CA3020219C - Premix for producing an absorption agent for removing acid gases from a fluid flow - Google Patents

Premix for producing an absorption agent for removing acid gases from a fluid flow Download PDF

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Publication number
CA3020219C
CA3020219C CA3020219A CA3020219A CA3020219C CA 3020219 C CA3020219 C CA 3020219C CA 3020219 A CA3020219 A CA 3020219A CA 3020219 A CA3020219 A CA 3020219A CA 3020219 C CA3020219 C CA 3020219C
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CA
Canada
Prior art keywords
acid
premixture
absorbent
amine
water
Prior art date
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Active
Application number
CA3020219A
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English (en)
French (fr)
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CA3020219A1 (en
Inventor
Thomas Ingram
Gerald Vorberg
Georg Sieder
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BASF SE
Original Assignee
BASF SE
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Publication of CA3020219A1 publication Critical patent/CA3020219A1/en
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Publication of CA3020219C publication Critical patent/CA3020219C/en
Active legal-status Critical Current
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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1456—Removing acid components
    • B01D53/1462—Removing mixtures of hydrogen sulfide and carbon dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1456—Removing acid components
    • B01D53/1468—Removing hydrogen sulfide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1456—Removing acid components
    • B01D53/1475—Removing carbon dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1493—Selection of liquid materials for use as absorbents
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
    • C10L3/10—Working-up natural gas or synthetic natural gas
    • C10L3/101—Removal of contaminants
    • C10L3/102—Removal of contaminants of acid contaminants
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
    • C10L3/10—Working-up natural gas or synthetic natural gas
    • C10L3/101—Removal of contaminants
    • C10L3/102—Removal of contaminants of acid contaminants
    • C10L3/103—Sulfur containing contaminants
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
    • C10L3/10—Working-up natural gas or synthetic natural gas
    • C10L3/101—Removal of contaminants
    • C10L3/102—Removal of contaminants of acid contaminants
    • C10L3/104—Carbon dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20426—Secondary amines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20431—Tertiary amines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20478—Alkanolamines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20478—Alkanolamines
    • B01D2252/20489—Alkanolamines with two or more hydroxyl groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/50—Combinations of absorbents
    • B01D2252/504—Mixtures of two or more absorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/60—Additives
    • B01D2252/604—Stabilisers or agents inhibiting degradation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/30—Sulfur compounds
    • B01D2257/302—Sulfur oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/30—Sulfur compounds
    • B01D2257/306—Organic sulfur compounds, e.g. mercaptans
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/30—Sulfur compounds
    • B01D2257/308—Carbonoxysulfide COS
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/40—Nitrogen compounds
    • B01D2257/408—Cyanides, e.g. hydrogen cyanide (HCH)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2258/00—Sources of waste gases
    • B01D2258/02—Other waste gases
    • B01D2258/0283—Flue gases
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/54—Specific separation steps for separating fractions, components or impurities during preparation or upgrading of a fuel
    • C10L2290/541—Absorption of impurities during preparation or upgrading of a fuel
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/54—Specific separation steps for separating fractions, components or impurities during preparation or upgrading of a fuel
    • C10L2290/545—Washing, scrubbing, stripping, scavenging for separating fractions, components or impurities during preparation or upgrading of a fuel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/40—Capture or disposal of greenhouse gases of CO2

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Gas Separation By Absorption (AREA)
  • Treating Waste Gases (AREA)
CA3020219A 2016-04-18 2017-04-06 Premix for producing an absorption agent for removing acid gases from a fluid flow Active CA3020219C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP16165810.9 2016-04-18
EP16165810 2016-04-18
PCT/EP2017/058285 WO2017182289A1 (de) 2016-04-18 2017-04-06 Vormischung zur herstellung eines absorptionsmittels zur entfernung von sauergasen aus einem fluidstrom

Publications (2)

Publication Number Publication Date
CA3020219A1 CA3020219A1 (en) 2017-10-26
CA3020219C true CA3020219C (en) 2024-06-18

Family

ID=55913454

Family Applications (1)

Application Number Title Priority Date Filing Date
CA3020219A Active CA3020219C (en) 2016-04-18 2017-04-06 Premix for producing an absorption agent for removing acid gases from a fluid flow

Country Status (8)

Country Link
US (1) US11045759B2 (https=)
EP (1) EP3445474B1 (https=)
JP (1) JP7009387B2 (https=)
CN (1) CN109069983B (https=)
BR (1) BR112018071033A2 (https=)
CA (1) CA3020219C (https=)
EA (1) EA039814B1 (https=)
WO (1) WO2017182289A1 (https=)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2877641T3 (es) 2017-02-10 2021-11-17 Basf Se Proceso para la remoción de gases ácidos de una corriente de fluido y los correspondientes usos
EP3624922B1 (en) 2017-05-15 2021-07-07 Basf Se Absorbent, process for producing it and process for selectively removing hydrogen sulfide using it
KR20230121098A (ko) * 2020-12-16 2023-08-17 다우 글로벌 테크놀로지스 엘엘씨 산성 가스를 제거하기 위한 수성 흡수 매질

