EP0070192B2 - Detergent additives and detergent compositions containing them - Google Patents
Detergent additives and detergent compositions containing them Download PDFInfo
- Publication number
- EP0070192B2 EP0070192B2 EP82303676A EP82303676A EP0070192B2 EP 0070192 B2 EP0070192 B2 EP 0070192B2 EP 82303676 A EP82303676 A EP 82303676A EP 82303676 A EP82303676 A EP 82303676A EP 0070192 B2 EP0070192 B2 EP 0070192B2
- Authority
- EP
- European Patent Office
- Prior art keywords
- weight
- soap
- detergent composition
- detergent
- chain length
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 78
- 239000003599 detergent Substances 0.000 title claims abstract description 67
- 239000000654 additive Substances 0.000 title description 11
- 239000000344 soap Substances 0.000 claims abstract description 67
- 239000000463 material Substances 0.000 claims abstract description 39
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 29
- 229910000323 aluminium silicate Inorganic materials 0.000 claims abstract description 26
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 claims abstract description 20
- 150000003839 salts Chemical class 0.000 claims abstract description 9
- 229920006395 saturated elastomer Polymers 0.000 claims abstract description 7
- 238000005341 cation exchange Methods 0.000 claims abstract description 6
- 229910052816 inorganic phosphate Inorganic materials 0.000 claims abstract description 5
- -1 alkali metal salt Chemical class 0.000 claims description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- 229910052783 alkali metal Inorganic materials 0.000 claims description 7
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 6
- 239000000194 fatty acid Substances 0.000 claims description 6
- 229930195729 fatty acid Natural products 0.000 claims description 6
- 239000003760 tallow Substances 0.000 claims description 5
- 244000060011 Cocos nucifera Species 0.000 claims description 4
- 235000013162 Cocos nucifera Nutrition 0.000 claims description 4
- 239000002178 crystalline material Substances 0.000 claims description 4
- 240000002791 Brassica napus Species 0.000 claims description 2
- 235000004977 Brassica sinapistrum Nutrition 0.000 claims description 2
- 239000011149 active material Substances 0.000 claims description 2
- 229910019142 PO4 Inorganic materials 0.000 abstract description 10
- 239000010452 phosphate Substances 0.000 abstract description 6
- 229910021536 Zeolite Inorganic materials 0.000 abstract description 5
- 239000010457 zeolite Substances 0.000 abstract description 5
- 150000001875 compounds Chemical class 0.000 description 24
- 239000012190 activator Substances 0.000 description 19
- 239000002245 particle Substances 0.000 description 14
- 239000007844 bleaching agent Substances 0.000 description 13
- 229910052757 nitrogen Inorganic materials 0.000 description 13
- 239000011734 sodium Substances 0.000 description 13
- 229910052708 sodium Inorganic materials 0.000 description 13
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 12
- 239000011575 calcium Substances 0.000 description 11
- 239000000047 product Substances 0.000 description 11
- 238000005406 washing Methods 0.000 description 11
- 235000021317 phosphate Nutrition 0.000 description 9
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 8
- 229910052791 calcium Inorganic materials 0.000 description 8
- 239000004744 fabric Substances 0.000 description 8
- 239000008187 granular material Substances 0.000 description 8
- 230000000996 additive effect Effects 0.000 description 7
