EP0057611A2 - Poudres de savon et procédé pour leur préparation - Google Patents
Poudres de savon et procédé pour leur préparation Download PDFInfo
- Publication number
- EP0057611A2 EP0057611A2 EP82300529A EP82300529A EP0057611A2 EP 0057611 A2 EP0057611 A2 EP 0057611A2 EP 82300529 A EP82300529 A EP 82300529A EP 82300529 A EP82300529 A EP 82300529A EP 0057611 A2 EP0057611 A2 EP 0057611A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- spray
- particles
- soap
- water
- dried
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 239000000344 soap Substances 0.000 title claims abstract description 45
- 238000000034 method Methods 0.000 title claims description 11
- 238000004519 manufacturing process Methods 0.000 title claims description 4
- 239000000843 powder Substances 0.000 title description 16
- 239000002245 particle Substances 0.000 claims abstract description 61
- 239000000126 substance Substances 0.000 claims abstract description 11
- 239000000203 mixture Substances 0.000 claims description 14
- 150000003839 salts Chemical class 0.000 claims description 11
- 239000011230 binding agent Substances 0.000 claims description 7
- 239000004115 Sodium Silicate Substances 0.000 claims description 5
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 5
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 5
- 239000007864 aqueous solution Substances 0.000 claims description 4
- 229910019142 PO4 Inorganic materials 0.000 claims description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 235000021122 unsaturated fatty acids Nutrition 0.000 claims description 3
- 150000004670 unsaturated fatty acids Chemical class 0.000 claims description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 2
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 2
- 238000009472 formulation Methods 0.000 claims description 2
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims description 2
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims description 2
- 238000005507 spraying Methods 0.000 claims description 2
- 229910021653 sulphate ion Inorganic materials 0.000 claims description 2
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims 1
- 239000010452 phosphate Substances 0.000 claims 1
- 238000000576 coating method Methods 0.000 abstract description 13
- 239000011248 coating agent Substances 0.000 abstract description 12
- 238000009736 wetting Methods 0.000 abstract description 6
- 239000006185 dispersion Substances 0.000 abstract description 4
- 238000004090 dissolution Methods 0.000 abstract description 3
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 abstract description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 abstract description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 abstract description 2
- 239000005642 Oleic acid Substances 0.000 abstract description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 abstract description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 abstract description 2
- 239000000463 material Substances 0.000 abstract description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 abstract description 2
- 239000003760 tallow Substances 0.000 abstract description 2
- 235000013162 Cocos nucifera Nutrition 0.000 abstract 1
- 244000060011 Cocos nucifera Species 0.000 abstract 1
- -1 phosphates Chemical class 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- 229910017053 inorganic salt Inorganic materials 0.000 description 6
- 229910052708 sodium Inorganic materials 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- 239000002253 acid Substances 0.000 description 4
- 239000007771 core particle Substances 0.000 description 4
- 235000014113 dietary fatty acids Nutrition 0.000 description 4
- 239000000194 fatty acid Substances 0.000 description 4
- 229930195729 fatty acid Natural products 0.000 description 4
- 150000004665 fatty acids Chemical class 0.000 description 4
- 238000001694 spray drying Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 206010053567 Coagulopathies Diseases 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 230000035602 clotting Effects 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 230000001464 adherent effect Effects 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
- 150000003138 primary alcohols Chemical class 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 229960001922 sodium perborate Drugs 0.000 description 2
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- OYHQOLUKZRVURQ-HZJYTTRNSA-N Linoleic acid Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC(O)=O OYHQOLUKZRVURQ-HZJYTTRNSA-N 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- BGRWYDHXPHLNKA-UHFFFAOYSA-N Tetraacetylethylenediamine Chemical compound CC(=O)N(C(C)=O)CCN(C(C)=O)C(C)=O BGRWYDHXPHLNKA-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 229910000288 alkali metal carbonate Inorganic materials 0.000 description 1
