EP0017120A1 - Détergent de lavage de textile ayant un effet apprêtant - Google Patents
Détergent de lavage de textile ayant un effet apprêtant Download PDFInfo
- Publication number
- EP0017120A1 EP0017120A1 EP80101534A EP80101534A EP0017120A1 EP 0017120 A1 EP0017120 A1 EP 0017120A1 EP 80101534 A EP80101534 A EP 80101534A EP 80101534 A EP80101534 A EP 80101534A EP 0017120 A1 EP0017120 A1 EP 0017120A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- ethers
- content
- percent
- weight
- composition according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/227—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin with nitrogen-containing groups
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
Definitions
- the invention relates to a textile detergent which exerts a finishing or stiffening effect on the washed textiles during the washing process, so that a separate aftertreatment process, usually after the last rinse cycle, is unnecessary.
- appretierend acting, nonionic and / or zwitterionic surfactants containing laundry detergent is characterized by a content of 0.5 to 10 percent by weight of water-soluble, quaternary ammonium group-containing amino-ethers of P oly- saccharides.
- Suitable quaternary group ethers of polysaccharides are in particular ethers of polygalactomannan and starch.
- polygalactomannan is the main component of guar flour and is made up of trisaccharide units with the following structure:
- the ether groups can form on the -CH 2 0H groups, the degree of substitution being in the range from 0.05 to 0.2, preferably from 0.07 to 0.15, ether groups per anhydrogalactomannan unit shown above.
- the degree of substitution for starch ethers is 0.05 to 0.12, preferably 0.07 to 0.1 ether groups per anhydroglucose unit.
- the ether group can be introduced in a manner known per se, for example by reacting the polygalactomannan or starch with ethyleneimine (compare US Pat. No. 3,303,184) and then partially or completely quaternizing the amino group.
- ethyleneimine compare US Pat. No. 3,303,184
- Such reaction products are described for example in GB-PS 1 136 842 and are known as additives in paper manufacture or as flocculants.
- the quaternary salts can be present as halides, in particular chlorides, sulfates, alkyl sulfates, nitrates, phosphates and as salts of organic acids, for example as acetates, citrates or lactates.
- the detergent content of the aforementioned quaternary ammonium ether is preferably 1 to 5 percent by weight.
- the detergents contain at least one nonionic or zwitterionic surfactant and calcium ion-binding skeleton salts as further constituents. They can also contain conventional detergent components, such as washing alkalis, neutral salts, graying inhibitors, bleaching agents and stabilizers or activators for bleaching agents, enzymes, dyes and fragrances. Con - compounds with anionic character, can react with the quaternary sparingly polysaccharide to form esters or insoluble electroneutral salts are not to be included in the media.
- Useful zwitterionic compounds are those with a betaine structure, such as carboxylate betaines, sulfate betaines and sulfobetaines, containing a straight-chain hydrocarbon radical having 12 to 18 carbon atoms, such as, for example, by reacting tertiary amines with halocarboxylic acids (for example monochloroacetic acid), haloalkylsulfonic acid esters, haloalkylsulfonic acids or sultones (for example propane sultone) are available.
- halocarboxylic acids for example monochloroacetic acid
- haloalkylsulfonic acid esters for example haloalkylsulfonic acids or sultones
- propane sultone propane sultone
- the surfactant component preferably consists of nonionic compounds.
- the content of nonionic surfactants in the laundry detergent is generally 1 to 30 percent by weight.
- the maximum content is slightly lower in powdery to granular detergents, i.e. it generally does not exceed 25 percent by weight and is preferably 3-15 percent by weight.
- Suitable nonionic surfactants are, in particular, ethoxylation products of saturated or monounsaturated aliphatic primary alcohols having 12 to 24, preferably 12 to 18 carbon atoms and 3 to 20, in particular 4 to 15, ethylene glycol ether groups.
- Suitable alcohols from which the present ethoxylation products are derived are, for example, those of natural origin, such as coconut oil or tallow fatty alcohols or oleyl alcohol, furthermore oxo alcohols or synthetic alcohols obtained by ethylene polymerization.
- nonionic surfactants are ethoxylation products of secondary alcohols and vicinal diols each having 12 to 18 carbon atoms and of alkylphenols with 6 to 12 carbon atoms in the alkyl radical, the number of glycol ether groups likewise being 3 to 20, preferably 4 to 15.
- the abovementioned ethoxylated alcohols and alkylphenols can also be replaced in whole or in part by those which are prepared with 0.5 to 3 mol of propylene oxide per mol of starting compound and only in 2. Stage the prospective amount of ethylene oxide is deposited.
