EA006017B1 - Способ получения олефинов - Google Patents
Способ получения олефинов Download PDFInfo
- Publication number
- EA006017B1 EA006017B1 EA200300108A EA200300108A EA006017B1 EA 006017 B1 EA006017 B1 EA 006017B1 EA 200300108 A EA200300108 A EA 200300108A EA 200300108 A EA200300108 A EA 200300108A EA 006017 B1 EA006017 B1 EA 006017B1
- Authority
- EA
- Eurasian Patent Office
- Prior art keywords
- catalyst
- catalytic
- catalytic layer
- metal
- promoter
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 62
- 150000001336 alkenes Chemical class 0.000 title claims abstract description 28
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 8
- 239000003054 catalyst Substances 0.000 claims abstract description 202
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims abstract description 111
- 229910052751 metal Inorganic materials 0.000 claims abstract description 65
- 239000002184 metal Substances 0.000 claims abstract description 65
- 229910052697 platinum Inorganic materials 0.000 claims abstract description 54
- 239000010949 copper Substances 0.000 claims abstract description 50
- 239000000203 mixture Substances 0.000 claims abstract description 42
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 41
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 41
- 239000007789 gas Substances 0.000 claims abstract description 33
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 32
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 31
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 31
- 239000001301 oxygen Substances 0.000 claims abstract description 31
- 229910052802 copper Inorganic materials 0.000 claims abstract description 30
- 238000002485 combustion reaction Methods 0.000 claims abstract description 26
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 claims abstract description 25
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000000446 fuel Substances 0.000 claims abstract description 18
- 230000000737 periodic effect Effects 0.000 claims abstract description 17
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract description 5
- 230000003197 catalytic effect Effects 0.000 claims description 184
- 239000001257 hydrogen Substances 0.000 claims description 27
- 229910052739 hydrogen Inorganic materials 0.000 claims description 27
- 150000003624 transition metals Chemical group 0.000 claims description 27
- 229910052723 transition metal Inorganic materials 0.000 claims description 26
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 19
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 18
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 14
- 239000000919 ceramic Substances 0.000 claims description 9
- 229910052763 palladium Inorganic materials 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 229910052799 carbon Inorganic materials 0.000 claims description 7
- 238000006356 dehydrogenation reaction Methods 0.000 claims description 7
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 6
- 229910052804 chromium Inorganic materials 0.000 claims description 6
- 229910052703 rhodium Inorganic materials 0.000 claims description 6
- 239000010948 rhodium Substances 0.000 claims description 6
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims description 6
- -1 P1 / 8p Substances 0.000 claims description 5
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims description 4
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 3
- 239000001569 carbon dioxide Substances 0.000 claims description 3
- 239000001273 butane Substances 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 claims description 2
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 claims description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims description 2
- 239000012188 paraffin wax Substances 0.000 claims description 2
- 239000001294 propane Substances 0.000 claims description 2
