EA200500285A1 - Способ радикальной регулируемой полимеризации акриловой кислоты и ее солей, полученные полимеры и их применение - Google Patents

Способ радикальной регулируемой полимеризации акриловой кислоты и ее солей, полученные полимеры и их применение

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Publication number
EA200500285A1
EA200500285A1 EA200500285A EA200500285A EA200500285A1 EA 200500285 A1 EA200500285 A1 EA 200500285A1 EA 200500285 A EA200500285 A EA 200500285A EA 200500285 A EA200500285 A EA 200500285A EA 200500285 A1 EA200500285 A1 EA 200500285A1
Authority
EA
Eurasian Patent Office
Prior art keywords
acrylic acid
paper
radical
salt
application
Prior art date
Application number
EA200500285A
Other languages
English (en)
Other versions
EA007462B1 (ru
Inventor
Жан-Марк Сюо
Жан-Бернар Эгра
Original Assignee
Коатекс С. А. С.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Коатекс С. А. С. filed Critical Коатекс С. А. С.
Publication of EA200500285A1 publication Critical patent/EA200500285A1/ru
Publication of EA007462B1 publication Critical patent/EA007462B1/ru

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/04—Acids, Metal salts or ammonium salts thereof
    • C08F20/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Paper (AREA)
  • Paints Or Removers (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

Настоящее изобретение касается способа регулируемой радикальной полимеризации акриловой кислоты и ее солей в реакционной среде, содержащей только воду. Изобретение также касается гомополимеров и сополимеров акриловой кислоты, полученных способом полимеризации. Наконец, изобретение касается применения указанных гомополимеров и сополимеров акриловой кислоты в таких областях промышленности, как целлюлозно-бумажная промышленность и, в частности, для наложения бумажных листов и загрузки бумажной массы, в нефтяной промышленности или в области крашения, обработки вод, производства моющих средств, керамики, цемента или гидравлических связующих, общественных работ, производства чернил и лаков, шлихтования текстиля или в области обработки кожи.Отчет о международном поиске был опубликован 2004.04.08.
EA200500285A 2002-07-26 2003-07-24 Способ радикальной регулируемой полимеризации акриловой кислоты и ее солей, полученные полимеры и их применение EA007462B1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0209499A FR2842814B1 (fr) 2002-07-26 2002-07-26 Procede de polymerisation radicalaire controlee de l'acide acrylique et de ses sels, les polymeres obtenus, et leurs applications.
PCT/FR2003/002337 WO2004014967A2 (fr) 2002-07-26 2003-07-24 Procede de polymerisation radicalaire controlee de l’acide acrylique et de ses sels, les polymeres obtenus, et leurs applications

Publications (2)

Publication Number Publication Date
EA200500285A1 true EA200500285A1 (ru) 2005-06-30
EA007462B1 EA007462B1 (ru) 2006-10-27

Family

ID=30011511

Family Applications (1)

Application Number Title Priority Date Filing Date
EA200500285A EA007462B1 (ru) 2002-07-26 2003-07-24 Способ радикальной регулируемой полимеризации акриловой кислоты и ее солей, полученные полимеры и их применение

Country Status (24)

Country Link
US (2) US7462676B2 (ru)
EP (1) EP1529065B1 (ru)
JP (1) JP2006509053A (ru)
KR (1) KR100999003B1 (ru)
CN (2) CN100415775C (ru)
AT (1) ATE455799T1 (ru)
AU (1) AU2003274203A1 (ru)
BR (1) BR0312903A (ru)
CA (1) CA2493395C (ru)
DE (1) DE60331074D1 (ru)
EA (1) EA007462B1 (ru)
EC (1) ECSP055596A (ru)
ES (1) ES2339005T3 (ru)
FR (1) FR2842814B1 (ru)
HR (1) HRP20050180A2 (ru)
IL (1) IL166236A0 (ru)
MA (1) MA27286A1 (ru)
MX (1) MXPA05001014A (ru)
NO (1) NO333005B1 (ru)
PL (1) PL373964A1 (ru)
RS (1) RS20050067A (ru)
TN (1) TNSN05024A1 (ru)
WO (1) WO2004014967A2 (ru)
ZA (1) ZA200500697B (ru)