- 235000019832 sodium triphosphate Nutrition 0.000 description 7
- 125000000129 anionic group Chemical group 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 6
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 5
- 125000000217 alkyl group Chemical group 0.000 description 5
- 239000007795 chemical reaction product Substances 0.000 description 5
- 230000007613 environmental effect Effects 0.000 description 5
- 125000000864 peroxy group Chemical group O(O*)* 0.000 description 5
- 239000003352 sequestering agent Substances 0.000 description 5
- 150000001298 alcohols Chemical class 0.000 description 4
- 150000001340 alkali metals Chemical class 0.000 description 4
- 159000000007 calcium salts Chemical class 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 150000004665 fatty acids Chemical class 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- BGRWYDHXPHLNKA-UHFFFAOYSA-N Tetraacetylethylenediamine Chemical compound CC(=O)N(C(C)=O)CCN(C(C)=O)C(C)=O BGRWYDHXPHLNKA-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000013543 active substance Substances 0.000 description 3
- 238000004061 bleaching Methods 0.000 description 3
- 150000001768 cations Chemical class 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 235000019864 coconut oil Nutrition 0.000 description 3
- 239000003240 coconut oil Substances 0.000 description 3
- 239000008139 complexing agent Substances 0.000 description 3
- 230000003247 decreasing effect Effects 0.000 description 3
- 238000005469 granulation Methods 0.000 description 3
- 230000003179 granulation Effects 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- 229910052910 alkali metal silicate Inorganic materials 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical class OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- WJJMNDUMQPNECX-UHFFFAOYSA-N dipicolinic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=N1 WJJMNDUMQPNECX-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 231100001261 hazardous Toxicity 0.000 description 2
- 230000003301 hydrolyzing effect Effects 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 238000005342 ion exchange Methods 0.000 description 2
- SUMDYPCJJOFFON-UHFFFAOYSA-N isethionic acid Chemical compound OCCS(O)(=O)=O SUMDYPCJJOFFON-UHFFFAOYSA-N 0.000 description 2
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 2
- 150000004682 monohydrates Chemical class 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 229960001922 sodium perborate Drugs 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 125000001424 substituent group Chemical group 0.000 description 2
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 2
- 150000004685 tetrahydrates Chemical class 0.000 description 2
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 2
- 239000004711 α-olefin Substances 0.000 description 2
- MSELUFTVMYHJGR-UHFFFAOYSA-N (1,3-diacetyl-5-propanoyloxyimidazolidin-4-yl) propanoate Chemical compound CCC(=O)OC1C(OC(=O)CC)N(C(C)=O)CN1C(C)=O MSELUFTVMYHJGR-UHFFFAOYSA-N 0.000 description 1
- NIHKFGMYMWGERR-UHFFFAOYSA-N (3-chlorobenzoyl) 3-chlorobenzoate Chemical compound ClC1=CC=CC(C(=O)OC(=O)C=2C=C(Cl)C=CC=2)=C1 NIHKFGMYMWGERR-UHFFFAOYSA-N 0.000 description 1
- WBBAZMPYEDKGEU-UHFFFAOYSA-N (5-acetyloxy-1,3-diformylimidazolidin-4-yl) acetate Chemical compound CC(=O)OC1C(OC(C)=O)N(C=O)CN1C=O WBBAZMPYEDKGEU-UHFFFAOYSA-N 0.000 description 1
- CIOXZGOUEYHNBF-UHFFFAOYSA-N (carboxymethoxy)succinic acid Chemical compound OC(=O)COC(C(O)=O)CC(O)=O CIOXZGOUEYHNBF-UHFFFAOYSA-N 0.000 description 1
