EA039814B1 - Предварительно приготовленная смесь для получения абсорбента для удаления кислотных газов из потока текучей среды - Google Patents

Предварительно приготовленная смесь для получения абсорбента для удаления кислотных газов из потока текучей среды Download PDF

Info

Publication number
EA039814B1
EA039814B1 EA201892359A EA201892359A EA039814B1 EA 039814 B1 EA039814 B1 EA 039814B1 EA 201892359 A EA201892359 A EA 201892359A EA 201892359 A EA201892359 A EA 201892359A EA 039814 B1 EA039814 B1 EA 039814B1
Authority
EA
Eurasian Patent Office
Prior art keywords
acid
dicarboxylic acid
water
absorbent
amine
Prior art date
Application number
EA201892359A
Other languages
English (en)
Russian (ru)
Other versions
EA201892359A1 (ru
Inventor
Томас Инграм
Геральд Форберг
Георг Зидер
Original Assignee
Басф Се
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Басф Се filed Critical Басф Се
Publication of EA201892359A1 publication Critical patent/EA201892359A1/ru
Publication of EA039814B1 publication Critical patent/EA039814B1/ru

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1456—Removing acid components
    • B01D53/1462—Removing mixtures of hydrogen sulfide and carbon dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1456—Removing acid components
    • B01D53/1468—Removing hydrogen sulfide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1456—Removing acid components
    • B01D53/1475—Removing carbon dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1493—Selection of liquid materials for use as absorbents
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
    • C10L3/10—Working-up natural gas or synthetic natural gas
    • C10L3/101—Removal of contaminants
    • C10L3/102—Removal of contaminants of acid contaminants
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
    • C10L3/10—Working-up natural gas or synthetic natural gas
    • C10L3/101—Removal of contaminants
    • C10L3/102—Removal of contaminants of acid contaminants
    • C10L3/103—Sulfur containing contaminants
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
    • C10L3/10—Working-up natural gas or synthetic natural gas
    • C10L3/101—Removal of contaminants
    • C10L3/102—Removal of contaminants of acid contaminants
    • C10L3/104—Carbon dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20426—Secondary amines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20431—Tertiary amines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20478—Alkanolamines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20478—Alkanolamines
    • B01D2252/20489—Alkanolamines with two or more hydroxyl groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/50—Combinations of absorbents
    • B01D2252/504—Mixtures of two or more absorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/60—Additives
    • B01D2252/604—Stabilisers or agents inhibiting degradation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/30—Sulfur compounds
    • B01D2257/302—Sulfur oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/30—Sulfur compounds
    • B01D2257/306—Organic sulfur compounds, e.g. mercaptans
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/30—Sulfur compounds
    • B01D2257/308—Carbonoxysulfide COS
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/40—Nitrogen compounds
    • B01D2257/408—Cyanides, e.g. hydrogen cyanide (HCH)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2258/00—Sources of waste gases
    • B01D2258/02—Other waste gases
    • B01D2258/0283—Flue gases
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/54—Specific separation steps for separating fractions, components or impurities during preparation or upgrading of a fuel
    • C10L2290/541—Absorption of impurities during preparation or upgrading of a fuel
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/54—Specific separation steps for separating fractions, components or impurities during preparation or upgrading of a fuel
    • C10L2290/545—Washing, scrubbing, stripping, scavenging for separating fractions, components or impurities during preparation or upgrading of a fuel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/40—Capture or disposal of greenhouse gases of CO2

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Gas Separation By Absorption (AREA)
  • Treating Waste Gases (AREA)
EA201892359A 2016-04-18 2017-04-06 Предварительно приготовленная смесь для получения абсорбента для удаления кислотных газов из потока текучей среды EA039814B1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP16165810 2016-04-18
PCT/EP2017/058285 WO2017182289A1 (de) 2016-04-18 2017-04-06 Vormischung zur herstellung eines absorptionsmittels zur entfernung von sauergasen aus einem fluidstrom

Publications (2)

