EP0025986B1 - Procédé et dispositif pour l'utilisation de la chaleur recueillie à basse température - Google Patents
Procédé et dispositif pour l'utilisation de la chaleur recueillie à basse température Download PDFInfo
- Publication number
- EP0025986B1 EP0025986B1 EP80105607A EP80105607A EP0025986B1 EP 0025986 B1 EP0025986 B1 EP 0025986B1 EP 80105607 A EP80105607 A EP 80105607A EP 80105607 A EP80105607 A EP 80105607A EP 0025986 B1 EP0025986 B1 EP 0025986B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- heat
- absorber
- absorption
- desorber
- flux
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B35/00—Boiler-absorbers, i.e. boilers usable for absorption or adsorption
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24D—DOMESTIC- OR SPACE-HEATING SYSTEMS, e.g. CENTRAL HEATING SYSTEMS; DOMESTIC HOT-WATER SUPPLY SYSTEMS; ELEMENTS OR COMPONENTS THEREFOR
- F24D17/00—Domestic hot-water supply systems
- F24D17/02—Domestic hot-water supply systems using heat pumps
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B17/00—Sorption machines, plants or systems, operating intermittently, e.g. absorption or adsorption type
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B27/00—Machines, plants or systems, using particular sources of energy
- F25B27/002—Machines, plants or systems, using particular sources of energy using solar energy
- F25B27/007—Machines, plants or systems, using particular sources of energy using solar energy in sorption type systems
Definitions
- the invention relates to a method for using heat absorbed at a low temperature, which is released to a heat consumer at a higher temperature level with the interposition of a multi-stage absorption heat pump.
- a method of this type is known from DE-A-2 743 488.
- the heat absorbed by the solar collector is converted from a poor solution of a working material pair to a evaporator in the solar collector to an absorber operated with a rich solution transported, from which the released heat of absorption generated in it is fed to a heating circuit as a heat consumer by means of a separate heat transfer stream.
- the poor solution of a working material pair consisting of a refrigerant (e.g. water) as a liquid working fluid and a liquid sorbent (e.g.
- aqueous lithium bromide solution for absorbing the low-temperature heat is passed through the solar collector and the refrigerant evaporating there as steam fed the rich solution of the working material pair in the absorber.
- the refrigerant evaporating there as steam fed the rich solution of the working material pair in the absorber.
- several expulsion stages and absorber stages are necessary, as well as pumps which deliver the poor solution of the working material pair to the solar collector and the rich solution to the absorber.
- the working material pair for example water as a refrigerant and aqueous lithium bromine solution
- the solar collector is fed directly to the solar collector as a liquid absorbent.
- a single-stage absorption heat pump is also known (US Pat. No. 2,253,907), in which the divided generator is opposed by only one condenser or only one evaporator, so that partial recovery of the heat of condensation is not possible.
- Degasser and absorber stages are in direct connection for the direct transport of working fluid (hydrogen) from one metal hydride to the other metal hydride.
- working fluid hydrogen
- thermodynamic units for the use of liquid working fluid pairs is not specified.
- This known heat pump differs from the well-known Altenkirch multi-stage absorption chillers only in that instead of the heat of condensation (at Attenkirch), the heat of absorption of the first stage is used to achieve the desorption of a second stage.
- This principle of absorption and desorption of metal hydrides known more under the name “chemical heat pump”, allows only limited use in the field of heat pumps, because the same restrictions exist that apply to the application of Altenkirch's multi-stage.
- a periodically acting single-stage absorption heat pump in which two independent desorber and absorber or evaporator and evaporator stages are provided, is known (DE-OS 2 801 895). These two stages are switched during operation at certain time intervals in order to ensure continuous operation in the evaporator stage.
- the invention is based on the object of designing the above-mentioned method for using heat absorbed at low temperature in such a way that the limitations of the known methods are avoided, that work can be carried out more economically than with the known methods and that it is simple and inexpensive devices that can be produced and that cause little noise during operation can be carried out.
- a particularly suitable absorption heat pump for carrying out the method is to be specified.
- the method according to the invention can only be carried out with low-temperature heat, as long as the return of the heat transfer stream coming from the heat consumer can evaporate the working medium (refrigerant) of the working material pair in the degasser or evaporator stages. Thereafter, a regeneration of the rich solution of the working material pair in the absorber stages and possibly the poor solution of the working material pair in the degassing stages is required. This specified regeneration of the working substance pair is carried out until the working substance pair has reached its original richer concentration in the absorber stages and, if appropriate, has reached its original poorer concentration in the degassing stages.
