EP0000209B1 - Polarisator für sichtbares Licht bestehend aus einem mit Jod gefärbten Polyvinylalkoholfilm und Verfahren zu seiner Herstellung - Google Patents
Polarisator für sichtbares Licht bestehend aus einem mit Jod gefärbten Polyvinylalkoholfilm und Verfahren zu seiner Herstellung Download PDFInfo
- Publication number
- EP0000209B1 EP0000209B1 EP78200002A EP78200002A EP0000209B1 EP 0000209 B1 EP0000209 B1 EP 0000209B1 EP 78200002 A EP78200002 A EP 78200002A EP 78200002 A EP78200002 A EP 78200002A EP 0000209 B1 EP0000209 B1 EP 0000209B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- iodine
- polyvinyl alcohol
- stained
- staining
- solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000011630 iodine Substances 0.000 title claims description 25
- 229910052740 iodine Inorganic materials 0.000 title claims description 25
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 title claims description 23
- 239000004372 Polyvinyl alcohol Substances 0.000 title claims description 22
- 229920002451 polyvinyl alcohol Polymers 0.000 title claims description 22
- 238000000034 method Methods 0.000 title claims description 14
- NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 claims description 66
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 claims description 30
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 claims description 17
- 238000010521 absorption reaction Methods 0.000 claims description 17
- 239000011592 zinc chloride Substances 0.000 claims description 15
- 235000005074 zinc chloride Nutrition 0.000 claims description 15
- 238000010186 staining Methods 0.000 claims description 14
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 12
- 239000004327 boric acid Substances 0.000 claims description 12
- 239000002344 surface layer Substances 0.000 claims description 10
- 229920002554 vinyl polymer Polymers 0.000 claims description 8
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims description 5
- 239000000243 solution Substances 0.000 description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 15
- 229910001868 water Inorganic materials 0.000 description 15
- 229920006217 cellulose acetate butyrate Polymers 0.000 description 10
- 239000000463 material Substances 0.000 description 10
- 239000000203 mixture Substances 0.000 description 7
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 6
- 239000010410 layer Substances 0.000 description 6
- 230000003287 optical effect Effects 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 5
- 230000015556 catabolic process Effects 0.000 description 4
- 238000006731 degradation reaction Methods 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- IPCXNCATNBAPKW-UHFFFAOYSA-N zinc;hydrate Chemical compound O.[Zn] IPCXNCATNBAPKW-UHFFFAOYSA-N 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000005670 electromagnetic radiation Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 230000005855 radiation Effects 0.000 description 3
- 238000009472 formulation Methods 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 150000007519 polyprotic acids Polymers 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 230000004044 response Effects 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- UAYWVJHJZHQCIE-UHFFFAOYSA-L zinc iodide Chemical compound I[Zn]I UAYWVJHJZHQCIE-UHFFFAOYSA-L 0.000 description 2
- YYPNJNDODFVZLE-UHFFFAOYSA-N 3-methylbut-2-enoic acid Chemical compound CC(C)=CC(O)=O YYPNJNDODFVZLE-UHFFFAOYSA-N 0.000 description 1
- 201000004569 Blindness Diseases 0.000 description 1
- 229920000298 Cellophane Polymers 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- DKNPRRRKHAEUMW-UHFFFAOYSA-N Iodine aqueous Chemical compound [K+].I[I-]I DKNPRRRKHAEUMW-UHFFFAOYSA-N 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 238000002835 absorbance Methods 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000008033 biological extinction Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- -1 for instance Chemical class 0.000 description 1
- 238000007429 general method Methods 0.000 description 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
- 150000002496 iodine Chemical class 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- WRTMQOHKMFDUKX-UHFFFAOYSA-N triiodide Chemical compound I[I-]I WRTMQOHKMFDUKX-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 150000003752 zinc compounds Chemical class 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 239000011686 zinc sulphate Substances 0.000 description 1
- 235000009529 zinc sulphate Nutrition 0.000 description 1
Images
Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/30—Polarising elements
- G02B5/3025—Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state
- G02B5/3033—Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state in the form of a thin sheet or foil, e.g. Polaroid
Definitions
- a highly efficient light polarising element has been prepared which finds utility not only in conventional situations but in some unconventional situations, where as close to absolute extinction as is possible is required in the crossed position as in, for example, flash blindness goggles, such as might be employed by welders and others exposed to sudden bursts of extremely bright visible radiation which is potentially harmful to the eyes.
