DK2794787T3 - Tørremiddel til selvoxiderende belægningssammensætninger - Google Patents
Tørremiddel til selvoxiderende belægningssammensætninger Download PDFInfo
- Publication number
- DK2794787T3 DK2794787T3 DK12809736.7T DK12809736T DK2794787T3 DK 2794787 T3 DK2794787 T3 DK 2794787T3 DK 12809736 T DK12809736 T DK 12809736T DK 2794787 T3 DK2794787 T3 DK 2794787T3
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- DK
- Denmark
- Prior art keywords
- drying
- heteroatoms
- optionally substituted
- resin
- composition
- Prior art date
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Classifications
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- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
- B05D3/04—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to gases
- B05D3/0406—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to gases the gas being air
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/24—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials for applying particular liquids or other fluent materials
- B05D7/26—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials for applying particular liquids or other fluent materials synthetic lacquers or varnishes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/10—Metal compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0091—Complexes with metal-heteroatom-bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/08—Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09F—NATURAL RESINS; FRENCH POLISH; DRYING-OILS; OIL DRYING AGENTS, i.e. SICCATIVES; TURPENTINE
- C09F9/00—Compounds to be used as driers, i.e. siccatives
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F26—DRYING
- F26B—DRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
- F26B5/00—Drying solid materials or objects by processes not involving the application of heat
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- Chemical & Material Sciences (AREA)
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- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Molecular Biology (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Claims (15)
1. Tørremiddel til lufttørring af selvoxiderende harpikssammensætninger, hvilket tørremiddel kan opnås ved: tilvejebringelse af et mangansalt med den almene formel Mn2+[X]n, hvor an-ionen X er valgt blandt PFe', SbFe', AsFe', BF4', B(C6F5)4', Cl', Br, I', NO3' og R2COO', i hvilket tilfælde n=2, eller anionen X er SO42', i hvilket tilfælde n=1, og hvor R2= (Ci-C2o)-alkyl, som eventuelt er substitueret med heteroatomer, (Ce-C2o)-aryl, som eventuelt er substitueret med heteroatomer, eller en polymer rest; og tilvejebringelse af 1,4,7-trisubstitueret-1,4,7-triazacyclononan (L), hvor 1,4,7-trisubstitueret-1,4,7-triazacyclononanet (L) har den almene struktur
hvor Ri er (Ci-C2o)-alkyl, som eventuelt er substitueret med heteroatomer, eller (Ce-C2o)-aryl, som eventuelt er substitueret med heteroatomer; og blanding af mangansaltet med 1,4,7- trisubstitueret-1,4,7-triazacyclononanet; hvor 1,4,7-trisubstitueret-1,4,7-triazacyclononanet (L) tilvejebringes i en sådan mængde, at det molære forhold Mn:L er mindst 1,25:1 og fortrinsvis mindst 1,5:1.
2. Tørremiddel ifølge krav 1, hvor Ri er (Ci-Cej-alkyl, fortrinsvis methyl.
3. Tørremiddel ifølge et hvilket som helst af kravene 1 -2, hvor n=2, og anionen X er R2COO-.
4. Tørremiddel ifølge krav 3, hvor R2 er en (Ci-C2o)-alkylgruppe, fortrinsvis en (C4-Ci2)-alkylgruppe, hvor alkylgruppen er ligekædet eller forgrenet, mættet eller umættet.
5. Tørremiddel ifølge et hvilket som helst af kravene 1-4, hvor det molære forhold Mn:L er mindre end 20:1, fortrinsvis mindre end 10:1.
6. Lufttørrende selvoxiderende harpikssammensætning, som omfatter: a) et tørremiddel ifølge et hvilket som helst af kravene 1 -5 og b) en polymer, som omfatter umættede alifatiske grupper.
7. Harpikssammensætning ifølge krav 6, hvor harpiksen, som tørrer, er valgt blandt alkyder, vinylpolymerer, polyurethanharpikser, hyperforgrenede harpikser og blandinger deraf.
8. Harpikssammensætning ifølge krav 7, hvor harpiksen, som tørrer, omfatter et alkyd.
9. Belægningssammensætning, som omfatter harpikssammensætningen ifølge et hvilket som helst af kravene 6-8.
10. Belægningssammensætning ifølge krav 9, hvor sammensætningen indeholder et eller flere hjælpe- og/eller koordineringstørremidler i en mængde, som ikke overstiger 10 vægtprocent.
11. Fremgangsmåde til belægning af et underlag, hvilken fremgangsmåde omfatter følgende trin: påføring af belægningssammensætningen ifølge krav 10 på underlaget og tørring af belægningssammensætningen i nærværelse af luft.
12. Fremgangsmåde ifølge krav 11, hvor tørringen sker ved omgivelsestemperatur.
13. Underlag, som er forsynet med en belægningssammensætning ifølge et hvilket som helst af kravene 7-10.
14. Anvendelse af en sammensætning ifølge et hvilket som helst af kravene 7-10 i maling, klæbemidler, lak, blæk og fernis.
