EA201170534A1 - Способ получения железа прямого восстановления - Google Patents

Способ получения железа прямого восстановления

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Publication number
EA201170534A1
EA201170534A1 EA201170534A EA201170534A EA201170534A1 EA 201170534 A1 EA201170534 A1 EA 201170534A1 EA 201170534 A EA201170534 A EA 201170534A EA 201170534 A EA201170534 A EA 201170534A EA 201170534 A1 EA201170534 A1 EA 201170534A1
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EA
Eurasian Patent Office
Prior art keywords
gas
reactor
accordance
conversion
carbon dioxide
Prior art date
Application number
EA201170534A
Other languages
English (en)
Other versions
EA017978B1 (ru
Inventor
Клаус Кноп
Стен Онгстрем
Original Assignee
Луоссаваара-Киирунаваара Аб
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Луоссаваара-Киирунаваара Аб filed Critical Луоссаваара-Киирунаваара Аб
Publication of EA201170534A1 publication Critical patent/EA201170534A1/ru
Publication of EA017978B1 publication Critical patent/EA017978B1/ru

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21B—MANUFACTURE OF IRON OR STEEL
    • C21B13/00—Making spongy iron or liquid steel, by direct processes
    • C21B13/02—Making spongy iron or liquid steel, by direct processes in shaft furnaces
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21B—MANUFACTURE OF IRON OR STEEL
    • C21B13/00—Making spongy iron or liquid steel, by direct processes
    • C21B13/02—Making spongy iron or liquid steel, by direct processes in shaft furnaces
    • C21B13/029—Introducing coolant gas in the shaft furnaces
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21B—MANUFACTURE OF IRON OR STEEL
    • C21B13/00—Making spongy iron or liquid steel, by direct processes
    • C21B13/0046—Making spongy iron or liquid steel, by direct processes making metallised agglomerates or iron oxide
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21B—MANUFACTURE OF IRON OR STEEL
    • C21B13/00—Making spongy iron or liquid steel, by direct processes
    • C21B13/0073—Selection or treatment of the reducing gases
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/50—Carbon oxides
    • B01D2257/504—Carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21B—MANUFACTURE OF IRON OR STEEL
    • C21B2100/00—Handling of exhaust gases produced during the manufacture of iron or steel
    • C21B2100/20—Increasing the gas reduction potential of recycled exhaust gases
    • C21B2100/24—Increasing the gas reduction potential of recycled exhaust gases by shift reactions
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21B—MANUFACTURE OF IRON OR STEEL
    • C21B2100/00—Handling of exhaust gases produced during the manufacture of iron or steel
    • C21B2100/20—Increasing the gas reduction potential of recycled exhaust gases
    • C21B2100/26—Increasing the gas reduction potential of recycled exhaust gases by adding additional fuel in recirculation pipes
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21B—MANUFACTURE OF IRON OR STEEL
    • C21B2100/00—Handling of exhaust gases produced during the manufacture of iron or steel
    • C21B2100/20—Increasing the gas reduction potential of recycled exhaust gases
    • C21B2100/28—Increasing the gas reduction potential of recycled exhaust gases by separation
    • C21B2100/282—Increasing the gas reduction potential of recycled exhaust gases by separation of carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21B—MANUFACTURE OF IRON OR STEEL
    • C21B2100/00—Handling of exhaust gases produced during the manufacture of iron or steel
    • C21B2100/20—Increasing the gas reduction potential of recycled exhaust gases
    • C21B2100/28—Increasing the gas reduction potential of recycled exhaust gases by separation
    • C21B2100/284—Increasing the gas reduction potential of recycled exhaust gases by separation of nitrogen
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21B—MANUFACTURE OF IRON OR STEEL
    • C21B2100/00—Handling of exhaust gases produced during the manufacture of iron or steel
    • C21B2100/40—Gas purification of exhaust gases to be recirculated or used in other metallurgical processes
    • C21B2100/44—Removing particles, e.g. by scrubbing, dedusting
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21B—MANUFACTURE OF IRON OR STEEL
    • C21B2100/00—Handling of exhaust gases produced during the manufacture of iron or steel
    • C21B2100/60—Process control or energy utilisation in the manufacture of iron or steel
    • C21B2100/66—Heat exchange
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/10—Reduction of greenhouse gas [GHG] emissions
    • Y02P10/122—Reduction of greenhouse gas [GHG] emissions by capturing or storing CO2
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/10—Reduction of greenhouse gas [GHG] emissions
    • Y02P10/134—Reduction of greenhouse gas [GHG] emissions by avoiding CO2, e.g. using hydrogen
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/10—Reduction of greenhouse gas [GHG] emissions
    • Y02P10/143—Reduction of greenhouse gas [GHG] emissions of methane [CH4]

