EA200800110A1 - Кобальтовые катализаторы на носителе для синтеза фишера-тропша - Google Patents

Кобальтовые катализаторы на носителе для синтеза фишера-тропша

Info

Publication number
EA200800110A1
EA200800110A1 EA200800110A EA200800110A EA200800110A1 EA 200800110 A1 EA200800110 A1 EA 200800110A1 EA 200800110 A EA200800110 A EA 200800110A EA 200800110 A EA200800110 A EA 200800110A EA 200800110 A1 EA200800110 A1 EA 200800110A1
Authority
EA
Eurasian Patent Office
Prior art keywords
synthesis
tropsha
fisher
media
cobalt catalysts
Prior art date
Application number
EA200800110A
Other languages
English (en)
Other versions
EA014214B1 (ru
Inventor
Питер Ричард Эллис
Питер Трентон Бишоп
Original Assignee
Джонсон Мэтти Плс
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Джонсон Мэтти Плс filed Critical Джонсон Мэтти Плс
Publication of EA200800110A1 publication Critical patent/EA200800110A1/ru
Publication of EA014214B1 publication Critical patent/EA014214B1/ru

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/005—Spinels
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/75—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/889—Manganese, technetium or rhenium
    • B01J23/8896—Rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0205—Impregnation in several steps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/06—Washing
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/332—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8913—Cobalt and noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391—Physical properties of the active metal ingredient
    • B01J35/392—Metal surface area
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B01J37/18—Reducing with gases containing free hydrogen

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Описаны катализатор, содержащий 5-75 мас.% кобальта, нанесенного на оксидный носитель, состоящий из алюминия, и 0,01-20 мас.% лития, и способ получения указанного катализатора. Такие катализаторы пригодны для применения при синтезе углеводородов способом Фишера-Тропша.
EA200800110A 2005-06-23 2006-06-08 Кобальтовые катализаторы на носителе для синтеза фишера-тропша EA014214B1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GBGB0512791.5A GB0512791D0 (en) 2005-06-23 2005-06-23 Catalysts
PCT/GB2006/050143 WO2006136863A1 (en) 2005-06-23 2006-06-08 Supported cobalt catalysts for the fischer tropsch synthesis

Publications (2)

Publication Number Publication Date
EA200800110A1 true EA200800110A1 (ru) 2008-06-30
EA014214B1 EA014214B1 (ru) 2010-10-29

Family

ID=34856016

Family Applications (1)

Application Number Title Priority Date Filing Date
EA200800110A EA014214B1 (ru) 2005-06-23 2006-06-08 Кобальтовые катализаторы на носителе для синтеза фишера-тропша

Country Status (9)

Country Link
US (2) US20100048742A1 (ru)
EP (1) EP1893332A1 (ru)
JP (1) JP5052510B2 (ru)
CN (1) CN101203304B (ru)
AU (1) AU2006260683B2 (ru)
EA (1) EA014214B1 (ru)
GB (1) GB0512791D0 (ru)
WO (1) WO2006136863A1 (ru)
ZA (1) ZA200710856B (ru)

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GB0819847D0 (en) * 2008-10-30 2008-12-03 Johnson Matthey Plc Cobalt catalysts
SG173637A1 (en) * 2009-02-26 2011-09-29 Sasol Tech Pty Ltd Process for the preparation of fischer - tropsch catalysts and their use
CN102441393B (zh) * 2010-10-12 2016-01-13 中国石油化工股份有限公司 一种以改性氧化铝为载体的费托合成催化剂及其应用
RU2476583C1 (ru) * 2011-08-19 2013-02-27 ЮГ Инвестмент Лтд. Способ переработки углеродосодержащего сырья и катализатор для его осуществления
RU2493914C1 (ru) * 2012-08-24 2013-09-27 Общество с ограниченной ответственностью "Объединенный центр исследований и разработок" Способ получения кобальтового катализатора
KR101298783B1 (ko) 2012-12-14 2013-08-26 한국가스공사 피셔-트롭쉬 촉매의 제조방법
EP3024573B1 (en) 2013-07-24 2021-09-08 Shell Internationale Research Maatschappij B.V. Process for preparing a chlorine comprising catalyst, the prepared catalyst, and its use
EP3024577A1 (en) 2013-07-24 2016-06-01 Shell Internationale Research Maatschappij B.V. Process for preparing a chlorine comprising catalyst, the prepared catalyst, and its use
RU2610523C1 (ru) * 2015-10-28 2017-02-13 Федеральное государственное бюджетное учреждение науки Институт катализа им. Г.К. Борескова Сибирского отделения Российской академии наук Способ приготовления катализатора получения углеводородов из синтез-газа и способ его использования
CA3028590C (en) * 2016-08-11 2021-08-03 Sasol South Africa Limited A cobalt-containing catalyst composition
RU2638217C1 (ru) 2016-12-15 2017-12-12 Публичное акционерное общество "Нефтяная компания "Роснефть" Компактный реактор для получения синтетических углеводородов в процессе Фишера-Тропша, способ активации катализатора Фишера-Тропша и способ осуществления синтеза Фишера-Тропша в компактном варианте с его использованием

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Also Published As

Publication number Publication date
JP2008546527A (ja) 2008-12-25
WO2006136863A1 (en) 2006-12-28
AU2006260683B2 (en) 2011-05-12
CN101203304A (zh) 2008-06-18
CN101203304B (zh) 2011-12-14
GB0512791D0 (en) 2005-07-27
AU2006260683A1 (en) 2006-12-28
EA014214B1 (ru) 2010-10-29
US20120190758A1 (en) 2012-07-26
JP5052510B2 (ja) 2012-10-17
ZA200710856B (en) 2008-12-31
US20100048742A1 (en) 2010-02-25
EP1893332A1 (en) 2008-03-05

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MM4A Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s)

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