EP0036362A1 - Vorrichtung zur thermischen Behandlung pulverförmiger oder körniger Stoffe - Google Patents
Vorrichtung zur thermischen Behandlung pulverförmiger oder körniger Stoffe Download PDFInfo
- Publication number
- EP0036362A1 EP0036362A1 EP81400375A EP81400375A EP0036362A1 EP 0036362 A1 EP0036362 A1 EP 0036362A1 EP 81400375 A EP81400375 A EP 81400375A EP 81400375 A EP81400375 A EP 81400375A EP 0036362 A1 EP0036362 A1 EP 0036362A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- waveguide
- sheath
- partitions
- materials
- propeller
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000007669 thermal treatment Methods 0.000 title claims abstract description 6
- 239000008187 granular material Substances 0.000 title claims description 4
- 239000000463 material Substances 0.000 claims abstract description 54
- 238000005192 partition Methods 0.000 claims abstract description 27
- 239000002184 metal Substances 0.000 claims abstract description 6
- 238000011282 treatment Methods 0.000 claims abstract description 6
- 230000005855 radiation Effects 0.000 claims abstract description 5
- 230000005284 excitation Effects 0.000 claims description 9
- 238000010438 heat treatment Methods 0.000 claims description 8
- 238000004891 communication Methods 0.000 claims description 5
- 239000004020 conductor Substances 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 3
- 239000011261 inert gas Substances 0.000 claims description 3
- 239000012254 powdered material Substances 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 150000001768 cations Chemical class 0.000 claims 1
- 230000000750 progressive effect Effects 0.000 claims 1
- 238000009434 installation Methods 0.000 description 7
- 238000000034 method Methods 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 239000004793 Polystyrene Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 241001674048 Phthiraptera Species 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 229940082150 encore Drugs 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- -1 polyethylene Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000000135 prohibitive effect Effects 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B6/00—Heating by electric, magnetic or electromagnetic fields
- H05B6/64—Heating using microwaves
- H05B6/78—Arrangements for continuous movement of material
- H05B6/784—Arrangements for continuous movement of material wherein the material is moved using a tubular transport line, e.g. screw transport systems
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F26—DRYING
- F26B—DRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
- F26B17/00—Machines or apparatus for drying materials in loose, plastic, or fluidised form, e.g. granules, staple fibres, with progressive movement
- F26B17/18—Machines or apparatus for drying materials in loose, plastic, or fluidised form, e.g. granules, staple fibres, with progressive movement with movement performed by rotating helical blades or other rotary conveyors which may be heated moving materials in stationary chambers, e.g. troughs
- F26B17/20—Machines or apparatus for drying materials in loose, plastic, or fluidised form, e.g. granules, staple fibres, with progressive movement with movement performed by rotating helical blades or other rotary conveyors which may be heated moving materials in stationary chambers, e.g. troughs the axis of rotation being horizontal or slightly inclined
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F26—DRYING
- F26B—DRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
- F26B3/00—Drying solid materials or objects by processes involving the application of heat
- F26B3/32—Drying solid materials or objects by processes involving the application of heat by development of heat within the materials or objects to be dried, e.g. by fermentation or other microbiological action
- F26B3/34—Drying solid materials or objects by processes involving the application of heat by development of heat within the materials or objects to be dried, e.g. by fermentation or other microbiological action by using electrical effects
- F26B3/347—Electromagnetic heating, e.g. induction heating or heating using microwave energy
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B6/00—Heating by electric, magnetic or electromagnetic fields
- H05B6/64—Heating using microwaves
- H05B6/78—Arrangements for continuous movement of material
Definitions
- the present invention relates to a new device for the thermal treatment of divided materials and in particular of powdered or granular materials.
- Heat treatment using microwaves (MO) or ultra high frequency waves (UHF) which are between approximately 300 Megahertz and approximately 30 Gigahertz is currently spreading more and more, thanks in particular to the great availability of this energy. , to its good propagation in various atmospheres, to its good regulation and to its satisfactory enslavement.
- the homogeneous heating throughout the mass of the treated product which it also provides, has enabled numerous applications of this form of energy, both domestic and industrial applications.
- Coaxial devices have thus been produced in which the materials to be treated are located inside the waveguide or else devices with transmitting antennas, in which the materials to be treated receive the MO radiation.