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Manufacture Of Iron (AREA)
  • Waste-Gas Treatment And Other Accessory Devices For Furnaces (AREA)
  • Hydrogen, Water And Hydrids (AREA)

Abstract

Настоящее изобретение относится к способу прямого восстановления железной руды, выполняемому посредством агрегата, включающего гравитационную печь (2), которая имеет по меньшей мере одну зону (8) восстановления железной руды в верхней части вышеупомянутого и по меньшей мере одну зону (9) отложения углерода и одну зону (10) охлаждения восстановленного металла в нижней части вышеупомянутого и средства загрузки восстановительной газовой смеси в реактор в соответствии с зоной восстановления, средства для повторного использования выпуска или отходящего из реактора реакторного газа для синтез-газа и смешивание рециркулирующего газа с природным газом для образования восстановительной газовой смеси. В соответствии с изобретением на первой стадии (5) преобразования не вступивший в реакцию моноксид углерода СО и пар, присутствующий в отходящем реакторном газе, преобразуют в двуокись углерода и водорода в соответствии с реакцией конверсии водяного газа СО+HO=CO+Н, на второй стадии преобразования обезвоженный отходящий реакторный газ, включающий в основном диоксид углерода и водород, обрабатывают для удаления диоксида углерода и на третьей стадии преобразования выполняют физическое разделение и азота, и оксида углерода от восстановительного синтез-газа для снижения уровней СО и любых существующих в рециркулирующем газе других газов до такого низкого уровня, насколько это возможно, чтобы рециркулирующий восстановительный газ являлся насколько это возможно приближенным к чистому водороду H.
EA201170534A 2008-10-06 2009-09-22 Способ получения железа прямого восстановления EA017978B1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
SE0802100A SE532975C2 (sv) 2008-10-06 2008-10-06 Förfarande för produktion av direktreducerat järn
PCT/SE2009/051049 WO2010042023A1 (en) 2008-10-06 2009-09-22 Process for production of direct reduced iron

Publications (2)

Publication Number Publication Date
EA201170534A1 true EA201170534A1 (ru) 2011-10-31
EA017978B1 EA017978B1 (ru) 2013-04-30

Family

ID=42100796

Family Applications (1)

Application Number Title Priority Date Filing Date
EA201170534A EA017978B1 (ru) 2008-10-06 2009-09-22 Способ получения железа прямого восстановления

Country Status (13)

Country Link
US (1) US8709128B2 (ru)
EP (1) EP2347018A4 (ru)
KR (1) KR101587199B1 (ru)
CN (1) CN102232119B (ru)
AU (1) AU2009302946B2 (ru)
BR (1) BRPI0920029B1 (ru)
CA (1) CA2739577A1 (ru)
EA (1) EA017978B1 (ru)
MX (1) MX2011003644A (ru)
MY (1) MY153906A (ru)
SE (1) SE532975C2 (ru)
UA (1) UA105772C2 (ru)
WO (1) WO2010042023A1 (ru)

