EA001619B1 - Способ получения базового компонента смазочного масла - Google Patents
Способ получения базового компонента смазочного масла Download PDFInfo
- Publication number
- EA001619B1 EA001619B1 EA199900108A EA199900108A EA001619B1 EA 001619 B1 EA001619 B1 EA 001619B1 EA 199900108 A EA199900108 A EA 199900108A EA 199900108 A EA199900108 A EA 199900108A EA 001619 B1 EA001619 B1 EA 001619B1
- Authority
- EA
- Eurasian Patent Office
- Prior art keywords
- catalyst
- noble metal
- process according
- group
- lubricating oil
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 111
- 239000010687 lubricating oil Substances 0.000 title claims abstract description 63
- 230000008569 process Effects 0.000 title abstract description 62
- 239000003054 catalyst Substances 0.000 claims abstract description 255
- 238000006243 chemical reaction Methods 0.000 claims abstract description 82
- 239000011148 porous material Substances 0.000 claims abstract description 57
- 238000004517 catalytic hydrocracking Methods 0.000 claims abstract description 56
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims abstract description 54
- 238000006317 isomerization reaction Methods 0.000 claims abstract description 51
- 239000003921 oil Substances 0.000 claims abstract description 51
- 229910000510 noble metal Inorganic materials 0.000 claims abstract description 50
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims abstract description 49
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 43
- 238000005984 hydrogenation reaction Methods 0.000 claims abstract description 41
- 239000010457 zeolite Substances 0.000 claims abstract description 35
- 239000001257 hydrogen Substances 0.000 claims abstract description 34
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 34
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 33
- 239000011159 matrix material Substances 0.000 claims abstract description 31
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract description 29
- DCAYPVUWAIABOU-UHFFFAOYSA-N hexadecane Chemical compound CCCCCCCCCCCCCCCC DCAYPVUWAIABOU-UHFFFAOYSA-N 0.000 claims abstract description 27
- 239000002808 molecular sieve Substances 0.000 claims abstract description 25
- 229910052697 platinum Inorganic materials 0.000 claims abstract description 25
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims abstract description 25
- 229910052763 palladium Inorganic materials 0.000 claims abstract description 22
- 239000000203 mixture Substances 0.000 claims abstract description 14
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 9
- 239000000956 alloy Substances 0.000 claims abstract description 9
- 238000012545 processing Methods 0.000 claims description 15
- 229910000323 aluminium silicate Inorganic materials 0.000 claims description 14
- 239000000463 material Substances 0.000 claims description 12
- 229910001260 Pt alloy Inorganic materials 0.000 claims description 4
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract description 13
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract description 11
- 229910001252 Pd alloy Inorganic materials 0.000 abstract description 5
- 239000000377 silicon dioxide Substances 0.000 abstract description 4
- 229910001657 ferrierite group Inorganic materials 0.000 abstract description 3
- 229910052681 coesite Inorganic materials 0.000 abstract 1
- 229910052906 cristobalite Inorganic materials 0.000 abstract 1
- 230000001747 exhibiting effect Effects 0.000 abstract 1
- 239000012013 faujasite Substances 0.000 abstract 1
- 235000012239 silicon dioxide Nutrition 0.000 abstract 1
- 229910052682 stishovite Inorganic materials 0.000 abstract 1
- 229910052905 tridymite Inorganic materials 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 description 46
- 239000000047 product Substances 0.000 description 39
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 36
- 239000012188 paraffin wax Substances 0.000 description 33
- 239000002585 base Substances 0.000 description 32
- 229910052751 metal Inorganic materials 0.000 description 26
- 239000002184 metal Substances 0.000 description 26
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 24
- 229910052717 sulfur Inorganic materials 0.000 description 24
- 239000011593 sulfur Substances 0.000 description 24
- 238000009835 boiling Methods 0.000 description 22
- 238000005336 cracking Methods 0.000 description 19
- 229910052757 nitrogen Inorganic materials 0.000 description 18
- 239000010953 base metal Substances 0.000 description 14
