EA200100390A1 - Комплексы металлов с мостиковыми связями для газофазной полимеризации - Google Patents

Комплексы металлов с мостиковыми связями для газофазной полимеризации

Info

Publication number
EA200100390A1
EA200100390A1 EA200100390A EA200100390A EA200100390A1 EA 200100390 A1 EA200100390 A1 EA 200100390A1 EA 200100390 A EA200100390 A EA 200100390A EA 200100390 A EA200100390 A EA 200100390A EA 200100390 A1 EA200100390 A1 EA 200100390A1
Authority
EA
Eurasian Patent Office
Prior art keywords
gas
phase polymerization
bridges
metal complexes
group
Prior art date
Application number
EA200100390A
Other languages
English (en)
Other versions
EA004039B1 (ru
Inventor
Дейвид Д. Девор
Дейвид Р. Нейтхамер
Original Assignee
Бп Кемикэлз Лимитед
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Бп Кемикэлз Лимитед filed Critical Бп Кемикэлз Лимитед
Publication of EA200100390A1 publication Critical patent/EA200100390A1/ru
Publication of EA004039B1 publication Critical patent/EA004039B1/ru

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/34—Polymerisation in gaseous state
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00—Metallocene catalysts
    • C08F2420/08—Heteroatom bridge, i.e. Cp or analog where the bridging atom linking the two Cps or analogs is a heteroatom different from Si
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/901—Monomer polymerized in vapor state in presence of transition metal containing catalyst
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

В заявке описан способ газофазной полимеризации олефинов, в котором катализатор включает новый комплекс переходного металла группы 4, включающий борную или алюминиевую мостиковую группу, включающую азотсодержащую группу, в частности амидную группу.Отчет о международном поиске был опубликован 2000.09.08.
EA200100390A 1998-10-08 1999-09-08 Способ полимеризации олефинов EA004039B1 (ru)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US10351198P 1998-10-08 1998-10-08
US38399599A 1999-08-26 1999-08-26
PCT/US1999/020539 WO2000020462A2 (en) 1998-10-08 1999-09-08 Bridged metal complexes for gas phase polymerizations

Publications (2)

Publication Number Publication Date
EA200100390A1 true EA200100390A1 (ru) 2001-10-22
EA004039B1 EA004039B1 (ru) 2003-12-25

Family

ID=26800546

Family Applications (1)

Application Number Title Priority Date Filing Date
EA200100390A EA004039B1 (ru) 1998-10-08 1999-09-08 Способ полимеризации олефинов

Country Status (23)

Country Link
US (1) US6891005B2 (ru)
EP (1) EP1141034B1 (ru)
JP (1) JP2002526607A (ru)
KR (1) KR20010085900A (ru)
CN (1) CN1152891C (ru)
AR (1) AR024218A1 (ru)
AT (1) ATE226964T1 (ru)
AU (1) AU754409B2 (ru)
BR (1) BR9914358A (ru)
CA (1) CA2346544A1 (ru)
CZ (1) CZ20011215A3 (ru)
DE (1) DE69903753T2 (ru)
EA (1) EA004039B1 (ru)
EG (1) EG22810A (ru)
ES (1) ES2188235T3 (ru)
ID (1) ID28541A (ru)
MY (1) MY119600A (ru)
NO (1) NO994876L (ru)
PL (1) PL348255A1 (ru)
SK (1) SK4462001A3 (ru)
TR (1) TR200100965T2 (ru)
UA (1) UA57864C2 (ru)
WO (1) WO2000020462A2 (ru)