- 229910052720 vanadium Inorganic materials 0.000 claims 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract description 38
- 239000005977 Ethylene Substances 0.000 abstract description 38
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract description 12
- 229910017052 cobalt Inorganic materials 0.000 abstract description 6
- 239000010941 cobalt Substances 0.000 abstract description 6
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract description 6
- 229910052759 nickel Inorganic materials 0.000 abstract description 6
- 229910052741 iridium Inorganic materials 0.000 abstract description 4
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 abstract description 4
- 229910052721 tungsten Inorganic materials 0.000 abstract 1
- 239000010410 layer Substances 0.000 description 181
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 58
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 38
- 238000002474 experimental method Methods 0.000 description 27
- 239000000243 solution Substances 0.000 description 25
- 238000006243 chemical reaction Methods 0.000 description 20
- 229910052757 nitrogen Inorganic materials 0.000 description 19
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 17
- 239000012798 spherical particle Substances 0.000 description 17
- 150000002739 metals Chemical class 0.000 description 14
- 238000002360 preparation method Methods 0.000 description 14
- 239000000047 product Substances 0.000 description 13
- 239000011148 porous material Substances 0.000 description 12
- 239000002994 raw material Substances 0.000 description 12
- 238000005336 cracking Methods 0.000 description 11
- 239000003153 chemical reaction reagent Substances 0.000 description 10
- 239000002356 single layer Substances 0.000 description 10
- FOSZYDNAURUMOT-UHFFFAOYSA-J azane;platinum(4+);tetrachloride Chemical compound N.N.N.N.[Cl-].[Cl-].[Cl-].[Cl-].[Pt+4] FOSZYDNAURUMOT-UHFFFAOYSA-J 0.000 description 9
- 238000001354 calcination Methods 0.000 description 9
- 230000000694 effects Effects 0.000 description 9
- 238000005470 impregnation Methods 0.000 description 9
- 239000007864 aqueous solution Substances 0.000 description 8
- 150000002431 hydrogen Chemical class 0.000 description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 239000011575 calcium Substances 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 238000012545 processing Methods 0.000 description 5
- 239000000376 reactant Substances 0.000 description 5
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 5
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 4
- 239000000969 carrier Substances 0.000 description 4
- 239000012876 carrier material Substances 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 239000006260 foam Substances 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
- 239000008367 deionised water Substances 0.000 description 3
- 229910021641 deionized water Inorganic materials 0.000 description 3
- 238000010790 dilution Methods 0.000 description 3
- 239000012895 dilution Substances 0.000 description 3
- 230000001590 oxidative effect Effects 0.000 description 3
- 235000012239 silicon dioxide Nutrition 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 239000003426 co-catalyst Substances 0.000 description 2
- UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 description 2
- 229910001981 cobalt nitrate Inorganic materials 0.000 description 2
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000006261 foam material Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 229910052762 osmium Inorganic materials 0.000 description 2
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- SSVFCHUBLIJAMI-UHFFFAOYSA-N platinum;hydrochloride Chemical compound Cl.[Pt] SSVFCHUBLIJAMI-UHFFFAOYSA-N 0.000 description 2
