EP0094827A1 - Procédé simultané d'hydrocracking et d'hydrodéparaffinage catalytique d'huiles d'hydrocarbures à l'aide de zéolithe-bêta - Google Patents

Procédé simultané d'hydrocracking et d'hydrodéparaffinage catalytique d'huiles d'hydrocarbures à l'aide de zéolithe-bêta Download PDF

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Publication number
EP0094827A1
EP0094827A1 EP83302774A EP83302774A EP0094827A1 EP 0094827 A1 EP0094827 A1 EP 0094827A1 EP 83302774 A EP83302774 A EP 83302774A EP 83302774 A EP83302774 A EP 83302774A EP 0094827 A1 EP0094827 A1 EP 0094827A1
Authority
EP
European Patent Office
Prior art keywords
zeolite
catalyst
silica
process according
oil
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP83302774A
Other languages
German (de)
English (en)
Other versions
EP0094827B1 (fr
Inventor
Rene Bernard Lapierre
Randall David Partridge
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Oil Corp
Original Assignee
Mobil Oil Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mobil Oil Corp filed Critical Mobil Oil Corp
Priority to AT83302774T priority Critical patent/ATE15910T1/de
Publication of EP0094827A1 publication Critical patent/EP0094827A1/fr
Application granted granted Critical
Publication of EP0094827B1 publication Critical patent/EP0094827B1/fr
Expired legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
    • C10G47/12—Inorganic carriers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
    • C10G11/04—Oxides
    • C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
    • C10G45/64—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
    • C10G47/12—Inorganic carriers
    • C10G47/16—Crystalline alumino-silicate carriers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)
EP83302774A 1982-05-18 1983-05-17 Procédé simultané d'hydrocracking et d'hydrodéparaffinage catalytique d'huiles d'hydrocarbures à l'aide de zéolithe-bêta Expired EP0094827B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT83302774T ATE15910T1 (de) 1982-05-18 1983-05-17 Gleichzeitige katalytische hydrocrackung und entwachsung von kohlenwasserstoffoelen mit zeolith-beta.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US37942182A 1982-05-18 1982-05-18
US379421 1982-05-18

Publications (2)

Publication Number Publication Date
EP0094827A1 true EP0094827A1 (fr) 1983-11-23
EP0094827B1 EP0094827B1 (fr) 1985-10-02

Family

ID=23497202

Family Applications (1)

Application Number Title Priority Date Filing Date
EP83302774A Expired EP0094827B1 (fr) 1982-05-18 1983-05-17 Procédé simultané d'hydrocracking et d'hydrodéparaffinage catalytique d'huiles d'hydrocarbures à l'aide de zéolithe-bêta

Country Status (21)

Country Link
EP (1) EP0094827B1 (fr)
JP (1) JPH0631327B2 (fr)
KR (1) KR910001498B1 (fr)
AR (1) AR244779A1 (fr)
AT (1) ATE15910T1 (fr)
AU (1) AU563075B2 (fr)
BR (1) BR8302595A (fr)
CA (1) CA1196880A (fr)
DE (1) DE3360923D1 (fr)
DK (1) DK161461C (fr)
ES (1) ES8407089A1 (fr)
FI (1) FI71504C (fr)
GR (1) GR78562B (fr)
IN (1) IN158145B (fr)
MY (1) MY8700240A (fr)
NO (1) NO831715L (fr)
NZ (1) NZ204093A (fr)
PH (1) PH17912A (fr)
PT (1) PT76706B (fr)
SG (1) SG77586G (fr)
ZA (1) ZA833588B (fr)

