EA200400136A1 - Способ получения жидких углеводородов - Google Patents

Способ получения жидких углеводородов

Info

Publication number
EA200400136A1
EA200400136A1 EA200400136A EA200400136A EA200400136A1 EA 200400136 A1 EA200400136 A1 EA 200400136A1 EA 200400136 A EA200400136 A EA 200400136A EA 200400136 A EA200400136 A EA 200400136A EA 200400136 A1 EA200400136 A1 EA 200400136A1
Authority
EA
Eurasian Patent Office
Prior art keywords
suspension
catalyst particles
liquid
synthesis gas
solid catalyst
Prior art date
Application number
EA200400136A
Other languages
English (en)
Other versions
EA005795B1 (ru
Inventor
Бхарат Лайджарам Бхат
Дирк Кунрад Энгел
Эдвард Клайд Хейдорн
Маттейс Мария Герардус Зенден
Original Assignee
Шелл Интернэшнл Рисерч Маатсхаппий Б.В.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Шелл Интернэшнл Рисерч Маатсхаппий Б.В. filed Critical Шелл Интернэшнл Рисерч Маатсхаппий Б.В.
Publication of EA200400136A1 publication Critical patent/EA200400136A1/ru
Publication of EA005795B1 publication Critical patent/EA005795B1/ru

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/332—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/34—Apparatus, reactors
    • C10G2/342—Apparatus, reactors with moving solid catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Настоящее изобретение касается способа получения жидких углеводородов, который включает контактирование синтез-газа с суспензией твердых частиц катализатора и жидкостью в баке реактора путем введения синтез-газа в суспензию на низком уровне в условиях, способствующих превращению синтез-газа в жидкие углеводороды, причем твердые частицы катализатора включают каталитически активный металл, выбранный из кобальта и железа, на огнеупорном пористом оксидном носителе, преимущественно выбираемом из кремнезема, окиси алюминия, оксида титана, оксида циркония или их смеси, где катализатор присутствует в количестве от 10 до 40% от общего объема суспензии жидких и твердых веществ, и отделения жидкого материала от твердых частиц катализатора с использованием фильтрационной системы, включающей асимметричную фильтрующую среду (селективная сторона на стороне суспензии) и имеющей перепад давления над фильтрующей средой по меньшей мере 0,1 бар, причем распределение размера частиц в процессе таково, что по крайней мере некоторое количество частиц катализатора является меньшим среднего размера пор селективного слоя фильтрующей среды. Изобретение включает также аппарат для проведения описанного выше процесса.Отчет о международном поиске был опубликован 2003.11.20.
EA200400136A 2001-07-03 2002-07-03 Способ получения жидких углеводородов EA005795B1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US30294701P 2001-07-03 2001-07-03
PCT/EP2002/007534 WO2003004582A2 (en) 2001-07-03 2002-07-03 Process for the production of liquid hydrocarbons

Publications (2)

Publication Number Publication Date
EA200400136A1 true EA200400136A1 (ru) 2004-06-24
EA005795B1 EA005795B1 (ru) 2005-06-30

Family

ID=23169930

Family Applications (1)

Application Number Title Priority Date Filing Date
EA200400136A EA005795B1 (ru) 2001-07-03 2002-07-03 Способ получения жидких углеводородов

Country Status (12)