- 239000010453 quartz Substances 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 229910052707 ruthenium Inorganic materials 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- DANYXEHCMQHDNX-UHFFFAOYSA-K trichloroiridium Chemical compound Cl[Ir](Cl)Cl DANYXEHCMQHDNX-UHFFFAOYSA-K 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 229910000505 Al2TiO5 Inorganic materials 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 241000264877 Hippospongia communis Species 0.000 description 1
- 241001026509 Kata Species 0.000 description 1
- 229910021626 Tin(II) chloride Inorganic materials 0.000 description 1
- JFBZPFYRPYOZCQ-UHFFFAOYSA-N [Li].[Al] Chemical compound [Li].[Al] JFBZPFYRPYOZCQ-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- KHCPSOMSJYAQSY-UHFFFAOYSA-L azane;dichloroplatinum Chemical compound N.N.N.N.Cl[Pt]Cl KHCPSOMSJYAQSY-UHFFFAOYSA-L 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- MXCNPGJZHAUBMR-UHFFFAOYSA-H calcium zirconium(4+) diphosphate Chemical compound [Ca++].[Zr+4].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O MXCNPGJZHAUBMR-UHFFFAOYSA-H 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 229910002090 carbon oxide Inorganic materials 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 1
- 229910052878 cordierite Inorganic materials 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- JSKIRARMQDRGJZ-UHFFFAOYSA-N dimagnesium dioxido-bis[(1-oxido-3-oxo-2,4,6,8,9-pentaoxa-1,3-disila-5,7-dialuminabicyclo[3.3.1]nonan-7-yl)oxy]silane Chemical compound [Mg++].[Mg++].[O-][Si]([O-])(O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2)O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2 JSKIRARMQDRGJZ-UHFFFAOYSA-N 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000003837 high-temperature calcination Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 230000002101 lytic effect Effects 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 150000005673 monoalkenes Chemical class 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000005839 oxidative dehydrogenation reaction Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000011236 particulate material Substances 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- FHMDYDAXYDRBGZ-UHFFFAOYSA-N platinum tin Chemical compound [Sn].[Pt] FHMDYDAXYDRBGZ-UHFFFAOYSA-N 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- AABBHSMFGKYLKE-SNAWJCMRSA-N propan-2-yl (e)-but-2-enoate Chemical compound C\C=C\C(=O)OC(C)C AABBHSMFGKYLKE-SNAWJCMRSA-N 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000011819 refractory material Substances 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229910052702 rhenium Inorganic materials 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
- 229910001233 yttria-stabilized zirconia Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/42—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
- C07C5/48—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with oxygen as an acceptor
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/08—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of gallium, indium or thallium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/14—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of germanium, tin or lead
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C07C2523/24—Chromium, molybdenum or tungsten
- C07C2523/28—Molybdenum
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C07C2523/24—Chromium, molybdenum or tungsten
- C07C2523/30—Tungsten
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
- C07C2523/42—Platinum
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
- C07C2523/44—Palladium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
- C07C2523/46—Ruthenium, rhodium, osmium or iridium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
- C07C2523/56—Platinum group metals
- C07C2523/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/72—Copper
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with noble metals
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/20—C2-C4 olefins
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/22—Higher olefins
