EA199800068A1 - Катализатор и способ получения углеводородов - Google Patents
Катализатор и способ получения углеводородовInfo
- Publication number
- EA199800068A1 EA199800068A1 EA199800068A EA199800068A EA199800068A1 EA 199800068 A1 EA199800068 A1 EA 199800068A1 EA 199800068 A EA199800068 A EA 199800068A EA 199800068 A EA199800068 A EA 199800068A EA 199800068 A1 EA199800068 A1 EA 199800068A1
- Authority
- EA
- Eurasian Patent Office
- Prior art keywords
- cobalt
- catalyst
- producing hydrocarbons
- vanadium
- manganese
- Prior art date
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/847—Vanadium, niobium or tantalum or polonium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/847—Vanadium, niobium or tantalum or polonium
- B01J23/8472—Vanadium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/889—Manganese, technetium or rhenium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/889—Manganese, technetium or rhenium
- B01J23/8892—Manganese
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
- C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
- C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
- C07C1/0425—Catalysts; their physical properties
- C07C1/043—Catalysts; their physical properties characterised by the composition
- C07C1/0435—Catalysts; their physical properties characterised by the composition containing a metal of group 8 or a compound thereof
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
- C07C2521/04—Alumina
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- C07C2521/08—Silica
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C07C2523/20—Vanadium, niobium or tantalum
- C07C2523/22—Vanadium
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C07C2523/32—Manganese, technetium or rhenium
- C07C2523/34—Manganese
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
- C07C2523/56—Platinum group metals
- C07C2523/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tatalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C07C2523/656—Manganese, technetium or rhenium
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/74—Iron group metals
- C07C2523/75—Cobalt
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
- C07C2523/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C07C2523/847—Vanadium, niobium or tantalum
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
- C07C2523/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C07C2523/889—Manganese, technetium or rhenium
Abstract
Настоящее изобретение относится к катализатору для использования в способе получения углеводородов, включающему кобальт и марганец и/или ванадий на носителе при атомном отношении кобальт:(марганец+ванадий), равном по крайней мере 12:1. Предпочтительно атомное отношение кобальт:(марганец+ванадий) равно не более чем 1500:1. Изобретение также относится к способу получения углеводородов, включающему контактирование смеси водорода и окиси углерода при повышенной температуре и давлении с катализатором, описанным выше. Обычно по крайней мере часть кобальта присутствует в металлическом состоянии.Международная заявка была опубликована вместе с отчетом о международном поиске.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP95201644 | 1995-06-16 | ||
PCT/EP1996/002577 WO1997000231A1 (en) | 1995-06-16 | 1996-06-12 | Catalyst and process for the preparation of hydrocarbons |
Publications (2)
Publication Number | Publication Date |
---|---|
EA199800068A1 true EA199800068A1 (ru) | 1998-08-27 |
EA000319B1 EA000319B1 (ru) | 1999-04-29 |
Family
ID=8220390
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EA199800068A EA000319B1 (ru) | 1995-06-16 | 1996-06-12 | Катализатор и способ получения углеводородов |
Country Status (20)
Country | Link |
---|---|
US (1) | US5981608A (ru) |
EP (1) | EP0833807B1 (ru) |
JP (1) | JP4319701B2 (ru) |
KR (1) | KR100447463B1 (ru) |
CN (1) | CN1087193C (ru) |
AU (1) | AU698391B2 (ru) |
BR (1) | BR9608451A (ru) |
CA (1) | CA2224690C (ru) |
DE (1) | DE69632189T2 (ru) |
DK (1) | DK0833807T3 (ru) |
DZ (1) | DZ2051A1 (ru) |
EA (1) | EA000319B1 (ru) |
ES (1) | ES2215194T3 (ru) |
MY (1) | MY117350A (ru) |
NO (1) | NO317854B1 (ru) |
NZ (1) | NZ311669A (ru) |
PE (1) | PE12497A1 (ru) |
TW (1) | TW349882B (ru) |
WO (1) | WO1997000231A1 (ru) |
ZA (1) | ZA965078B (ru) |
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WO2016091697A1 (en) * | 2014-12-12 | 2016-06-16 | Bp P.L.C. | Fischer-tropsch process using reductively-activated cobalt catalyst |
RU2710375C2 (ru) | 2014-12-19 | 2019-12-26 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. | Способ приготовления катализатора |