Cited By (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0140608A1 (fr) * 1983-10-13 1985-05-08 Mobil Oil Corporation Catalyseur et procédé pour l'hydrocraquage et le déparaffinage d'huiles hydrocarbonées
EP0180354A1 (fr) * 1984-10-29 1986-05-07 Mobil Oil Corporation Procédé d'hydrotraitement et de déparaffinage de charges pétrolières
EP0183363A1 (fr) * 1984-10-29 1986-06-04 Mobil Oil Corporation Catalysateur et procédé pour la démétallisation, la désulfurisation et le déparaffinage de résidus
EP0186447A2 (fr) * 1984-12-27 1986-07-02 Mobil Oil Corporation Craquage catalytique de charges paraffiniques avec zéolithe bêta
EP0189648A1 (fr) * 1984-12-27 1986-08-06 Mobil Oil Corporation Procédé pour cracking hydrogénant et déparaffinage catalytique
US4612108A (en) * 1985-08-05 1986-09-16 Mobil Oil Corporation Hydrocracking process using zeolite beta
EP0214717A1 (fr) * 1985-06-21 1987-03-18 Mobil Oil Corporation Procédé d'hydrocraquage utilisant un zéolite bêta
WO1988005070A1 (fr) * 1987-01-12 1988-07-14 Chevron Research Company Procede de fabrication de distillats moyens a l'aide d'un tamis moleculaire en silico-aluminophosphate
US4788378A (en) * 1986-05-13 1988-11-29 Mobil Oil Corporation Dewaxing by isomerization
US4788370A (en) * 1986-05-13 1988-11-29 Mobil Oil Corporation Catalytic conversion
US4812223A (en) * 1987-05-01 1989-03-14 Mobil Oil Corporation Hydrocracking naphthas using mildly steamed, noble metal-containing zeolite beta
US4839025A (en) * 1979-10-15 1989-06-13 Union Oil Company Of California Mild hydrocracking with a catalyst containing non-hydrolyzable halogen
US4851109A (en) * 1987-02-26 1989-07-25 Mobil Oil Corporation Integrated hydroprocessing scheme for production of premium quality distillates and lubricants
US4898846A (en) * 1986-03-21 1990-02-06 W. R. Grace & Co.-Conn. Cracking catalysts with octane enhancement
US4911823A (en) * 1984-12-27 1990-03-27 Mobil Oil Corporation Catalytic cracking of paraffinic feedstocks with zeolite beta
FR2678180A1 (fr) * 1991-06-27 1992-12-31 Inst Francais Du Petrole Catalyseur de craquage de charges hydrocarbonees riches en composes naphteniques et/ou en paraffines comprenant une zeolithe d'indice de contrainte inferieure a 1 et une matrice.
EP0955093A1 (fr) * 1998-05-06 1999-11-10 Institut Francais Du Petrole Catalyseur à base de zéolithe bêta et d'element promoteur et procédé d'hydrocraquage
FR2778410A1 (fr) * 1998-05-06 1999-11-12 Inst Francais Du Petrole Procede d'hydrocraquage avec un catalyseur a base de zeolithe beta et d'element du groupe vii b
US6803337B1 (en) * 1999-03-12 2004-10-12 Agip Petroli S.P.A. Catalytic composition for the upgrading of hydrocarbon mixtures
EP1762606A1 (fr) 2005-09-13 2007-03-14 Shell Internationale Researchmaatschappij B.V. Procédé pour la désulfuration de courants d'hydrocarbures
US8758598B2 (en) * 2002-06-28 2014-06-24 Haldor Topsoe A/S Catalyst comprising zeolite beta and its use in hydrocarbon conversion process

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0967014B1 (fr) * 1998-06-25 2006-03-15 Institut Français du Pétrole Catalyseur d'hydrocraquage comprenant une zéolite beta et un élément du groupe VB
US8263517B2 (en) * 2007-12-28 2012-09-11 Exxonmobil Research And Engineering Company Hydroprocessing catalysts with low surface area binders
KR101354235B1 (ko) * 2010-04-14 2014-02-13 에스케이이노베이션 주식회사 수소화 탈왁스 공정을 위한 촉매 및 이의 제조 방법

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2625340A1 (de) * 1975-06-10 1976-12-30 Mobil Oil Corp Synthetische kristalline aluminosilicatzeolithe, verfahren zu deren herstellung und deren verwendung

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3308069A (en) 1964-05-01 1967-03-07 Mobil Oil Corp Catalytic composition of a crystalline zeolite
JPS514515B2 (fr) * 1972-08-03 1976-02-12
US3923641A (en) 1974-02-20 1975-12-02 Mobil Oil Corp Hydrocracking naphthas using zeolite beta
CA1117457A (fr) * 1977-03-28 1982-02-02 Christopher Olavesen Deparaffinage catalyse par un zeolithe l en presence d'hydrogene
US4222855A (en) * 1979-03-26 1980-09-16 Mobil Oil Corporation Production of high viscosity index lubricating oil stock
US4434047A (en) * 1981-11-13 1984-02-28 Standard Oil Company (Indiana) Catalytic dewaxing-hydrotreating process

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2625340A1 (de) * 1975-06-10 1976-12-30 Mobil Oil Corp Synthetische kristalline aluminosilicatzeolithe, verfahren zu deren herstellung und deren verwendung