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB0017173.6A GB0017173D0 (en) | 2000-07-12 | 2000-07-12 | Process for the production of olefins |
| PCT/GB2001/002822 WO2002004389A1 (en) | 2000-07-12 | 2001-06-26 | Process for the production of olefins |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EA200300108A1 EA200300108A1 (ru) | 2003-06-26 |
| EA006017B1 true EA006017B1 (ru) | 2005-08-25 |
Family
ID=9895564
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EA200300108A EA006017B1 (ru) | 2000-07-12 | 2001-06-26 | Способ получения олефинов |
| EA200500612A EA007784B1 (ru) | 2000-07-12 | 2001-06-26 | Способ получения олефинов |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EA200500612A EA007784B1 (ru) | 2000-07-12 | 2001-06-26 | Способ получения олефинов |
Country Status (20)
| Country | Link |
|---|---|
| US (1) | US7135603B2 (enExample) |
| EP (1) | EP1299331A1 (enExample) |
| JP (1) | JP2004502836A (enExample) |
| KR (1) | KR100817465B1 (enExample) |
| CN (2) | CN1208292C (enExample) |
| AR (1) | AR029705A1 (enExample) |
| AU (2) | AU2001274338B2 (enExample) |
| BR (1) | BR0112469A (enExample) |
| CA (1) | CA2414186A1 (enExample) |
| CZ (1) | CZ200361A3 (enExample) |
| EA (2) | EA006017B1 (enExample) |
| EG (1) | EG22541A (enExample) |
| GB (1) | GB0017173D0 (enExample) |
| MX (1) | MXPA03000302A (enExample) |
| MY (1) | MY140050A (enExample) |
| NO (1) | NO20030163L (enExample) |
| PL (1) | PL358722A1 (enExample) |
| TW (1) | TW567181B (enExample) |
| WO (1) | WO2002004389A1 (enExample) |
| ZA (1) | ZA200210393B (enExample) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4467872B2 (ja) * | 2002-08-09 | 2010-05-26 | 三菱重工業株式会社 | ガス化ガス用のｃｏｓ処理装置とｃｏｓ処理方法 |
| GB0229497D0 (en) * | 2002-12-18 | 2003-01-22 | Bp Chem Int Ltd | Process for the production of olefins |
| GB0312093D0 (en) * | 2003-05-27 | 2003-07-02 | Bp Chem Int Ltd | Process for the production of olefins |
| GB0312966D0 (en) * | 2003-06-05 | 2003-07-09 | Bp Chem Int Ltd | Process for the production of olefins |
| GB0501255D0 (en) * | 2005-01-21 | 2005-03-02 | Bp Chem Int Ltd | Process for the production of olefins |
| GB0501253D0 (en) * | 2005-01-21 | 2005-03-02 | Bp Chem Int Ltd | Process for the production of olefins |
| WO2006117509A1 (en) * | 2005-04-29 | 2006-11-09 | Ineos Europe Limited | Process for the production of olefins by autothermal cracking |
| EP1899437A1 (en) * | 2005-07-06 | 2008-03-19 | Ineos Europe Limited | Process for the production of olefins |
| KR100948228B1 (ko) * | 2006-09-28 | 2010-03-18 | 주식회사 엘지화학 | 탄화수소 수증기 열분해용 인산화물 촉매, 이의 제조방법및 이를 이용한 경질 올레핀의 제조방법 |
| US7935654B2 (en) * | 2006-09-28 | 2011-05-03 | Lg Chem, Ltd. | Oxide catalyst and phosphoric oxide catalyst for hydrocarbon steam cracking, method for preparing the same and method for preparing olefin by using the same |
| US20080177117A1 (en) * | 2006-10-16 | 2008-07-24 | Abraham Benderly | Integrated catalytic process for converting alkanes to alkenes and catalysts useful for same |
| US8105971B2 (en) * | 2009-04-02 | 2012-01-31 | Lummus Technology Inc. | Process for making catalysts useful for the conversion of paraffins to olefins |
| US8519210B2 (en) * | 2009-04-02 | 2013-08-27 | Lummus Technology Inc. | Process for producing ethylene via oxidative dehydrogenation (ODH) of ethane |
| US8105972B2 (en) * | 2009-04-02 | 2012-01-31 | Lummus Technology Inc. | Catalysts for the conversion of paraffins to olefins and use thereof |
| WO2010133565A1 (en) * | 2009-05-20 | 2010-11-25 | Basf Se | Monolith catalyst and use thereof |
| CN102041033B (zh) * | 2009-10-20 | 2013-09-25 | 中国石油化工股份有限公司 | 一种结合选择性氢燃烧技术的烃类裂解制取低碳烯烃的方法 |
| AU2011201715B8 (en) * | 2010-04-15 | 2014-08-21 | China Petroleum & Chemical Corporation | A process for selective oxidative dehydrogenation of a hydrogen-containing co mixed gas |
| WO2015092006A2 (en) * | 2013-12-20 | 2015-06-25 | Basf Se | Two-layer catalyst bed |