- the object of the present invention is therefore to provide a device which not only makes it possible, on the one hand, to conserve the single-mode waveguide - the most satisfactory device with the highest energy density - but also, d on the other hand, to provide a device which makes it possible to continuously advance the material to be treated at a large, constant and adjustable flow rate, while maintaining it in a maximum field of energy.
- One of the aims of the present invention is also to be able to use low power energy sources, produced in large series, therefore economically very advantageous.
- the present invention has for object a device for the thermal treatment of divided materials and in particular of powdered or granular materials, by UHF radiation, characterized in that it comprises in combination: - a waveguide in two parts: a fixed part consisting of a sheath made of metal or a similar conductive material, for seen from metal partitions perpendicular to said sheath, and comprising in the free space between the partitions a lining of non-polar material - and of a mobile part constituted by a helix of conductive material rotating around an axis, or screw Archimedes, whose pitch corresponds exactly to the distance between two successive partitions with which the sheath is provided; - A plurality of magnetrons applied against the outer surface of the sleeve, the distance between two successive magnetrons being a function of the pitch of the propeller and the material to be treated; - Two openings, one for the inlet, the other for the outlet of the material, said openings being dimensioned so that the wave used cannot leave the waveguide.
- the sheath and the partitions perpendicular to the sheath that is to say the fixed part of the waveguide, represent between 1/4 and 1/2 of the total height of the waveguide.
- the material to be treated would of course be within the maximum field of action, but the useful volume of the treated material would be reduced; if on the other hand the propeller touched the wall of the sheath, that is to say if one made disappear the fixed partitions perpendicular to the sheath, the volume of treated materials would be maximum, but also the loss of energy, because the current lines of the wall itself would be cut, the optimum effect being, according to the invention, between 1/4 and 1/2 of the total height of the waveguide.
- the width of the excitation device exceeds the pitch of the propeller.
- the thickness of the propeller in particular in the vicinity of the fixed part of the waveguide constituted by the partitions, is calculated in such a way that there is never any communication between two excitement guides.
- This modality of the invention which precisely allows the use of low-power and very cheap commercial magnetrons, makes the device according to the present invention particularly suitable for all heat treatments using large quantities of materials.
- the thickness of the fixed partitions perpendicular to the sheath is also calculated so that there is no communication between two excitation guides.
- the device is provided with means for recovering and using the magnetron cooling air to optionally remove water vapor from the treated material.
- the heat treatment device is pressurized by an inert gas, such as nitrogen for example.
- the material inlet and outlet openings are square section tubes whose side is at most equal to half the wavelength used for the treatment of the material.
- the material inlet and outlet openings are tubes of circular section, the diameters of which do not allow the propagation of the wave used for the treatment of the material.
- the thickness of the sheath lining which is made of non-polar materials such as polyethylene or polystyrene, and is housed between the partitions, represents 1 / 4 to 1/2 of the total height of the waveguide.
- the sheath is formed of two half-sheaths assembled by two flanges.
- the edge of the helix facing the partition is bevelled.
- the present invention relates more particularly to a new device for the heat treatment of large quantities of divided materials, as well as the overall devices and methods in which the devices according to the present invention are included.
- the partitions 9 facing the turns 10 of the propeller.
- such a module 7 can measure 600 mm in length. It is provided with two magnetrons 2 and two excitation guides 3 of 70 mm width for example (between two successive magnetrons there are, for example, three propeller pitch 18 of total length of 150 mm) the diameter of the material supply and output tubes is 60 nm for example.
- the nodule is particularly suitable for 2.45 GHz microwaves (the power of each of the magnetrons is 1 kw).
- the height 14 of the partitions 9. is 20 mm for example.
- the material to be treated is located between the turns of the propeller, in the lower part, near the drum axis 13. Knowing the minimum value of the loss factor E "of the material to be treated, as well as its volume , the number of turns between two sources is determined, so that all the energy emitted by one source is absorbed before the energy from the next source arrives.
- Figure 3 The movable part of this waveguide is shown in Figure 3 (Figure 3a is a longitudinal sectional view and Figure 3b is a cross-sectional view).
- the total height of the propeller plus drum is 440 mm, the propeller alone measuring 120 mm, which gives a fixed part / for this exemplary embodiment.
- this module allow the useful filling of 4.8 1, or 90 kg of material per hour.
- ten of these modules one in the extension of the other after the removal of the flanges 8, one arrives at a treatment of nearly a ton of materials per hour, for an apparatus the total length of which does not exceed 6 m.
