EP0088612B1 - Detergens - Google Patents

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Publication number
EP0088612B1
EP0088612B1 EP83301188A EP83301188A EP0088612B1 EP 0088612 B1 EP0088612 B1 EP 0088612B1 EP 83301188 A EP83301188 A EP 83301188A EP 83301188 A EP83301188 A EP 83301188A EP 0088612 B1 EP0088612 B1 EP 0088612B1
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EP
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Prior art keywords
detergent
polyether
coconut oil
solution
active agent
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EP83301188A
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English (en)
French (fr)
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EP0088612A1 (de
Inventor
William Keane
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BRIDGEMACE Ltd
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BRIDGEMACE Ltd
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Priority to AT83301188T priority Critical patent/ATE24931T1/de
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/86—Mixtures of anionic, cationic, and non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/43—Solvents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
    • C11D1/523—Carboxylic alkylolamides, or dialkylolamides, or hydroxycarboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain one hydroxy group per alkyl group
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols

Definitions

  • This invention relates to detergent particularly but not exclusively for use in domestic dishwashing although it may find industrial or alternative domestic applications.
  • Percentage compositions used in this specification are by weight unless indicated otherwise.
  • a mobile liquid detergent comprising not more than 8% water and not less than 90% of active detergents including an anionic surface active agent, an ethanolamide derivative of coconut oil and a non-ionic polyether, wherein a 0.01 % w/w solution of the active detergent exhibits a surface tension at 20°C of not more than 4.5x 10- 2 Nm- 2 (45 dyne cm-1) characterised in that the said mobile liquid detergent contains a total of not less than 50% of the ethanolamide derivative of coconut oil and the non-ionic polyether, and in that the liquid detergent may be diluted to form an aqueous solution having a strength in the range 7 to 50% by weight, which has a viscosity not less than 2 ⁇ 10 -4 m 2 s -1 (200 centistokes) in the absence of an inorganic thickening agent.
  • the viscosities are determined at 20°C.
  • An active detergent is a surface active agent, an 0.01 % aqueous solution of which exhibits a surface tension at 20°C of not more than 4.5 ⁇ 10 -2 Nm -1 (45 dyne/cm).
  • Preferred detergents in accordance with this invention comprise not less than 92% active detergent, not more than 1% polyethylene glycol and not more than 4% glycerine.
  • Detergents in accordance with this invention have an advantage that they do not contain a large proportion of water, thereby facilitating economical transportion and packing. Furthermore, use of inactive thickening agents such as sodium chloride in compositions which have been diluted for use is unnecessary since detergents in accordance with this invention thicken upon dilution with water alone.
  • a preferred high foaming composition may be diluted to a 15% to 45% aqueous solution having a viscosity not less than 2x10-4m2s-1 (200 centistokes) and being capable of passing a dishwashing and foam test as hereinafter defined.
  • the non-ionic polyether may comprise an alkylphenyl polyether or a polyether derivative of an alcohol.
  • Preferred alcohol polyethers may be derived from C 13 /C 15 or C 17 /C 18 aliphatic alcohols or from mixtures of oleyl and cetyl alcohols.
  • compositions may be diluted to 8% to 10% of their strength to produce solutions preferably having viscosities of 5 ⁇ 10 -4 to 10 ⁇ 10 -4 m 2 s -1 (500 to 1000 centistokes), but solutions showing viscosities up to 20 ⁇ 10 -4 m 2 s -1 (2000 centistokes) may also be obtained.
  • the dishwashing and foam test is performed as follows. Sodium chloride (2.5%), gelatine (2.5%), caramel (5%), instant potato (9.5%), fat (Trex or Tesco (Registered Trade Mark) lard 68%), and water (12.5%) are warmed and mixed together. The mixture is placed in a refrigerator for 24 hours and is removed from the refrigerator at least 30 minutes before use. A portion (5 g) of the mixture is applied to the surface of each plate used in the test and the plates are then left to stand for 1 hour. The plates are 23 cm in diameter and are white in colour.
  • a portion (0.5 g) of the detergent solution is placed in one end of a polyethylene bowl having internal dimensions of 33 cmx29 cm and a depth of 13 cm and which is inclined at an angle of 25° to the horizontal.
  • Water (5 1) at a temperature of 54°C is allowed to run onto the detergent through an aperture 6 mm in diameter located 40 cm above the detergent.
  • the bowl is arranged horizontally when half of the water has been added and the remaining water is allowed to pour into the opposite end of the bowl thereby providing a good foam covering the entire water surface.
