EA201400045A1 - Способ получения валеролактона из левулиновой кислоты - Google Patents

Способ получения валеролактона из левулиновой кислоты

Info

Publication number
EA201400045A1
EA201400045A1 EA201400045A EA201400045A EA201400045A1 EA 201400045 A1 EA201400045 A1 EA 201400045A1 EA 201400045 A EA201400045 A EA 201400045A EA 201400045 A EA201400045 A EA 201400045A EA 201400045 A1 EA201400045 A1 EA 201400045A1
Authority
EA
Eurasian Patent Office
Prior art keywords
levulinic acid
valerolactone
valerolacton
obtaining
adipic acid
Prior art date
Application number
EA201400045A
Other languages
English (en)
Other versions
EA025474B1 (ru
Inventor
Анна Мария Корнелия Франсиска Кастелейнс
Михеле Катерине Христианне Янсен
Хенрикус Вилхельмус Леонардус Мария Вассен
Original Assignee
ДСМ АйПи АССЕТС Б.В.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ДСМ АйПи АССЕТС Б.В. filed Critical ДСМ АйПи АССЕТС Б.В.
Publication of EA201400045A1 publication Critical patent/EA201400045A1/ru
Publication of EA025474B1 publication Critical patent/EA025474B1/ru

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/26—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
    • C07D307/30—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D307/32—Oxygen atoms
    • C07D307/33—Oxygen atoms in position 2, the oxygen atom being in its keto or unsubstituted enol form

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Polyamides (AREA)
  • Furan Compounds (AREA)

Abstract

Изобретение относится к способу получения валеролактона, включающему взаимодействие левулиновой кислоты с водородом при использовании твердого Ru катализатора, отличающемуся тем, что способ осуществляют в присутствии по меньшей мере 0,08% (мас./мас.) воды относительно количества левулиновой кислоты. Указанный способ может быть более быстрым и более селективным. Данный способ выгодно допускает получение валеролактона из возобновляемых источников. Валеролактон может быть использован при получении метилпентаноата, диметилового эфира адипиновой кислоты, адипиновой кислоты, гексаметилендиамина и полиамида 6,6.
EA201400045A 2011-06-21 2012-06-18 Способ получения валеролактона из левулиновой кислоты EA025474B1 (ru)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201161499438P 2011-06-21 2011-06-21
EP11170809 2011-06-21
PCT/EP2012/061558 WO2012175439A1 (en) 2011-06-21 2012-06-18 Process to produce valerolactone from levulinic acid

Publications (2)

Publication Number Publication Date
EA201400045A1 true EA201400045A1 (ru) 2014-05-30
EA025474B1 EA025474B1 (ru) 2016-12-30

Family

ID=47220247

Family Applications (1)

Application Number Title Priority Date Filing Date
EA201400045A EA025474B1 (ru) 2011-06-21 2012-06-18 Способ получения валеролактона из левулиновой кислоты

Country Status (10)

Country Link
US (1) US8598303B2 (ru)
EP (1) EP2537840B1 (ru)
JP (1) JP2014524905A (ru)
CN (1) CN103619826B (ru)
BR (1) BR102012015623B1 (ru)
CA (1) CA2839137A1 (ru)
EA (1) EA025474B1 (ru)
MY (1) MY163070A (ru)
PL (1) PL2537840T3 (ru)
WO (1) WO2012175439A1 (ru)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AR088124A1 (es) * 2011-04-01 2014-05-14 Dsm Ip Assets Bv Proceso para la preparacion de esteres de acido alcanoico en un proceso de carbonilacion utilizando ligandos de bifosfato bidentados de paladio
US20160031790A1 (en) * 2013-03-15 2016-02-04 Segetis, Inc. Method of manufacture of octanedioic acid, precursors, and derivatives
WO2016131821A1 (en) * 2015-02-18 2016-08-25 Dsm Ip Assets B.V. Hydrogenation of levulinic acid (la) to gamma-valerolactone (gvl) with a ruthenium (ru) catalyst pre-treated with hydrogen in water
WO2016135009A1 (en) 2015-02-24 2016-09-01 Dsm Ip Assets B.V. Process for the preparation of gamma valerolactone from levulinic acid
WO2017061865A1 (en) 2015-10-06 2017-04-13 Avantium Knowledge Centre B.V. Process for the preparation of gamma-valerolactone
JP6558446B2 (ja) 2015-11-16 2019-08-14 宇部興産株式会社 γ−バレロラクトンの製造方法
FI127191B (en) 2015-12-23 2018-01-15 Neste Oyj Co-production of levulinic acid and furfural from biomass
FI127020B (en) 2015-12-23 2017-09-29 Neste Oyj Selective process for the conversion of levulinic acid to gamma valerolactone
CN107824180A (zh) * 2017-08-25 2018-03-23 昆山普瑞凯纳米技术有限公司 一种用于乙酰丙酸加氢的负载型纳米金属催化剂的制备方法
CN112739773A (zh) * 2018-08-01 2021-04-30 布拉斯科美国有限责任公司 具有改善的韧性的热塑性组合物、由其制成的制品及其方法
CN113828339B (zh) * 2020-06-08 2023-08-29 中国石油大学(北京) 一种M-Co单原子合金催化剂及其制备方法与应用