- the method according to the invention can be used with great advantage if high-quality thermal energy (high-temperature heat) is available temporarily and irregularly. This can be used sensibly for regeneration. Is there a plant for the use of, for example, solar energy, geothermal energy or other low-temperature heat, sometimes also high-temperature heat, e.g. Exhaust heat, available, the heat pump can be switched over immediately, so that in the periods. in which the higher-quality energy is available, the working material pair is regenerated in the degasifier and absorber stages, so no heating energy for this; for example, an oil burner.
- high-quality thermal energy high-temperature heat
- the absorption heat pump according to the invention has the advantage that each associated absorber and degasser part (or evaporator plate) can be prefabricated and in it as an absorption unit that is completely sealed off from the outside with the common steam chamber and the means for bringing the steam into contact with the rich solution in the absorber part for an optimal heat and mass transfer.
- the absorption units are set to different evaporation and absorption temperatures corresponding to the stages.
- the chamber walls of the absorber parts and the evaporator are arranged separately from one another in a flow guide for a heat transfer stream. The from the low temperature heat source, e.g.
- the incoming heat transfer medium absorbs absorption heat through the flow around and / or through the individual absorber units, while the return flow of heat transfer medium flows through the individual absorption units in the opposite direction and emits heat to the degassing stages until the heat transfer fluid has cooled to a temperature at which it Is able to, for example, in the low temperature heat source the solar collector to absorb heat again.
- the special design of the absorption units favor the exchange of materials and heat.
- Each absorption unit 1 consists of a hermetically sealed chamber 2, which is divided into a degassing part 3 (or evaporator part) and an absorber part 4 lying next to it.
- the chamber 2 is filled with a liquid two-substance mixture 5 suitable for the absorption process as a working material pair and is set to a pressure which corresponds to the respective stage of the heat pump.
- the chambers 2 consist of a deep-drawn lower tub and a deep-drawn lid. These are connected to each other to form the hermetically sealed chamber 2.
- Both parts 3, 4 have a common vapor space.
- the lower part of the degassing part 3 is divided from the lower part of the absorber plate 4 by a double-walled partition 6 arranged in such a way that the two-component mixture 5 cannot pass from one part of the chamber to the other part, but the refrigerant vapor of the two-component mixture can.
- the outer surfaces of the degassing part 3 and the absorber part 4 are in heat exchange via large ribs 7 to two heat transfer streams 8 and 9, which are separated from each other by an insulating wall 10.
- the first heat transfer stream 8 (return flow) flowing back from the heat consumer in heat pump operation flows around the degasser part 3 and emits heat to the refrigerant or to the dilute poor solution of the two-substance mixture therein, so that part evaporates and the steam passes to the absorber part 4.
- the heat released in this process is released via the heat exchange ribs 7 of the absorber part 4 to the second heat transfer stream 9 (flow), which consumes the heat consumer in heat pump operation.
- a double-walled deflecting wall 11 reaching into the rich solution is arranged in the absorber part 4 as a means for bringing the steam into contact with the rich solution, which ensures that the steam which is transferred comes into better contact with the rich solution and a certain amount Movement on the surface of the rich solution in absorber part 4 occurs.
- the double-walled partition 6 and the insulating wall 10 ensure that no significant amounts of heat pass through the chamber wall from the degassing part 3 to the absorber part 4 and vice versa.
- the poor and the rich solution of the two-substance mixture 5 must be regenerated. This is done by operating the absorber part 4 as the expeller part and the degassing part 3 as the absorber part.
- the second heat transfer stream 9 is brought to a higher temperature than it has in the heating mode, so that it cools down as it flows around the absorber parts 4, which now operate as expellers.
- the first heat transfer medium stream 8 is now heated when the degassing parts 3 of the heat pump, which work as resorbers (or evaporators), flow around.
- the heat pump shown in Fig. 3 and 4 consists of a larger number, for. B. 10 to 30 disc-shaped absorption units 1.
- Each unit has a circular chamber 2 in plan, which is divided by an annular partition 6 into the outer degasser part 3 and the inner absorber part 4 such that the liquid mixture of two substances 5 does not move from one chamber part into the other other can, but the refrigerant vapor.
- the absorption units 1 are spaced one above the other by annular insulating walls 10 and arranged in a container 12 which is divided into cells 14 by partitions 13 for receiving an absorption unit. In each partition 13 through openings 15 for the heat transfer streams 8 and 9 are formed on both sides of the insulating wall.
- the annular insulating walls 10 separate the second heat carrier flow 9, which flows around the inner absorber parts 4 of the absorption units 1, from the first heat carrier flow 8, which flows around the outer degasser parts 3 of the absorption units 1.