  • a second bowl is filled with water for rinsing the plates. Two soiled plates are immersed into the water and a stopclock is immediately started. After 20 seconds the first plate is washed and rinsed.
  • a third plate is then immersed below the second plate and the second plate is then washed.
  • a fourth plate is then immersed below the third and the process is repeated until there is no foam remaining on the surface of the water.
  • the final temperature of the water must not be less than 45°C. The test is repeated ten times and the mean taken.
  • the detergent passes this test if eight or more plates can be washed before the foam dissipates when using a diluted solution equivalent to a maximum concentration of 0.01 % of the concentrated detergent.
  • the ethanolamide derivative of coconut oil may be a monoethanolamide or diethanolamide derivative. These may be formed by reacting coconut oil or the methyl ester thereof with either monoethanolamine or diethanolamine in the presence of sodium methoxide.
  • the major constituent of coconut oil is the triglyceride of dodecanoic acid although shorter and longer chain triglycerides are also present.
  • the anionic detergent is a salt of dodecylbenzenesulphonic acid or a mixture of salts of alkylbenzenesulphonic acids of which a major constituent is dodecylbenzenesulphonic acid. Suitable mixtures may be either broad cut or narrow cut, that is there may be greater or lesser variation in the lengths of the alkyl chains. Narrow cut mixtures are preferred.
  • the dodecylbenzenesulphonate is soft. There should be no propylene tetramer present.
  • the anionic detergent may comprise an alkyl sulphate, or an alkyl ether sulphate.
  • Alkyl sulphates may be derived from linear alk-1-ene having 12 to 18 carbon atoms for example sodium lauryl sulphate.
  • Preferred alcohol sulphates may be derived from products of the OXO or Ziegler processes.
  • Preferred ether sulphates are derived from ethylene oxide and may comprise a major proportion having the general formula:- wherein n is 13 or 15, m is 2 or 3 and X is Na, K, NH 4 or an ethanolamine.
  • Preferred detergents in accordance with the invention incorporate an alkylphenyl polyether such as OH terminated polyether.
  • the latter may be formed by reacting an alkyl phenol with ethylene oxide.
  • Preferred polyethers incorporate nonyl or octyl alkyl chains or mixtures including major proportions of such chains.
  • Preferred polyethers may comprise mixtures of polyether chains with major proportions of chains having 6 or 9 (CH 2 CH 2 0) units or, more preferably, major proportions of both 6 and 9 (CH 2 CH 2 0) unit containing chains. A greater proportion of chains having 6 (CH 2 CH 2 0) units to chains having 9 (CH 2 CH 2 0) units is particularly preferred. Smaller proportions of polyethers with larger ether chain lengths may be incorporated for example having 12 (CH 2 CH 2 0) units.
  • Preferred detergents in accordance with this invention incorporate a base.
  • Preferred bases include monoethanolamine, diethanolamine, triethanolamine or potassium or sodium hydroxides. Monoethanolamine and triethanolamine are particularly preferred.
  • Detergents in accordance with this invention may be selected from a wide range of compositions in which the proportions of the ingredients are chosen so that they may be diluted to form an aqueous solution having a strength in the range 7 to 50% by weight, which has a viscosity of at least 2x10-4m2s-' (200 centistokes) in the absence of an inorganic thickening agent, and which has adequate cleaning properties in accordance with the plate washing test.
  • the ratio of anionic detergent to nonionic detergent is important, an excess of nonionic detergent being essential.
  • the ratio of anionic detergent to insoluble polyethers is also important, a greater proportion of anionic detergent having been found to increase the solubility of the polyether constituent.
  • the detergent composition of this invention incorporates not more than 30% of anionic detergent estimated as the free acid. More preferably there is between 15% and 25% of dodecylbenzenesulphonic acid present in detergents which do not contain alkyl or ether sulphates. If the latter compounds are present the preferred proportion of dodecylbenzenesulphonic acid is 8% to 25%.
  • the proportion of alkyl or ether sulphate is preferably 10% to 30% based on the weight of the commercially available solutions, the latter containing approximately 70% of the pure compounds.
  • the proportion of the ethanolamide derivative of coconut oil has an important effect of the viscosity of the detergent.
  • the derivative also serves to stabilise the foam.
  • alkylphenyl polyethers having a side chain incorporating a small number of (CH 2 CH 2 0) groups is a key factor effecting the viscosity of detergents in accordance with the invention.
  • such polyethers alone may be insoluble in water.