Family Cites Families (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3320162A (en) * 1964-05-22 1967-05-16 Phillips Petroleum Co Increasing the base number of calcium petroleum sulfonate
US3320164A (en) * 1965-07-14 1967-05-16 Brunel Henri Non-corrosive, lubricating, cutting and cooling additives
US4347227A (en) * 1981-03-11 1982-08-31 Union Oil Company Of California Process for removing SOx and NOx compounds from gas streams
US4466902A (en) * 1982-01-31 1984-08-21 Ipposha Oil Industries, Co., Ltd. Rust inhibitor
EP0134948A3 (en) 1983-06-30 1987-10-14 Union Carbide Corporation Absorbent formulation for enhanced removal of acid gases from gas mixtures and processes using same
US4892674A (en) * 1987-10-13 1990-01-09 Exxon Research And Engineering Company Addition of severely-hindered amine salts and/or aminoacids to non-hindered amine solutions for the absorption of H2 S
FR2708602B1 (fr) * 1993-08-02 1995-10-06 Oreal Procédé d'extraction des composés malodorants présents dans une formulation contenant au moins un composé comportant un groupe thiol et compositions désodorisées ainsi obtenues.
US6734155B1 (en) * 1997-07-09 2004-05-11 The Procter & Gamble Company Cleaning compositions comprising an oxidoreductase
US5843299A (en) * 1997-08-22 1998-12-01 Betzdearborn Inc. Corrosion inhibitor for alkanolamine units
FR2882942B1 (fr) * 2005-03-09 2007-06-15 Inst Francais Du Petrole Procede perfectionne de traitement d'un gaz contenant de l'hydrogene sulfure et du dioxyde de soufre
EP2024060B1 (de) 2006-05-19 2016-04-27 Basf Se Vormischung zur herstellung eines absorptionsmittels zum entfernen saurer gase aus fluidströmen
EP2350346A1 (en) 2008-10-24 2011-08-03 Lonza Inc. Alkanolamine-based carbon dioxide absorption solutions with reduced corrosivity
US8221712B2 (en) * 2009-05-12 2012-07-17 Basf Se Absorption medium for the selective removal of hydrogen sulfide from fluid streams
JP5627956B2 (ja) * 2010-08-30 2014-11-19 バブコック日立株式会社 二酸化炭素を含む排ガスの処理方法および装置
JP2013133458A (ja) * 2011-12-27 2013-07-08 Idemitsu Kosan Co Ltd 水性洗浄剤
KR102131467B1 (ko) 2012-06-29 2020-07-07 다우 글로벌 테크놀로지스 엘엘씨 수성 알칸올아민 용액 및 가스 혼합물로부터 황화수소의 제거 방법
EP2990090A1 (de) 2014-08-25 2016-03-02 Basf Se Absorptionsmittel zur selektiven Entfernung von Schwefelwasserstoff aus einem Fluidstrom
EP3186222B1 (de) * 2014-08-25 2018-06-06 Basf Se Diamin mit tert-alkylamino- und primärer aminogruppe zur verwendung in der gaswäsche
KR20180057628A (ko) * 2015-09-29 2018-05-30 바스프 에스이 황화수소의 선택적 제거를 위한 흡수제
CN105413397A (zh) * 2015-10-21 2016-03-23 中石化节能环保工程科技有限公司 脱出尾气中co2的复合吸收剂
EP3448543B1 (en) * 2016-04-25 2020-06-10 Basf Se Use of morpholine-based hindered amine compounds for selective removal of hydrogen sulfide
ES2877641T3 (es) * 2017-02-10 2021-11-17 Basf Se Proceso para la remoción de gases ácidos de una corriente de fluido y los correspondientes usos
EP3624922B1 (en) * 2017-05-15 2021-07-07 Basf Se Absorbent, process for producing it and process for selectively removing hydrogen sulfide using it

Also Published As

Publication number Publication date
EP3445474B1 (de) 2020-03-18
EA201892359A1 (ru) 2019-03-29
JP2019513553A (ja) 2019-05-30
US20190126193A1 (en) 2019-05-02
EA039814B1 (ru) 2022-03-16
CA3020219A1 (en) 2017-10-26
WO2017182289A1 (de) 2017-10-26
US11045759B2 (en) 2021-06-29
JP7009387B2 (ja) 2022-01-25
BR112018071033A2 (pt) 2019-02-12
CN109069983A (zh) 2018-12-21
CN109069983B (zh) 2021-12-24
EP3445474A1 (de) 2019-02-27

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