Families Citing this family (43)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2546266C2 (ru) * 2009-07-31 2015-04-10 Хил Текнолоджиз, С.А. Де К.В. Способ производства железа прямого восстановления с ограниченными выбросами со2 в атмосферу
AT510177B1 (de) * 2010-07-20 2012-05-15 Siemens Vai Metals Tech Gmbh Verfahren zur reinigung eines mit stäuben beladenen gasstroms
AT510618B1 (de) * 2010-11-04 2013-02-15 Siemens Vai Metals Tech Gmbh Verfahren zur entfernung von co2 aus abgasen
FR2968575A1 (fr) * 2010-12-08 2012-06-15 Air Liquide Procede et appareil de production d'un fluide enrichi en dioxyde de carbone a partir d'un gaz residuaire d'une unite siderurgique
DE102011002615A1 (de) 2011-01-13 2012-07-19 Siemens Aktiengesellschaft Verfahren zur Behandlung eines kohlendioxidhaltigen Abgases aus einem Elektroschmelzprozess
AT511243B1 (de) * 2011-03-17 2013-01-15 Siemens Vai Metals Tech Gmbh Hüttentechnische anlage mit effizienter abwärmenutzung
WO2013013295A1 (en) * 2011-07-26 2013-01-31 Hatch Ltd. Improved process for direct reduction of iron oxide
AT511892B1 (de) * 2011-08-31 2013-07-15 Siemens Vai Metals Tech Gmbh Verfahren zur aufbereitung von abgasen aus anlagen zur roheisenherstellung und/oder von synthesegas
AT511992B1 (de) * 2011-09-29 2013-12-15 Siemens Vai Metals Tech Gmbh Verfahren und vorrichtung zur herstellung von wasserstoff aus bei der roheisenerzeugung anfallenden gasen
EP2574683A1 (en) * 2011-09-29 2013-04-03 L'Air Liquide Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude Ironmaking process and installation
JP2013108108A (ja) * 2011-11-17 2013-06-06 Mitsubishi Heavy Ind Ltd 直接還元鉄製造システム
JP2013108109A (ja) * 2011-11-17 2013-06-06 Mitsubishi Heavy Ind Ltd 直接還元鉄製造システム
EP2626124A1 (de) * 2012-02-13 2013-08-14 Siemens VAI Metals Technologies GmbH Verfahren und Vorrichtung zur Reduktion von eisenoxidhaltigen Einsatzstoffen
EP2628805A1 (de) * 2012-02-14 2013-08-21 Siemens VAI Metals Technologies GmbH Verfahren und Vorrichtung zur Reduktion von eisenoxidhältigen Einsatzstoffen in einem Hochdruckreduktionsaggregat
US8709131B2 (en) 2012-02-15 2014-04-29 Midrex Technologies, Inc. Method and system for the production of direct reduced iron using a synthesis gas with a high carbon monoxide content
KR20140115350A (ko) * 2012-02-15 2014-09-30 미드렉스 테크놀리지스, 인코오포레이티드 높은 일산화탄소 함유량을 갖는 합성가스를 이용하는 직접환원철의 제조방법 및 그 시스템
CN102620569B (zh) * 2012-03-09 2013-03-13 唐山京兆科技开发有限公司 一种工业炉窑资源循环利用系统
KR101321930B1 (ko) * 2012-06-07 2013-10-28 주식회사 포스코 환원철 제조장치 및 이를 이용한 환원철 제조방법
GB2507246A (en) * 2012-07-31 2014-04-30 David Andrew Johnston Direct reduction of iron using a carbon monoxide-hydrogen mixture derived from carbon dioxide and water
CN102864265B (zh) * 2012-09-24 2014-05-28 中南大学 一种气基直接还原尾气回收利用的方法
KR101376138B1 (ko) * 2012-12-27 2014-03-19 주식회사 포스코 용철제조장치 및 용철제조방법
US10065857B2 (en) 2013-03-12 2018-09-04 Midrex Technologies, Inc. Systems and methods for generating carbon dioxide for use as a reforming oxidant in making syngas or reformed gas
US10260117B2 (en) 2013-07-22 2019-04-16 Saudi Basic Industries Corporation Use of top gas in direct reduction processes
KR101550893B1 (ko) * 2013-12-10 2015-09-18 주식회사 포스코 용철제조방법 및 용철제조장치
US9868999B2 (en) * 2014-07-15 2018-01-16 Midrex Technologies, Inc. Methods and systems for producing direct reduced iron utilizing a petroleum refinery bottoms or petroleum coke gasifier and a hot gas cleaner
CN104477909B (zh) * 2014-11-24 2016-06-01 西南化工研究设计院有限公司 一种用于甲醇脱氢合成甲酸甲酯装置脱氢尾气中一氧化碳和氢气回收的工艺
US9534265B2 (en) 2014-12-15 2017-01-03 Midrex Technologies, Inc. Methods and systems for producing direct reduced iron incorporating a carbon dioxide and steam reformer fed by recovered carbon dioxide
AT516273B1 (de) 2015-01-19 2016-04-15 Bilfinger Bohr Und Rohrtechnik Gmbh Verfahren und Anlage zur Behandlung von Verbrennungsabgas
US10316376B2 (en) * 2015-06-24 2019-06-11 Midrex Technologies, Inc. Methods and systems for increasing the carbon content of sponge iron in a reduction furnace
US10661340B2 (en) * 2016-08-03 2020-05-26 Reid Reactors Llc Method and apparatus for producing metallic iron from iron oxide fines
US10434576B2 (en) * 2016-08-03 2019-10-08 Reid Reactors Llc Method and apparatus for producing metallic iron from iron oxide fines
WO2018116090A1 (en) * 2016-12-22 2018-06-28 Sabic Global Technologies B.V. Direct reduction process for the production of direct-reduced iron with high purity methane
CN106521074B (zh) * 2017-01-13 2018-03-30 刘冬冬 一种利用甲醇裂解生产直接还原铁的设备及工艺
CN106995864A (zh) * 2017-03-23 2017-08-01 江苏省冶金设计院有限公司 转炉煤气利用系统和利用转炉煤气的方法
KR102105427B1 (ko) 2018-01-09 2020-04-28 (주)케이텍 스크류형의 직접환원철법 냉각장치
KR102112017B1 (ko) 2018-10-29 2020-05-18 (주)케이텍 직접환원철의 고효율 건조를 위한 열풍 타입 고속 건조장치
IT201900002081A1 (it) * 2019-02-13 2020-08-13 Danieli Off Mecc Impianto di riduzione diretta e relativo processo
IT201900002089A1 (it) * 2019-02-13 2020-08-13 Danieli Off Mecc Impianto di riduzione diretta e relativo processo
CN109913606A (zh) * 2019-03-27 2019-06-21 东北大学 一种基于感应加热的煤制氢气竖炉炼铁系统及工艺
SE543341C2 (en) * 2019-04-01 2020-12-08 Greeniron H2 Ab Method and device for producing direct reduced metal
CN111961784B (zh) * 2020-08-31 2021-09-07 山东大学 一种铁矿粉鼓泡床还原反应的方法与系统
DE102021112208A1 (de) * 2021-05-11 2022-11-17 Thyssenkrupp Steel Europe Ag Verfahren zur Direktreduktion von Eisenerz
WO2022251059A1 (en) * 2021-05-24 2022-12-01 Nucor Corporation Direct reduced iron system and method using synthetic combustion air