  • the cloud point of the insoluble polyether is less than zero.
  • Mixtures incorporating nonylphenyl polyether are particularly preferred ingredients, a wide range of ether chain lengths being advantageous.
  • Nonylphenyl polyethers are particularly efficacious in control of the viscosity of the diluted detergent.
  • Nonylphenyl polyethers having a low solubility in water, notably those comprising six (CH 2 CH 2 0) groups are particularly preferred as a major proportion of total polyethers in the detergent.
  • Preferred detergent compositions of this invention incorporate between 25% and 55% of nonylphenyl polyether. More preferably there is between 40% and 55% of the polyether.
  • Detergent compositions of this invention often incorporate a blend of nonylphenyl polyethers.
  • s (300 cp) may comprise 1 ⁇ 5% of nonylphenyl polyether incorporating 12 (CH 2 CH 2 O) units, 25 ⁇ 45% of nonylphenyl polyether incorporating 6 (CH 2 CH 2 0) units and 2-10% of nonylphenyl polyethers having 8 or 9 (CH 2 CH 2 0) units.
  • the actual percentages of these three components are chosen so that the total percentage of polyether falls within the aforementioned range of 25-55%.
  • a particular efficacious range for the three aforementioned polyethers is 1-3% with 12 (CH 2 CH 2 0) units, 30-45% with 6 (CH 2 CH 2 0) units and 5-10% with 8 or 9 (CH 2 CH 2 0) units.
  • Bases having a low molecular weight are preferred, monoethanolamine having been found to provide more viscous detergents than diethanolamine.
  • Use of triethanolamine has the advantage of maintaining a constant pH in the detergent.
  • Ethanolamines may be used in conjunction with sodium or potassium hydroxides, the ratio of alkali metal hydroxide to ethanolamine being important.
  • the amount of mono-, di- and triethanolamine present is approximately 1.0­1.5 ⁇ the stoichiometric amount based on the sulphonate and sulphate present being desirable.
  • the amount of mono, di- or triethanolamine is preferably selected so that a 10% aqueous solution of the detergent has a pH of 6.8 to 9, more preferably of 7.5 to 8.5.
  • a relatively larger proportion of diethanolamine or triethanolamine is required if this reagent is used in place of ethanolamine since the mono derivative is the most active.
  • Detergent in accordance with this invention may be diluted to form aqueous solutions of more than 7% strength, for example 8%, 10%, 20%, 25% and 40%.
  • a particular preferred detergent comprises ingredients not exceeding a total of 100% and comprising, 7% to 30% of dodecylbenzenesulphonic acid, 10% to 30% of a solution equivalent to a 70% solution of anionic detergent of the formula: wherein n is 13 or 15 and m is 3; X is Na or NH 4 or an ethanolamine, 25% to 50% of nonylphenyl polyether; 5% to 40% of coconut oil diethanolamide and residual percentages of ethanolamine and triethanolamine.
  • the detergent may comprise: 7% to 15% of dodecylbenzenesulphonic acid; 15% to 25% of the said solution of anionic detergent; 30% to 45% of nonylphenyl polyether; 20% to 35% of coconut oil diethanolamide; 1% to 4% of ethanolamine and 2% to 5% of triethanolamine.
  • the total percentage of nonylphenyl polyether and coconut oil diethanolamide is preferably 50% to 65%.
  • the total percentage of dodecylbenzenesulphonic acid and the said anionic detergent is preferably 20% to 35%.
  • the percentage of coconut oil diethanolamide is preferably 15% to 35%. This detergent yields self-thickening 10-25% aqueous solutions.
  • Such detergents having a total percentage of polyether and coconut oil diethanolamide less than 50% form self thickening 15% to 45% aqueous solutions.
  • Table 2 shows the compositions and properties of preferred detergents including the viscosities of 7%, 8%, 10% and 20% aqueous solutions;
  • a detergent was prepared from a nonylphenyl polyether incorporating six (CH 2 CH 2 0) units in the side chain (36%), dodecylbenzenesulphonic acid (30%) monoethanolamine (9%), coconut oil diethanolamide (25%).
  • a 72% aqueous solution of the detergent had a viscosity of 300 cs an 8% solution was found to have a viscosity of 1000 cs and a 10% solution was found to be thixotropic and to have a viscosity of 2000 cs on a Ford Cup No. 4. 5 gm of the 10% solution was found to clean 9 plates according to the plate test.
  • a detergent was prepared from nonylphenyl polyether incorporating six (CH 2 CH 2 0) units (18%), dodecylbenzenesulphonic acid (20%) monoethanolamine (7%), coconut oil diethanolamide (37%) and nonylphenyl polyether incorporating 9 (CH 2 CH 2 0) units (18%).
  • An 8% aqueous solution of the detergent was found to have a viscosity of 210 cs and a 10% solution was found to have a viscosity of 2000 cs 5 g of the 10% solution was found to clean 12 plates.
  • a detergent was prepared from nonylphenyl polyether containing six (CH 2 CH 2 0) units (20%) dodecylbenzenesulphonic acid (20%), monoethanolamide (7%), coconut oil diethanolamide (33%) and nonylphenyl polyether containing nine (CH 2 CH 2 0) units (20%).
