EA200901593A1 - Способ полимеризации олефинов - Google Patents

Способ полимеризации олефинов

Info

Publication number
EA200901593A1
EA200901593A1 EA200901593A EA200901593A EA200901593A1 EA 200901593 A1 EA200901593 A1 EA 200901593A1 EA 200901593 A EA200901593 A EA 200901593A EA 200901593 A EA200901593 A EA 200901593A EA 200901593 A1 EA200901593 A1 EA 200901593A1
Authority
EA
Eurasian Patent Office
Prior art keywords
nickel
olefins
polymerization
polymer
olefin
Prior art date
Application number
EA200901593A
Other languages
English (en)
Other versions
EA017439B1 (ru
Inventor
Кай Хортманн
Давид Вандевьель
Уилльям Дж. Готьер
Original Assignee
Тотал Петрокемикалс Рисерч Фелюй
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Тотал Петрокемикалс Рисерч Фелюй filed Critical Тотал Петрокемикалс Рисерч Фелюй
Publication of EA200901593A1 publication Critical patent/EA200901593A1/ru
Publication of EA017439B1 publication Critical patent/EA017439B1/ru

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/148—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound
    • C07C7/14833—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound with metals or their inorganic compounds
    • C07C7/1485—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound with metals or their inorganic compounds oxides; hydroxides; salts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/755—Nickel
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Water Supply & Treatment (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

Способ полимеризации олефинов, включающий стадии: а) пропускание содержащего олефины углеводородного сырья через сорбирующий материал, включающий никель, осажденный на материал-носитель, где указанный никель присутствует как в виде оксида никеля, так и в виде металлического никеля; б) осуществление конверсии по меньшей мере части олефинов, содержащихся в указанном углеводородном сырье, с получением полимера, в присутствии одного или более металлоценовых катализаторов и в) извлечение полимерного продукта.
EA200901593A 2007-06-22 2008-06-20 Способ полимеризации олефинов EA017439B1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP07110842A EP2006012A1 (en) 2007-06-22 2007-06-22 Process for the polymerisation of olefins
PCT/EP2008/057906 WO2009000782A1 (en) 2007-06-22 2008-06-20 Process for the polymerisation of olefins

Publications (2)

Publication Number Publication Date
EA200901593A1 true EA200901593A1 (ru) 2010-06-30
EA017439B1 EA017439B1 (ru) 2012-12-28

Family

ID=38577643

Family Applications (1)

Application Number Title Priority Date Filing Date
EA200901593A EA017439B1 (ru) 2007-06-22 2008-06-20 Способ полимеризации олефинов

Country Status (7)

Country Link
US (1) US20100234544A1 (ru)
EP (2) EP2006012A1 (ru)
JP (1) JP2010525134A (ru)
KR (2) KR20090128563A (ru)
CN (1) CN101668578A (ru)
EA (1) EA017439B1 (ru)
WO (1) WO2009000782A1 (ru)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101868443A (zh) 2007-09-20 2010-10-20 特拉维夫大学拉莫特有限公司 N-苯基邻氨基苯甲酸衍生物及其用途
CN102453140B (zh) * 2010-10-19 2013-08-14 中国石油化工股份有限公司 一种负载茂金属型催化剂及其制备方法
CN102453137B (zh) * 2010-10-19 2013-07-03 中国石油化工股份有限公司 一种烯烃聚合方法
CN102731689B (zh) * 2011-03-31 2013-11-06 中国石油化工股份有限公司 一种烯烃聚合方法
CN102952218B (zh) * 2011-08-25 2014-08-06 中国石油化工股份有限公司 一种烯烃聚合方法
WO2014006069A1 (en) * 2012-07-06 2014-01-09 Total Research & Technology Feluy Process for the polymerization of olefins
CN103586079B (zh) * 2012-08-14 2015-08-19 中国石油化工股份有限公司 一种负载型茂金属催化剂及其制备方法和应用以及乙酸正丁酯的制备方法
CN103586080B (zh) * 2012-08-14 2015-08-19 中国石油化工股份有限公司 一种负载型茂金属催化剂及其制备方法和应用以及乙酸正丁酯的制备方法
CN103586081B (zh) * 2012-08-14 2015-08-19 中国石油化工股份有限公司 一种负载型茂金属催化剂及其制备方法和应用以及乙酸正丁酯的制备方法
CN103586078B (zh) * 2012-08-14 2015-08-19 中国石油化工股份有限公司 一种负载型茂金属催化剂及其制备方法和应用以及乙酸正丁酯的制备方法