- those nonionic surfactants which are derived from the abovementioned compounds and which have ethylene glycol and propylene glycol ether groups in a different order may also be present, for example alcohols with 10 to 30 ethylene glycol ether groups and 3 to 30 propylene glycol ether groups; also ethoxylation products of mercaptans, fatty acid amides and fatty acids.
- the water-soluble, 20 to 250 ethylene glycol ether groups and 10 to 100 propylene glycol can also be used
- the compounds mentioned usually contain 1 to 5 ethylene glycol units per propylene glycol unit.
- Nonionic compounds of the amine oxide and sulfoxide type which can optionally also be ethoxylated, can also be used.
- Suitable structural substances are the polymer phosphates of sodium and potassium.
- the pentasodium triphosphate is particularly suitable as the polymer phosphate, which may be present in a mixture with its hydrolysis products, the mono- and diphosphates, and also more highly condensed phosphates, for example the tetraphosphates.
- These aluminosilicates generally have a grain size of 0.1 to 20 ⁇ and are preferably crystalline.
- the skeleton salts also include salts of complexing aminopolycarboxylic acids, in particular alkali salts of nitrilotriacetic acid and ethylenediaminotetraacetic acid.
- the higher homologs of the aminopolycarboxylic acids mentioned are also suitable.
- Salts are also nitrogen-free polycarboxylic acids which form complex salts with calcium ions, which also include polymers containing carboxyl groups suitable. Examples are citric acid, tartaric acid, benzene hexacarboxylic acid and tetrahydrofuran tetracarboxylic acid.
- Polycarboxylic acids containing carboxymethyl ether groups can also be used, such as 2,2'-oxydisuccinic acid and polyhydric alcohols or hydroxycarboxylic acids partially or completely etherified with glycolic acid, for example triscarboxymethylglycerol, biscarboxymethylglyceric acid and carboxymethyloxysuccinic acid.
- complexing polyphosphonic acid salts can be present, for example the alkali salts of aminopolyphosphonic acids, in particular aminotri- (methylenephosphonic acid), 1-hydroxyethane-1,1-diphosphonic acid, phenylhydroxymethane diphosphonic acid, methylene diphosphonic acid and salts of the higher homologues of the polyphosphonic acids mentioned. Mixtures of the aforementioned complexing agents can also be used.
- Suitable washing alkalis are alkali carbonates, bicarbonates, borates and silicates with a Na 2 0: Si0 2 ratio of 1: 1 to 1: 3.5.
- Sodium sulfate and sodium chloride are suitable as neutral salts.
- Graying inhibitors are compounds from the class of cellulose ethers in amounts of from 0.1 to 5 percent by weight, in particular nonionic compounds, such as methyl cellulose, hydroxyethyl cellulose, methyl hydroxyethyl cellulose and methyl hydroxypropyl cellulose. Mixtures of the aforementioned cellulose ethers or mixed ethers can also be used,
- bleaching agents may be present, preferably per compounds such as sodium percarbonate, but in particular sodium perborate tetrahydrate.
- suitable ingredients are foam inhibitors, in particular polydimethylsiloxanes, proteolytic or amylolytic enzymes, and bleach activators, such as tetraacetylethylene diamine or tetraacetylglycoluril.
- the enzymes and bleach activators can be coated with water-soluble or dispersible coating substances.
- the agents can also be in liquid form and contain water or organic solvents, such as low molecular weight alcohols, glycols, glycol ethers and ether alcohols.
- Hydrotropic substances such as the alkali metal salts of toluene, xylene, ethylbenzene and cumene sulfonic acid or alkyl sulfates or alkyl sulfonates having 4 to 8 carbon atoms, may also be present.
- the preparation of powdered or granular laundry detergent may be conducted in a known manner, for example by G ranulation or spray drying, with the present invention concomitantly polysaccharide ether can be added to verstäubenden Waschstoffbrei (slurry) to the.
- the textile detergents are suitable for use in the delicates range (20 - 40 ° C) and for cottons (90 - 98 ° C), but especially for the treatment of so-called "easy-care textiles" in the 40 - 60 ° C range. They are suitable for washing textiles made of cellulose fibers (cotton, linen), refined cellulose (wash-andwear equipment) as well as those made of synthetic fibers or blended fabrics.
- Powdery to granular detergents can have the following general composition (in percent by weight):
- Liquid laundry detergents can have the following composition (in percent by weight):
- the textile detergents according to the invention are not only distinguished by their high washability but also by valuable finishing and stiffening properties. This manifests itself in an increased bending stiffness and an improved surface smoothness of the washed textiles. These effects are known per se as a result of a finishing treatment, but so far a separate aftertreatment which increases the water consumption and is time-consuming has always been necessary for this. In contrast, the use of the agents according to the invention leads to a simplification of the washing process or to savings in water and energy.