- 230000000694 effects Effects 0.000 description 14
- 229930195733 hydrocarbon Natural products 0.000 description 13
- 150000002430 hydrocarbons Chemical class 0.000 description 13
- 238000004519 manufacturing process Methods 0.000 description 13
- 239000002994 raw material Substances 0.000 description 13
- 239000004215 Carbon black (E152) Substances 0.000 description 12
- 150000002739 metals Chemical class 0.000 description 12
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 11
- 239000002199 base oil Substances 0.000 description 11
- 150000001875 compounds Chemical class 0.000 description 11
- 238000004821 distillation Methods 0.000 description 11
- 239000007789 gas Substances 0.000 description 11
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 10
- 239000011230 binding agent Substances 0.000 description 10
- 239000002253 acid Substances 0.000 description 9
- 230000007423 decrease Effects 0.000 description 9
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 9
- 229910052753 mercury Inorganic materials 0.000 description 9
- 235000019809 paraffin wax Nutrition 0.000 description 9
- 235000019271 petrolatum Nutrition 0.000 description 9
- 150000001491 aromatic compounds Chemical class 0.000 description 8
- 239000003208 petroleum Substances 0.000 description 8
- -1 platinum group metals Chemical class 0.000 description 8
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 7
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 7
- 229910052809 inorganic oxide Inorganic materials 0.000 description 7
- 238000002441 X-ray diffraction Methods 0.000 description 6
- 239000010779 crude oil Substances 0.000 description 6
- 229910052759 nickel Inorganic materials 0.000 description 6
- 238000000926 separation method Methods 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 229910052721 tungsten Inorganic materials 0.000 description 6
- 239000010937 tungsten Substances 0.000 description 6
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 5
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 5
- 229910021529 ammonia Inorganic materials 0.000 description 5
- 229910017052 cobalt Inorganic materials 0.000 description 5
- 239000010941 cobalt Substances 0.000 description 5
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 5
- 238000009826 distribution Methods 0.000 description 5
- 238000005470 impregnation Methods 0.000 description 5
- 229910052741 iridium Inorganic materials 0.000 description 5
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 229910052750 molybdenum Inorganic materials 0.000 description 5
- 239000011733 molybdenum Substances 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 229910052707 ruthenium Inorganic materials 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 5
- 239000005662 Paraffin oil Substances 0.000 description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 239000012530 fluid Substances 0.000 description 4
- 125000005842 heteroatom Chemical group 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 230000002829 reductive effect Effects 0.000 description 4
- 229910052710 silicon Inorganic materials 0.000 description 4
- 239000010703 silicon Substances 0.000 description 4
- 238000000638 solvent extraction Methods 0.000 description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 3
- 206010030113 Oedema Diseases 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 229910052804 chromium Inorganic materials 0.000 description 3
- 239000011651 chromium Substances 0.000 description 3
- 238000000975 co-precipitation Methods 0.000 description 3
- 230000008021 deposition Effects 0.000 description 3
- 239000000314 lubricant Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 238000002459 porosimetry Methods 0.000 description 3
- 229910052703 rhodium Inorganic materials 0.000 description 3
- 239000010948 rhodium Substances 0.000 description 3
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 3
- 229920006395 saturated elastomer Polymers 0.000 description 3
- 229910052814 silicon oxide Inorganic materials 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 239000001993 wax Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 238000004523 catalytic cracking Methods 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 239000000295 fuel oil Substances 0.000 description 2