- the sleeve 6 can advantageously be constituted by two half-sleeves 11, assembled by the flanges 15, to facilitate the mounting of these devices.
- FIG. 4 represents a "section" of the waveguide delimited by the sheath 6, the two fixed partitions 9, the two turns 10, and the surface of the drum axis 13.
- the material divided during processing 17 is located in the lower part of the Archimedes screw above the gasket 16.
- the thickness 12 of the turns 10 in the vicinity of the partitions 9, is calculated so that there is never any communication between two excitation guides. (It is 15 mm for the example - nonlimiting - described in the above).
- the edge 19 of the propeller which faces the partition 9 is cut in a bevel.
- the width of the excitation device 3 applied against the sheath 6 is such that it exceeds the pitch of the propeller 18, this to avoid the reflection of the wave on the source.
- the device according to the present invention can, if desired, be pressurized by an inert gas - such as nitrogen for example -. It may also include (not shown in the figures) means for using the cooling air of the magnetrons 2 to remove, if necessary, the water vapor, for example, released from the treated material.
- an inert gas - such as nitrogen for example -. It may also include (not shown in the figures) means for using the cooling air of the magnetrons 2 to remove, if necessary, the water vapor, for example, released from the treated material.
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Electromagnetism (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Microbiology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biotechnology (AREA)
- Biomedical Technology (AREA)
- Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Constitution Of High-Frequency Heating (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Powder Metallurgy (AREA)
- Tunnel Furnaces (AREA)
- Feeding, Discharge, Calcimining, Fusing, And Gas-Generation Devices (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT81400375T ATE8091T1 (de) | 1980-03-13 | 1981-03-11 | Vorrichtung zur thermischen behandlung pulverfoermiger oder koerniger stoffe. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR8005607 | 1980-03-13 | ||
FR8005607A FR2478418A1 (fr) | 1980-03-13 | 1980-03-13 | Nouveau dispositif pour le traitement thermique de matieres en poudre ou en grains |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0036362A1 true EP0036362A1 (de) | 1981-09-23 |
EP0036362B1 EP0036362B1 (de) | 1984-06-20 |
Family
ID=9239626
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP81400375A Expired EP0036362B1 (de) | 1980-03-13 | 1981-03-11 | Vorrichtung zur thermischen Behandlung pulverförmiger oder körniger Stoffe |
Country Status (9)
Country | Link |
---|---|
US (1) | US4406937A (de) |
EP (1) | EP0036362B1 (de) |
JP (2) | JPS56149796A (de) |
AR (1) | AR225948A1 (de) |
AT (1) | ATE8091T1 (de) |
BR (1) | BR8101462A (de) |
CA (1) | CA1161907A (de) |
DE (1) | DE3164268D1 (de) |
FR (1) | FR2478418A1 (de) |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0093474A2 (de) * | 1982-04-29 | 1983-11-09 | Clini-Therm Acquisition Corp. | Verfahren und Vorrichtung zum Befördern und zum Behandeln mit Radiowellen von dielektrischen Materialien |
FR2526573A1 (fr) * | 1982-05-06 | 1983-11-10 | Doryokuro Kakunenryo | Appareil de traitement thermique a micro-ondes |
EP0345020A2 (de) * | 1988-05-31 | 1989-12-06 | Kawata Co., Ltd | Vorrichtung zum Trocknen und Kristallisieren von Granulat |
EP0535771A1 (de) * | 1991-10-04 | 1993-04-07 | Matsui Manufacturing Co., Ltd. | Vorrichtung zur Trocknung von pulverförmigem oder körnigem Gut |
WO1993009647A1 (de) * | 1991-11-05 | 1993-05-13 | Oscar Gossler Kg (Gmbh & Co.) | Vorrichtung zur mikrowellen-bestrahlung von materialien |