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2368366A (en) * 1942-08-21 1945-01-30 Monsanto Chemicals Process for the production of lactones
US2786852A (en) * 1953-08-19 1957-03-26 Quaker Oats Co Process of preparing gammavalerolactone
GB896949A (en) * 1957-12-14 1962-05-23 Basf Ag Improvements in the production of proto-anemonin and its homologues
US3065263A (en) 1959-11-17 1962-11-20 Rayonier Inc Process for the manufacture of levulinic acid
NL8103173A (nl) * 1981-07-02 1983-02-01 Stamicarbon Werkwijze voor de bereiding van een 5-alkyl-butyrolacton.
DE3609139A1 (de) 1986-03-19 1987-09-24 Basf Ag Verfahren zur herstellung von 4-pentensaeureestern
US4897497A (en) 1988-04-26 1990-01-30 Biofine Incorporated Lignocellulose degradation to furfural and levulinic acid
US5608105A (en) 1995-06-07 1997-03-04 Biofine Incorporated Production of levulinic acid from carbohydrate-containing materials
US5883266A (en) * 1998-01-16 1999-03-16 Battelle Memorial Institute Hydrogenated 5-carbon compound and method of making
MY127358A (en) 2000-03-14 2006-11-30 Shell Int Research Process for the carbonylation of ethylenically unsaturated compounds
EP1368333A1 (en) * 2001-03-16 2003-12-10 E.I. Dupont De Nemours And Company Production of 5-methylbutyrolactone from levulinic acid
US6835849B2 (en) 2002-07-15 2004-12-28 E. I. Du Pont De Nemours And Company Synthesis of alkenoate esters from lactones and alcohols
US6946563B2 (en) * 2003-06-16 2005-09-20 E. I. Du Pont De Nemours And Company Production of 5-methyl-dihydro-furan-2-one from levulinic acid in supercritical media
EP1699750B1 (en) 2003-12-19 2013-11-06 Shell Internationale Research Maatschappij B.V. A process for the preparation of an alkyl alkenoate
JP2008525372A (ja) * 2004-12-23 2008-07-17 シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ ラクトン、或いはγ−カルボニル基を含有する、カルボン酸又はエステルの水素化法
BRPI0811547A2 (pt) * 2007-05-22 2014-11-18 Shell Int Research Processo para converter ácido levulínico em ácido pentanóico
CN101376650B (zh) * 2008-09-08 2013-04-03 中国科学技术大学 一种以乙酰丙酸和甲酸直接制备γ-戊内酯的方法
EP2373637B1 (de) * 2008-12-05 2013-05-22 Basf Se Verfahren zur herstellung von delta-valerolacton in der gasphase
US8148553B2 (en) * 2009-06-23 2012-04-03 Wisconsin Alumni Research Foundation Catalytic conversion of cellulose to liquid hydrocarbon fuels by progressive removal of oxygen to facilitate separation processes and achieve high selectivities

Also Published As

Publication number Publication date
EP2537840A1 (en) 2012-12-26
WO2012175439A1 (en) 2012-12-27
EP2537840B1 (en) 2013-07-24
BR102012015623B1 (pt) 2014-12-30
MY163070A (en) 2017-08-15
JP2014524905A (ja) 2014-09-25
CN103619826A (zh) 2014-03-05
US8598303B2 (en) 2013-12-03
CA2839137A1 (en) 2012-12-27
US20120329981A1 (en) 2012-12-27
CN103619826B (zh) 2015-09-23
PL2537840T3 (pl) 2013-12-31
EA025474B1 (ru) 2016-12-30

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Legal Events

Date Code Title Description
MM4A Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s)

Designated state(s): AM AZ BY KZ KG TJ TM RU