Publication Number Publication Date
EA201892359A1 EA201892359A1 (ru) 2019-03-29
EA039814B1 true EA039814B1 (ru) 2022-03-16

Family

ID=55913454

Family Applications (1)

Application Number Title Priority Date Filing Date
EA201892359A EA039814B1 (ru) 2016-04-18 2017-04-06 Предварительно приготовленная смесь для получения абсорбента для удаления кислотных газов из потока текучей среды

Country Status (8)

Country Link
US (1) US11045759B2 (https=)
EP (1) EP3445474B1 (https=)
JP (1) JP7009387B2 (https=)
CN (1) CN109069983B (https=)
BR (1) BR112018071033A2 (https=)
CA (1) CA3020219C (https=)
EA (1) EA039814B1 (https=)
WO (1) WO2017182289A1 (https=)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2877641T3 (es) 2017-02-10 2021-11-17 Basf Se Proceso para la remoción de gases ácidos de una corriente de fluido y los correspondientes usos
EP3624922B1 (en) 2017-05-15 2021-07-07 Basf Se Absorbent, process for producing it and process for selectively removing hydrogen sulfide using it
KR20230121098A (ko) * 2020-12-16 2023-08-17 다우 글로벌 테크놀로지스 엘엘씨 산성 가스를 제거하기 위한 수성 흡수 매질

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0134948A2 (en) * 1983-06-30 1985-03-27 Union Carbide Corporation Absorbent formulation for enhanced removal of acid gases from gas mixtures and processes using same
WO2007135100A1 (de) * 2006-05-19 2007-11-29 Basf Se Vormischung zur herstellung eines absorptionsmittels zum entfernen saurer gase aus fluidströmen
EP2990090A1 (de) * 2014-08-25 2016-03-02 Basf Se Absorptionsmittel zur selektiven Entfernung von Schwefelwasserstoff aus einem Fluidstrom

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3320162A (en) * 1964-05-22 1967-05-16 Phillips Petroleum Co Increasing the base number of calcium petroleum sulfonate
US3320164A (en) * 1965-07-14 1967-05-16 Brunel Henri Non-corrosive, lubricating, cutting and cooling additives
US4347227A (en) * 1981-03-11 1982-08-31 Union Oil Company Of California Process for removing SOx and NOx compounds from gas streams
US4466902A (en) * 1982-01-31 1984-08-21 Ipposha Oil Industries, Co., Ltd. Rust inhibitor
US4892674A (en) * 1987-10-13 1990-01-09 Exxon Research And Engineering Company Addition of severely-hindered amine salts and/or aminoacids to non-hindered amine solutions for the absorption of H2 S
FR2708602B1 (fr) * 1993-08-02 1995-10-06 Oreal Procédé d'extraction des composés malodorants présents dans une formulation contenant au moins un composé comportant un groupe thiol et compositions désodorisées ainsi obtenues.
US6734155B1 (en) * 1997-07-09 2004-05-11 The Procter & Gamble Company Cleaning compositions comprising an oxidoreductase
US5843299A (en) * 1997-08-22 1998-12-01 Betzdearborn Inc. Corrosion inhibitor for alkanolamine units
FR2882942B1 (fr) * 2005-03-09 2007-06-15 Inst Francais Du Petrole Procede perfectionne de traitement d'un gaz contenant de l'hydrogene sulfure et du dioxyde de soufre
EP2350346A1 (en) 2008-10-24 2011-08-03 Lonza Inc. Alkanolamine-based carbon dioxide absorption solutions with reduced corrosivity
US8221712B2 (en) * 2009-05-12 2012-07-17 Basf Se Absorption medium for the selective removal of hydrogen sulfide from fluid streams
JP5627956B2 (ja) * 2010-08-30 2014-11-19 バブコック日立株式会社 二酸化炭素を含む排ガスの処理方法および装置
JP2013133458A (ja) * 2011-12-27 2013-07-08 Idemitsu Kosan Co Ltd 水性洗浄剤
KR102131467B1 (ko) 2012-06-29 2020-07-07 다우 글로벌 테크놀로지스 엘엘씨 수성 알칸올아민 용액 및 가스 혼합물로부터 황화수소의 제거 방법
EP3186222B1 (de) * 2014-08-25 2018-06-06 Basf Se Diamin mit tert-alkylamino- und primärer aminogruppe zur verwendung in der gaswäsche
KR20180057628A (ko) * 2015-09-29 2018-05-30 바스프 에스이 황화수소의 선택적 제거를 위한 흡수제
CN105413397A (zh) * 2015-10-21 2016-03-23 中石化节能环保工程科技有限公司 脱出尾气中co2的复合吸收剂
EP3448543B1 (en) * 2016-04-25 2020-06-10 Basf Se Use of morpholine-based hindered amine compounds for selective removal of hydrogen sulfide
ES2877641T3 (es) * 2017-02-10 2021-11-17 Basf Se Proceso para la remoción de gases ácidos de una corriente de fluido y los correspondientes usos
EP3624922B1 (en) * 2017-05-15 2021-07-07 Basf Se Absorbent, process for producing it and process for selectively removing hydrogen sulfide using it