EP3344729B1 (en) | 2015-09-04 | 2019-12-11 | Shell International Research Maatschappij B.V. | Process to prepare paraffins and waxes |
MY194211A (en) | 2015-09-04 | 2022-11-21 | Shell Int Research | Method of manufacturing hydrocarbons |
CN108430629B (zh) | 2015-12-21 | 2021-11-12 | 国际壳牌研究有限公司 | 氢化催化剂及其制备方法 |
EP3535350B1 (en) | 2016-11-07 | 2021-09-08 | Shell Internationale Research Maatschappij B.V. | Method of producing hydrocarbons |
EP3628400A1 (en) | 2018-09-26 | 2020-04-01 | Bp P.L.C. | Fischer-tropsch process, supported fischer-tropsch synthesis catalyst and uses thereof |
CN112166169A (zh) | 2018-02-09 | 2021-01-01 | 英国石油有限公司 | 费-托方法、负载型费-托合成催化剂及其用途 |
CN111867725A (zh) | 2018-03-20 | 2020-10-30 | 国际壳牌研究有限公司 | 含钴催化剂的制备 |
EA202190846A1 (ru) | 2018-09-28 | 2021-07-07 | Бп П.Л.К. | Способ фишера-тропша |
GB201903502D0 (en) | 2019-03-14 | 2019-05-01 | Johnson Matthey Plc | Cobalt catalysts and precursors therefor |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2026657A1 (en) * | 1970-06-01 | 1972-01-27 | Heinrich Koppers Gmbh, 4300 Essen | Catalytic combustion of ammonia - to nitrogen and water , using excess oxygen over cobalt/copper oxide |
US3912763A (en) * | 1973-07-19 | 1975-10-14 | Phillips Petroleum Co | Oxidative dehydrogenation of alkenes or alkadienes to furan compounds |
US4588708A (en) * | 1985-04-15 | 1986-05-13 | Kansas State University Research Foundation | Bimetallic solvated metal atom dispersed catalysts |
CA1340441C (en) * | 1988-04-25 | 1999-03-16 | Chang Jung Kim | Water addition for increased co/h2 hydrocarbon synthesis activity over catalysts comprising rhenium promoted cobalt on titania |
US5290530A (en) * | 1991-05-31 | 1994-03-01 | Kabushiki Kaisha Riken | Method of cleaning exhaust gas |
US5162284A (en) * | 1991-08-05 | 1992-11-10 | Exxon Research And Engineering Co. | Copper promoted cobalt-manganese spinel catalyst and method for making the catalyst for Fischer-Tropsch synthesis |
NZ244132A (en) * | 1991-08-28 | 1993-12-23 | Broken Hill Pty Co Ltd | Fischer-tropsch catalysts comprising cobalt and scandium. |
DE4325847A1 (de) * | 1993-07-31 | 1995-02-02 | Basf Ag | Kobaltkatalysatoren |
-
1996
- 1996-06-12 NZ NZ311669A patent/NZ311669A/xx unknown
- 1996-06-12 BR BR9608451A patent/BR9608451A/pt not_active Application Discontinuation
- 1996-06-12 DK DK96921991T patent/DK0833807T3/da active
- 1996-06-12 AU AU63033/96A patent/AU698391B2/en not_active Ceased
- 1996-06-12 DZ DZ960095A patent/DZ2051A1/fr active
- 1996-06-12 EP EP96921991A patent/EP0833807B1/en not_active Expired - Lifetime
- 1996-06-12 CN CN96194640A patent/CN1087193C/zh not_active Expired - Fee Related
- 1996-06-12 CA CA002224690A patent/CA2224690C/en not_active Expired - Fee Related
- 1996-06-12 JP JP50264797A patent/JP4319701B2/ja not_active Expired - Fee Related
- 1996-06-12 EA EA199800068A patent/EA000319B1/ru not_active IP Right Cessation
- 1996-06-12 ES ES96921991T patent/ES2215194T3/es not_active Expired - Lifetime
- 1996-06-12 WO PCT/EP1996/002577 patent/WO1997000231A1/en active IP Right Grant
- 1996-06-12 DE DE69632189T patent/DE69632189T2/de not_active Expired - Lifetime
- 1996-06-12 KR KR1019970709450A patent/KR100447463B1/ko not_active IP Right Cessation
- 1996-06-14 MY MYPI96002412A patent/MY117350A/en unknown
- 1996-06-14 ZA ZA965078A patent/ZA965078B/xx unknown
- 1996-06-17 PE PE1996000466A patent/PE12497A1/es not_active Application Discontinuation
- 1996-07-17 TW TW085108681A patent/TW349882B/zh active
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1997
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Also Published As
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NO975881D0 (no) | 1997-12-15 |
KR100447463B1 (ko) | 2004-10-14 |
CA2224690C (en) | 2007-06-05 |
TW349882B (en) | 1999-01-11 |
ZA965078B (en) | 1997-01-23 |
DE69632189D1 (de) | 2004-05-19 |
KR19990022980A (ko) | 1999-03-25 |
AU698391B2 (en) | 1998-10-29 |
DZ2051A1 (fr) | 2002-10-23 |
JPH11507866A (ja) | 1999-07-13 |
AU6303396A (en) | 1997-01-15 |
WO1997000231A1 (en) | 1997-01-03 |
EP0833807A1 (en) | 1998-04-08 |
PE12497A1 (es) | 1997-05-09 |
BR9608451A (pt) | 1999-01-05 |
NO975881L (no) | 1997-12-15 |
CN1087193C (zh) | 2002-07-10 |
DK0833807T3 (da) | 2004-05-17 |
MX9710023A (es) | 1998-07-31 |
EA000319B1 (ru) | 1999-04-29 |
MY117350A (en) | 2004-06-30 |
DE69632189T2 (de) | 2005-04-21 |
EP0833807B1 (en) | 2004-04-14 |
CN1187180A (zh) | 1998-07-08 |
NZ311669A (en) | 1998-12-23 |
ES2215194T3 (es) | 2004-10-01 |
JP4319701B2 (ja) | 2009-08-26 |
NO317854B1 (no) | 2004-12-20 |
CA2224690A1 (en) | 1997-01-03 |
US5981608A (en) | 1999-11-09 |
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