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5470456A (en) * 1984-07-27 1995-11-28 Fina Research, S.A. Process for removing carbonyl-sulfide from liquid hydrocarbon feedstocks
LU85487A1 (fr) * 1984-07-27 1986-02-12 Labofina Sa Procede de purification de charges d'hydrocarbures liquides
DE3777182D1 (de) * 1987-09-24 1992-04-09 Fina Research Verfahren zur entfernung von arsin aus leichte olefine enthaltenden kohlenwasserstoffbeschickungen.
JPH0570373A (ja) * 1991-09-10 1993-03-23 Mitsubishi Petrochem Co Ltd プロピレン中に含有される硫化カルボニルと一酸化炭素を同時に除去する方法
ES2101287T3 (es) * 1993-09-20 1997-07-01 Fina Research Procedimiento para la separacion de arsina y sulfuro de carbonilo de suministros hidrocarburicos que contienen olefina(s) ligera(s).
RU2152421C1 (ru) * 1994-05-19 2000-07-10 Мицуи Петрокемикал Индастриз Лтд. СПОСОБ ОЧИСТКИ α-ОЛЕФИНОВ ДЛЯ ПОЛИМЕРИЗАЦИИ И СПОСОБ ПОЛУЧЕНИЯ ПОЛИ-α-ОЛЕФИНОВ
JPH0834749A (ja) * 1994-05-19 1996-02-06 Mitsui Petrochem Ind Ltd 重合用オレフィンの精製法およびポリオレフィンの製造法
DE69831819T2 (de) * 1997-01-30 2006-07-06 Total Petrochemicals Research Feluy, Seneffe Selektive Wirkung von Metallocen-Katalysatoren für die Herstellung von isotaktischen Polyolefinen
US20030105376A1 (en) * 2001-11-30 2003-06-05 Foral Michael J. Purification of polyolefin feedstocks using multiple adsorbents
JP4023261B2 (ja) * 2002-08-30 2007-12-19 東ソー株式会社 オレフィン重合用触媒およびオレフィン重合体の製造方法
US6855783B2 (en) * 2003-04-11 2005-02-15 Fina Technology, Inc. Supported metallocene catalysts
JP4381898B2 (ja) * 2004-06-18 2009-12-09 三井化学株式会社 プロピレン系重合体、プロピレン系重合体の製造方法、及び塗装性材料
JP4318611B2 (ja) * 2004-08-09 2009-08-26 株式会社Ａｄｅｋａ 安定化ポリマーの製造方法

Also Published As

Publication number Publication date
EP2006012A1 (en) 2008-12-24
US20100234544A1 (en) 2010-09-16
KR20090128563A (ko) 2009-12-15
KR20120096083A (ko) 2012-08-29
WO2009000782A1 (en) 2008-12-31
EP2160233A1 (en) 2010-03-10
JP2010525134A (ja) 2010-07-22
CN101668578A (zh) 2010-03-10
EA017439B1 (ru) 2012-12-28
EP2160233B1 (en) 2012-10-17

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Legal Events

Date Code Title Description
MM4A Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s)

Designated state(s): AM AZ BY KZ KG MD TJ TM

TC4A Change in name of a patent proprietor in a eurasian patent
MM4A Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s)

Designated state(s): RU