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0134948A2 (en) * 1983-06-30 1985-03-27 Union Carbide Corporation Absorbent formulation for enhanced removal of acid gases from gas mixtures and processes using same
WO2007135100A1 (de) * 2006-05-19 2007-11-29 Basf Se Vormischung zur herstellung eines absorptionsmittels zum entfernen saurer gase aus fluidströmen
EP2990090A1 (de) * 2014-08-25 2016-03-02 Basf Se Absorptionsmittel zur selektiven Entfernung von Schwefelwasserstoff aus einem Fluidstrom

Also Published As

Publication number Publication date
EP3445474B1 (de) 2020-03-18
EA201892359A1 (ru) 2019-03-29
JP2019513553A (ja) 2019-05-30
US20190126193A1 (en) 2019-05-02
CA3020219C (en) 2024-06-18
CA3020219A1 (en) 2017-10-26
WO2017182289A1 (de) 2017-10-26
US11045759B2 (en) 2021-06-29
JP7009387B2 (ja) 2022-01-25
BR112018071033A2 (pt) 2019-02-12
CN109069983A (zh) 2018-12-21
CN109069983B (zh) 2021-12-24
EP3445474A1 (de) 2019-02-27

Similar Documents

Publication Publication Date Title
AU2014336725B2 (en) Method for removal of SOx from gas using compound amine alcohol solution
CN104168979B (zh) 从气体混合物中吸收co2的方法
JP6945617B2 (ja) 硫化水素を選択的に除去するためのモルホリン系ヒンダードアミン化合物の使用
JP6843846B2 (ja) 硫化水素を選択的に除去するための環状アミン
CN103814013A (zh) 用于从气体混合物除去硫化氢的氨基吡啶衍生物
EA039814B1 (ru) Предварительно приготовленная смесь для получения абсорбента для удаления кислотных газов из потока текучей среды
US8894954B2 (en) Process for removing mercaptans from a gas stream
RU2506985C2 (ru) Способ удаления кислотных газов из газового потока
JP5047481B2 (ja) ガスの精製方法
JP6586529B2 (ja) 硫化水素スカベンジング添加剤組成物およびその使用方法
JP6606291B2 (ja) 窒素系硫化水素スカベンジャーおよびその使用方法
CN118577100B (zh) 一种高效复配脱硫脱碳溶剂及其制备方法
CN108822908A (zh) 一种天然气有机硫脱除剂及其制备方法
CN116507398A (zh) 从含有酸性气体的气体混合物中去除酸性气体
WO2021047928A1 (en) Process for removal of acid gases from a fluid stream
JP2011152542A (ja) 吸収液、吸収液を用いたガス中のｃｏ２又はｈ２ｓ除去装置及び方法
CA3020537A1 (en) Composition comprising organoborates and physical solvents and use thereof for the removal of acid gases from hydrocarbon fluid streams