EA010668B1 - Применение органических полисульфидов в борьбе с коррозией, вызываемой кислой сырой нефтью - Google Patents
Применение органических полисульфидов в борьбе с коррозией, вызываемой кислой сырой нефтью Download PDFInfo
- Publication number
- EA010668B1 EA010668B1 EA200601679A EA200601679A EA010668B1 EA 010668 B1 EA010668 B1 EA 010668B1 EA 200601679 A EA200601679 A EA 200601679A EA 200601679 A EA200601679 A EA 200601679A EA 010668 B1 EA010668 B1 EA 010668B1
- Authority
- EA
- Eurasian Patent Office
- Prior art keywords
- formula
- sulfur
- distillation
- radicals
- hydrocarbon stream
- Prior art date
Links
- 230000007797 corrosion Effects 0.000 title claims abstract description 21
- 238000005260 corrosion Methods 0.000 title claims abstract description 21
- 150000008116 organic polysulfides Chemical class 0.000 title description 4
- 239000002253 acid Substances 0.000 title description 2
- 238000000034 method Methods 0.000 claims abstract description 21
- 125000005608 naphthenic acid group Chemical group 0.000 claims abstract description 15
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 7
- 229910052751 metal Inorganic materials 0.000 claims abstract description 6
- 239000002184 metal Substances 0.000 claims abstract description 6
- 239000010779 crude oil Substances 0.000 claims description 21
- 150000002430 hydrocarbons Chemical class 0.000 claims description 15
- 229930195733 hydrocarbon Natural products 0.000 claims description 13
- 150000001875 compounds Chemical class 0.000 claims description 12
- 239000004215 Carbon black (E152) Substances 0.000 claims description 10
- 238000004821 distillation Methods 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 9
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 8
- 238000009434 installation Methods 0.000 claims description 8
- 229910052717 sulfur Chemical group 0.000 claims description 8
- 239000011593 sulfur Chemical group 0.000 claims description 8
- 238000005292 vacuum distillation Methods 0.000 claims description 6
- LNMBCRKRCIMQLW-UHFFFAOYSA-N 2-tert-butylsulfanyl-2-methylpropane Chemical class CC(C)(C)SC(C)(C)C LNMBCRKRCIMQLW-UHFFFAOYSA-N 0.000 claims description 5
- 239000003921 oil Substances 0.000 claims description 5
- 238000012545 processing Methods 0.000 claims description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 4
- 125000005842 heteroatom Chemical group 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- 239000001301 oxygen Substances 0.000 claims description 4
- 239000007789 gas Substances 0.000 claims description 3
- 125000004434 sulfur atom Chemical group 0.000 claims description 2
- 239000005077 polysulfide Substances 0.000 abstract description 5
- 229920001021 polysulfide Polymers 0.000 abstract description 5
- 150000008117 polysulfides Polymers 0.000 abstract description 5
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 23
- 230000002378 acidificating effect Effects 0.000 description 10
- 229910052742 iron Inorganic materials 0.000 description 10
- 238000012360 testing method Methods 0.000 description 10
- 239000003112 inhibitor Substances 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 5
- 239000002480 mineral oil Substances 0.000 description 5
- 235000010446 mineral oil Nutrition 0.000 description 5
- 230000001629 suppression Effects 0.000 description 4
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 231100000069 corrosive reaction Toxicity 0.000 description 3
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 3
- 150000003568 thioethers Chemical class 0.000 description 3
- 239000000654 additive Substances 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- NHHSUCWHDQEHTJ-UHFFFAOYSA-N 2-(tert-butyltetrasulfanyl)-2-methylpropane Chemical compound CC(C)(C)SSSSC(C)(C)C NHHSUCWHDQEHTJ-UHFFFAOYSA-N 0.000 description 1
- NYLJHRUQFXQNPN-UHFFFAOYSA-N 2-(tert-butyltrisulfanyl)-2-methylpropane Chemical compound CC(C)(C)SSSC(C)(C)C NYLJHRUQFXQNPN-UHFFFAOYSA-N 0.000 description 1
