EA201400498A1 - Способ получения синтез-газа для производства метанола - Google Patents
Способ получения синтез-газа для производства метанолаInfo
- Publication number
- EA201400498A1 EA201400498A1 EA201400498A EA201400498A EA201400498A1 EA 201400498 A1 EA201400498 A1 EA 201400498A1 EA 201400498 A EA201400498 A EA 201400498A EA 201400498 A EA201400498 A EA 201400498A EA 201400498 A1 EA201400498 A1 EA 201400498A1
- Authority
- EA
- Eurasian Patent Office
- Prior art keywords
- methanol
- synthesis gas
- stream
- production
- relates
- Prior art date
Links
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/22—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds
- C01B3/24—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons
- C01B3/26—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons using catalysts
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/22—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds
- C01B3/24—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons
- C01B3/28—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons using moving solid particles
- C01B3/30—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons using moving solid particles using the fluidised bed technique
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/386—Catalytic partial combustion
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/48—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents followed by reaction of water vapour with carbon monoxide
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
- C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
- C07C29/1516—Multisteps
- C07C29/1518—Multisteps one step being the formation of initial mixture of carbon oxides and hydrogen for synthesis
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
- C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
- C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
- C01B2203/0261—Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a catalytic partial oxidation step [CPO]
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/042—Purification by adsorption on solids
- C01B2203/043—Regenerative adsorption process in two or more beds, one for adsorption, the other for regeneration
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
- C01B2203/0475—Composition of the impurity the impurity being carbon dioxide
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/06—Integration with other chemical processes
- C01B2203/061—Methanol production
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1205—Composition of the feed
- C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
- C01B2203/1235—Hydrocarbons
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/14—Details of the flowsheet
- C01B2203/141—At least two reforming, decomposition or partial oxidation steps in parallel
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/14—Details of the flowsheet
- C01B2203/142—At least two reforming, decomposition or partial oxidation steps in series
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Настоящее изобретение относится к способу получения синтез-газа из углеводородсодержащего сырья, причем этот синтез-газ является особенно подходящим для последующего применения в производстве метанола. В этом способе сырье (100) разделяют на два потока, где один поток подвергают каталитическому парциальному окислению (КПО) (2), а другой поток подвергают реформингу с водяным паром с последующим процессом конверсии (51) водяного газа. Затем оба потока снова объединяют и в дальнейшем поток можно использовать в синтезе метанола. Предпочтительно рекомбинированный поток имеет параметр R, который означает молярное соотношение (Н-СО)/(СО+СО), в диапазоне 1,9-2,2 и предпочтительно около 2. Кроме того, изобретение относится к способу получения метанола из углеводородсодержащего сырья, в котором первый синтез-газ получают по способу изобретения, причем этот синтез-газ в дальнейшем используется для производства метанола. Кроме того, изобретение относится к способу модернизации существующего метанольного завода для процесса производства метанола согласно изобретению.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP11186764 | 2011-10-26 | ||
PCT/NL2012/050748 WO2013062415A1 (en) | 2011-10-26 | 2012-10-26 | Method for producing synthesis gas for methanol production |
Publications (2)
Publication Number | Publication Date |
---|---|
EA201400498A1 true EA201400498A1 (ru) | 2014-09-30 |
EA026825B1 EA026825B1 (ru) | 2017-05-31 |
Family
ID=47144031
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EA201400498A EA026825B1 (ru) | 2011-10-26 | 2012-10-26 | Способ получения синтез-газа для производства метанола |
Country Status (7)
Country | Link |
---|---|
US (1) | US9102532B2 (ru) |
EP (1) | EP2771275B1 (ru) |
CN (1) | CN103889891B (ru) |
CA (1) | CA2853421C (ru) |
DK (1) | DK2771275T3 (ru) |
EA (1) | EA026825B1 (ru) |
WO (1) | WO2013062415A1 (ru) |
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2016016253A1 (en) * | 2014-07-29 | 2016-02-04 | Eni S.P.A. | Integrated short contact time catalytic partial oxidation/gas heated reforming process for the production of synthesis gas |