- 239000000017 hydrogel Substances 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 238000005342 ion exchange Methods 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 229940049311 joint gel Drugs 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 239000000395 magnesium oxide Substances 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000010705 motor oil Substances 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- 229910052762 osmium Inorganic materials 0.000 description 2
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 2
- 239000010690 paraffinic oil Substances 0.000 description 2
- 230000000737 periodic effect Effects 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 231100000572 poisoning Toxicity 0.000 description 2
- 230000000607 poisoning effect Effects 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 125000000101 thioether group Chemical group 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052726 zirconium Inorganic materials 0.000 description 2
- FRWYFWZENXDZMU-UHFFFAOYSA-N 2-iodoquinoline Chemical compound C1=CC=CC2=NC(I)=CC=C21 FRWYFWZENXDZMU-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 1
- 229910000013 Ammonium bicarbonate Inorganic materials 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 239000004113 Sepiolite Substances 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- SHPBBNULESVQRH-UHFFFAOYSA-N [O-2].[O-2].[Ti+4].[Zr+4] Chemical compound [O-2].[O-2].[Ti+4].[Zr+4] SHPBBNULESVQRH-UHFFFAOYSA-N 0.000 description 1
- AGMNAIOLVWYHRE-UHFFFAOYSA-N [O-2].[Th+4].[Si+2]=O.[O-2].[O-2] Chemical compound [O-2].[Th+4].[Si+2]=O.[O-2].[O-2] AGMNAIOLVWYHRE-UHFFFAOYSA-N 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 239000008186 active pharmaceutical agent Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical class O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 235000012538 ammonium bicarbonate Nutrition 0.000 description 1
- 239000001099 ammonium carbonate Substances 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- 235000012216 bentonite Nutrition 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- LTPBRCUWZOMYOC-UHFFFAOYSA-N beryllium oxide Inorganic materials O=[Be] LTPBRCUWZOMYOC-UHFFFAOYSA-N 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000012876 carrier material Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000003841 chloride salts Chemical class 0.000 description 1
- 238000003776 cleavage reaction Methods 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 238000007405 data analysis Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000000994 depressogenic effect Effects 0.000 description 1
- 239000010710 diesel engine oil Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000005194 fractionation Methods 0.000 description 1
- 239000012458 free base Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000007373 indentation Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- OTUXRAAQAFDEQT-UHFFFAOYSA-N magnesium oxosilicon(2+) oxygen(2-) Chemical compound [O-2].[Mg+2].[Si+2]=O.[O-2] OTUXRAAQAFDEQT-UHFFFAOYSA-N 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- MOWMLACGTDMJRV-UHFFFAOYSA-N nickel tungsten Chemical compound [Ni].[W] MOWMLACGTDMJRV-UHFFFAOYSA-N 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 238000009828 non-uniform distribution Methods 0.000 description 1
- 125000001477 organic nitrogen group Chemical group 0.000 description 1
- FMLYSTGQBVZCGN-UHFFFAOYSA-N oxosilicon(2+) oxygen(2-) titanium(4+) Chemical compound [O-2].[Ti+4].[Si+2]=O.[O-2].[O-2] FMLYSTGQBVZCGN-UHFFFAOYSA-N 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- 239000003348 petrochemical agent Substances 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 238000004375 physisorption Methods 0.000 description 1
- 229920013639 polyalphaolefin Polymers 0.000 description 1
- 239000010734 process oil Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000006722 reduction reaction Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 239000011819 refractory material Substances 0.000 description 1
- 229910052702 rhenium Inorganic materials 0.000 description 1
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 1
- 238000009738 saturating Methods 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 235000019355 sepiolite Nutrition 0.000 description 1
- 229910052624 sepiolite Inorganic materials 0.000 description 1
- 239000003079 shale oil Substances 0.000 description 1
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Chemical class [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 1
- 235000019351 sodium silicates Nutrition 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000010689 synthetic lubricating oil Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000004227 thermal cracking Methods 0.000 description 1