Families Citing this family (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000020426A1 (en) * 1998-10-08 2000-04-13 The Dow Chemical Company Bridged metal complexes
EP1074557A3 (de) * 1999-07-31 2003-02-26 Basell Polyolefine GmbH Übergangsmetallverbindung, Ligandensystem, Katalysatorsystem und seine Verwendung zur Polymerisation von Olefinen
DE60128990T2 (de) * 2000-03-14 2008-02-28 Denki Kagaku Kogyo K.K. Übergangsmetallkatalysator-komponente für die polymerisierung und verfahren zur polymerherstellung unter verwendung desselben
US6376408B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6399723B1 (en) 2000-06-30 2002-06-04 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376409B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376412B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380120B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6414095B1 (en) 2000-06-30 2002-07-02 Exxon Mobil Chemical Patents Inc. Metallocene compositions
US6380121B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380123B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376413B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376407B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376411B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380330B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376627B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6870016B1 (en) 2000-06-30 2005-03-22 Exxonmobil Chemical Patents Inc. Polymerization process and polymer composition
US6380334B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376410B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380331B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US7122498B2 (en) 2000-06-30 2006-10-17 Exxonmobil Chemical Patents Inc. Metallocenes and catalyst compositions derived therefrom
US6380122B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380124B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
JP2004516340A (ja) * 2000-09-25 2004-06-03 バセル テクノロジー カンパニー ビー．ブイ． エチレンポリマーの製造方法
DE10158656A1 (de) * 2001-11-30 2003-06-26 Basell Polyolefine Gmbh Organoübergangsmetallverbindung, Biscyclopentadienylligandsystem, Katalysatorsystem und Verfahren zur Herstellung von Polyolefinen
US20060089253A1 (en) * 2002-08-13 2006-04-27 Shahram Mihan Monocyclopentadienyl complexes
US9217049B2 (en) 2013-11-19 2015-12-22 Chevron Phillips Chemical Company Lp Dual catalyst systems for producing polymers with a broad molecular weight distribution and a uniform short chain branch distribution
CN105849138A (zh) * 2013-11-19 2016-08-10 切弗朗菲利浦化学公司 含有具有烯基取代基的硼桥接的环戊二烯基-芴基茂金属化合物的催化剂系统
WO2015077100A2 (en) 2013-11-19 2015-05-28 Chevron Phillips Chemical Company Lp Boron-bridged bis-indenyl metallocene catalyst systems and polymers produced therefrom
US9540465B2 (en) 2013-11-19 2017-01-10 Chevron Phillips Chemical Company Lp Boron-bridged metallocene catalyst systems and polymers produced therefrom
EP3131933B1 (en) * 2014-04-17 2019-11-13 Chevron Phillips Chemical Company LP Boron-bridged metallocene catalyst systems and polymers produced therefrom
WO2015179628A1 (en) 2014-05-22 2015-11-26 Chevron Phillips Chemical Company Lp Dual catalyst systems for producing polymers with a broad molecular weight distribution and a uniform short chain branch distribution
CN106715450B (zh) * 2014-09-10 2019-10-22 Sabic环球技术有限责任公司 用于烯烃聚合的硼桥连的2-茚基茂金属复合物
WO2019200525A1 (zh) * 2018-04-17 2019-10-24 南通纺织丝绸产业技术研究院 2,6-二异丙基苯胺基锂在催化羰基化合物和硼烷硼氢化反应中的应用

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Publication number Priority date Publication date Assignee Title
US5399636A (en) * 1993-06-11 1995-03-21 Phillips Petroleum Company Metallocenes and processes therefor and therewith
JP3275211B2 (ja) * 1991-05-20 2002-04-15 ザ ダウ ケミカル カンパニー 付加重合触媒の製造方法
US5486585A (en) * 1993-08-26 1996-01-23 Exxon Chemical Patents Inc. Amidosilyldiyl bridged catalysts and method of polymerization using said catalysts.
DE19709486A1 (de) * 1997-03-07 1998-09-10 Studiengesellschaft Kohle Mbh Verfahren und Katalysatoren zur stereospezifischen Polymerisation von Olefinen mit chiralen Halbsandwich-Metallocen-Katalysatoren

Also Published As

Publication number Publication date
CA2346544A1 (en) 2000-04-13
PL348255A1 (en) 2002-05-20
DE69903753T2 (de) 2003-03-20
EA004039B1 (ru) 2003-12-25
ES2188235T3 (es) 2003-06-16
CN1329621A (zh) 2002-01-02
JP2002526607A (ja) 2002-08-20
KR20010085900A (ko) 2001-09-07
CZ20011215A3 (cs) 2001-10-17
ID28541A (id) 2001-05-31
MY119600A (en) 2005-06-30
EG22810A (en) 2003-08-31
NO994876L (no) 2000-04-10
DE69903753D1 (de) 2002-12-05
CN1152891C (zh) 2004-06-09
EP1141034A2 (en) 2001-10-10
WO2000020462A2 (en) 2000-04-13
EP1141034B1 (en) 2002-10-30
US6891005B2 (en) 2005-05-10
NO994876D0 (no) 1999-10-07
TR200100965T2 (tr) 2001-08-21
AU754409B2 (en) 2002-11-14
AR024218A1 (es) 2002-09-25
SK4462001A3 (en) 2002-01-07
WO2000020462A3 (en) 2000-09-08
UA57864C2 (ru) 2003-07-15
US20030199650A1 (en) 2003-10-23
AU5815199A (en) 2000-04-26
ATE226964T1 (de) 2002-11-15
BR9914358A (pt) 2001-11-27

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MM4A Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s)

Designated state(s): AM AZ BY KZ KG MD TJ TM

MM4A Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s)

Designated state(s): RU