- VAVZXZURPCYUHS-RQOWECAXSA-N (z)-3-(hydrazinecarbonyl)-4-oxopent-2-enoic acid Chemical compound OC(=O)/C=C(C(=O)C)\C(=O)NN VAVZXZURPCYUHS-RQOWECAXSA-N 0.000 description 1
- BPSYZMLXRKCSJY-UHFFFAOYSA-N 1,3,2-dioxaphosphepan-2-ium 2-oxide Chemical compound O=[P+]1OCCCCO1 BPSYZMLXRKCSJY-UHFFFAOYSA-N 0.000 description 1
- GJBQPJPEBXKJSF-UHFFFAOYSA-N 1,4-di(propanoyl)piperazine-2,5-dione Chemical compound CCC(=O)N1CC(=O)N(C(=O)CC)CC1=O GJBQPJPEBXKJSF-UHFFFAOYSA-N 0.000 description 1
- CBBKKVPJPRZOCM-UHFFFAOYSA-N 1,4-diacetylpiperazine-2,5-dione Chemical compound CC(=O)N1CC(=O)N(C(C)=O)CC1=O CBBKKVPJPRZOCM-UHFFFAOYSA-N 0.000 description 1
- JTZUXKIKHMIVSD-UHFFFAOYSA-N 1-(carbamoylamino)propan-2-ylurea Chemical compound NC(=O)NC(C)CNC(N)=O JTZUXKIKHMIVSD-UHFFFAOYSA-N 0.000 description 1
- NOGFHTGYPKWWRX-UHFFFAOYSA-N 2,2,6,6-tetramethyloxan-4-one Chemical compound CC1(C)CC(=O)CC(C)(C)O1 NOGFHTGYPKWWRX-UHFFFAOYSA-N 0.000 description 1
- MUSGYYOCMDPAEO-UHFFFAOYSA-N 2,4,6,8-tetrazabicyclo[3.3.1]nonane-3,7-dione Chemical compound C1C2NC(=O)NC1NC(=O)N2 MUSGYYOCMDPAEO-UHFFFAOYSA-N 0.000 description 1
- CFPOJWPDQWJEMO-UHFFFAOYSA-N 2-(1,2-dicarboxyethoxy)butanedioic acid Chemical compound OC(=O)CC(C(O)=O)OC(C(O)=O)CC(O)=O CFPOJWPDQWJEMO-UHFFFAOYSA-N 0.000 description 1
- LVVZBNKWTVZSIU-UHFFFAOYSA-N 2-(carboxymethoxy)propanedioic acid Chemical compound OC(=O)COC(C(O)=O)C(O)=O LVVZBNKWTVZSIU-UHFFFAOYSA-N 0.000 description 1
- WFXJWACFHGTNEH-UHFFFAOYSA-N 3,6-dimethyl-1,4-di(propanoyl)piperazine-2,5-dione Chemical compound CCC(=O)N1C(C)C(=O)N(C(=O)CC)C(C)C1=O WFXJWACFHGTNEH-UHFFFAOYSA-N 0.000 description 1
- BTTRMCQEPDPCPA-UHFFFAOYSA-N 4-chlorophthalic anhydride Chemical compound ClC1=CC=C2C(=O)OC(=O)C2=C1 BTTRMCQEPDPCPA-UHFFFAOYSA-N 0.000 description 1
- UXVMHSYMNTYLPO-UHFFFAOYSA-N 4-ethoxycarbonyloxybenzoic acid Chemical class CCOC(=O)OC1=CC=C(C(O)=O)C=C1 UXVMHSYMNTYLPO-UHFFFAOYSA-N 0.000 description 1
- YNSJJJCTNXHMEW-UHFFFAOYSA-N 4-methoxy-n-methyl-n-methylsulfonylbenzamide Chemical compound COC1=CC=C(C(=O)N(C)S(C)(=O)=O)C=C1 YNSJJJCTNXHMEW-UHFFFAOYSA-N 0.000 description 1
- 102000013142 Amylases Human genes 0.000 description 1
- 108010065511 Amylases Proteins 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 1
- QEVGZEDELICMKH-UHFFFAOYSA-N Diglycolic acid Chemical compound OC(=O)COCC(O)=O QEVGZEDELICMKH-UHFFFAOYSA-N 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- KWYHDKDOAIKMQN-UHFFFAOYSA-N N,N,N',N'-tetramethylethylenediamine Chemical compound CN(C)CCN(C)C KWYHDKDOAIKMQN-UHFFFAOYSA-N 0.000 description 1
- SUZRRICLUFMAQD-UHFFFAOYSA-N N-Methyltaurine Chemical compound CNCCS(O)(=O)=O SUZRRICLUFMAQD-UHFFFAOYSA-N 0.000 description 1
- RXTCWPTWYYNTOA-UHFFFAOYSA-N O=P1OCCCCCO1 Chemical compound O=P1OCCCCCO1 RXTCWPTWYYNTOA-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 102000035195 Peptidases Human genes 0.000 description 1
- 108091005804 Peptidases Proteins 0.000 description 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 1
- 229930182556 Polyacetal Natural products 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 239000004365 Protease Substances 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical class OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000001083 [(2R,3R,4S,5R)-1,2,4,5-tetraacetyloxy-6-oxohexan-3-yl] acetate Substances 0.000 description 1
- UAOKXEHOENRFMP-ZJIFWQFVSA-N [(2r,3r,4s,5r)-2,3,4,5-tetraacetyloxy-6-oxohexyl] acetate Chemical compound CC(=O)OC[C@@H](OC(C)=O)[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](OC(C)=O)C=O UAOKXEHOENRFMP-ZJIFWQFVSA-N 0.000 description 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