Families Citing this family (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2868068B1 (fr) * 2004-03-29 2006-07-14 Coatex Soc Par Actions Simplif Nouveaux composes soufres : utilisation comme agent de transfert pour la polymerisation radicalaire controlee de l'acide acrylique, polymeres obtenus et leurs applications
FR2842814B1 (fr) 2002-07-26 2004-10-22 Coatex Sas Procede de polymerisation radicalaire controlee de l'acide acrylique et de ses sels, les polymeres obtenus, et leurs applications.
US7851572B2 (en) * 2004-07-28 2010-12-14 Coatex S.A.S. Polymers produced by using sulphur compounds in the form of transfer agents for controlled radical polymerisation of acrylic acid and the use thereof
FR2868072B1 (fr) * 2004-07-28 2006-06-30 Coatex Soc Par Actions Simplif Polymeres obtenus par l'utilisation de composes soufres comme agents de transfert pour la polymerisation radicalaire controlee de l'acide acrylique et leurs applications
US20090198028A1 (en) * 2006-06-21 2009-08-06 Basf Se 1,2-dithiol-3-thiones as chain-transfer agents in free-radical polymerization reactions
WO2008009607A1 (en) * 2006-07-18 2008-01-24 Lamberti Spa Concentrated gypsum suspensions for coating colour of paper
FI122734B (fi) * 2007-05-21 2012-06-15 Kemira Oyj Prosessikemikaali käytettäväksi paperin tai kartongin valmistuksessa
FR2933419B1 (fr) 2008-07-07 2010-08-20 Coatex Sas Utilisation de polymeres(meth) acryliques dans un procede de fabrication d'une suspension aqueuse de carbonate de calcium
EP2143688B1 (fr) 2008-07-07 2016-09-07 Omya International AG Procédé de fabrication de suspensions aqueuses de carbonate de calcium et suspensions obtenues ainsi que leurs utilisations
FR2940141B1 (fr) 2008-12-19 2010-12-17 Coatex Sas Utilisation de polymeres acryliques neutralises par le lithium comme agents dispersants ou d'aide au broyage en milieu aqueux de matieres minerales
FR2941235B1 (fr) * 2009-01-16 2011-01-14 Coatex Sas Utilisation de polymeres acryliques peigne avec des groupes hydrophobes comme agents de couplage dans un procede de broyage de matieres minerales avec des liants.
CN101698784B (zh) * 2009-09-22 2012-01-25 北京高盟新材料股份有限公司 压敏导电胶黏剂组合物及其制备方法
CN101857657B (zh) * 2010-06-29 2012-11-14 上海东升新材料有限公司 抗盐性碳酸钙分散剂及其制备方法
CN101864014B (zh) * 2010-06-29 2012-11-14 上海东升新材料有限公司 碳酸钙高效分散剂的制备方法
CN102050903B (zh) * 2010-09-29 2012-07-04 上海东升新材料有限公司 碳酸钙分散剂的制备方法及应用
FR2967593B1 (fr) 2010-11-19 2012-12-28 Coatex Sas Utilisation d'amines en combinaison avec des polymeres acryliques dans la fabrication de suspensions aqueuses de matieres minerales
PT2455429E (pt) 2010-11-19 2013-11-07 Omya Int Ag Processo de preparação de suspensões aquosas de materiais minerais por meio de aminas, em combinação com polímeros vinilcarboxílicos
BR112013015120B1 (pt) 2010-12-17 2020-11-03 Basf Se método de produção de um polímero, polímero, suspensão, e, uso de uma suspensão
CN102153714B (zh) * 2010-12-29 2013-10-23 浙江大学 一种制备阳离子型超支化乙烯或丙烯酰胺类聚合物的方法
CN102585081B (zh) * 2012-01-16 2015-08-26 深圳市瑞成科讯实业有限公司 流变改质剂及其制备方法
SI2712895T1 (sl) 2012-09-26 2016-09-30 Omya International Ag Reološko stabilna vodna suspenzija mineralne snovi, ki vsebuje organske polimere, ki imajo zmanjšano vsebnost hlapno organske spojine (voc)
FR2998309B1 (fr) * 2012-11-20 2015-04-10 Snf Sas Composition et procede d'encollage pour materiaux textile
CN104371077A (zh) * 2014-05-23 2015-02-25 江苏省建筑科学研究院有限公司 一种星形聚羧酸水泥分散剂的制备方法
EP3294709A1 (en) * 2015-05-08 2018-03-21 The Lubrizol Corporation Water soluble chain transfer agents
EP3130453A1 (en) * 2015-08-13 2017-02-15 Sika Technology AG Tire filling based on acrylic hydrogels
US10442732B2 (en) 2016-05-20 2019-10-15 United States Gypsum Company Gypsum slurries with linear polycarboxylate dispersants
WO2018081964A1 (en) 2016-11-02 2018-05-11 Basf Se Acrylic acid polymers neutralized with sodium and calcium ions and having a narrow molecular weight distribution
CN107936167A (zh) * 2017-12-21 2018-04-20 苏州希尔盖森新材料有限公司 一种具有亲水性的聚苯乙烯微球
EP3543302B1 (en) * 2018-03-22 2021-03-17 Coatex Composition for hard surface substrate marking
CN108587525B (zh) * 2018-03-19 2020-05-08 黄石科森色谱科技有限公司 一种薄层色谱板粘合剂的制备方法
ES2939375T3 (es) * 2018-06-04 2023-04-21 Coatex Sas Copolímero y molienda de un material mineral
MX2021008506A (es) 2019-02-11 2021-08-19 Dow Global Technologies Llc Metodo de polimerizacion por transferencia inversa de yodo y composiciones de este.
AU2020221038A1 (en) 2019-02-11 2021-09-02 Dow Global Technologies Llc Iodine transfer polymerization method and compositions therefrom
CN111117389A (zh) * 2020-01-06 2020-05-08 雷晓芳 一种用于船舶防腐的试剂组及其使用方法
CN112409529B (zh) * 2020-11-12 2022-04-22 常熟聚和化学有限公司 基于丙烯酸/二甲基二烯丙基氯化铵制备聚丙烯酸钠的方法及应用