- 229910052910 alkali metal silicate Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 150000001642 boronic acid derivatives Chemical class 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000010410 dusting Methods 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000010954 inorganic particle Substances 0.000 description 1
- 235000020778 linoleic acid Nutrition 0.000 description 1
- OYHQOLUKZRVURQ-IXWMQOLASA-N linoleic acid Natural products CCCCC\C=C/C\C=C\CCCCCCCC(O)=O OYHQOLUKZRVURQ-IXWMQOLASA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical class OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 235000003441 saturated fatty acids Nutrition 0.000 description 1
- 150000003333 secondary alcohols Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910021647 smectite Inorganic materials 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- DZCAZXAJPZCSCU-UHFFFAOYSA-K sodium nitrilotriacetate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CC([O-])=O DZCAZXAJPZCSCU-UHFFFAOYSA-K 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 125000001273 sulfonato group Chemical class [O-]S(*)(=O)=O 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 235000020238 sunflower seed Nutrition 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C11D11/02—Preparation in the form of powder by spray drying
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0039—Coated compositions or coated components in the compositions, (micro)capsules
Definitions
- This invention relates to soap powders and to a process for preparing them.
- the present invention provides spray-dried particles comprising a major proportion of water-soluble soap and having an average diameter of 300-700 microns coated with particles of an inorganic substance, characterised in that the inorganic substance is water-soluble and that at least 80% by weight of its particles have an average diameter of less than 100 microns.
- United States Patent No 2,592,535 also discloses the coating of soap with hygroscopic salts, such as phosphates, to reduce loss of moisture from spray-dried soap particles and consequently to reduce dusting.
- hygroscopic salts such as phosphates
- British Patent Nos 1,401,726 and 1,463,978 relate to particles containing major proportions of soaps and lime-so 3 p dispersants such as ether sulphates. It was apparently found that the lime-soap dispersants adversely affected the solubility properties of the soap particles and it was proposed to counteract that by impregnating them with smectite clay particles having a size below 50 microns. However such particles are not water-soluble and so will remain in suspension in the wash liquor, which may not be desirable.
- the average diameter of the soap particles can vary from 300-700 microns, preferably 500-600 microns, in which case the average diameter of the inorganic particles is such that at least 80% by weight of them are less than 100 microns, preferably less than 50 microns.
- the ratio of the diameter of the soap particles to that of the coating particles is preferably from 6:1 to 8:1, most preferably 7:1.
- the spray-dried soap-containing particles need not consist entirely of soap, but may contain up to 49% by weight of other soap powder components.
- these are detergency builders, foam boosters or foam suppressants, powder structurants, anti-oxidants, softening agents and water.
- the particles comprise from 60-80% by weight of soap.
- Soap powders are either produced by spray-drying in which a relatively cool slurry is sprayed into a hot drying gas, or by spray-cooling, in which hotter slurry is sprayed into relatively cold drying gas, and there are a number of intermediate processes which combine both spray-drying and spray-cooling. All of these processes are included within the term 'spray-dried' as used herein.
- the term 'coated' is used herein to denote a situation where a plurality of particles of the water-soluble inorganic substance are adherent to the spray-dried soap particles. It does not necessarily imply that so many are adherent that the soap particle is completely coated. It is within the scope of the invention for it to be only partly so.
- the nature of the water-soluble soap is not critical to the invention. For economic reasons it will normally be a sodium or potassium soap, but any other cation will be satisfactory provided that it is non-toxic and does not cause unwanted side effects in the composition.
- the fatty acid component of the soap may be derived from mixtures of saturated and partially unsaturated fatty acids in the C S -C 26 chain length region. Coconut oil and tallow, which are the traditional soap-making materials are preferred sources of the mixed fatty acids, the former containing predominantly C12 and Cl4 saturated fatty acids and the latter saturated C 14 and C 18 acids and mono-unsaturated Cl6 acids.
