WO2009136711A3 - 피셔-트롭쉬 합성용 코발트계 촉매 및 이의 제조방법 - Google Patents

피셔-트롭쉬 합성용 코발트계 촉매 및 이의 제조방법 Download PDF

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Publication number
WO2009136711A3
WO2009136711A3 PCT/KR2009/002329 KR2009002329W WO2009136711A3 WO 2009136711 A3 WO2009136711 A3 WO 2009136711A3 KR 2009002329 W KR2009002329 W KR 2009002329W WO 2009136711 A3 WO2009136711 A3 WO 2009136711A3
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WO
WIPO (PCT)
Prior art keywords
fischer
cobalt
based catalyst
production method
method therefor
Prior art date
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PCT/KR2009/002329
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English (en)
French (fr)
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WO2009136711A2 (ko
Inventor
이윤조
전기원
박조용
배종욱
Original Assignee
한국화학연구원
대림산업 주식회사
두산메카텍 주식회사
한국석유공사
현대엔지니어링 주식회사
에스케이에너지 주식회사
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Application filed by 한국화학연구원, 대림산업 주식회사, 두산메카텍 주식회사, 한국석유공사, 현대엔지니어링 주식회사, 에스케이에너지 주식회사 filed Critical 한국화학연구원
Publication of WO2009136711A2 publication Critical patent/WO2009136711A2/ko
Publication of WO2009136711A3 publication Critical patent/WO2009136711A3/ko

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/75—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8913—Cobalt and noble metals
    • B01J35/23—
    • B01J35/393—
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/06—Washing
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/332—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites

Abstract

본 발명은 피셔-트롭쉬(Fischer-Tropsch, F-T) 합성용 코발트계 촉매 및 이의 제조 방법에 관한 것으로서, 구체적으로는 미리 피셔-트롭쉬 반응에 활성이 있는 코발트계 촉매성분을 포함하는 나노입자를 제조한 후 이들을 촉매 지지체에 담지하여 제조되는, 일산화탄소의 높은 전환율, 액체탄화수소로의 선택성 및 촉매 안전성을 갖는 피셔-트롭쉬 합성용 코발트계 촉매 및 이의 제조 방법에 관한 것이다.
PCT/KR2009/002329 2008-05-06 2009-05-01 피셔-트롭쉬 합성용 코발트계 촉매 및 이의 제조방법 WO2009136711A2 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR1020080041737A KR101015492B1 (ko) 2008-05-06 2008-05-06 피셔-트롭쉬 합성용 코발트계 촉매 및 이의 제조방법
KR10-2008-0041737 2008-05-06

Publications (2)

Publication Number Publication Date
WO2009136711A2 WO2009136711A2 (ko) 2009-11-12
WO2009136711A3 true WO2009136711A3 (ko) 2010-03-04

Family

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PCT/KR2009/002329 WO2009136711A2 (ko) 2008-05-06 2009-05-01 피셔-트롭쉬 합성용 코발트계 촉매 및 이의 제조방법

Country Status (2)

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KR (1) KR101015492B1 (ko)
WO (1) WO2009136711A2 (ko)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101412518B1 (ko) * 2012-08-29 2014-06-26 한국과학기술연구원 합성가스를 이용한 액체 탄화수소 제조용 촉매, 및 이의 제조 방법
KR101578192B1 (ko) * 2013-01-30 2015-12-17 한국화학연구원 CoO상 입자를 포함하는 피셔 트롭시 합성용 촉매 및 이를 이용하여 천연가스로부터 액체 탄화수소를 제조하는 방법
KR101373823B1 (ko) 2013-10-22 2014-03-11 한국에너지기술연구원 선택적 합성오일 생성을 위한 피셔-트롭쉬 반응용 금속 구조체 기반 코발트계 촉매 및 그 제조 방법, 이 금속 구조체 기반 코발트계 촉매를 이용한 선택적 합성 오일 제조 방법
CN106938170B (zh) * 2017-03-31 2023-02-28 武汉金中石化工程有限公司 一种钴基固定床费托合成弛放气的处理装置及处理方法
KR102149821B1 (ko) 2018-05-31 2020-08-31 한국화학연구원 피셔―트롭쉬 합성반응용 촉매 구조물
CN110876933B (zh) * 2018-09-05 2023-03-31 国家能源投资集团有限责任公司 复合氧化物载体和钴基费托合成催化剂及其制备方法
KR102563207B1 (ko) * 2018-10-31 2023-08-02 에스케이이노베이션 주식회사 코발트계 단원자 탈수소화 촉매 및 이를 이용하여 파라핀으로부터 대응되는 올레핀을 제조하는 방법
EP3928864A1 (en) 2020-06-25 2021-12-29 SK Innovation Co., Ltd. Cobalt-based single-atom dehydrogenation catalysts having improved thermal stability and method for producing olefins from corresponding paraffins by using the same
CN114377703B (zh) * 2020-10-16 2023-09-29 国家能源投资集团有限责任公司 氧化硅负载的钴基费托合成催化剂及其制备方法和应用
CN114717590B (zh) * 2022-03-10 2023-08-08 中国科学院海洋研究所 一种钴基析氯催化剂电极制备方法

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JP2000061306A (ja) * 1998-08-12 2000-02-29 Inst Fr Petrole 有機化合物の変換反応において使用可能な担持触媒
US20030211940A1 (en) * 2000-06-12 2003-11-13 Sasol Technology (Proprietary) Limited Cobalt catalysts
US20080051474A1 (en) * 2004-11-29 2008-02-28 Dogterom Ronald J Catalytic Process For The Conversion Of Co (II)Hydroxide In Co (III)Hydroxide

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100867281B1 (ko) * 2001-10-12 2008-11-06 재단법인서울대학교산학협력재단 크기분리 과정 없이 균일하고 결정성이 우수한 금속,합금, 금속 산화물, 및 복합금속 산화물 나노입자를제조하는 방법

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000061306A (ja) * 1998-08-12 2000-02-29 Inst Fr Petrole 有機化合物の変換反応において使用可能な担持触媒
US20030211940A1 (en) * 2000-06-12 2003-11-13 Sasol Technology (Proprietary) Limited Cobalt catalysts
US20080051474A1 (en) * 2004-11-29 2008-02-28 Dogterom Ronald J Catalytic Process For The Conversion Of Co (II)Hydroxide In Co (III)Hydroxide

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Publication number Publication date
KR101015492B1 (ko) 2011-02-22
WO2009136711A2 (ko) 2009-11-12
KR20090116054A (ko) 2009-11-11

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