Cited By (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4839025A (en) * 1979-10-15 1989-06-13 Union Oil Company Of California Mild hydrocracking with a catalyst containing non-hydrolyzable halogen
EP0140608A1 (fr) * 1983-10-13 1985-05-08 Mobil Oil Corporation Catalyseur et procédé pour l'hydrocraquage et le déparaffinage d'huiles hydrocarbonées
AU573630B2 (en) * 1983-10-13 1988-06-16 Mobil Oil Corp. Catalyst for hydrocracking and dewaxing hydrocarbon oils
EP0180354A1 (fr) * 1984-10-29 1986-05-07 Mobil Oil Corporation Procédé d'hydrotraitement et de déparaffinage de charges pétrolières
EP0183363A1 (fr) * 1984-10-29 1986-06-04 Mobil Oil Corporation Catalysateur et procédé pour la démétallisation, la désulfurisation et le déparaffinage de résidus
EP0186447A2 (fr) * 1984-12-27 1986-07-02 Mobil Oil Corporation Craquage catalytique de charges paraffiniques avec zéolithe bêta
EP0189648A1 (fr) * 1984-12-27 1986-08-06 Mobil Oil Corporation Procédé pour cracking hydrogénant et déparaffinage catalytique
US4911823A (en) * 1984-12-27 1990-03-27 Mobil Oil Corporation Catalytic cracking of paraffinic feedstocks with zeolite beta
EP0186447A3 (en) * 1984-12-27 1987-11-11 Mobil Oil Corporation Catalytic cracking of paraffinic feedstocks with zeolite beta
EP0214717A1 (fr) * 1985-06-21 1987-03-18 Mobil Oil Corporation Procédé d'hydrocraquage utilisant un zéolite bêta
EP0216443A1 (fr) * 1985-08-05 1987-04-01 Mobil Oil Corporation Procédé d'hydrocraquage utilisant de la zéolite bêta
US4612108A (en) * 1985-08-05 1986-09-16 Mobil Oil Corporation Hydrocracking process using zeolite beta
US4898846A (en) * 1986-03-21 1990-02-06 W. R. Grace & Co.-Conn. Cracking catalysts with octane enhancement
US4788378A (en) * 1986-05-13 1988-11-29 Mobil Oil Corporation Dewaxing by isomerization
US4788370A (en) * 1986-05-13 1988-11-29 Mobil Oil Corporation Catalytic conversion
WO1988005070A1 (fr) * 1987-01-12 1988-07-14 Chevron Research Company Procede de fabrication de distillats moyens a l'aide d'un tamis moleculaire en silico-aluminophosphate
JPH01502273A (ja) * 1987-01-12 1989-08-10 シェブロン　リサーチ　カンパニー シリカアルミノ燐酸塩モレキユラーシーブ使用の中間留分製造方法
US4851109A (en) * 1987-02-26 1989-07-25 Mobil Oil Corporation Integrated hydroprocessing scheme for production of premium quality distillates and lubricants
US4812223A (en) * 1987-05-01 1989-03-14 Mobil Oil Corporation Hydrocracking naphthas using mildly steamed, noble metal-containing zeolite beta
FR2678180A1 (fr) * 1991-06-27 1992-12-31 Inst Francais Du Petrole Catalyseur de craquage de charges hydrocarbonees riches en composes naphteniques et/ou en paraffines comprenant une zeolithe d'indice de contrainte inferieure a 1 et une matrice.
EP0955093A1 (fr) * 1998-05-06 1999-11-10 Institut Francais Du Petrole Catalyseur à base de zéolithe bêta et d'element promoteur et procédé d'hydrocraquage
FR2778410A1 (fr) * 1998-05-06 1999-11-12 Inst Francais Du Petrole Procede d'hydrocraquage avec un catalyseur a base de zeolithe beta et d'element du groupe vii b
US6524470B1 (en) 1998-05-06 2003-02-25 Institut Francais du Pétrole Catalyst comprising beta zeolite and promoter element for hydrocracking
US6803337B1 (en) * 1999-03-12 2004-10-12 Agip Petroli S.P.A. Catalytic composition for the upgrading of hydrocarbon mixtures
US7156980B2 (en) 1999-03-12 2007-01-02 Agip Petroli S.P.A. Catalytic composition for the upgrading of hydrocarbon mixtures
US7754637B2 (en) 1999-03-12 2010-07-13 Agip Petroli S.P.A. Catalytic composition for the upgrading of hydrocarbon mixtures
US8758598B2 (en) * 2002-06-28 2014-06-24 Haldor Topsoe A/S Catalyst comprising zeolite beta and its use in hydrocarbon conversion process
EP1762606A1 (fr) 2005-09-13 2007-03-14 Shell Internationale Researchmaatschappij B.V. Procédé pour la désulfuration de courants d'hydrocarbures

Also Published As

Publication number Publication date
DK161461B (da) 1991-07-08
KR840004776A (ko) 1984-10-24
PT76706A (en) 1983-06-01
AU563075B2 (en) 1987-06-25
BR8302595A (pt) 1984-01-17
ZA833588B (en) 1984-12-24
FI831724L (fi) 1983-11-19
DK219883D0 (da) 1983-05-17
DK219883A (da) 1983-11-19
ES522482A0 (es) 1984-08-16
ES8407089A1 (es) 1984-08-16
JPS58210994A (ja) 1983-12-08
CA1196880A (fr) 1985-11-19
EP0094827B1 (fr) 1985-10-02
PT76706B (en) 1985-11-28
DK161461C (da) 1991-12-16
JPH0631327B2 (ja) 1994-04-27
GR78562B (fr) 1984-09-27
FI71504C (fi) 1987-01-19
FI831724A0 (fi) 1983-05-17
FI71504B (fi) 1986-10-10
DE3360923D1 (en) 1985-11-07
IN158145B (fr) 1986-09-13
NZ204093A (en) 1985-01-31
ATE15910T1 (de) 1985-10-15
MY8700240A (en) 1987-12-31
AR244779A1 (es) 1993-11-30
AU1437783A (en) 1983-11-24
SG77586G (en) 1987-02-27
NO831715L (no) 1983-11-21
KR910001498B1 (ko) 1991-03-09
PH17912A (en) 1985-01-25

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