- the invention is also particularly applicable to soaps formed from fatty acid mixtures containing high proportions of unsaturated acids such as oleic acid and linoleic acid. These soaps tend to be soft and creepy when in spray-dried form and the coating of the invention is especially suitable for improving their powder properties.
- Sunflower seed oil is an example of an oil which contains fatty acids of this type. When the spray-dried particles contain an unsaturated fatty acid having 16 or more carbon atoms then it is preferred that the content of this acid should be 25% or more by weight of the particle.
- the soap particles may also contain anionic surfactants in amounts up to 15% by weight of the particle.
- anionic surfactant is not critical, any of the surfactants conventionally used or proposed for use in fabric washing powders being suitable. Examples of these are sodium alkyl benzene sulphonates, preferably C 10 -C 14 alkyl, sodium primary and secondary alkyl sulphate, preferably C 10 -C 22 alkyl, olefine sulphonate salts and sodium alkane sulphonates.
- the soap particles may also contain nonionic surfactants in amounts up to about 30% by weight of the particles.
- Ethoxylated and propoxylated primary and secondary alcohols are the preferred nonionic surfactants, primary alcohols containing 7 to 25 carbon atoms ethoxylated with from 5 to 30 moles of ethylene oxide per mole of alcohol being most preferred.
- the invention is particularly applicable to spray-dried particles which are soft, and examples of components which may make the particles soft are polyethylene glycols, ethoxylated alkanolamides, alkyl phosphoric acid esters and quaternary ammonium salts.
- the water-soluble inorganic salt for coating the spray-dried soap particles is preferably present in an amount of from 3 to 25% by weight of the total soap powder formulation.
- the lower amount is the general level which will normally be used when the salt is only performing a coating function, whereas the upper amount is the maximum amount which will normally be used when the salt performs a function in addition to coating, such as detergency building or bleaching.
- Suitable salts within which term are included oxides as well as oxyacid salts, are the water-soluble phosphates, carbonates, percarbonates, borates, perborates, sulphates and metasilicates and aluminosilicates, particularly the sodium and potassium salts.
- certain organic compounds can be used for coating. Examples of such compounds are the salts of nitrilotriacetic acid, preferably sodium nitrilotriacetate, and tetraacetyl ethylene diamine.
- the invention provides, in a second aspect, a process for the manufacture of spray-dried particles comprising a major proportion of a water-soluble soap inorganic substance, at least 80% of which have an average diameter of less than 100 microns, characterised by forming a mixture of the two types of particle, imparting relative motion to them and spraying them with an aqueous solution of a binder.
- binder which ensures adhesion between the spray-dried soap particles and the inorganic salt particles is not critical, conventional binders such as water, sodium silicate solution and sodium carboxymethyl cellulose solution being satisfactory.
- sodium silicate solution 3-10% by weight based on the total soap powder composition, in the form of a 20-60% w/v solution, would be a typical amount of binder to be used.
- the process of the invention in a number of the conventional granulating apparatus.
- One such apparatus is the Eirich pan (registered trade mark) which is an inclined pan rotatable about its major axis.
- Another is the Schugi mixer (registered trade mark) which consists of a cylindrical chamber provided with inclined ribbon-like mixing blades rotatable about the major axis of the cylinder.
- the coated particles will require drying in a fluidised bed through which warm air is pumped, so since it is necessary to have a fluidised bed apparatus available and since it is possible to carry out the coating process ab initio in a fluidised bed, it is preferred to carry out the process in that way.
- Spray-dried particles containing a major proportion of soap and having the composition shown below were prepared by conventional slurry-making and spray-drying techniques in two size ranges, 450 and 350 microns. The resultant particles are subsequently referred to as 'core particles'. Parts by Weight
- a mixture of finely-divided inorganic salts suitable for forming a coating on the above spray-dried particles was then prepared.