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- 238000005917 acylation reaction Methods 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229910000288 alkali metal carbonate Inorganic materials 0.000 description 1
- 150000008041 alkali metal carbonates Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 159000000013 aluminium salts Chemical group 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 235000019418 amylase Nutrition 0.000 description 1
- 229940025131 amylases Drugs 0.000 description 1
- 229920001448 anionic polyelectrolyte Polymers 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 238000010936 aqueous wash Methods 0.000 description 1
- 150000005840 aryl radicals Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 150000004651 carbonic acid esters Chemical class 0.000 description 1
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- 150000007942 carboxylates Chemical class 0.000 description 1
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- XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical compound [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 description 1
- 235000011180 diphosphates Nutrition 0.000 description 1
- PGOQAJNPEBNJGZ-UHFFFAOYSA-L dipotassium;2-[carboxylatomethyl(carboxymethyl)amino]acetate Chemical compound [K+].[K+].OC(=O)CN(CC([O-])=O)CC([O-])=O PGOQAJNPEBNJGZ-UHFFFAOYSA-L 0.000 description 1
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- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 1
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- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
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- 150000004676 glycans Chemical class 0.000 description 1
- 125000001188 haloalkyl group Chemical group 0.000 description 1
- 229940091173 hydantoin Drugs 0.000 description 1
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- 229910052739 hydrogen Inorganic materials 0.000 description 1
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- WRIRWRKPLXCTFD-UHFFFAOYSA-N malonamide Chemical class NC(=O)CC(N)=O WRIRWRKPLXCTFD-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
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- 229910052751 metal Inorganic materials 0.000 description 1
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- RTWNYYOXLSILQN-UHFFFAOYSA-N methanediamine Chemical compound NCN RTWNYYOXLSILQN-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
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- JTDAEOGFKHOVGK-UHFFFAOYSA-N n',n'-diacetylpropanediamide Chemical compound CC(=O)N(C(C)=O)C(=O)CC(N)=O JTDAEOGFKHOVGK-UHFFFAOYSA-N 0.000 description 1
- UJPCOKISUIXFFR-UHFFFAOYSA-N n-acetyl-n-(4-methylphenyl)acetamide Chemical compound CC(=O)N(C(C)=O)C1=CC=C(C)C=C1 UJPCOKISUIXFFR-UHFFFAOYSA-N 0.000 description 1
- KBDYPDHUODKDRK-UHFFFAOYSA-N n-acetyl-n-phenylacetamide Chemical compound CC(=O)N(C(C)=O)C1=CC=CC=C1 KBDYPDHUODKDRK-UHFFFAOYSA-N 0.000 description 1
- DDNVNUWFESEAHN-UHFFFAOYSA-N n-methyl-n-methylsulfonylacetamide Chemical compound CC(=O)N(C)S(C)(=O)=O DDNVNUWFESEAHN-UHFFFAOYSA-N 0.000 description 1
- FVCXXYLGLXGBDR-UHFFFAOYSA-N n-methyl-n-methylsulfonylbenzamide Chemical compound CS(=O)(=O)N(C)C(=O)C1=CC=CC=C1 FVCXXYLGLXGBDR-UHFFFAOYSA-N 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- MPQXHAGKBWFSNV-UHFFFAOYSA-N oxidophosphanium Chemical group [PH3]=O MPQXHAGKBWFSNV-UHFFFAOYSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 150000004965 peroxy acids Chemical class 0.000 description 1