  • An 8% aqueous solution of the detergent was found to have a viscosity of 200 cs and a 10% solution was found to have a viscosity of 2000 cs.
  • the detergent (5 g of 10% solution) was found to clean 13 plates.
  • a detergent was prepared from coconut oil diethanolamide (33%) nonylphenylpolyether containing 9 (CH 2 CH 2 0) units (5%), nonylphenylpolyether containing 6 (CH 2 CH 2 0) units (35%), dodecylbenzenesulphonic acid (21 %) and monoethanolamine (6%).
  • a (10%) aqueous solution of the detergent was found to have a viscosity of 1600 cs and 7% aqueous solution was found to have a viscosity of 700 cs.
  • the detergent (5 g of 10% solution was found to clean 10 plates).
  • a detergent was prepared from coconut oil diethanolamide (32.8%) nonylphenylpolyether containing 9 (CH 2 CH 2 0) groups (10.8%), nonylphenylpolyether containing 6 (CH 2 CH 2 0) groups (29.5%), narrow cut dodecylbenzenesulphonic acid (20.9%) and monoethanolamine (5.9%).
  • a detergent was prepared from coconut oil diethanolamide (25.94%), nonylphenylpolyether containing 12 (CH 2 CH 2 0) groups (0.89%), nonylphenylpolyether containing 8 (CH 2 CH 2 0) groups (4.47%), nonylphenylpolyether containing 6 (CH 2 CH 2 0) groups (30.41 %), a sodium sulphated C 13 /C 15 alcohol with 3 (CH 2 CH 2 0) groups (Synperonic 3S70 a 70% commercial solution manufactured by ICI, 24.15%), dodecylbenzenesulphonic acid (8.68%), monoethanolamine (0.54%), triethanolamine (4.47%) and preservative (0.45%; Ketrol T, Cochrane and Keane Chemicals).
  • the resultant detergent yielded viscous, high foaming solutions upon dilution to a strength of 10%, 15% or 20%.
  • a detergent was prepared from coconut oil diethanolamide (20%), nonylphenylpolyether containing 9 (CH 2 CH 2 0) groups (2%), nonylphenylpolyether containing 6 (CH 2 CH 2 0) groups (43%), Synperonic 3S70 (20%), dodecylbenzenesulphonic acid (10%), monoethanolamine (1%) and triethanolamine (4%).
  • the resultant detergent yielded viscous detergents upon dilution to a strength of 9% to 10%.
  • a detergent was prepared from coconut oil diethanolamide (25%), nonylphenylpolyether containing 6 (CH 2 CH 2 0) groups (25%), Synperonic 3S70 (20%), dodecylbenzenesulphonic acid (20%), monoethanolamine (2%) and triethanolamine (8%).
  • the resultant detergent produced viscous detergents when diluted to strengths of 15%, 20%, 25%, 30% and 40%.
  • Table 2 shows the composition and properties of preferred detergents.
  • the compositions of the detergents indicated by the reference numbers 18, 20, 26, 28 and 29 may be determined from Figure 6.
  • Figure 1 is a three-dimensional diagram showing the proportions of N6, N9, CD and dodecylbenzenesulphonic acid which may be present in detergents in accordance with the invention.
  • Figure 2 is a plan view of the latter diagram.
  • Figures 3 to 6 are sections through the diagram shown in Figures 1 and 2 showing variation of the ingredients N6, N9 and CD at constant proportions of dodecylbenzenesulphonic acid.
  • Figure 3 illustrates the variation at D of Figure 2 of a total of 40% of N9, N6 and CD in detergents containing constant proportions of 40% Acid, 11 % MEO and 9% CD.
  • the shaded area shows the preferred compositions.
  • Figure 4 shows the variation at B of Figure 2 of a total of 60% of N9, N6 and CD in detergents containing constant proportions of 30% Acid, 9% MEO and 1 % CD.
  • the shaded area shows preferred compositions.
  • Figure 5 shows the variations at A of Figure 2 of a total of 70% of N9, N6 and CD in detergents containing constant properties of 20% Acid, 7% MEO and 3% CD.
  • the first shaded area shows preferred compositions including diethanolamide prepared from coconut oil or from the methyl ester thereof.
  • the second shaded area shows additional preferred compositions including diethanolamide prepared from coconut oil only.
  • Figure 6 is a section of Figure 2 taken close to Figure 6 and showing variation of a total of 70% of N6, N9 and CD, in compositions containing constant proportions of 21 % Acid, 6% MEO and 3% of CD.
  • the two shaded areas show preferred and especially preferred compositions.
  • Detergents including 65% or more of dodecylbenzenesulphonic acid have been found to form gels or to be unstable. Detergents comprising less than 17% of the acid have been found to have poor cleaning capacity and to exhibit low foam stability. Compositions containing 10-25% of ether sulphate need only contain 8% to 15% of the acid.
  • the ingredients NP6, NP9 and NP12 are manufactured under the Registered Trade Mark Synperonic by ICI although alternative brands may also be used.
  • coconut oil derivatives which are useful in accordance with the invention may be obtained under the Registered Trade Mark Ethylan, manufactured by Diamond Shamrock Process Chemicals Limited. Coconut oil may also be obtained from Rewo Chemicals Limited and Baxenden Chemicals Limited.
  • Dodecylbenzenesulphonic acid may be obtained from Shell, BP, CFC or Henkel.
  • Ethanolamine should preferably be the last ingredient which is added when making detergents in accordance with this invention.