- the composition is shown below
- the core particles and the mixture of inorganic salts, together with 25 parts of sodium perborate were then placed in an Anhydro (registered trade mark) fluidised bed and sprayed with a 30% w/v aqueous solution of sodium silicate (Na 2 O:SiO 2 , 2:1).
- the coated particles obtained had good flow properties, a narrow particle size distribution and a bulk density of around 0.4 g/cc.
- the wetting, dispersion and dissolution properties of the coated particles were then assessed as follows.
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Cosmetics (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB8103444 | 1981-02-04 | ||
| GB8103444 | 1981-02-04 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0057611A2 true EP0057611A2 (fr) | 1982-08-11 |
| EP0057611A3 EP0057611A3 (fr) | 1982-08-25 |
Family
ID=10519451
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP82300529A Ceased EP0057611A3 (fr) | 1981-02-04 | 1982-02-02 | Poudres de savon et procédé pour leur préparation |
Country Status (9)
| Country | Link |
|---|---|
| EP (1) | EP0057611A3 (fr) |
| AR (1) | AR225710A1 (fr) |
| BR (1) | BR8200575A (fr) |
| CA (1) | CA1185498A (fr) |
| ES (1) | ES8302082A1 (fr) |
| GR (1) | GR76050B (fr) |
| NO (1) | NO820321L (fr) |
| PT (1) | PT74385B (fr) |
| ZA (1) | ZA82687B (fr) |
Cited By (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0076137A2 (fr) * | 1981-09-29 | 1983-04-06 | Unilever Plc | Procédé pour la manufacture de poudre de savon |
| WO1996014385A1 (fr) * | 1994-11-02 | 1996-05-17 | Henkel Kommanditgesellschaft Auf Aktien | Preparations solides de substances destinees au lavage de textiles en plusieurs etapes |
| WO2000037604A1 (fr) * | 1998-12-22 | 2000-06-29 | The Procter & Gamble Company | Procede de preparation d'une composition detergente granulaire |
| WO2000053719A1 (fr) * | 1999-03-09 | 2000-09-14 | The Procter & Gamble Company | Particules de detergent enrobees ou partiellement enrobees de couches |
| WO2003035818A2 (fr) * | 2001-10-25 | 2003-05-01 | Henkel Kommanditgesellschaft Auf Aktien | Moyen, dispositif et procede de production |
| US6596683B1 (en) | 1998-12-22 | 2003-07-22 | The Procter & Gamble Company | Process for preparing a granular detergent composition |
| US6858572B1 (en) | 1999-03-09 | 2005-02-22 | The Procter & Gamble Company | Process for producing coated detergent particles |
| WO2006016712A1 (fr) | 2004-08-11 | 2006-02-16 | Nof Corporation | Composition de savon en poudre |
| US7022660B1 (en) | 1999-03-09 | 2006-04-04 | The Procter & Gamble Company | Process for preparing detergent particles having coating or partial coating layers |
| DE102006056534A1 (de) * | 2006-11-27 | 2008-05-29 | "Durable" Hunke & Jochheim Gmbh & Co. Kg | Klemmmappe |
| WO2012049033A1 (fr) * | 2010-10-14 | 2012-04-19 | Unilever Plc | Procédé à cuve à laver le linge à chargement par le haut |
| DE202013001479U1 (de) | 2013-02-15 | 2013-04-23 | Companycreator Gmbh | Klemmmappe mit Klemmorgan zur ruck- und widerstandsfreien Einführung von Schriftgut. |