- 125000005342 perphosphate group Chemical group 0.000 description 1
- 235000019271 petrolatum Nutrition 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 235000019381 petroleum wax Nutrition 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- BXRNXXXXHLBUKK-UHFFFAOYSA-N piperazine-2,5-dione Chemical class O=C1CNC(=O)CN1 BXRNXXXXHLBUKK-UHFFFAOYSA-N 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 235000013966 potassium salts of fatty acid Nutrition 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- WBHQBSYUUJJSRZ-UHFFFAOYSA-M sodium bisulfate Chemical compound [Na+].OS([O-])(=O)=O WBHQBSYUUJJSRZ-UHFFFAOYSA-M 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- 229940045872 sodium percarbonate Drugs 0.000 description 1
- 235000013875 sodium salts of fatty acid Nutrition 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000003381 solubilizing effect Effects 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- JEVFKQIDHQGBFB-UHFFFAOYSA-K tripotassium;2-[bis(carboxylatomethyl)amino]acetate Chemical compound [K+].[K+].[K+].[O-]C(=O)CN(CC([O-])=O)CC([O-])=O JEVFKQIDHQGBFB-UHFFFAOYSA-K 0.000 description 1
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 1
- HERBOKBJKVUALN-UHFFFAOYSA-K trisodium;2-[bis(carboxylatomethyl)amino]acetate;hydrate Chemical compound O.[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CC([O-])=O HERBOKBJKVUALN-UHFFFAOYSA-K 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/128—Aluminium silicates, e.g. zeolites
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
Definitions
- the present invention relates to additives for detergent compositions, and to detergent compositions containing them. These compositions are particularly, but not essentially, adapted for fabric washing.
- the invention relates more particularly to substantially phosphate-free detergent compositions.
- the subject of the invention is a detergent composition
- a detergent composition comprising a ternary builder system consisting of aluminosilicate, soap and NTA.
- the soap used in the detergent additive of the invention preferably contains at least 5 % by weight, more preferably at least 8 %, of material having a chain length of C 18 and above. It may also be advantageous, from the point of view of solubility, for the soap used in the detergent additive of the invention to contain at least 1 %, preferably at least 3 %, of material being a chain length of C 14 and below.
- the water-insoluble aluminosilicate is a crystalline material having the formula described by the unit cell content: wherein z is from 20 to 30, preferably about 27.
- Preferred compounds falling within the ambit of the above-described definition and formula are nitrilotriacetic acid and its alkali metal salts, especially trisodium nitrilotriacetate monohydrate, tripotassium nitrilotriacetate, disodium nitrilotriacetate and dipotassium nitrilotriacetate.
- the soap and NTA together constitute up to 75 % by weight of the builder system of the invention, preferably from 20 % to 50 %.
- the ratio of soap to NTA is from 3 : 1 to 1 : 1.
- the detergent composition of the present invention contains an efficient builder system yielding good detergency results.
- the content of the specified organic builders preferably will not exceed 40 %, and more preferably does not exceed 27 %.
- the preferred range for the content of the soap is up to 20 %; for the NTA the preferred range is from 2 % to 10 %.