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2821471A (en) * 1956-12-19 1958-01-28 Texaco Development Corp Process for reduction of iron ore
US3864465A (en) * 1972-12-15 1975-02-04 Hydrocarbon Research Inc Production Of High Purity Hydrogen
US4363654A (en) * 1980-04-08 1982-12-14 Geoffrey Frederick Production of reducing gas for furnace injection
US5110350A (en) 1983-05-16 1992-05-05 Hylsa S.A. De C.V. Method of reducing iron ore
US4756750A (en) * 1987-04-27 1988-07-12 Air Products And Chemicals, Inc. Process for the direct reduction of iron ore
CN1093883C (zh) * 1997-10-10 2002-11-06 伊尔萨有限公司 控制直接还原铁渗碳的方法和设备
US6027545A (en) * 1998-02-20 2000-02-22 Hylsa, S.A. De C.V. Method and apparatus for producing direct reduced iron with improved reducing gas utilization
US6152984A (en) * 1998-09-10 2000-11-28 Praxair Technology, Inc. Integrated direct reduction iron system
IT1310535B1 (it) * 1999-02-18 2002-02-18 Danieli Off Mecc Procedimento di riduzione diretta di materiale metallicoe relativo impianto
US6562103B2 (en) * 2001-07-27 2003-05-13 Uop Llc Process for removal of carbon dioxide for use in producing direct reduced iron
MXPA05012242A (es) * 2003-05-15 2006-02-08 Hylsa Sa Metodo y aparato para el uso mejorado de fuentes primarias de energia en plantas integrales de acero.
ITMI20060158A1 (it) 2006-01-31 2007-08-01 Danieli Off Mecc Processo ed impianto di riduzione

Also Published As

Publication number Publication date
UA105772C2 (ru) 2014-06-25
KR101587199B1 (ko) 2016-01-20
CN102232119A (zh) 2011-11-02
SE0802100A1 (sv) 2010-04-07
KR20110070893A (ko) 2011-06-24
AU2009302946A1 (en) 2010-04-15
WO2010042023A1 (en) 2010-04-15
AU2009302946B2 (en) 2014-12-18
BRPI0920029B1 (pt) 2018-01-09
CA2739577A1 (en) 2010-04-15
EP2347018A4 (en) 2017-04-26
CN102232119B (zh) 2013-12-18
BRPI0920029A2 (pt) 2015-12-15
MX2011003644A (es) 2011-07-28
SE532975C2 (sv) 2010-06-01
EA017978B1 (ru) 2013-04-30
EP2347018A1 (en) 2011-07-27
US20110247457A1 (en) 2011-10-13
US8709128B2 (en) 2014-04-29
MY153906A (en) 2015-04-15

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