| CN103180427A (zh) * | 2010-10-14 | 2013-06-26 | 荷兰联合利华有限公司 | 洗涤剂组合物的包装和分配 |
| US8883702B2 (en) | 2010-10-14 | 2014-11-11 | Conopco, Inc. | Packaged particulate detergent composition |
| US9062281B2 (en) | 2010-10-14 | 2015-06-23 | Conopco, Inc. | Particulate detergent compositions comprising fluorescer |
| US9273271B2 (en) | 2010-10-14 | 2016-03-01 | Conopco Inc. | Laundry detergent particles |
| US9284517B2 (en) | 2010-10-14 | 2016-03-15 | Conopco Inc. | Laundry detergent particle |
| US9290725B2 (en) | 2010-10-14 | 2016-03-22 | Conopco Inc. | Laundry detergent particles |
| US9290723B2 (en) | 2010-10-14 | 2016-03-22 | Conopco Inc. | Laundry detergent particles |
| US9290724B2 (en) | 2010-10-14 | 2016-03-22 | Conopco, Inc. | Laundry detergent particles |
| US9365811B2 (en) | 2010-10-14 | 2016-06-14 | Conopco Inc. | Manufacture of coated particulate detergents |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2592535A (en) * | 1941-08-01 | 1952-04-15 | Lever Brothers Ltd | Process of dedusting soap and the resulting product |
| US2715110A (en) * | 1952-06-13 | 1955-08-09 | Lever Brothers Ltd | Method for the production of a granulated soap product |
| DE2340882A1 (de) * | 1972-08-17 | 1974-02-21 | Lion Fat Oil Co Ltd | Verfahren zur herstellung koerniger wasch- und reinigungsmittel |
| GB2027048A (en) * | 1978-08-03 | 1980-02-13 | Unilever Ltd | Soap Powder |
-
1982
- 1982-02-02 GR GR67183A patent/GR76050B/el unknown
- 1982-02-02 EP EP82300529A patent/EP0057611A3/fr not_active Ceased
- 1982-02-02 ES ES509268A patent/ES8302082A1/es not_active Expired
- 1982-02-03 CA CA000395451A patent/CA1185498A/fr not_active Expired
- 1982-02-03 NO NO820321A patent/NO820321L/no unknown
- 1982-02-03 PT PT74385A patent/PT74385B/pt unknown
- 1982-02-03 ZA ZA82687A patent/ZA82687B/xx unknown
- 1982-02-03 BR BR8200575A patent/BR8200575A/pt unknown
- 1982-02-04 AR AR288340A patent/AR225710A1/es active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2592535A (en) * | 1941-08-01 | 1952-04-15 | Lever Brothers Ltd | Process of dedusting soap and the resulting product |
| US2715110A (en) * | 1952-06-13 | 1955-08-09 | Lever Brothers Ltd | Method for the production of a granulated soap product |
| DE2340882A1 (de) * | 1972-08-17 | 1974-02-21 | Lion Fat Oil Co Ltd | Verfahren zur herstellung koerniger wasch- und reinigungsmittel |
| GB2027048A (en) * | 1978-08-03 | 1980-02-13 | Unilever Ltd | Soap Powder |
Cited By (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0076137B1 (fr) * | 1981-09-29 | 1987-01-21 | Unilever Plc | Procédé pour la manufacture de poudre de savon |
| EP0076137A2 (fr) * | 1981-09-29 | 1983-04-06 | Unilever Plc | Procédé pour la manufacture de poudre de savon |
| WO1996014385A1 (fr) * | 1994-11-02 | 1996-05-17 | Henkel Kommanditgesellschaft Auf Aktien | Preparations solides de substances destinees au lavage de textiles en plusieurs etapes |
| WO2000037604A1 (fr) * | 1998-12-22 | 2000-06-29 | The Procter & Gamble Company | Procede de preparation d'une composition detergente granulaire |
| US6596683B1 (en) | 1998-12-22 | 2003-07-22 | The Procter & Gamble Company | Process for preparing a granular detergent composition |