- suitable synthetic anionic detergent compounds are sodium and potassium alkyl sulphates, especially those obtained by sulphating higher (Cs - C 18 ) alcohols produced for example from tallow or coconut oil; sodium and potassium alkyl (Cs - C 20 ) benzene sulphonates, particularly sodium linear secondary alkyl (Cio - Cis) benzene sulphonates; sodium alkyl glyceryl ether sulphates, especially those ethers of the higher alcohols derived from tallow or coconut oil and synthetic alcohols derived from petroleum; sodium coconut oil fatty acid monoglyceride sulphates and sulphonates; sodium and potassium salts of sulphuric acid esters of higher (Cs - C 18 ) fatty alcohol-alkylene oxide, particularly ethylene oxide, reaction products; the reaction products of fatty acids such as coconut fatty acids esterified with isethionic acid and neutralised with sodium hydroxide; sodium and potassium salts of fatty acid amides of
- the inorganic persalt acts to release active oxygen in solution
- the activator is usually an organic compound having one or more reactive acyl residues, which cause the formation of peracids, the latter providing for a more effective bleaching action at lower temperatures than can be obtained by use of the peroxy bleach compound alone.
- the ratio by weight of the peroxy bleach compound to the activator is generally from about 20 : 1 to about 1 : 1, preferably about 15 : 1 to about 2 : 1.
- the activator should not have more than 20 % by weight of particles with a size of less than 50 ⁇ m.
- the activator may have a certain amount of particles of a size greater than 150 ⁇ m, but it should not contain more than 5 % by weight of particles > 300 ⁇ m, and not more than 20 % by weight of particles > 200 ⁇ m, preferably > 150 ⁇ m. It is to be understood that these particle sizes refer to the activator present in the granules, and not to the granules themselves.
- the latter have a particle size, the major part of it ranging from 100 to 2000 ⁇ m, preferably 250 to 1000 ⁇ m. Up to 5 % by weight of granules with a particle size of > 1700 gm and up to 10 % by weight of granules ⁇ 250 ⁇ m is tolerable.
- the granules incorporating the activator preferably in this finely-divided form, may be obtained by granulating a suitable carrier material, such as sodium tripolyphosphate and/or potassium tripolyphosphate with activator particles of the required size. Other granulation methods, e. g. using organic and/or inorganic granulation aids, can also be usefully applied. The granules can be subsequently dried, if required. Basically, any granulation process is applicable, as long as the granule contains the activator, and as long as the other materials present in the granule do not negatively affect the activator.
- the detergent compositions of the invention can contain any of the conventional additives in the amounts in which such materials are normally employed in fabric washing detergent compositions.
- these additives include lather boosters such as alkanolamides, particularly the monoethanolamides derived from palm kernel fatty acids and coconut fatty acids; lather depressants such as alkyl phosphates, silicones, or alkyl phosphonic acids incorporated in petroleum jelly, wax or mineral oil; anti-redeposition agents such as sodium carboxymethylcellulose and cellulose ethers; fabric softening agents; inorganic salts such as sodium sulphate and sodium carbonate; and, usually present in very minor amounts, fluorescent agents, perfumes, enzymes such as proteases and amylases.
- lather boosters such as alkanolamides, particularly the monoethanolamides derived from palm kernel fatty acids and coconut fatty acids
- lather depressants such as alkyl phosphates, silicones, or alkyl phosphonic acids incorporated in petroleum jelly, wax or mineral
- any antideposition agent is normally from about 0.1 % to about 5 % by weight, preferably from about 0.2 % to about 1.5 % by weight of the composition.
- the preferred antideposition agents are anionic polyelectrolytes, especially polymeric aliphatic carboxylates, or organic phosphonates.
- the ingredients and concentrations were as follows: It will be seen that the detergent additive according to the invention was used at concentrations of from 2.00 to 5.00 g/litre, and the other components of the composition were used at a constant total concentration of 2.495 g/litre, so that the total concentration ranged from 4.495 to 7.495 g/litre. Thus the percentage of the total composition constituted by the detergent additive of the invention at each concentration of the latter was as follows: All percentages given in the Examples are by weight and are based on the anhydrous materials.