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2303681A1 (fr) 1975-03-11 1976-10-08 Quigniot Andre Dispositif de suspension a bras tires avec quadrilatere deformable pour train a multiples roues ou demi-essieu auto-suiveur a bras tires
FR2610637B1 (fr) * 1987-02-11 1989-05-12 Coatex Sa Agent de pretraitement de materiaux mineraux grossiers en vue d'applications pigmentaires
US6335404B1 (en) * 1994-04-05 2002-01-01 Rohm And Haas Company Aqueous process for preparing aqueous weight carboxyl containing polymers
FR2751335B1 (fr) * 1996-07-19 1998-08-21 Coatex Sa Procede d'obtention de polymere hydrosolubles, polymeres obtenus et leurs utilisations
FR2764892B1 (fr) 1997-06-23 2000-03-03 Rhodia Chimie Sa Procede de synthese de polymeres a blocs
AU1911399A (en) 1997-12-18 1999-07-05 Commonwealth Scientific And Industrial Research Organisation Polymerization process with living characteristics and polymers made therefrom
DE19836808A1 (de) * 1998-08-14 2000-02-24 Basf Ag Verdickungsmittel für tensidhaltige Zusammensetzungen
FR2794463B1 (fr) 1999-06-04 2005-02-25 Rhodia Chimie Sa Procede de synthese de polymeres par polymerisation radicalaire controlee a l'aide de xanthates halogenes
FR2799471B1 (fr) 1999-10-11 2001-12-28 Rhodia Chimie Sa Procede de preparation de polymeres greffes
FR2802208B1 (fr) 1999-12-09 2003-02-14 Rhodia Chimie Sa Procede de synthese de polymeres par polymerisation radicalaire controlee a l'aide de xanthates
FR2802830B1 (fr) * 1999-12-27 2002-06-07 Coatex Sa Utilisation de polymeres hydrosolubles comme agent de dispersion de suspension aqueuse de carbonate de calcium suspensions aqueuses obtenues et leurs utilisations
FR2812296B1 (fr) 2000-07-25 2002-12-20 Rhodia Chimie Sa Procede de synthese de copolymeres hybrides et organiques par polymerisation radicalaire controlee
FR2814168B1 (fr) 2000-09-18 2006-11-17 Rhodia Chimie Sa Procede de synthese de polymeres a blocs par polymerisation radicalaire controlee en presence d'un compose disulfure
FR2842814B1 (fr) 2002-07-26 2004-10-22 Coatex Sas Procede de polymerisation radicalaire controlee de l'acide acrylique et de ses sels, les polymeres obtenus, et leurs applications.

Also Published As

Publication number Publication date
IL166236A0 (en) 2006-01-15
EP1529065A2 (fr) 2005-05-11
NO20051039L (no) 2005-02-25
CN100582127C (zh) 2010-01-20
EA007462B1 (ru) 2006-10-27
WO2004014967A3 (fr) 2004-04-08
CN100415775C (zh) 2008-09-03
WO2004014967A2 (fr) 2004-02-19
US7462676B2 (en) 2008-12-09
DE60331074D1 (de) 2010-03-11
HRP20050180A2 (en) 2005-10-31
PL373964A1 (en) 2005-09-19
US20070106042A1 (en) 2007-05-10
CN101012293A (zh) 2007-08-08
CN1671748A (zh) 2005-09-21
EP1529065B1 (fr) 2010-01-20
JP2006509053A (ja) 2006-03-16
RS20050067A (en) 2007-06-04
ECSP055596A (es) 2005-07-06
MXPA05001014A (es) 2005-05-16
FR2842814B1 (fr) 2004-10-22
NO333005B1 (no) 2013-02-11
ATE455799T1 (de) 2010-02-15
CA2493395C (fr) 2012-01-03
US20060111534A1 (en) 2006-05-25
FR2842814A1 (fr) 2004-01-30
MA27286A1 (fr) 2005-04-01
KR100999003B1 (ko) 2010-12-09
TNSN05024A1 (fr) 2007-05-14
ES2339005T3 (es) 2010-05-14
BR0312903A (pt) 2005-06-14
ZA200500697B (en) 2006-08-30
KR20050030640A (ko) 2005-03-30
CA2493395A1 (fr) 2004-02-19
AU2003274203A1 (en) 2004-02-25

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Legal Events

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MM4A Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s)

Designated state(s): RU