EA201491942A1 - Способ очистки газовых смесей, содержащих кислые газы - Google Patents

Способ очистки газовых смесей, содержащих кислые газы

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Publication number
EA201491942A1
EA201491942A1 EA201491942A EA201491942A EA201491942A1 EA 201491942 A1 EA201491942 A1 EA 201491942A1 EA 201491942 A EA201491942 A EA 201491942A EA 201491942 A EA201491942 A EA 201491942A EA 201491942 A1 EA201491942 A1 EA 201491942A1
Authority
EA
Eurasian Patent Office
Prior art keywords
absorbent solution
relative
total mass
activator
tertiary amine
Prior art date
Application number
EA201491942A
Other languages
English (en)
Other versions
EA027606B1 (ru
Inventor
Клер Вайс
Рено Кадур
Цзин Чжао
Виренкумар Ша
Original Assignee
Тоталь С.А.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Тоталь С.А. filed Critical Тоталь С.А.
Publication of EA201491942A1 publication Critical patent/EA201491942A1/ru
Publication of EA027606B1 publication Critical patent/EA027606B1/ru

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1493—Selection of liquid materials for use as absorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1425—Regeneration of liquid absorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1456—Removing acid components
    • B01D53/1462—Removing mixtures of hydrogen sulfide and carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
    • C10L3/10—Working-up natural gas or synthetic natural gas
    • C10L3/101—Removal of contaminants
    • C10L3/102—Removal of contaminants of acid contaminants
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
    • C10L3/10—Working-up natural gas or synthetic natural gas
    • C10L3/101—Removal of contaminants
    • C10L3/102—Removal of contaminants of acid contaminants
    • C10L3/103—Sulfur containing contaminants
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
    • C10L3/10—Working-up natural gas or synthetic natural gas
    • C10L3/101—Removal of contaminants
    • C10L3/102—Removal of contaminants of acid contaminants
    • C10L3/104—Carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/12—Liquefied petroleum gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/10—Inorganic absorbents
    • B01D2252/103—Water
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/202—Alcohols or their derivatives
    • B01D2252/2023—Glycols, diols or their derivatives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20431—Tertiary amines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20436—Cyclic amines
    • B01D2252/20447—Cyclic amines containing a piperazine-ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20478—Alkanolamines
    • B01D2252/20489—Alkanolamines with two or more hydroxyl groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/205—Other organic compounds not covered by B01D2252/00 - B01D2252/20494
    • B01D2252/2056—Sulfur compounds, e.g. Sulfolane, thiols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/50—Combinations of absorbents
    • B01D2252/504—Mixtures of two or more absorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/60—Additives
    • B01D2252/602—Activators, promoting agents, catalytic agents or enzymes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/30—Sulfur compounds
    • B01D2257/306—Organic sulfur compounds, e.g. mercaptans
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/30—Sulfur compounds
    • B01D2257/308—Carbonoxysulfide COS
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/54—Specific separation steps for separating fractions, components or impurities during preparation or upgrading of a fuel
    • C10L2290/541—Absorption of impurities during preparation or upgrading of a fuel

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Gas Separation By Absorption (AREA)
  • Treating Waste Gases (AREA)

Abstract

Способ очистки газовой смеси, содержащей кислые газы, такой как природный газ, включающий стадию приведения в контакт газовой смеси с абсорбирующим раствором, содержащим следующие компоненты, предпочтительно состоящим из них: от 35 до 45 мас.% по меньшей мере одного третичного амина относительно суммарной массы абсорбирующего раствора; от 4 до 12 мас.% по меньшей мере одного активатора относительно суммарной массы абсорбирующего раствора, выбранного из первичных аминов и вторичных аминов; причем суммарное содержание третичного амина и активатора составляет от 38 до 50 мас.% относительно суммарной массы абсорбирующего раствора, и суммарная концентрация третичного амина и активатора составляет от 3,8 до 4,2 моль/л; от 17 до 25 мас.% по меньшей мере одного C-Cтиоалканола относительно суммарной массы абсорбирующего раствора; и остальное составляет вода до достижения 100 мас.%. Абсорбирующий раствор, применяемый при данном способе.
EA201491942A 2012-05-25 2013-05-23 Способ очистки газовых смесей, содержащих кислые газы EA027606B1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1254844A FR2990878B1 (fr) 2012-05-25 2012-05-25 Procede de purification de melanges gazeux contenant des gaz acides.
PCT/EP2013/060586 WO2013174907A1 (fr) 2012-05-25 2013-05-23 Procede de purification de melanges gazeux contenant des gaz acides