- a detergent of the following composition was used (in percent by weight):
- curtain tape and bleaching nettle were used as textile material.
- the washing treatment was carried out in an automatic washing machine having a horizontally mounted drum at 40 O C ( "easy-care program").
- the detergent concentration was 8.4 g / l, the liquor ratio (kg of laundry to liter of wash liquor) 1:20, the water hardness 16 ° dH and the washing time 20 minutes.
- the change in tensile resistance was measured on the curtain tapes, and the change in stiffness and static or sliding friction on the nettle fabric after 1 and 3 washing treatments (abbreviation 1 W and 3 W, respectively).
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Emergency Medicine (AREA)
- Molecular Biology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Textile Engineering (AREA)
- Detergent Compositions (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
- Woven Fabrics (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT80101534T ATE1248T1 (de) | 1979-03-26 | 1980-03-24 | Appretierend wirkendes textilwaschmittel. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE2911857 | 1979-03-26 | ||
DE19792911857 DE2911857A1 (de) | 1979-03-26 | 1979-03-26 | Appretierend wirkendes textilwaschmittel |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0017120A1 true EP0017120A1 (fr) | 1980-10-15 |
EP0017120B1 EP0017120B1 (fr) | 1982-06-23 |
EP0017120B2 EP0017120B2 (fr) | 1985-09-04 |
Family
ID=6066464
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP80101534A Expired EP0017120B2 (fr) | 1979-03-26 | 1980-03-24 | Détergent de lavage de textile ayant un effet apprêtant |
Country Status (7)
Country | Link |
---|---|
US (1) | US4289642A (fr) |
EP (1) | EP0017120B2 (fr) |
AT (1) | ATE1248T1 (fr) |
BR (1) | BR8001788A (fr) |
DE (2) | DE2911857A1 (fr) |
DK (1) | DK89880A (fr) |
ZA (1) | ZA801721B (fr) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1987003682A1 (fr) * | 1985-12-03 | 1987-06-18 | Hoffmann's Stärkefabriken Ag | Produit de soins pour la lessive |
US5150312A (en) * | 1989-06-16 | 1992-09-22 | International Business Machines Corporation | Animation processor method and apparatus |
EP0607529A2 (fr) * | 1993-01-20 | 1994-07-27 | Hüls Aktiengesellschaft | Agents adoucissants aqueux pour de traitement de textils |
WO2005105965A1 (fr) | 2004-04-30 | 2005-11-10 | Henkel Kommanditgesellschaft Auf Aktien | Produit d'entretien pour textiles renfermant un ether de cellulose comportant des groupes amine |
WO2009016060A1 (fr) * | 2007-07-31 | 2009-02-05 | Henkel Ag & Co. Kgaa | Produit d'entretien pour textiles avec de l'éther de cellulose contenant des groupes amino |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB8334159D0 (en) * | 1983-12-22 | 1984-02-01 | Unilever Plc | Perfume |
DE3842007A1 (de) * | 1988-12-14 | 1990-06-21 | Henkel Kgaa | Fluessiges bis pastoeses, bleichmittelhaltiges waschmittel |
DE4411681A1 (de) * | 1994-04-05 | 1995-10-12 | Hoechst Ag | Verfahren zur Herstellung niedermolekularer Polysaccharidether |
US5851971A (en) * | 1997-09-25 | 1998-12-22 | Colgate-Palmolive Company | Liquid cleaning compositions |
US6180582B1 (en) * | 1997-09-26 | 2001-01-30 | Colgate-Palmolive Co. | Liquid cleaning compositions |
GB2342358A (en) * | 1998-10-09 | 2000-04-12 | Procter & Gamble | Detergent compositions comprising cationic polymers |
US6281172B1 (en) | 1999-04-07 | 2001-08-28 | Akzo Nobel Nv | Quaternary nitrogen containing amphoteric water soluble polymers and their use in drilling fluids |
AU1152601A (en) * | 1999-10-22 | 2001-05-08 | Reckitt Benckiser France | Compositions and their use |
US6849586B2 (en) | 2001-10-26 | 2005-02-01 | S. C. Johnson & Son, Inc. | Hard surface cleaners containing chitosan |
US20060217287A1 (en) * | 2005-03-22 | 2006-09-28 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Fabric softening composition |
US20060223739A1 (en) * | 2005-04-05 | 2006-10-05 | Unilever Home And Personal Care Usa, Division Of Conopco, Inc. | Fabric softening composition with cationic polymer, soap, and amphoteric surfactant |