EP0590411A2 (de) * | 1992-09-16 | 1994-04-06 | Doryokuro Kakunenryo Kaihatsu Jigyodan | Vorrichtung für kontinuierliche Denitrierung |
NL1006690C2 (nl) * | 1997-07-30 | 1999-02-02 | Marinus Minkjan | Microgolf productverwerkingsmachine. |
CN102065591A (zh) * | 2010-11-16 | 2011-05-18 | 成都纽曼和瑞微波技术有限公司 | 一种大功率组合应用的微波回环腔体 |
WO2012045923A1 (fr) | 2010-10-08 | 2012-04-12 | Innovation & Development Company (Idco) | Dispositif de traitement thermique en continu, en particulier de matériaux divisés, par rayonnement micro-ondes. |
FR3046518A1 (fr) * | 2016-01-06 | 2017-07-07 | Inovfruit | Applicateur micro-ondes monomode, dispositif et procede de traitement thermique de produits |
WO2023242489A1 (fr) | 2022-06-17 | 2023-12-21 | Innovation & Development Company | Four rotatif à micro-ondes pour le traitement thermique de matériaux divisés |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4671757A (en) * | 1985-06-06 | 1987-06-09 | Beta Raven, Inc. | Microwave heating in a pellet mill |
US4826575A (en) * | 1985-11-18 | 1989-05-02 | Karamian Narbik A | Apparatus for production of high-purity water by microwave technology |
US5227598A (en) * | 1991-12-23 | 1993-07-13 | General Electric Company | In place regeneration of adsorbents using microwaves |
CA2454577A1 (en) * | 2001-07-20 | 2003-01-30 | American Purification, Inc. | Microwave desorber for removing contaminants from resin |
WO2005003664A1 (en) * | 2003-06-20 | 2005-01-13 | Amut Spa | DEVICE AND METHOD FOR HEATING AND / OR DRYING PLASTIC MATERIALS |
US7498548B2 (en) * | 2006-05-02 | 2009-03-03 | Ranger Research, Inc. | Microwave heating system and method for removing volatiles from adsorbent materials |
GB0725308D0 (en) * | 2007-12-28 | 2008-02-06 | Holliday R | Combined heater and conveyor |
KR100977542B1 (ko) * | 2008-11-27 | 2010-08-24 | 한국전기연구원 | 동축 도파관 형태의 공진기로 구성되는 마이크로파 반응기 및 그 방법 |
CA2814008C (en) * | 2010-10-07 | 2015-10-06 | Milt D. Mathis | Microwave rotary kiln |
WO2013018358A1 (ja) * | 2011-08-04 | 2013-02-07 | パナソニック株式会社 | マイクロ波加熱装置 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1471131A (fr) * | 1966-03-15 | 1967-02-24 | Elliott Brothers London Ltd | Appareil de chauffage à haute fréquence pour traitement thermique |
US3549848A (en) * | 1969-02-06 | 1970-12-22 | Varian Associates | Composite microwave applicator and product conveyor |
US3777095A (en) * | 1972-05-15 | 1973-12-04 | Tokyo Shibaura Electric Co | Microwave heating apparatus |
GB1369677A (en) * | 1972-02-25 | 1974-10-09 | Rotax Ltd | Apparatus for heating a web of a dielectric material |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS50131140A (de) * | 1974-04-03 | 1975-10-17 |
-
1980
- 1980-03-13 FR FR8005607A patent/FR2478418A1/fr active Granted
-
1981
- 1981-03-05 US US06/240,946 patent/US4406937A/en not_active Expired - Fee Related
- 1981-03-11 EP EP81400375A patent/EP0036362B1/de not_active Expired
- 1981-03-11 AT AT81400375T patent/ATE8091T1/de active
- 1981-03-11 DE DE8181400375T patent/DE3164268D1/de not_active Expired
- 1981-03-12 AR AR284589A patent/AR225948A1/es active
- 1981-03-12 JP JP3592381A patent/JPS56149796A/ja active Pending
- 1981-03-12 BR BR8101462A patent/BR8101462A/pt unknown
- 1981-03-13 CA CA000372923A patent/CA1161907A/en not_active Expired
-
1986
- 1986-10-06 JP JP1986153619U patent/JPS6271898U/ja active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1471131A (fr) * | 1966-03-15 | 1967-02-24 | Elliott Brothers London Ltd | Appareil de chauffage à haute fréquence pour traitement thermique |
US3549848A (en) * | 1969-02-06 | 1970-12-22 | Varian Associates | Composite microwave applicator and product conveyor |