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Claims (20)

1. Bewegliches flüssiges Reinigungsmittel mit nicht mehr als 8 Gew.-% Wasser und nicht weniger als 90 Gew.-% aktivem Reinigungsmittel einschließlich einem anionischen oberflächenaktiven Mittel, einem Ethanolamidderivat von Kokosnußöl und einem nicht-ionischen Polyether (worin eine 0,01 gew.%ige Lösung des aktiven Reinigungsmittels bei 20°C eine Oberflächenspannung von nicht mehr als 4,5x10-2Nm-2 (45 Dyn cm-1) aufweist), dadurch gekennzeichnet, daß das bewegliche flüssige Reinigungsmittel insgesamt nicht weniger als 50 Gew.-% des Ethanolamidderivates von Kokosnußöl und des nicht-ionischen Polyethers enthält und daß das flüssige Reinigungsmittel unter Bildung einer wäßrigen Lösung mit einer Stärke im Bereich von 7 bis 50 Gew.-% verdünnt werden kann, die in Abwesenheit eines anorganischen Dickungsmittels eine Viskosität von nicht weniger als 2×10-4m2s-1 (200 Zentistokes) aufweist.
2. Reinigungsmittel nach Anspruch 1, dadurch gekennzeichnet, daß es nicht weniger als 92% aktives Reinigungsmittel, nicht mehr als 1% Polyethylenglykol und nicht mehr als 4% Glyzerin enthält.
3. Reinigungsmittel nach Anspruch 1, dadurch gekennzeichnet, daß 8 bis 10%ige wäßrige Lösungen eine Viskosität von 5×10-4 bis 10×10-4m2s-1 (500 bis 1000 Zentistokes) aufweisen.
4. Reinigungsmittel nach Anspruch 1, dadurch gekennzeichnet, daß 15 bis 45%ige wäßrige Lösungen eine Viskosität von nicht weniger als 2x10-4m2s-' (200 Zentistokes) aufweisen.
5. Reinigungsmittel nach einem der vorstehenden Ansprüche, dadurch gekennzeichnet, daß es einen Polyether, ausgewählt aus einem Alkylphenylpolyether oder einem Polyether, der sich von aliphatischen Alkoholen, ausgewählt aus: Alkoholen mit 13 bis 15 Kohlenstoffatomen, Alkoholen mit 17 oder 18 Kohlenstoffatomen oder einer Mischung von Oleyl- und Cetylalkoholen ableitet, enthält.
6. Reinigungsmittel nach einem der vorstehenden Ansprüche, dadurch gekennzeichnet, daß das anionische oberflächenaktive Mittel Dodecylbenzolsulfonsäure oder ein Salz hiervon enthält.
7. Reinigungsmittel nach einem der vorstehenden Ansprüche, dadurch gekennzeichnet, daß es ein anionisches oberflächenaktives Mittel, ausgewählt aus einem Alkylsulfat oder einem anionischen oberflächenaktiven Mittel der folgenden Formel:
Figure imgb0009
in der n gleich 12 oder 15, m gleich 2 oder 3 und X gleich Na, K, NH4 oder ein Ethanolamin bedeuten, enthält.
8. Reinigungsmittel nach einem der Ansprüche 5 bis 7, dadurch gekennzeichnet, daß es einen Polyether der folgenden Formel:
Figure imgb0010
in der r und s für ganze Zahlen stehen, enthält.
9. Reinigungsmittel nach Anspruch 8, dadurch gekennzeichnet, daß r für 8 oder 9 und s für eine Zahl von 6 bis 12 steht.