- the round, disc-shaped absorption units 1 are provided in the middle with a through channel 16 for the second heat transfer stream 9.
- Fig. 3 shows schematically the operation of an absorption heat pump for the use of low temperature heat, e.g. of solar energy.
- a heat transfer fluid is heated in a low-temperature heat source 20, for example a solar collector, to which it flows via an inlet line, for example from +2 to + 12 ° C.
- This heat carrier flow heated in this way flows via an outlet line 17, a first three-way valve 23, a connecting line 18, a second three-way valve 24 and an inlet line 19 as a second heat carrier flow 9 via an inlet 28 to the absorber part 4 of the uppermost one of the absorption units 1 arranged one above the other and then passes through one after the other the following, rising in temperature absorber parts 4 and is in heat exchange with them.
- the heat carrier flow is absorbed by the refrigerant in the individual graded absorption units heated to a higher temperature, which is suitable for low-temperature heating at 45 ° C.
- This second heat transfer stream 9 leaves the absorber part 4 of the lowest absorption unit 1 through an outlet 34 and enters as a flow into a heat consumer, for example a heating circuit.
- the return flow of the heat consumer passes through the degassing part 3 of the lowest absorption unit 1 as the first heat transfer stream 8 with a temperature of 35 ° C. via an inlet 37 and then successively through the subsequent degassing parts 3 of the absorption units 1, which decrease in temperature.
- the returning heat transfer stream 8 cools from, e.g. B.
- the regenerating heat transfer stream heats up by flowing around the outer degassing parts 3 of the graded absorption units, which work as a resorber (or condenser), from a temperature of 30 to 80.degree a return line 27 is returned to the high-temperature heat source 25.
- the particular advantage of this absorption heat pump lies in the fact that lowering the flow and return temperatures or increasing the temperatures in the low-temperature heat source 20 improves the ratio of the amount of heat given off to the heat consumer to the amount of heat to be absorbed by the high-temperature heat source 25 becomes.
- Such a flexible adaptation results in a particularly low use of heating energy from fossil fuels in the high-temperature heat source 25 on average. The standard effort for such a heating system is minimal.
- the arrangement of the absorber parts 4, which also work as expeller parts, inside the disk-shaped absorption units 1 and the arrangement of the degassing parts 3, which also work as resorber stages, in the outer ring area of the absorption units 1 causes the warmer parts and heat transfer medium of colder parts and Heat carriers are surrounded and therefore only slight heat losses will occur.
- FIG. 5 and 6 show a combination of an absorption heat pump according to the invention with an oil, coal or gas burner 30 arranged centrally in the upper area as a high-temperature heat source and a hot water preparation tank 31 for the hot water supply integrated in the lower area.
- the second heat transfer stream 9 coming from the low-temperature heat source 20 via the outlet line 18, a four-way valve 29 and the inlet line 19 and heated in the absorber stages 4 of the absorption units 1 from 12 to 45 ° C. and emerging from a connection 34 Introduced via a line 32 into the inlet 35 of a heat exchanger 33 of the hot water preparation tank 31 before it reaches a heating circuit as a lead 21.
- the returning heat transfer stream 8 is again fed to the degassing points 3 of the absorption units 1, in which it cools down to about 2 ° C., so that it can heat up again to 12 ° C. in the low-temperature heat source 20 (solar collector).
- the outlet 38 of the heat carrier flow 8 led around the outer evaporator or degasifier parts 3 of the absorption units 1 via the four-way valve 29 with the inlet 28 of the around the inner absorber parts 4 of the absorption units 1 connected to leading heat transfer stream 9 and the burner 30 started.
- the absorber parts 4 now work as an expeller and the degassing parts 3 (or evaporator parts) as a resorber (or condenser).
- the burner 30 heats the heat carrier flow 9 in the inner absorber parts 4 of the upper absorption units to approximately 100 ° C., so that it can now serve as a regenerating heat carrier flow.
- This regenerating heat transfer stream 9 then cools by flowing around the inner one Absorber parts 4 of the lower absorption units 1, which are now working as expellers, drop to 50 ° and are then passed through the heat exchanger 33 of the hot water preparation tank 31 and, after leaving the outlet 36, as a feed 21 into the heating circuit.
- the return flow is introduced again as heat transfer stream 8 through the inlet 37 of the degassing part 3 of the lowermost absorption unit 1 and successively around the outer absorber parts 3 of the absorption units, which now work as a resorber, so that it heats up to a temperature of 800C and through the outlet 38 the top absorption unit emerges.
- the four-way valve 29 converted for regeneration and the feed line 19 the heat carrier flow is fed back directly into the inlet 28 of the absorber part 4 of the top absorption unit 1.