| JP6300281B2 (ja) * | 2015-03-26 | 2018-03-28 | Ｊｘｔｇエネルギー株式会社 | 共役ジエンの製造方法及び反応装置 |
| KR20240059648A (ko) | 2017-04-19 | 2024-05-07 | 더 보드 오브 리젠츠 오브 더 유니버시티 오브 텍사스 시스템 | 조작된 항원 수용체를 발현하는 면역 세포 |
| CN111918661A (zh) | 2018-02-21 | 2020-11-10 | 得克萨斯大学体系董事会 | 用于活化和扩增自然杀伤细胞的方法及其用途 |
| KR102628005B1 (ko) | 2019-11-27 | 2024-01-19 | 에스케이가스 주식회사 | 알칸족 가스로부터 올레핀 제조용 탈수소촉매 및 그 제조방법 |
| KR20250097066A (ko) * | 2023-12-21 | 2025-06-30 | 한국화학연구원 | 탈수소화 및 크래킹 반응을 통한 폐플라스틱으로부터 경질올레핀을 제조하는 방법 |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1213875A (en) * | 1982-11-29 | 1986-11-12 | Shigeo Uno | Catalyst for catalytic combustion |
| US5527979A (en) | 1993-08-27 | 1996-06-18 | Mobil Oil Corporation | Process for the catalytic dehydrogenation of alkanes to alkenes with simultaneous combustion of hydrogen |
| GB9819603D0 (en) * | 1998-09-08 | 1998-11-04 | Bp Chem Int Ltd | Process for the production of olefins |
-
2000
- 2000-07-12 GB GBGB0017173.6A patent/GB0017173D0/en not_active Ceased
-
2001
- 2001-06-26 EA EA200300108A patent/EA006017B1/ru not_active IP Right Cessation
- 2001-06-26 AU AU2001274338A patent/AU2001274338B2/en not_active Ceased
- 2001-06-26 EA EA200500612A patent/EA007784B1/ru not_active IP Right Cessation
- 2001-06-26 US US10/332,776 patent/US7135603B2/en not_active Expired - Fee Related
- 2001-06-26 CN CNB018125778A patent/CN1208292C/zh not_active Expired - Fee Related
- 2001-06-26 CN CNA2005100686892A patent/CN1690029A/zh active Pending
- 2001-06-26 BR BR0112469-2A patent/BR0112469A/pt not_active IP Right Cessation
- 2001-06-26 EP EP01940845A patent/EP1299331A1/en not_active Withdrawn
- 2001-06-26 AU AU7433801A patent/AU7433801A/xx active Pending
- 2001-06-26 WO PCT/GB2001/002822 patent/WO2002004389A1/en not_active Ceased
- 2001-06-26 CZ CZ200361A patent/CZ200361A3/cs unknown
- 2001-06-26 JP JP2002509058A patent/JP2004502836A/ja not_active Withdrawn
- 2001-06-26 CA CA002414186A patent/CA2414186A1/en not_active Abandoned
- 2001-06-26 KR KR1020037000320A patent/KR100817465B1/ko not_active Expired - Fee Related
- 2001-06-26 PL PL01358722A patent/PL358722A1/xx not_active IP Right Cessation
- 2001-06-26 MX MXPA03000302A patent/MXPA03000302A/es active IP Right Grant
- 2001-07-02 TW TW090116146A patent/TW567181B/zh not_active IP Right Cessation
- 2001-07-10 EG EG20010765A patent/EG22541A/xx active
- 2001-07-11 AR ARP010103300A patent/AR029705A1/es active IP Right Grant
- 2001-07-11 MY MYPI20013292A patent/MY140050A/en unknown
-
2002
- 2002-12-20 ZA ZA200210393A patent/ZA200210393B/en unknown
-
2003
- 2003-01-13 NO NO20030163A patent/NO20030163L/no not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| PL358722A1 (en) | 2004-08-09 |
| CA2414186A1 (en) | 2002-01-17 |
| US20040015031A1 (en) | 2004-01-22 |
| EG22541A (en) | 2003-03-31 |
| AU7433801A (en) | 2002-01-21 |
| GB0017173D0 (en) | 2000-08-30 |
| WO2002004389A1 (en) | 2002-01-17 |
| KR20030015375A (ko) | 2003-02-20 |
| AR029705A1 (es) | 2003-07-10 |
| EP1299331A1 (en) | 2003-04-09 |
| AU2001274338B2 (en) | 2005-12-22 |
| EA200500612A1 (ru) | 2005-08-25 |
| MY140050A (en) | 2009-11-30 |
| CN1208292C (zh) | 2005-06-29 |
| KR100817465B1 (ko) | 2008-03-31 |
| CZ200361A3 (cs) | 2003-04-16 |
| EA200300108A1 (ru) | 2003-06-26 |
| TW567181B (en) | 2003-12-21 |
| CN1690029A (zh) | 2005-11-02 |
| US7135603B2 (en) | 2006-11-14 |
| EA007784B1 (ru) | 2007-02-27 |
| NO20030163D0 (no) | 2003-01-13 |
| NO20030163L (no) | 2003-02-27 |
| MXPA03000302A (es) | 2004-04-05 |
| BR0112469A (pt) | 2003-07-29 |
| ZA200210393B (en) | 2003-11-13 |
| JP2004502836A (ja) | 2004-01-29 |
| CN1441758A (zh) | 2003-09-10 |
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| MM4A | Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s) |
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| MM4A | Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s) |
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