- 229910000975 Carbon steel Inorganic materials 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 229910000640 Fe alloy Inorganic materials 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229940058344 antitrematodals organophosphorous compound Drugs 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 230000033558 biomineral tissue development Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000009931 harmful effect Effects 0.000 description 1
- 231100000086 high toxicity Toxicity 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 229940059904 light mineral oil Drugs 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 150000002903 organophosphorus compounds Chemical class 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- -1 polyalkyl sulfides Chemical class 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229940061610 sulfonated phenol Drugs 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- WMXCDAVJEZZYLT-UHFFFAOYSA-N tert-butylthiol Chemical compound CC(C)(C)S WMXCDAVJEZZYLT-UHFFFAOYSA-N 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G75/00—Inhibiting corrosion or fouling in apparatus for treatment or conversion of hydrocarbon oils, in general
- C10G75/02—Inhibiting corrosion or fouling in apparatus for treatment or conversion of hydrocarbon oils, in general by addition of corrosion inhibitors
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G7/00—Distillation of hydrocarbon oils
- C10G7/02—Stabilising gasoline by removing gases by fractioning
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/24—Organic compounds containing sulfur, selenium and/or tellurium
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Anti-Oxidant Or Stabilizer Compositions (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR0403838A FR2868787B1 (fr) | 2004-04-13 | 2004-04-13 | Utilisation de polysulfures organiques contre la corrosion par les bruts acides |
| PCT/FR2005/000861 WO2005103208A1 (fr) | 2004-04-13 | 2005-04-08 | Utilisation de polysulfures organiques contre la corrosion par les bruts acides |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EA200601679A1 EA200601679A1 (ru) | 2007-04-27 |
| EA010668B1 true EA010668B1 (ru) | 2008-10-30 |
Family
ID=34944754
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EA200601679A EA010668B1 (ru) | 2004-04-13 | 2005-04-08 | Применение органических полисульфидов в борьбе с коррозией, вызываемой кислой сырой нефтью |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US20070163922A1 (fr) |
| EP (1) | EP1756251A1 (fr) |
| JP (1) | JP2007532745A (fr) |
| KR (1) | KR20070005676A (fr) |
| CN (1) | CN1973021A (fr) |
| AR (1) | AR050242A1 (fr) |
| AU (1) | AU2005235761B2 (fr) |
| BR (1) | BRPI0509789A (fr) |
| CA (1) | CA2562102A1 (fr) |
| EA (1) | EA010668B1 (fr) |
| FR (1) | FR2868787B1 (fr) |
| MX (1) | MXPA06011863A (fr) |
| NO (1) | NO20065183L (fr) |
| TW (1) | TWI314952B (fr) |
| UA (1) | UA84741C2 (fr) |
| WO (1) | WO2005103208A1 (fr) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104152192B (zh) * | 2013-05-13 | 2016-05-25 | 刘爱国 | 一种汽柴油防腐剂 |
| KR101990826B1 (ko) | 2019-03-18 | 2019-06-19 | 영화진흥위원회 | 청각장애인의 관람 환경 개선용 시각 제공장치 |
| US20210255609A1 (en) * | 2020-02-14 | 2021-08-19 | Exxonmobil Research And Engineering Company | Systems and methods for monitoring and predicting a risk state of an industrial process |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3062612A (en) * | 1959-04-25 | 1962-11-06 | Inst Francais Du Petrole | Method of protecting metals against electrochemical corrosion of the acidic type |
| DE3437936A1 (de) * | 1984-10-17 | 1986-04-17 | Peter, Siegfried, Prof.Dr., 8525 Uttenreuth | Verfahren und mittel zur bekaempfung der korrosion unter reduzierenden bedingungen |
| US5182013A (en) * | 1990-12-21 | 1993-01-26 | Exxon Chemical Patents Inc. | Naphthenic acid corrosion inhibitors |
| US5464525A (en) * | 1994-12-13 | 1995-11-07 | Betz Laboratories, Inc. | High temperature corrosion inhibitor |