10. Reinigungsmittel nach Anspruch 9, dadurch gekennzeichnet, daß bei einem Hauptanteil des Polyethers r gleich 8 oder 9 und s gleich 6 oder 9 ist und daß es einen größeren Anteil an Polyether mit s gleich 6 als mit s gleich 9 enthält.
11. Reinigungsmittel nach einem der vorstehenden Ansprüche, dadurch gekennzeichnet, daß es einen größeren Prozentsatz an anionischem oberflächenaktiven Mittel als Polyether enthält.
12. Reinigungsmittel nach einem der Ansprüche 1 bis 6 oder 11, falls nicht abhängig von Ansprüchen 7 bis 10, dadurch gekennzeichnet, daß es 15 bis 25% Dodecylbenzolsulfonsäure enthält.
13. Reinigungsmittel nach einem der Ansprüche 7 bis 10, dadurch gekennzeichnet, daß es 8 bis 25% Dodecylbenzolsulfonsäure und eine Menge, die 10 bis 30% einer 70%igen Lösung eines Alkyl- oder Ethersulfates äquivalent ist, enthält.
14. Reinigungsmittel nach einem der vorstehenden Ansprüche, dadurch gekennzeichnet, daß es 15 bis 33% des Ethanolamides enthält.
15. Reinigungsmittel nach Anspruch 8, dadurch gekennzeichnet, daß es 1 bis 5% Polyether mit r gleich 9 und s gleich 12, 25 bis 45% Polyether mit r gleich 9 und s gleich 6 und 2 bis 10% Polyether mit r gleich 9 und s gleich 8 oder 9 enthält.
16. Reinigungsmittel nach Anspruch 15, dadurch gekennzeichnet, daß es 1 bis 3% Polyether mit r gleich 9 und s gleich 12, 30 bis 45% Polyether mit r gleich 9 und s gleich 6 und 5 bis 10% Polyether mit r gleich 9 und s gleich 8 oder 9 enthält.
17. Reinigungsmittel nach einem der vorstehenden Ansprüche, dadurch gekennzeichnet, daß es Bestandteile enthält, die ausgewählt sind aus: 7 bis 30% einer Lösung, die äquivalent ist einer 70%igen Lösung eines anionischen oberflächenaktiven Mittels des Formel:
Figure imgb0011
worin bedeuten: n gleich 13 oder 15, m gleich 3, X gleich Na, NH4 oder ein Ethanolamin; 25 bis 50% Nonylphenylpolyether; 5 bis 40% Kokosnußöldiethanolamid und resetlichen Anteilen von Ethanolamin und Triethanolamin.
18. Reinigungsmittel nach Anspruch 17, dadurch gekennzeichnet, daß es Bestandteile enthält, die ausgewählt sind aus: 7 bis 15% Dodecylbenzolsulfonsäure; 15 bis 25% der Lösung des anionischen Reinigungsmittels; 30 bis 45% Nonylphenylpolyether; 20 bis 35% Kokosnußöldiethanolamid; 1 bis 4% Ethanolamin und 2 bis 5% Triethanolamin.
19. Reinigungsmittel nach Anspruch 17 oder 18, dadurch gekennzeichnet, daß es insgesamt 50 bis 65% Nonylphenylpolyether und Kokosnußöldiethanolamid enthält.
20. Reinigungsmittel nach Ansprüchen 18 oder 19, dadurch gekennzeichnet, daß es insgesamt 20 bis 35% Dodecylbenzolsulfonsäure und anionisches Reinigungsmittel enthält.
EP83301188A 1982-03-06 1983-03-04 Detergens Expired EP0088612B1 (de)