Country Link
US (1) US7067559B2 (ru)
EP (1) EP1419216B1 (ru)
CN (1) CN1292045C (ru)
AR (1) AR034670A1 (ru)
AU (1) AU2002328852B2 (ru)
CA (1) CA2451746A1 (ru)
DE (1) DE60225148T2 (ru)
EA (1) EA005795B1 (ru)
MX (1) MXPA04000123A (ru)
NO (1) NO20040006L (ru)
WO (1) WO2003004582A2 (ru)
ZA (1) ZA200309943B (ru)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1495093A2 (en) 2002-04-16 2005-01-12 Concophillips Company Solid/liquid separation system for multiphase converters
ITMI20030969A1 (it) * 2003-05-15 2004-11-16 Enitecnologie Spa Procedimento per la produzione in continuo di idrocarburi da gas di sintesi in reattori a sospensione e per la separazione della fase liquida prodotta dalla fase solida.
ITMI20031029A1 (it) 2003-05-22 2004-11-23 Enitecnologie Spa Procedimenti per la produzione in continuo di idrocarburi da gas di sintesi.
ITMI20031288A1 (it) 2003-06-25 2004-12-26 Enitecnologie Spa Processo per la produzione in continuo di idrocarburi da gas di sintesi in reattori a sospensione e per la separazione della fase liquida prodotta dalla fase solida.
US7378452B2 (en) * 2005-12-28 2008-05-27 Exxonmobil Research And Engineering Company Filtration system for slurry hydrocarbon synthesis process using both small and large pore filter elements
DE102007056170A1 (de) * 2006-12-28 2008-11-06 Dominik Peus Semikontinuierliches Verfahren zur Herstellung von Brennstoff aus Biomasse
US20080260631A1 (en) 2007-04-18 2008-10-23 H2Gen Innovations, Inc. Hydrogen production process
US8344199B2 (en) 2007-05-28 2013-01-01 The Petroleum Oil And Gas Corporation Of South Africa (Pty) Ltd. Removal of ultra-fine particles from a Fischer Tropsch stream
US9018128B2 (en) 2007-09-14 2015-04-28 Res Usa Llc Promoted, attrition resistant, silica supported precipitated iron catalyst
US20100084350A1 (en) * 2008-10-06 2010-04-08 Jing Liu Systems and Methods for Continuous Multiphase Reaction and Separation
US8022109B2 (en) 2008-12-23 2011-09-20 Exxonmobil Research And Engineering Company Product filtration system for slurry reactors
US9149781B2 (en) 2009-12-28 2015-10-06 Shell Oil Company Reactor with gas distribution system in bottom

Family Cites Families (13)

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Publication number Priority date Publication date Assignee Title
DE3245318C3 (de) 1982-12-08 1996-06-20 Bayer Ag Verfahren zur Durchführung von Druckreaktionen mit suspendierten Katalysatoren
US5324335A (en) 1986-05-08 1994-06-28 Rentech, Inc. Process for the production of hydrocarbons
CA2038772C (en) 1990-04-04 2001-12-25 Eric Herbolzheimer Catalyst fluidization improvements
GB9203958D0 (en) 1992-02-25 1992-04-08 Norske Stats Oljeselskap Catalytic multi-phase reactor
CA2105940C (en) 1992-10-05 2001-12-25 Robert M. Koros Bubble column, tube side slurry process and apparatus
NZ250750A (en) 1993-01-27 1995-02-24 Sasol Chem Ind Pty Reacting gases in a slurry bed which contains a filtration zone to separate liquid product
GB9301723D0 (en) 1993-01-28 1993-03-17 Norske Stats Oljeselskap Solid/liquid treatment apparatus and catalytic multi-phase reactor
GB2281224B (en) 1993-08-24 1998-02-11 Norske Stats Oljeselskap Solid/liquid slurry treatment apparatus and catalytic multi-phase reactor
US5600700A (en) 1995-09-25 1997-02-04 Vivid Technologies, Inc. Detecting explosives or other contraband by employing transmitted and scattered X-rays
NO953797L (no) * 1995-09-25 1997-03-26 Norske Stats Oljeselskap Fremgangsmåte og anlegg for behandling av en brönnström som produseres fra et oljefelt til havs
US5770629A (en) 1997-05-16 1998-06-23 Exxon Research & Engineering Company Slurry hydrocarbon synthesis with external product filtration
US6344490B1 (en) 1999-01-22 2002-02-05 Exxon Research And Engineering Company Removable filter for slurry hydrocarbon synthesis process
EG22489A (en) 1999-02-05 2003-02-26 Sasol Technology Process for producing liquid and optionally gaseous products from gaseous reactants

Also Published As

Publication number Publication date
DE60225148D1 (de) 2008-04-03
EP1419216B1 (en) 2008-02-20
NO20040006L (no) 2004-01-02
EP1419216A2 (en) 2004-05-19
US20040235966A1 (en) 2004-11-25
EA005795B1 (ru) 2005-06-30
US7067559B2 (en) 2006-06-27
ZA200309943B (en) 2004-05-24
AU2002328852B2 (en) 2007-06-07
WO2003004582A3 (en) 2003-11-20
MXPA04000123A (es) 2004-05-21
CA2451746A1 (en) 2003-01-16
CN1529744A (zh) 2004-09-15
WO2003004582A2 (en) 2003-01-16
AR034670A1 (es) 2004-03-03
DE60225148T2 (de) 2009-03-05
CN1292045C (zh) 2006-12-27

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MM4A Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s)

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