- 229910003452 thorium oxide Inorganic materials 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 239000011240 wet gel Substances 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
- C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
- C10G65/12—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including cracking steps and other hydrotreatment steps
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
- C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
- C10G45/64—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
- Lubricants (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US2175396P | 1996-07-15 | 1996-07-15 | |
| PCT/US1997/012339 WO1998002503A1 (en) | 1996-07-15 | 1997-07-15 | Layered catalyst system for lube oil hydroconversion |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EA199900108A1 EA199900108A1 (ru) | 1999-06-24 |
| EA001619B1 true EA001619B1 (ru) | 2001-06-25 |
Family
ID=21805944
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EA199900108A EA001619B1 (ru) | 1996-07-15 | 1997-07-15 | Способ получения базового компонента смазочного масла |
Country Status (13)
| Country | Link |
|---|---|
| EP (1) | EP0912660A1 (cs) |
| JP (1) | JP2000515185A (cs) |
| KR (1) | KR20000023803A (cs) |
| AU (1) | AU724363B2 (cs) |
| BR (1) | BR9710326A (cs) |
| CA (1) | CA2259539A1 (cs) |
| CZ (1) | CZ9699A3 (cs) |
| EA (1) | EA001619B1 (cs) |
| HU (1) | HUP0004280A3 (cs) |
| PL (1) | PL331037A1 (cs) |
| TR (1) | TR199900097T2 (cs) |
| TW (1) | TW399092B (cs) |
| WO (1) | WO1998002503A1 (cs) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9057026B2 (en) | 2009-08-18 | 2015-06-16 | Jx Nippon Oil & Energy Corporation | Method for producing lubricant base oil |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6162350A (en) * | 1997-07-15 | 2000-12-19 | Exxon Research And Engineering Company | Hydroprocessing using bulk Group VIII/Group VIB catalysts (HEN-9901) |
| FR2797270B1 (fr) * | 1999-08-02 | 2003-03-07 | Inst Francais Du Petrole | Procede et flexible de production de bases huiles et eventuellement de distillats moyens de tres haute qualite |
| FR2785617B1 (fr) * | 1998-11-06 | 2001-01-05 | Inst Francais Du Petrole | Procede flexible de production de bases huiles et eventuellement de distillats moyens de tres haute qualite |
| FR2785616B1 (fr) * | 1998-11-06 | 2000-12-08 | Inst Francais Du Petrole | Procede flexible de production de bases huiles et eventuellement de distillats moyens de tres haute qualite |
| DE69932186T2 (de) * | 1998-11-06 | 2006-11-23 | Institut Français du Pétrole, Rueil-Malmaison | Anpassungsfähiges verfahren zur herstellung medizinischer öle und gegebenenfalls mitteldestillaten |
| WO2000073402A1 (en) | 1999-05-28 | 2000-12-07 | Shell Internationale Research Maatschappij B.V. | Process to prepare a lubricating base oil |
| FR2808028B1 (fr) * | 2000-04-21 | 2003-09-05 | Inst Francais Du Petrole | Procede flexible de production de bases huiles avec une zeolithe zsm-48 |
| CA2505607A1 (en) * | 2000-11-16 | 2004-05-27 | Exxonmobil Research And Engineering Company | Process for improving basestock low temperature performance using a combination catalyst system |
| JP2004521977A (ja) | 2001-02-13 | 2004-07-22 | シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ | 潤滑剤組成物 |
| MY137259A (en) | 2001-03-05 | 2009-01-30 | Shell Int Research | Process to prepare a lubricating base oil and a gas oil. |
| AR032941A1 (es) * | 2001-03-05 | 2003-12-03 | Shell Int Research | Un procedimiento para preparar un aceite base lubricante y aceite base obtenido, con sus diversas utilizaciones |
| MY139353A (en) | 2001-03-05 | 2009-09-30 | Shell Int Research | Process to prepare a lubricating base oil and a gas oil |
| DE60305016T3 (de) * | 2002-02-25 | 2012-02-09 | Shell Internationale Research Maatschappij B.V. | Verfahren zur herstellung eines katalytisch entparaffinierten gasöls oder einer katalytisch entparaffinierten gasölmischkomponente |
| DE60302366T2 (de) | 2002-07-18 | 2006-08-03 | Shell Internationale Research Maatschappij B.V. | Verfahren zur herstellung eines mirkokristallinen wachses und eines mitteldestillat-brennstoffs oder -kraftstoffs |
| US7198710B2 (en) * | 2003-03-10 | 2007-04-03 | Chevron U.S.A. Inc. | Isomerization/dehazing process for base oils from Fischer-Tropsch wax |
| JP4938447B2 (ja) | 2003-06-23 | 2012-05-23 | シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ | 潤滑基油の製造方法 |