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Polarising Elements (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Shaping By String And By Release Of Stress In Plastics And The Like (AREA)
- Coloring (AREA)
Claims (5)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US81099677A | 1977-06-29 | 1977-06-29 | |
US810996 | 1977-06-29 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0000209A1 EP0000209A1 (de) | 1979-01-10 |
EP0000209B1 true EP0000209B1 (de) | 1982-02-10 |
Family
ID=25205251
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP78200002A Expired EP0000209B1 (de) | 1977-06-29 | 1978-06-01 | Polarisator für sichtbares Licht bestehend aus einem mit Jod gefärbten Polyvinylalkoholfilm und Verfahren zu seiner Herstellung |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP0000209B1 (de) |
JP (1) | JPS6033245B2 (de) |
AU (1) | AU517329B2 (de) |
DE (1) | DE2861617D1 (de) |
IT (1) | IT1097458B (de) |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5614533A (en) * | 1979-07-16 | 1981-02-12 | Shin Etsu Chem Co Ltd | Production of polarizing film or sheet |
JPH0612362B2 (ja) * | 1983-03-01 | 1994-02-16 | 住友化学工業株式会社 | 耐久性の優れた偏光板 |
US4591512A (en) * | 1985-01-25 | 1986-05-27 | Polaroid Corporation | Method of making light polarizer |
JP2663440B2 (ja) * | 1987-06-12 | 1997-10-15 | 三菱瓦斯化学株式会社 | 偏光フィルムの製造方法 |
JPH02244006A (ja) * | 1989-03-17 | 1990-09-28 | Nippon Kayaku Co Ltd | 位相差フィルム及びその製造法 |
JP4566384B2 (ja) | 2000-10-30 | 2010-10-20 | 日東電工株式会社 | 偏光板 |
JP2002148434A (ja) * | 2000-11-08 | 2002-05-22 | Nitto Denko Corp | 偏光板 |
JP2003029043A (ja) * | 2001-07-19 | 2003-01-29 | Nitto Denko Corp | 偏光子の製造方法、偏光子、偏光板および液晶表示装置 |
JP4043263B2 (ja) | 2002-03-18 | 2008-02-06 | 日東電工株式会社 | 偏光子の製造方法、偏光子、偏光板および画像表示装置 |
KR100938786B1 (ko) | 2002-12-12 | 2010-01-27 | 스미또모 가가꾸 가부시끼가이샤 | 편광 필름의 제조 방법 |
KR100916955B1 (ko) | 2003-04-21 | 2009-09-14 | 닛토덴코 가부시키가이샤 | 편광자, 그 제조 방법, 편광판, 광학 필름 및 화상 표시장치 |
JP2007316366A (ja) * | 2006-05-26 | 2007-12-06 | Nippon Shokubai Co Ltd | 偏光子保護フィルム、偏光板、および画像表示装置 |
JP6049600B2 (ja) | 2013-11-29 | 2016-12-21 | 住友化学株式会社 | 偏光子及びそれを含む偏光板 |
JP5996516B2 (ja) | 2013-11-29 | 2016-09-21 | 住友化学株式会社 | 偏光子及びそれを含む偏光板 |
JP5932760B2 (ja) | 2013-11-29 | 2016-06-08 | 住友化学株式会社 | 偏光子及びそれを含む偏光板 |
EP3454440A1 (de) * | 2017-09-11 | 2019-03-13 | Woertz Engineering AG | Anschlussvorrichtung und elektrische tunnelinstallation |
CN114355497A (zh) * | 2020-10-14 | 2022-04-15 | 恒美光电股份有限公司 | 一种偏光子及其处理方法和制得的偏光片 |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
USRE23297E (en) * | 1950-11-28 | Sheetlike light-polarizing complex | ||
US2328219A (en) * | 1938-10-29 | 1943-08-31 | Polaroid Corp | Light polarizer and process of manufacture |
CH216195A (de) * | 1938-12-09 | 1941-08-15 | Zeiss Ikon Ag | Verfahren zur Herstellung von Polarisationsfiltern. |
US2375963A (en) * | 1943-05-07 | 1945-05-15 | Polaroid Corp | Process of manufacturing lightpolarizing material |
DE1258084B (de) * | 1956-07-02 | 1968-01-04 | Polaroid Corp | Verfahren zur Herstellung gefaerbter, lichtpolarisierender Folien |
-
1978
- 1978-05-19 AU AU36277/78A patent/AU517329B2/en not_active Expired
- 1978-06-01 DE DE7878200002T patent/DE2861617D1/de not_active Expired
- 1978-06-01 EP EP78200002A patent/EP0000209B1/de not_active Expired
- 1978-06-28 JP JP53078504A patent/JPS6033245B2/ja not_active Expired
- 1978-06-29 IT IT25114/78A patent/IT1097458B/it active
Also Published As
Publication number | Publication date |
---|---|
AU517329B2 (en) | 1981-07-23 |
IT1097458B (it) | 1985-08-31 |
AU3627778A (en) | 1979-11-22 |
JPS5416575A (en) | 1979-02-07 |
DE2861617D1 (en) | 1982-03-18 |
EP0000209A1 (de) | 1979-01-10 |
JPS6033245B2 (ja) | 1985-08-01 |
IT7825114A0 (it) | 1978-06-29 |
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Legal Events
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PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
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