EA201791153A1 (ru) * | 2014-11-25 | 2017-11-30 | Хальдор Топсёэ А/С | Способ получения синтез-газа посредством рециркуляции газообразных продуктов горения |
PT3844135T (pt) | 2018-08-29 | 2022-10-06 | Eni Spa | Processo e sistema para a síntese do metanol |
CA3112531A1 (en) * | 2018-09-19 | 2020-03-26 | Eni S.P.A. | Process for the production of methanol from gaseous hydrocarbons |
WO2020142489A1 (en) * | 2019-01-02 | 2020-07-09 | Sabic Global Technologies, B.V. | Hydrogen enrichment in syngas produced via catalytic partial oxidation |
US20220081380A1 (en) * | 2019-01-17 | 2022-03-17 | Eni S.P.A. | Methanol production process from syngas produced by catalytic partial oxidation integrated with cracking |
AU2020208782A1 (en) * | 2019-01-18 | 2021-06-10 | Haldor Topsøe A/S | Method for the preparation of methanol synthesis gas |
CN113574040B (zh) * | 2019-01-21 | 2023-12-01 | 埃尼股份公司 | 甲醇生产方法 |
WO2020161667A1 (en) * | 2019-02-06 | 2020-08-13 | Sabic Global Technologies, B.V. | Methanol production process with increased energy efficiency |
WO2022235334A1 (en) * | 2021-05-03 | 2022-11-10 | Utility Global, Inc. | Hydrogen production system and method of use |
US11718575B2 (en) | 2021-08-12 | 2023-08-08 | Saudi Arabian Oil Company | Methanol production via dry reforming and methanol synthesis in a vessel |
US11578016B1 (en) | 2021-08-12 | 2023-02-14 | Saudi Arabian Oil Company | Olefin production via dry reforming and olefin synthesis in a vessel |
US11787759B2 (en) | 2021-08-12 | 2023-10-17 | Saudi Arabian Oil Company | Dimethyl ether production via dry reforming and dimethyl ether synthesis in a vessel |
US11617981B1 (en) | 2022-01-03 | 2023-04-04 | Saudi Arabian Oil Company | Method for capturing CO2 with assisted vapor compression |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA1263671A (en) | 1986-02-10 | 1989-12-05 | David Leon Banquy | Process for the production of synthesis gas |
EP0522744B1 (en) * | 1991-07-09 | 1997-08-13 | Imperial Chemical Industries Plc | Synthesis gas production |
IT1272532B (it) | 1993-08-27 | 1997-06-23 | Snam Progetti | Processo di ossidazione parziale catalitica del gas naturale per ottenere gas di sintesi e formaldeide |
IT1283585B1 (it) | 1996-04-11 | 1998-04-22 | Snam Progetti | Apparecchiatura per effettuare reazioni di ossidazione parziale |
CN1307539A (zh) | 1998-06-30 | 2001-08-08 | 国际壳牌研究有限公司 | 采用两种催化活性金属的催化部分氧化 |
CA2389105A1 (en) | 1999-10-29 | 2001-05-10 | Lanny D. Schmidt | Process for catalytic partial oxidation using particulate catalysts |
AU1767901A (en) | 1999-11-17 | 2001-05-30 | Conoco Inc. | Cobalt-based catalysts and process for producing synthesis gas |
EP1219566A1 (en) * | 2000-12-27 | 2002-07-03 | L'air Liquide, S.A. à Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procédés Georges Claude | Integrated process and installation for the production of synthesis gas |
US20040171701A1 (en) * | 2001-11-02 | 2004-09-02 | Technology Convergence Inc. | Methanol production process |
US6797252B2 (en) * | 2002-11-25 | 2004-09-28 | Conocophillips Company | Hydrocarbon gas to liquid conversion process |
US7932296B2 (en) * | 2003-03-16 | 2011-04-26 | Kellogg Brown & Root Llc | Catalytic partial oxidation reforming for syngas processing and products made therefrom |
WO2006117499A1 (en) | 2005-05-03 | 2006-11-09 | Quartey-Papafio Alexander H | Synthesis gas production process |
US7485767B2 (en) * | 2005-06-29 | 2009-02-03 | Exxonmobil Chemical Patents Inc. | Production of synthesis gas blends for conversion to methanol or Fischer-Tropsch liquids |
EP2199254A1 (en) * | 2008-12-11 | 2010-06-23 | BP p.l.c. | Integrated gas refinery |
WO2011018233A1 (en) * | 2009-08-14 | 2011-02-17 | Saudi Basic Industries Corporation (Sabic) | Combined reforming process for methanol production |
IT1398292B1 (it) * | 2009-12-16 | 2013-02-22 | Eni Spa | Processo per la produzione di idrogeno a partire da idrocarburi liquidi, idrocarburi gassosi e/o composti ossigenati anche derivanti da biomasse |
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2012
- 2012-10-26 WO PCT/NL2012/050748 patent/WO2013062415A1/en active Application Filing
- 2012-10-26 CN CN201280053004.5A patent/CN103889891B/zh active Active
- 2012-10-26 CA CA2853421A patent/CA2853421C/en active Active
- 2012-10-26 US US14/354,536 patent/US9102532B2/en active Active
- 2012-10-26 EP EP12783359.8A patent/EP2771275B1/en active Active
- 2012-10-26 EA EA201400498A patent/EA026825B1/ru not_active IP Right Cessation
- 2012-10-26 DK DK12783359.8T patent/DK2771275T3/da active
Also Published As
Publication number | Publication date |
---|---|
CN103889891B (zh) | 2016-09-14 |
CA2853421A1 (en) | 2013-05-02 |
EA026825B1 (ru) | 2017-05-31 |
US9102532B2 (en) | 2015-08-11 |
WO2013062415A1 (en) | 2013-05-02 |
EP2771275B1 (en) | 2019-07-24 |
CA2853421C (en) | 2019-04-23 |
DK2771275T3 (da) | 2019-08-19 |
CN103889891A (zh) | 2014-06-25 |
US20150087865A1 (en) | 2015-03-26 |
EP2771275A1 (en) | 2014-09-03 |
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