GB1369677A (en) * | 1972-02-25 | 1974-10-09 | Rotax Ltd | Apparatus for heating a web of a dielectric material |
US3777095A (en) * | 1972-05-15 | 1973-12-04 | Tokyo Shibaura Electric Co | Microwave heating apparatus |
Cited By (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0093474A3 (de) * | 1982-04-29 | 1986-01-22 | Clini-Therm Acquisition Corp. | Verfahren und Vorrichtung zum Befördern und zum Behandeln mit Radiowellen von dielektrischen Materialien |
EP0093474A2 (de) * | 1982-04-29 | 1983-11-09 | Clini-Therm Acquisition Corp. | Verfahren und Vorrichtung zum Befördern und zum Behandeln mit Radiowellen von dielektrischen Materialien |
FR2526573A1 (fr) * | 1982-05-06 | 1983-11-10 | Doryokuro Kakunenryo | Appareil de traitement thermique a micro-ondes |
EP0345020A2 (de) * | 1988-05-31 | 1989-12-06 | Kawata Co., Ltd | Vorrichtung zum Trocknen und Kristallisieren von Granulat |
EP0345020A3 (de) * | 1988-05-31 | 1991-07-03 | Kawata Co., Ltd | Vorrichtung zum Trocknen und Kristallisieren von Granulat |
EP0535771A1 (de) * | 1991-10-04 | 1993-04-07 | Matsui Manufacturing Co., Ltd. | Vorrichtung zur Trocknung von pulverförmigem oder körnigem Gut |
US5408074A (en) * | 1991-11-05 | 1995-04-18 | Oscar Gossler Kg (Gmbh & Co.) | Apparatus for the selective control of heating and irradiation of materials in a conveying path |
WO1993009647A1 (de) * | 1991-11-05 | 1993-05-13 | Oscar Gossler Kg (Gmbh & Co.) | Vorrichtung zur mikrowellen-bestrahlung von materialien |
US5589140A (en) * | 1992-09-16 | 1996-12-31 | Doryokuro Kakunenryo Kaihatsu Jigyodan | Continuous denitration apparatus |
EP0590411A3 (en) * | 1992-09-16 | 1994-05-25 | Doryokuro Kakunenryo | Continuous denitration apparatus |
EP0590411A2 (de) * | 1992-09-16 | 1994-04-06 | Doryokuro Kakunenryo Kaihatsu Jigyodan | Vorrichtung für kontinuierliche Denitrierung |
NL1006690C2 (nl) * | 1997-07-30 | 1999-02-02 | Marinus Minkjan | Microgolf productverwerkingsmachine. |
WO2012045923A1 (fr) | 2010-10-08 | 2012-04-12 | Innovation & Development Company (Idco) | Dispositif de traitement thermique en continu, en particulier de matériaux divisés, par rayonnement micro-ondes. |
FR2965907A1 (fr) * | 2010-10-08 | 2012-04-13 | Innovation & Dev Company Idco | Dispositif de traitement thermique en continu, en particulier de materiaux divises, par rayonnement micro-ondes |
CN102065591A (zh) * | 2010-11-16 | 2011-05-18 | 成都纽曼和瑞微波技术有限公司 | 一种大功率组合应用的微波回环腔体 |
CN102065591B (zh) * | 2010-11-16 | 2012-11-14 | 成都纽曼和瑞微波技术有限公司 | 一种大功率组合应用的微波回环腔体 |
FR3046518A1 (fr) * | 2016-01-06 | 2017-07-07 | Inovfruit | Applicateur micro-ondes monomode, dispositif et procede de traitement thermique de produits |
WO2017118821A1 (fr) * | 2016-01-06 | 2017-07-13 | Inovfruit | Applicateur micro-ondes monomode, dispositif et procede de traitement thermique de produits |
US11523476B2 (en) * | 2016-01-06 | 2022-12-06 | Inovfruit | Single-mode microwave applicator, device and method for thermal treatment of products |
WO2023242489A1 (fr) | 2022-06-17 | 2023-12-21 | Innovation & Development Company | Four rotatif à micro-ondes pour le traitement thermique de matériaux divisés |
FR3136840A1 (fr) | 2022-06-17 | 2023-12-22 | Innovation & Development Company | four rotatif à micro-ondes pour le traitement thermique de matériaux divisés |
Also Published As
Publication number | Publication date |
---|---|
US4406937A (en) | 1983-09-27 |
EP0036362B1 (de) | 1984-06-20 |
DE3164268D1 (en) | 1984-07-26 |
FR2478418B1 (de) | 1983-12-09 |
JPS56149796A (en) | 1981-11-19 |
JPS6271898U (de) | 1987-05-08 |
FR2478418A1 (fr) | 1981-09-18 |
ATE8091T1 (de) | 1984-07-15 |
AR225948A1 (es) | 1982-05-14 |
CA1161907A (en) | 1984-02-07 |
BR8101462A (pt) | 1981-09-15 |
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