US10273434B2 (en) * | 2010-06-18 | 2019-04-30 | Rhodia Operations | Protection of the color of textile fibers by means of cationic polysacchrides |
FR2961522B1 (fr) * | 2010-06-18 | 2013-03-15 | Rhodia Operations | Protection de la coloration de fibres textiles par des polysaccharides cationiques |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4031307A (en) * | 1976-05-03 | 1977-06-21 | Celanese Corporation | Cationic polygalactomannan compositions |
DE2658575A1 (de) * | 1976-12-23 | 1978-06-29 | Henkel Kgaa | Waeschenachspuelmittel mit steifenden und avivierenden eigenschaften |
US4169945A (en) * | 1978-01-05 | 1979-10-02 | Celanese Corporation | Process for production of polygalactomannan ethers |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3580853A (en) * | 1967-09-27 | 1971-05-25 | Procter & Gamble | Detergent compositions containing particle deposition enhancing agents |
US3753916A (en) * | 1967-09-27 | 1973-08-21 | Procter & Gamble | Detergent compositions containing particle deposition enhancing agents |
US3990991A (en) * | 1974-02-01 | 1976-11-09 | Revlon, Inc. | Shampoo conditioner formulations |
US4061602A (en) * | 1976-08-03 | 1977-12-06 | American Cyanamid Company | Conditioning shampoo composition containing a cationic derivative of a natural gum (such as guar) as the active conditioning ingredient |
US4179382A (en) * | 1977-11-21 | 1979-12-18 | The Procter & Gamble Company | Textile conditioning compositions containing polymeric cationic materials |
-
1979
- 1979-03-26 DE DE19792911857 patent/DE2911857A1/de not_active Withdrawn
-
1980
- 1980-02-29 US US06/126,037 patent/US4289642A/en not_active Expired - Lifetime
- 1980-03-03 DK DK89880A patent/DK89880A/da not_active Application Discontinuation
- 1980-03-24 ZA ZA00801721A patent/ZA801721B/xx unknown
- 1980-03-24 EP EP80101534A patent/EP0017120B2/fr not_active Expired
- 1980-03-24 DE DE8080101534T patent/DE3060571D1/de not_active Expired
- 1980-03-24 AT AT80101534T patent/ATE1248T1/de not_active IP Right Cessation
- 1980-03-25 BR BR8001788A patent/BR8001788A/pt unknown
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4031307A (en) * | 1976-05-03 | 1977-06-21 | Celanese Corporation | Cationic polygalactomannan compositions |
DE2658575A1 (de) * | 1976-12-23 | 1978-06-29 | Henkel Kgaa | Waeschenachspuelmittel mit steifenden und avivierenden eigenschaften |
US4169945A (en) * | 1978-01-05 | 1979-10-02 | Celanese Corporation | Process for production of polygalactomannan ethers |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1987003682A1 (fr) * | 1985-12-03 | 1987-06-18 | Hoffmann's Stärkefabriken Ag | Produit de soins pour la lessive |
EP0230565A1 (fr) * | 1985-12-03 | 1987-08-05 | Hoffmann's Stärkefabriken AG | Produit pour le post-traitement du linge |
US5150312A (en) * | 1989-06-16 | 1992-09-22 | International Business Machines Corporation | Animation processor method and apparatus |
EP0607529A2 (fr) * | 1993-01-20 | 1994-07-27 | Hüls Aktiengesellschaft | Agents adoucissants aqueux pour de traitement de textils |
EP0607529A3 (fr) * | 1993-01-20 | 1995-03-22 | Huels Chemische Werke Ag | Agents adoucissants aqueux pour de traitement de textils. |
US5447643A (en) * | 1993-01-20 | 1995-09-05 | Huels Aktiengesellschaft | Aqueous fabric softener for the treatment of textile |
WO2005105965A1 (fr) | 2004-04-30 | 2005-11-10 | Henkel Kommanditgesellschaft Auf Aktien | Produit d'entretien pour textiles renfermant un ether de cellulose comportant des groupes amine |
WO2009016060A1 (fr) * | 2007-07-31 | 2009-02-05 | Henkel Ag & Co. Kgaa | Produit d'entretien pour textiles avec de l'éther de cellulose contenant des groupes amino |
Also Published As
Publication number | Publication date |
---|---|
DK89880A (da) | 1980-09-27 |
ZA801721B (en) | 1981-06-24 |
EP0017120B2 (fr) | 1985-09-04 |
ATE1248T1 (de) | 1982-07-15 |
US4289642A (en) | 1981-09-15 |
EP0017120B1 (fr) | 1982-06-23 |
DE3060571D1 (en) | 1982-08-12 |
BR8001788A (pt) | 1980-11-18 |
DE2911857A1 (de) | 1980-10-16 |
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