- FIG. 7 and 8 show chambers 2 of absorption units 1, each of which is composed of a trough 42 and a cover 43 to form the hermetically sealed chamber 2.
- An annular partition 6 is arranged in the trough 42 and an annular deflecting wall 11 is arranged in the cover 43 in the radially outer region.
- An annular insulating wall 10 and an annular outer wall 40 are arranged between adjacent chambers 2.
- the flow guide for the first heat transfer stream 8 through the degassing parts 3 is formed by tubular through-channels 41 and the space between the insulating wall 10 and the outer wall 40.
- the flow guide for the second heat carrier flow 9 through the absorber parts 4 is formed by tubular through channels 16 ′ and the interior of the annular insulating walls 10
- each hermetically sealed chamber 2 is in turn ring-shaped.
- the inner absorber part 4 of the chamber 2 is arranged lower than the outer degasser part 3.
- Each chamber 2 is composed of two deep-drawn sheet metal shells into which radially extending beads 44 and concentrically extending beads 45 are embossed in order to enlarge the outer heat exchange surfaces.
- the flow guide for the first heat transfer stream 8 through the degasser runs along the concentric beads 45 and through outer channels 46 on the circumference of the chamber 2.
- the flow guide for the second heat transfer stream 9 through the absorber parts 4 runs along the radial beads 44 from the inside out and then around the inner partition 13 to the next absorber part 4.
- the upper deep-drawn sheet metal shell of the chamber has a deflecting wall reaching downwards into the rich solution of the absorber part, so that the steam with the rich solution enters into a good heat and material exchange.
- 11 and 12 show vertically extending absorption units with a lower degassing part 3 and an upper absorber part 4.
- a wall 10 ' initially connected radially and then vertically in the middle to the outer wall, occurs the rich solution of the absorber part 4 from the poor solution of the Two-substance mixture 5 in the degasser part 3.
- the vertical part of the wall 10 ' is overlaid by a bell-shaped steam guide wall 50 which extends downwards and corresponds to the deflection wall 11. It ensures that the steam rising from the degassing part 3 is passed through the rich solution of the absorber part 4 and that in the regeneration mode, the steam expelled in the absorber part 4 is pressed under the level of the solution in the degassing part 3 working as a absorber.
- the contact areas of the solution in the degassing part 3 and in the absorber part 4 can be enlarged by capillary and wicking walls 51 and 52 arranged there.
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Thermal Sciences (AREA)
- Physics & Mathematics (AREA)
- Sustainable Energy (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Sorption Type Refrigeration Machines (AREA)
- Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)
- Pressure Welding/Diffusion-Bonding (AREA)
Claims (13)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT80105607T ATE5439T1 (de) | 1979-09-21 | 1980-09-18 | Verfahren und vorrichtung zur nutzung von bei niedriger temperatur aufgenommener waerme. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE2938203 | 1979-09-21 | ||
DE19792938203 DE2938203A1 (de) | 1979-09-21 | 1979-09-21 | Verfahren und vorrichtung zur nutzung von bei niedriger temperatur aufgenommener waerme |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0025986A1 EP0025986A1 (fr) | 1981-04-01 |
EP0025986B1 true EP0025986B1 (fr) | 1983-11-23 |
Family
ID=6081460
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP80105607A Expired EP0025986B1 (fr) | 1979-09-21 | 1980-09-18 | Procédé et dispositif pour l'utilisation de la chaleur recueillie à basse température |
Country Status (4)
Country | Link |
---|---|
US (1) | US4368623A (fr) |
EP (1) | EP0025986B1 (fr) |
AT (1) | ATE5439T1 (fr) |
DE (2) | DE2938203A1 (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102008003630A1 (de) * | 2008-01-09 | 2009-07-16 | Helioplus Energy Systems Gmbh | Hybridklimatisierungssystem |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4422500A (en) * | 1980-12-29 | 1983-12-27 | Sekisui Kagaku Kogyo Kabushiki Kaisha | Metal hydride heat pump |