| US7022660B1 (en) | 1999-03-09 | 2006-04-04 | The Procter & Gamble Company | Process for preparing detergent particles having coating or partial coating layers |
| WO2000053719A1 (fr) * | 1999-03-09 | 2000-09-14 | The Procter & Gamble Company | Particules de detergent enrobees ou partiellement enrobees de couches |
| US6858572B1 (en) | 1999-03-09 | 2005-02-22 | The Procter & Gamble Company | Process for producing coated detergent particles |
| WO2003035818A2 (fr) * | 2001-10-25 | 2003-05-01 | Henkel Kommanditgesellschaft Auf Aktien | Moyen, dispositif et procede de production |
| WO2003035818A3 (fr) * | 2001-10-25 | 2003-09-18 | Henkel Kgaa | Moyen, dispositif et procede de production |
| EP1798280A4 (fr) * | 2004-08-11 | 2009-12-16 | Nof Corp | Composition de savon en poudre |
| EP1798280A1 (fr) * | 2004-08-11 | 2007-06-20 | Nof Corporation | Composition de savon en poudre |
| WO2006016712A1 (fr) | 2004-08-11 | 2006-02-16 | Nof Corporation | Composition de savon en poudre |
| US7820613B2 (en) | 2004-08-11 | 2010-10-26 | Nof Corporation | Powder soap composition |
| DE102006056534A1 (de) * | 2006-11-27 | 2008-05-29 | "Durable" Hunke & Jochheim Gmbh & Co. Kg | Klemmmappe |
| DE102006056534B4 (de) * | 2006-11-27 | 2008-07-31 | "Durable" Hunke & Jochheim Gmbh & Co. Kg | Klemmmappe |
| US8883702B2 (en) | 2010-10-14 | 2014-11-11 | Conopco, Inc. | Packaged particulate detergent composition |
| CN103180427A (zh) * | 2010-10-14 | 2013-06-26 | 荷兰联合利华有限公司 | 洗涤剂组合物的包装和分配 |
| WO2012049033A1 (fr) * | 2010-10-14 | 2012-04-19 | Unilever Plc | Procédé à cuve à laver le linge à chargement par le haut |
| US9062281B2 (en) | 2010-10-14 | 2015-06-23 | Conopco, Inc. | Particulate detergent compositions comprising fluorescer |
| CN103180427B (zh) * | 2010-10-14 | 2016-02-17 | 荷兰联合利华有限公司 | 洗涤剂组合物的包装和分配 |
| US9273271B2 (en) | 2010-10-14 | 2016-03-01 | Conopco Inc. | Laundry detergent particles |
| US9284517B2 (en) | 2010-10-14 | 2016-03-15 | Conopco Inc. | Laundry detergent particle |
| US9290725B2 (en) | 2010-10-14 | 2016-03-22 | Conopco Inc. | Laundry detergent particles |
| US9290723B2 (en) | 2010-10-14 | 2016-03-22 | Conopco Inc. | Laundry detergent particles |
| US9290724B2 (en) | 2010-10-14 | 2016-03-22 | Conopco, Inc. | Laundry detergent particles |
| US9365811B2 (en) | 2010-10-14 | 2016-06-14 | Conopco Inc. | Manufacture of coated particulate detergents |
| DE202013001479U1 (de) | 2013-02-15 | 2013-04-23 | Companycreator Gmbh | Klemmmappe mit Klemmorgan zur ruck- und widerstandsfreien Einführung von Schriftgut. |
Also Published As
| Publication number | Publication date |
|---|---|
| GR76050B (fr) | 1984-08-03 |
| ES509268A0 (es) | 1982-12-16 |
| CA1185498A (fr) | 1985-04-16 |
| ES8302082A1 (es) | 1982-12-16 |
| AR225710A1 (es) | 1982-04-15 |
| BR8200575A (pt) | 1982-12-07 |
| NO820321L (no) | 1982-08-05 |
| EP0057611A3 (fr) | 1982-08-25 |
| ZA82687B (en) | 1983-09-28 |
| PT74385B (en) | 1984-10-22 |
| PT74385A (en) | 1982-03-01 |
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