- Example 2 The procedure of Example 1 was repeated using different proportions of zeolite, soap and NTA. The results were as follows:
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT82303676T ATE15499T1 (de) | 1981-07-15 | 1982-07-13 | Detergenszusaetze und diese enthaltende detergenszusammensetzungen. |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB8121837 | 1981-07-15 | ||
| GB8121837 | 1981-07-15 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| EP0070192A1 EP0070192A1 (en) | 1983-01-19 |
| EP0070192B1 EP0070192B1 (en) | 1985-09-11 |
| EP0070192B2 true EP0070192B2 (en) | 1990-01-17 |
Family
ID=10523262
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP82303674A Expired EP0070190B1 (en) | 1981-07-15 | 1982-07-13 | Detergent additives and detergent compositions containing them |
| EP82303676A Expired - Lifetime EP0070192B2 (en) | 1981-07-15 | 1982-07-13 | Detergent additives and detergent compositions containing them |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP82303674A Expired EP0070190B1 (en) | 1981-07-15 | 1982-07-13 | Detergent additives and detergent compositions containing them |
Country Status (11)
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB9008013D0 (en) * | 1990-04-09 | 1990-06-06 | Unilever Plc | High bulk density granular detergent compositions and process for preparing them |
| US5508258A (en) * | 1990-08-03 | 1996-04-16 | Henkel Kommanditgesellschaft Auf Aktien | Use of surface-active alpha-sulfo-fatty acid di-salts in water and oil based drilling fluids and other drill-hole treatment agents |
| GB9022660D0 (en) * | 1990-10-18 | 1990-11-28 | Unilever Plc | Detergent compositions |
| RU2372958C2 (ru) | 2004-09-06 | 2009-11-20 | Фурукава Текно Матириал Ко., Лтд. | Композиция на основе поверхностно-активного вещества |
| JP5388260B2 (ja) * | 2006-03-03 | 2014-01-15 | 株式会社古河テクノマテリアル | 水添加型の消火剤 |
| JP5207161B2 (ja) * | 2006-08-10 | 2013-06-12 | ディバーシー株式会社 | 自動食器洗浄機への洗浄剤供給方法およびそれに用いられる自動食器洗浄機用タブレット洗浄剤組成物、並びにそれを用いた洗浄方法 |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NO148854C (no) * | 1973-04-13 | 1985-05-29 | Henkel Kgaa | Pulverformet til kornet vaske- eller blekemiddelblanding, uten eller med redusert fosfatinnhold |
| US4605509A (en) * | 1973-05-11 | 1986-08-12 | The Procter & Gamble Company | Detergent compositions containing sodium aluminosilicate builders |
| DE2333356C3 (de) * | 1973-06-30 | 1982-03-11 | Henkel KGaA, 4000 Düsseldorf | Waschmittel |
| AT335030B (de) * | 1974-01-14 | 1977-02-25 | Henkel & Cie Gmbh | Verfahren zum waschen von textilien, sowie mittel zur durchfuhrung des verfahrens |
| JPS5328163B2 (enrdf_load_stackoverflow) * | 1974-05-30 | 1978-08-12 | ||
| US3985669A (en) * | 1974-06-17 | 1976-10-12 | The Procter & Gamble Company | Detergent compositions |
| AT375395B (de) * | 1974-10-04 | 1984-07-25 | Henkel Kgaa | Verfahren zum waschen bzw. bleichen von textilien sowie mittel dazu |
| AT338948B (de) * | 1974-10-10 | 1977-09-26 | Henkel & Cie Gmbh | Pulverformige wasch- und reinigungsmittel und verfahren zu ihrer herstellung |
| JPS5228507A (en) * | 1975-08-29 | 1977-03-03 | Nippon Oil & Fats Co Ltd | Detergent composition |