| US5863415A (en) * | 1996-05-30 | 1999-01-26 | Baker Hughes Incorporated | Control of naphthenic acid corrosion with thiophosporus compounds |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2708199A (en) * | 1951-10-24 | 1955-05-10 | Continental Oil Co | Preparation of organic polysulfides |
| US3022351A (en) * | 1957-03-07 | 1962-02-20 | Phillips Petroleum Co | Production of organic polysulfides |
| US3038013A (en) * | 1959-08-25 | 1962-06-05 | Phillips Petroleum Co | Color improvement in synthesis of polysulfides |
| US5500107A (en) * | 1994-03-15 | 1996-03-19 | Betz Laboratories, Inc. | High temperature corrosion inhibitor |
| US5457234A (en) * | 1994-06-20 | 1995-10-10 | Phillips Petroleum Company | Process for treating organic polysulfide compounds |
| US5552085A (en) * | 1994-08-31 | 1996-09-03 | Nalco Chemical Company | Phosphorus thioacid ester inhibitor for naphthenic acid corrosion |
| US5630964A (en) | 1995-05-10 | 1997-05-20 | Nalco/Exxon Energy Chemicals, L.P. | Use of sulfiding agents for enhancing the efficacy of phosphorus in controlling high temperature corrosion attack |
-
2004
- 2004-04-13 FR FR0403838A patent/FR2868787B1/fr not_active Expired - Fee Related
-
2005
- 2005-04-08 CA CA002562102A patent/CA2562102A1/fr not_active Abandoned
- 2005-04-08 JP JP2007507813A patent/JP2007532745A/ja not_active Withdrawn
- 2005-04-08 EA EA200601679A patent/EA010668B1/ru not_active IP Right Cessation
- 2005-04-08 BR BRPI0509789-4A patent/BRPI0509789A/pt not_active IP Right Cessation
- 2005-04-08 AU AU2005235761A patent/AU2005235761B2/en not_active Expired - Fee Related
- 2005-04-08 KR KR1020067021376A patent/KR20070005676A/ko not_active Application Discontinuation
- 2005-04-08 UA UAA200610725A patent/UA84741C2/ru unknown
- 2005-04-08 US US11/547,920 patent/US20070163922A1/en not_active Abandoned
- 2005-04-08 EP EP05753703A patent/EP1756251A1/fr not_active Withdrawn
- 2005-04-08 WO PCT/FR2005/000861 patent/WO2005103208A1/fr active Application Filing
- 2005-04-08 MX MXPA06011863A patent/MXPA06011863A/es active IP Right Grant
- 2005-04-08 CN CNA2005800194186A patent/CN1973021A/zh active Pending
- 2005-04-11 TW TW094111355A patent/TWI314952B/zh not_active IP Right Cessation
- 2005-04-12 AR ARP050101429A patent/AR050242A1/es active IP Right Grant
-
2006
- 2006-11-10 NO NO20065183A patent/NO20065183L/no not_active Application Discontinuation
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3062612A (en) * | 1959-04-25 | 1962-11-06 | Inst Francais Du Petrole | Method of protecting metals against electrochemical corrosion of the acidic type |
| DE3437936A1 (de) * | 1984-10-17 | 1986-04-17 | Peter, Siegfried, Prof.Dr., 8525 Uttenreuth | Verfahren und mittel zur bekaempfung der korrosion unter reduzierenden bedingungen |
| US5182013A (en) * | 1990-12-21 | 1993-01-26 | Exxon Chemical Patents Inc. | Naphthenic acid corrosion inhibitors |
| US5464525A (en) * | 1994-12-13 | 1995-11-07 | Betz Laboratories, Inc. | High temperature corrosion inhibitor |
| US5863415A (en) * | 1996-05-30 | 1999-01-26 | Baker Hughes Incorporated | Control of naphthenic acid corrosion with thiophosporus compounds |
Also Published As
| Publication number | Publication date |
|---|---|
| BRPI0509789A (pt) | 2007-10-23 |
| AU2005235761B2 (en) | 2009-12-17 |
| EP1756251A1 (fr) | 2007-02-28 |
| TW200606246A (en) | 2006-02-16 |
| US20070163922A1 (en) | 2007-07-19 |
| FR2868787A1 (fr) | 2005-10-14 |
| WO2005103208A1 (fr) | 2005-11-03 |
| CA2562102A1 (fr) | 2005-11-03 |
| FR2868787B1 (fr) | 2006-06-23 |
| AU2005235761A1 (en) | 2005-11-03 |
| JP2007532745A (ja) | 2007-11-15 |
| TWI314952B (en) | 2009-09-21 |
| AR050242A1 (es) | 2006-10-11 |
| UA84741C2 (ru) | 2008-11-25 |
| CN1973021A (zh) | 2007-05-30 |
| NO20065183L (no) | 2006-11-10 |
| EA200601679A1 (ru) | 2007-04-27 |
| KR20070005676A (ko) | 2007-01-10 |
| MXPA06011863A (es) | 2007-04-16 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM4A | Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s) |
Designated state(s): AM KG MD TJ |
|
| MM4A | Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s) |
Designated state(s): AZ BY KZ TM RU |