| JP2007526381A (ja) | 2004-03-02 | 2007-09-13 | シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ | ２種以上の基油グレード及び中間蒸留物の連続的製造方法 |
| US20050269245A1 (en) * | 2004-06-03 | 2005-12-08 | Huve Laurent G | Process for desulphurising and dewaxing a hydrocarbon feedstock boiling in the gasoil boiling range |
| EP1828351A1 (en) * | 2004-12-23 | 2007-09-05 | Shell Internationale Research Maatschappij B.V. | Process to prepare two iso paraffinic products from a fisher-tropsch derived feed |
| TWI473652B (zh) | 2008-12-26 | 2015-02-21 | Nippon Oil Corp | Hydrogenated isomerization catalyst, method for producing the same, dewaxing method for hydrocarbon oil and method for producing lubricating base oil |
| CA2762660C (en) | 2009-06-12 | 2017-11-28 | Albemarle Europe Sprl | Sapo molecular sieve catalysts and their preparation and uses |
| CN101942321B (zh) * | 2009-07-09 | 2015-01-14 | 中国石油化工股份有限公司 | 一种异构脱蜡生产润滑油基础油的方法 |
| US8431014B2 (en) | 2009-10-06 | 2013-04-30 | Chevron U.S.A. Inc. | Process and catalyst system for improving dewaxing catalyst stability and lubricant oil yield |
| US20120000818A1 (en) * | 2010-06-30 | 2012-01-05 | Exxonmobil Research And Engineering Company | Process for the preparation of group ii and group iii lube base oils |
| CN103459563B (zh) * | 2011-03-31 | 2015-06-17 | 雪佛龙美国公司 | 用于改进脱蜡催化剂稳定性和润滑油产率的新型方法和催化剂体系 |
| EP2734605B1 (en) * | 2011-07-20 | 2017-10-25 | ExxonMobil Research and Engineering Company | Production of lubricating oil basestocks |
| US9587184B2 (en) * | 2011-09-21 | 2017-03-07 | Exxonmobil Research And Engineering Company | Lubricant base oil hydroprocessing and blending |
| JP6506667B2 (ja) * | 2015-09-29 | 2019-04-24 | Ｊｘｔｇエネルギー株式会社 | 潤滑油基油の製造方法 |
| JP6034479B2 (ja) * | 2015-12-11 | 2016-11-30 | シェブロン ユー．エス．エー． インコーポレイテッド | 脱蝋触媒の安定性及び潤滑油の収率を改良するための新規なプロセス及び触媒システム |
| WO2022164868A1 (en) * | 2021-01-26 | 2022-08-04 | Chevron U.S.A. Inc. | Process for making heavy grade base oil products |
| CN116790286A (zh) * | 2023-07-12 | 2023-09-22 | 山东公泉化工股份有限公司 | 一种加氢裂化方法 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0188898B1 (en) * | 1984-12-21 | 1990-09-19 | Mobil Oil Corporation | Cascade dewaxing process |
| US4913797A (en) * | 1985-11-21 | 1990-04-03 | Mobil Oil Corporation | Catalyst hydrotreating and dewaxing process |
| US5358628A (en) * | 1990-07-05 | 1994-10-25 | Mobil Oil Corporation | Production of high viscosity index lubricants |
| US5935414A (en) * | 1993-10-08 | 1999-08-10 | Akzo Nobel Nv | Hydrocracking and hydrodewaxing process |
| US5565086A (en) * | 1994-11-01 | 1996-10-15 | Exxon Research And Engineering Company | Catalyst combination for improved wax isomerization |
-
1997
- 1997-07-15 CZ CZ9996A patent/CZ9699A3/cs unknown
- 1997-07-15 JP JP10506261A patent/JP2000515185A/ja active Pending
- 1997-07-15 BR BR9710326A patent/BR9710326A/pt not_active Application Discontinuation
- 1997-07-15 TR TR1999/00097T patent/TR199900097T2/xx unknown
- 1997-07-15 WO PCT/US1997/012339 patent/WO1998002503A1/en not_active Ceased
- 1997-07-15 EP EP97933476A patent/EP0912660A1/en not_active Ceased
- 1997-07-15 EA EA199900108A patent/EA001619B1/ru not_active IP Right Cessation
- 1997-07-15 HU HU0004280A patent/HUP0004280A3/hu unknown
- 1997-07-15 CA CA002259539A patent/CA2259539A1/en not_active Abandoned
- 1997-07-15 AU AU36649/97A patent/AU724363B2/en not_active Ceased
- 1997-07-15 PL PL97331037A patent/PL331037A1/xx unknown
-
1998
- 1998-07-15 TW TW087111496A patent/TW399092B/zh active
-
1999
- 1999-01-15 KR KR1019997000287A patent/KR20000023803A/ko not_active Ceased
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9057026B2 (en) | 2009-08-18 | 2015-06-16 | Jx Nippon Oil & Energy Corporation | Method for producing lubricant base oil |
Also Published As
| Publication number | Publication date |
|---|---|
| BR9710326A (pt) | 1999-08-17 |
| AU3664997A (en) | 1998-02-09 |
| KR20000023803A (ko) | 2000-04-25 |
| CA2259539A1 (en) | 1998-01-22 |
| EA199900108A1 (ru) | 1999-06-24 |
| HUP0004280A2 (hu) | 2001-04-28 |
| AU724363B2 (en) | 2000-09-21 |
| CZ9699A3 (cs) | 1999-04-14 |
| TR199900097T2 (xx) | 1999-03-22 |
| JP2000515185A (ja) | 2000-11-14 |
| WO1998002503A1 (en) | 1998-01-22 |
| EP0912660A1 (en) | 1999-05-06 |
| PL331037A1 (en) | 1999-06-21 |
| HUP0004280A3 (en) | 2001-06-28 |
| TW399092B (en) | 2000-07-21 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM4A | Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s) |
Designated state(s): AM AZ BY KZ KG MD TJ TM RU |