Zusammensetzungen zum Spülen von Wäsche Expired EP0108180B1 (de)

Priority Applications (3)

Application Number Priority Date Filing Date Title
EP82402036A EP0108180B1 (de) 1982-11-05 1982-11-05 Zusammensetzungen zum Spülen von Wäsche
DE8282402036T DE3274747D1 (en) 1982-11-05 1982-11-05 Rinse compositions for laundry
AT82402036T ATE24333T1 (de) 1982-11-05 1982-11-05 Zusammensetzungen zum spuelen von waesche.

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP82402036A EP0108180B1 (de) 1982-11-05 1982-11-05 Zusammensetzungen zum Spülen von Wäsche

Publications (2)

Publication Number Publication Date
EP0108180A1 true EP0108180A1 (de) 1984-05-16
EP0108180B1 EP0108180B1 (de) 1986-12-17

Family

ID=8189947

Family Applications (1)

Application Number Title Priority Date Filing Date
EP82402036A Expired EP0108180B1 (de) 1982-11-05 1982-11-05 Zusammensetzungen zum Spülen von Wäsche

Country Status (3)

Country Link
EP (1) EP0108180B1 (de)
AT (1) ATE24333T1 (de)
DE (1) DE3274747D1 (de)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997043394A2 (en) * 1996-05-17 1997-11-20 The Procter & Gamble Company Detergent composition
WO1997043393A2 (en) * 1996-05-17 1997-11-20 The Procter & Gamble Company Detergent composition
US9028561B2 (en) 2009-05-05 2015-05-12 Milliken & Company Bluing composition and method for treating textile articles using the same

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1390457A (fr) * 1963-05-28 1965-02-26 Colgate Palmolive Co Compositions de blanchissage perfectionnées
FR1581422A (de) * 1967-09-21 1969-09-12
FR2040418A1 (de) * 1969-04-30 1971-01-22 Henkel & Cie Gmbh
FR2130652A1 (de) * 1971-03-24 1972-11-03 Henkel & Cie Gmbh
FR2409303A1 (fr) * 1977-11-18 1979-06-15 Unilever Nv Compositions de blanchiment liquides colorees versables et leurs procedes de preparation

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PH17340A (en) * 1980-03-11 1984-08-01 Unilever Nv Detergent composition

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1390457A (fr) * 1963-05-28 1965-02-26 Colgate Palmolive Co Compositions de blanchissage perfectionnées
FR1581422A (de) * 1967-09-21 1969-09-12
FR2040418A1 (de) * 1969-04-30 1971-01-22 Henkel & Cie Gmbh
FR2130652A1 (de) * 1971-03-24 1972-11-03 Henkel & Cie Gmbh
FR2409303A1 (fr) * 1977-11-18 1979-06-15 Unilever Nv Compositions de blanchiment liquides colorees versables et leurs procedes de preparation

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997043394A2 (en) * 1996-05-17 1997-11-20 The Procter & Gamble Company Detergent composition
WO1997043393A2 (en) * 1996-05-17 1997-11-20 The Procter & Gamble Company Detergent composition
WO1997043394A3 (en) * 1996-05-17 1997-12-24 Procter & Gamble Detergent composition
WO1997043393A3 (en) * 1996-05-17 1997-12-31 Procter & Gamble Detergent composition
US6136769A (en) * 1996-05-17 2000-10-24 The Procter & Gamble Company Alkoxylated cationic detergency ingredients
US9028561B2 (en) 2009-05-05 2015-05-12 Milliken & Company Bluing composition and method for treating textile articles using the same

Also Published As

Publication number Publication date
EP0108180B1 (de) 1986-12-17
ATE24333T1 (de) 1987-01-15
DE3274747D1 (en) 1987-01-29

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