Priority Applications (1)

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AT83301188T ATE24931T1 (de) 1982-03-06 1983-03-04 Detergens.

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GB8206667 1982-03-06
GB8206667 1982-03-06

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EP0088612A1 EP0088612A1 (de) 1983-09-14
EP0088612B1 true EP0088612B1 (de) 1987-01-14

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DE (1) DE3369157D1 (de)
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Families Citing this family (11)

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Publication number Priority date Publication date Assignee Title
CA1276852C (en) * 1985-06-21 1990-11-27 Francis John Leng Liquid detergent composition
FR2601960B1 (fr) * 1986-07-25 1989-05-26 Lesieur Cotelle Composition detergente, visqueuse, diluable et son procede d'obtention
GB8625104D0 (en) * 1986-10-20 1986-11-26 Unilever Plc Detergent compositions
US5453215A (en) * 1992-09-08 1995-09-26 Lever Brothers Company, Division Of Conopco, Inc. Process for producing concentrated laundry detergent by manufacture of low moisture content detergent slurries
ZA936554B (en) * 1992-09-08 1995-03-06 Unilever Plc Detergent composition and process for its production.
US5474713A (en) * 1994-03-23 1995-12-12 Amway Corporation High actives cleaning compositions and methods of use
CA2208038C (en) * 1994-12-22 2004-01-27 Unilever Plc Detergent composition
CN1070228C (zh) * 1997-08-06 2001-08-29 广州市荔湾区得洁洗涤剂厂 超浓缩膏状半固体洗洁精
GB201010109D0 (en) * 2010-06-17 2010-07-21 Reckitt Benckiser Inc Adhesive lavatory treatment compositions
DE102014200062A1 (de) * 2014-01-07 2015-07-09 Henkel Ag & Co. Kgaa Waschmittel enthaltend Alkanolamid
US20210292687A1 (en) * 2018-08-15 2021-09-23 Baldwin Jimek Ab Roll of cleaning fabric and related apparatus and methods

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0034039A1 (de) * 1980-02-05 1981-08-19 THE PROCTER & GAMBLE COMPANY Flüssige Reinigungsmittelzusammensetzung

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DK132534A (de) * 1967-04-13
GB1540386A (en) * 1976-11-15 1979-02-14 John W Surface active compositions
GB1573908A (en) * 1977-05-13 1980-08-28 Nkro Chemicals Ltd Liquid surfactant concentrates
US4268406A (en) * 1980-02-19 1981-05-19 The Procter & Gamble Company Liquid detergent composition

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0034039A1 (de) * 1980-02-05 1981-08-19 THE PROCTER & GAMBLE COMPANY Flüssige Reinigungsmittelzusammensetzung

Also Published As

Publication number Publication date
EP0088612A1 (de) 1983-09-14
ATE24931T1 (de) 1987-01-15
GB2116994B (en) 1985-10-30
GB8305884D0 (en) 1983-04-07
DE3369157D1 (en) 1987-02-19
GB2116994A (en) 1983-10-05

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