FR2539854A1 (fr) * | 1983-04-22 | 1984-07-27 | Cetiat | Installation de refrigeration par adsorption sur un adsorbant solide et procede pour sa mise en oeuvre |
DE3405800C2 (de) * | 1984-02-17 | 1986-11-20 | Knoche, Karl-Friedrich, Prof. Dr.-Ing., 5100 Aachen | Verfahren zum Betreiben einer Generator-Absorptionswärmepumpen-Heizanlage für die Raumheizung und/oder Warmwasserbereitung und Generator-Absorptionswärmepumpen-Heizanlage |
JPS61180891A (ja) * | 1985-02-04 | 1986-08-13 | Hitachi Ltd | 熱エネルギーの蓄熱方法と蓄熱装置 |
FR2585812B1 (fr) * | 1985-07-30 | 1987-10-23 | Jeumont Schneider | Machine thermique a adsorption-desorption |
JPH0694968B2 (ja) * | 1986-01-28 | 1994-11-24 | 西淀空調機株式会社 | 吸着式冷凍装置 |
DE3901558A1 (de) * | 1989-01-20 | 1990-07-26 | Zeolith Tech | Sorptionsbehaelter fuer feste sorptionsmittel |
DE4121131A1 (de) * | 1991-06-26 | 1993-01-07 | Zeolith Tech | Sorptionsmittelbehaelter-anordnung und sorptionsverfahren mit regenerativem waermetausch |
DE4431864A1 (de) * | 1994-09-07 | 1996-03-14 | Zahnradfabrik Friedrichshafen | Fahrantrieb |
US5666818A (en) * | 1995-12-26 | 1997-09-16 | Instituto Tecnologico And De Estudios Superiores | Solar driven ammonia-absorption cooling machine |
US9207003B2 (en) * | 2014-04-02 | 2015-12-08 | King Fahd University Of Petroleum And Minerals | Intermittent absorption system with a liquid-liquid heat exchanger |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE227099C (fr) * | ||||
US1506531A (en) * | 1921-12-12 | 1924-08-26 | Westinghouse Electric & Mfg Co | Refrigeration apparatus |
US1729083A (en) * | 1925-03-11 | 1929-09-24 | Silica Gel Corp | Refrigeration process and apparatus |
DE505267C (de) * | 1927-06-27 | 1930-08-16 | Silica Gel Corp | Verfahren zur Kaelteerzeugung |
US1960824A (en) * | 1929-05-03 | 1934-05-29 | Electrolux Servel Corp | Refrigeration |
DE620249C (de) * | 1930-08-17 | 1935-10-19 | Siemens Schuckertwerke Akt Ges | Absorptionsapparat, bestehend aus zwei in sich geschlossenen einzelnen Absorptionsmaschinen |
DE671791C (de) * | 1931-12-09 | 1939-02-17 | Siemens Schuckertwerke Akt Ges | Absorptionsapparat |
US2138686A (en) * | 1933-02-28 | 1938-11-29 | Altenkirch Edmund | Intermittent absorption refrigerating apparatus |
US2253907A (en) * | 1936-12-15 | 1941-08-26 | Julius Y Levine | Refrigerating apparatus |
NL7601906A (nl) * | 1976-02-25 | 1977-08-29 | Philips Nv | Cyclische desorptiekoelmachine resp. - warmte- pomp. |
GB1572737A (en) * | 1977-01-17 | 1980-08-06 | Exxon France | Heat pump |
US4121432A (en) * | 1977-03-24 | 1978-10-24 | Institute Of Gas Technology | Solid adsorption air conditioning apparatus and method |
DE2720561A1 (de) * | 1977-05-07 | 1978-11-09 | Tchernev Dimiter I | Sorptionssystem fuer die nutzbarmachung schwacher (solarer) waermequellen |
DE2743488A1 (de) * | 1977-09-28 | 1979-03-29 | Karl Friedrich Prof Dr Knoche | Verfahren und vorrichtung zur nutzung von sonnenenergie fuer raumheizung |
US4224803A (en) * | 1978-11-07 | 1980-09-30 | Leonard Greiner | Chemical heat pump |
US4187688A (en) * | 1978-10-10 | 1980-02-12 | Owens-Illinois, Inc. | Solar powered intermittent cycle heat pump |
-
1979
- 1979-09-21 DE DE19792938203 patent/DE2938203A1/de not_active Ceased
-
1980
- 1980-09-18 AT AT80105607T patent/ATE5439T1/de not_active IP Right Cessation
- 1980-09-18 DE DE8080105607T patent/DE3065698D1/de not_active Expired
- 1980-09-18 EP EP80105607A patent/EP0025986B1/fr not_active Expired
- 1980-09-22 US US06/189,117 patent/US4368623A/en not_active Expired - Lifetime
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102008003630A1 (de) * | 2008-01-09 | 2009-07-16 | Helioplus Energy Systems Gmbh | Hybridklimatisierungssystem |
Also Published As
Publication number | Publication date |
---|---|
ATE5439T1 (de) | 1983-12-15 |
US4368623A (en) | 1983-01-18 |
EP0025986A1 (fr) | 1981-04-01 |
DE3065698D1 (en) | 1983-12-29 |
DE2938203A1 (de) | 1981-04-02 |
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