| JPS52117908A (en) * | 1976-03-31 | 1977-10-03 | Nitsusan Setsuken Kk | Detergent composition |
| BE5T2 (fr) * | 1977-06-21 | 1980-02-08 | Procter & Gamble Europ | Wasmiddelrn |
| IT1160682B (it) * | 1977-10-14 | 1987-03-11 | Po Corp. | Composizioni detergenti con coadiuvante di silano-zeolite |
| CA1137076A (en) * | 1978-12-13 | 1982-12-07 | John R. Bauer | Fluid spray mixer - reactor system |
| JPS55108496A (en) * | 1979-02-13 | 1980-08-20 | Nippon Gousei Senzai Kk | Detergent composition |
| US4265777A (en) * | 1980-04-17 | 1981-05-05 | The Procter & Gamble Company | Detergent compositions containing an aluminosilicate detergency builder and an unsaturated fatty acid soap |
-
1982
- 1982-07-09 NZ NZ201213A patent/NZ201213A/en unknown
- 1982-07-09 NZ NZ201212A patent/NZ201212A/en unknown
- 1982-07-13 AU AU85985/82A patent/AU8598582A/en not_active Abandoned
- 1982-07-13 DE DE8282303674T patent/DE3267784D1/de not_active Expired
- 1982-07-13 AT AT82303674T patent/ATE16818T1/de not_active IP Right Cessation
- 1982-07-13 DE DE8282303676T patent/DE3266194D1/de not_active Expired
- 1982-07-13 AT AT82303676T patent/ATE15499T1/de not_active IP Right Cessation
- 1982-07-13 AU AU85984/82A patent/AU554225B2/en not_active Ceased
- 1982-07-13 EP EP82303674A patent/EP0070190B1/en not_active Expired
- 1982-07-13 EP EP82303676A patent/EP0070192B2/en not_active Expired - Lifetime
- 1982-07-14 NO NO822433A patent/NO822433L/no unknown
- 1982-07-14 DK DK314782A patent/DK314782A/da not_active Application Discontinuation
- 1982-07-14 BR BR8204092A patent/BR8204092A/pt not_active IP Right Cessation
- 1982-07-14 ZA ZA825006A patent/ZA825006B/xx unknown
- 1982-07-14 DK DK314982A patent/DK314982A/da not_active Application Discontinuation
- 1982-07-14 ZA ZA825005A patent/ZA825005B/xx unknown
- 1982-07-14 CA CA000407291A patent/CA1191068A/en not_active Expired
- 1982-07-14 CA CA000407293A patent/CA1197156A/en not_active Expired
- 1982-07-14 NO NO822434A patent/NO822434L/no unknown
- 1982-07-14 BR BR8204091A patent/BR8204091A/pt unknown
- 1982-07-15 JP JP57123750A patent/JPS5823897A/ja active Granted
- 1982-07-15 JP JP57123749A patent/JPS5823896A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| ATE15499T1 (de) | 1985-09-15 |
| AU8598482A (en) | 1983-01-20 |
| BR8204091A (pt) | 1983-07-05 |
| AU554225B2 (en) | 1986-08-14 |
| EP0070192A1 (en) | 1983-01-19 |
| JPS5823897A (ja) | 1983-02-12 |
| BR8204092A (pt) | 1983-07-05 |
| DE3266194D1 (en) | 1985-10-17 |
| NO822434L (no) | 1983-01-17 |
| ZA825006B (en) | 1984-02-29 |
| NZ201213A (en) | 1985-07-31 |
| EP0070192B1 (en) | 1985-09-11 |
| JPS5823896A (ja) | 1983-02-12 |
| NO822433L (no) | 1983-01-17 |
| ZA825005B (en) | 1984-02-29 |
| EP0070190A1 (en) | 1983-01-19 |
| ATE16818T1 (de) | 1985-12-15 |
| DE3267784D1 (en) | 1986-01-16 |
| EP0070190B1 (en) | 1985-12-04 |
| DK314982A (da) | 1983-01-16 |
| CA1191068A (en) | 1985-07-30 |
| NZ201212A (en) | 1985-08-16 |
| CA1197156A (en) | 1985-11-26 |
| DK314782A (da) | 1983-01-16 |
| JPS6116315B2 (enrdf_load_stackoverflow) | 1986-04-30 |
| AU8598582A (en) | 1983-01-20 |
| JPH045720B2 (enrdf_load_stackoverflow) | 1992-02-03 |
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