Publications (2)

Publication Number Publication Date
EA201491942A1 true EA201491942A1 (ru) 2015-04-30
EA027606B1 EA027606B1 (ru) 2017-08-31

Family

ID=48485184

Family Applications (1)

Application Number Title Priority Date Filing Date
EA201491942A EA027606B1 (ru) 2012-05-25 2013-05-23 Способ очистки газовых смесей, содержащих кислые газы

Country Status (9)

Country Link
US (1) US10071339B2 (ru)
CN (1) CN104334252A (ru)
BR (1) BR112014028972B1 (ru)
CA (1) CA2874362C (ru)
EA (1) EA027606B1 (ru)
FR (1) FR2990878B1 (ru)
MY (1) MY180805A (ru)
NO (1) NO20141524A1 (ru)
WO (1) WO2013174907A1 (ru)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3247484B1 (en) * 2015-01-22 2023-09-20 Carbon Clean Solutions Limited Solvent and method for removing acid gases from a gaseous mixture
CA2991180C (en) * 2015-07-03 2019-04-23 Dorf Ketal Chemicals (India) Private Limited Hydrogen sulfide scavenging additive compositions, and medium comprising the same
WO2017165339A1 (en) * 2016-03-21 2017-09-28 Board Of Regents, The University Of Texas System Blends of thermally degraded amines for co2 capture
CN107433108A (zh) * 2016-05-26 2017-12-05 中国石油化工股份有限公司 一种用于炼厂催化干气中脱硫脱碳的吸收溶剂
CN110385022B (zh) * 2018-04-19 2022-07-15 中国石油化工股份有限公司 脱硫剂及其应用和轻烃脱硫加工的方法
CN115253600B (zh) * 2022-08-08 2024-03-05 华北电力大学（保定） 一种具有良好循环解吸稳定性、低腐蚀性的相变吸收剂的制备与应用
CN115178057A (zh) * 2022-08-08 2022-10-14 北京清新环境技术股份有限公司 一种二氧化碳的化学吸收剂及其制备方法、应用和再生方法

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US3864460A (en) 1973-07-12 1975-02-04 Nrg Inc Method for removing hydrogen sulfide from hydrocarbon gas streams without pollution of the atmosphere
FR2328657A1 (fr) 1975-10-21 1977-05-20 Elf Aquitaine Procede d'enrichissement en h2s des gaz acides
DE2551717C3 (de) * 1975-11-18 1980-11-13 Basf Ag, 6700 Ludwigshafen und ggf. COS aus Gasen
DE2828498A1 (de) 1978-06-29 1980-01-17 Linde Ag Verfahren und vorrichtung zur zerlegung eines gasgemisches
IT1132170B (it) 1980-07-04 1986-06-25 Snam Progetti Processo di separazione selettiva di idrogeno solforato da miscele gassose contenenti anche anidride carbonica
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ES2054049T5 (es) 1988-05-24 1997-12-16 Elf Aquitaine Liquido absorbente de gases acidos que contiene una alcanol-amina terciaria y un activador de absorcion del co2, y su aplicacion a la desacidificacion de gas conteniendo co2 y eventualmente otros gases acidos.
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FR2896244B1 (fr) 2006-01-18 2013-04-12 Total Sa Procede de purification de melanges gazeux contenant des mercaptans et autres gaz acides
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FR2947185B1 (fr) 2009-06-26 2011-07-01 Total Sa Procede de traitement de gaz acides

Also Published As

Publication number Publication date
US20150139877A1 (en) 2015-05-21
BR112014028972B1 (pt) 2020-12-29
FR2990878B1 (fr) 2014-05-16
CA2874362A1 (fr) 2013-11-28
NO20141524A1 (no) 2014-12-17
EA027606B1 (ru) 2017-08-31
BR112014028972A2 (pt) 2017-07-25
CN104334252A (zh) 2015-02-04
MY180805A (en) 2020-12-09
US10071339B2 (en) 2018-09-11
FR2990878A1 (fr) 2013-11-29
WO2013174907A1 (fr) 2013-11-28
CA2874362C (fr) 2020-07-14

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