15. Anvendelse af en blanding som et tørremiddel til selvtørring af en selvoxiderende harpikssammensætning, hvilken blanding omfatter: 1,4,7-trisubstitueret-1,4,7-triazacyclononan (L) med den almene struktur
hvor Ri er (Ci-C2o)-alkyl, som eventuelt er substitueret med heteroatomer, eller (C6-C2o)-aryl, som eventuelt er substitueret med heteroatomer; og et mangansalt med den almene formel Mn2+[X]n, hvor anionen X er valgt blandt PFe', SbFe', AsFe', BF4', B(C6Fs)4', Cl', Br, I', NO3' og R2COO', i hvilket tilfælde n=2, eller anionen X er SO42', i hvilket tilfælde n=1, og hvor R2= (C1-C20)-alkyl, som eventuelt er substitueret med heteroatomer, (C6-C2o)-aryl, som eventuelt er substitueret med heteroatomer, eller en polymer rest; hvor 1,4,7-trisubstitueret-1,4,7-triazacyclononanet (L) er til stede i en sådan mængde, at det molære forhold Mn:Ler mindst 1,25:1 og fortrinsvis mindst 1,5:1.
Applications Claiming Priority (2)
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EP11194692.7A EP2607435A1 (en) | 2011-12-20 | 2011-12-20 | Drier for autoxidisable coating composition |
PCT/EP2012/075682 WO2013092442A1 (en) | 2011-12-20 | 2012-12-17 | Drier for auto-oxidisable coating compositions |
Publications (1)
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DK2794787T3 true DK2794787T3 (da) | 2015-12-21 |
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DK12809736.7T DK2794787T3 (da) | 2011-12-20 | 2012-12-17 | Tørremiddel til selvoxiderende belægningssammensætninger |
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US (1) | US9587085B2 (da) |
EP (2) | EP2607435A1 (da) |
CN (1) | CN103998545B (da) |
AR (1) | AR089318A1 (da) |
AU (1) | AU2012357981B2 (da) |
BR (1) | BR112014013947B1 (da) |
CA (1) | CA2858929A1 (da) |
DK (1) | DK2794787T3 (da) |
ES (1) | ES2554279T3 (da) |
HU (1) | HUE027054T2 (da) |
MA (1) | MA35828B1 (da) |
MY (1) | MY170134A (da) |
PL (1) | PL2794787T3 (da) |
RU (1) | RU2626860C2 (da) |
SG (1) | SG11201402678SA (da) |
TN (1) | TN2014000251A1 (da) |
WO (1) | WO2013092442A1 (da) |
ZA (1) | ZA201404274B (da) |
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BR112015018938B1 (pt) | 2013-02-11 | 2022-05-10 | Chemsenti Limited | Formulação, método de preparação de tal formulação, método de preparação de uma composição de revestimento oxidavelmente curável e kit |
AR099218A1 (es) * | 2014-01-31 | 2016-07-06 | Catexel Ltd | Composición |
EP3037464A1 (en) * | 2014-12-24 | 2016-06-29 | Akzo Nobel Coatings International B.V. | Coating composition comprising an alkyd-comprising resin and a drier |
CN104817874A (zh) * | 2015-04-17 | 2015-08-05 | 陆开云 | 用于印刷油墨的环保干燥剂 |
AR107070A1 (es) | 2015-12-18 | 2018-03-14 | Catexel Ltd | Composición de recubrimiento oxidativamente curable |
AR107530A1 (es) | 2016-02-05 | 2018-05-09 | Catexel Ltd | Método para preparar una formulación para un recubrimiento curable por oxidación |
EP3272823A1 (en) | 2016-07-19 | 2018-01-24 | ALLNEX AUSTRIA GmbH | Drier compositions for alkyd resins |
FI3818115T3 (fi) | 2018-07-05 | 2024-01-30 | Milliken Industrials Ltd | Oksidatiivisesti kovettuva pinnoitekoostumus |
EP3827059B1 (en) * | 2018-07-23 | 2022-05-04 | Akzo Nobel Coatings International B.V. | Water-in-oil coating composition |
PL3674340T3 (pl) | 2019-06-20 | 2021-12-06 | Umicore | Kompleksy polimerowe zawierające mangan |
WO2023052294A1 (en) * | 2021-09-30 | 2023-04-06 | Borchers Gmbh | Process for improving resin performance using lewis acids |
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EP0729938B1 (en) * | 1995-02-28 | 2001-09-05 | Mitsui Chemicals, Inc. | A method for producing aryl alkyl hydroperoxides |
US5731095A (en) | 1996-10-23 | 1998-03-24 | Oxazogen, Inc. | Dendritic polymer coatings |
US6624223B1 (en) | 1996-12-24 | 2003-09-23 | University Of Southern Mississippi | Internally plasticized and low VOC latex compositions and applications thereof |
US6174948B1 (en) | 1996-12-24 | 2001-01-16 | The University Of Southern Mississippi | Latex compositions containing ethylenically unsaturated esters of fatty compounds and applications thereof |
NL1007186C2 (nl) | 1997-10-01 | 1999-04-07 | Dsm Nv | ß-hydroxyalkylamide groepen bevattend condensatiepolymeer. |
EP1306401A1 (en) | 2001-10-29 | 2003-05-02 | Dsm N.V. | Oil soluble hyperbranched polyesteramides and method for making the same |
US20050245639A1 (en) | 2002-05-03 | 2005-11-03 | Oostveen Everardus A | Drier for air-drying coatings |
EP1382648A1 (en) | 2002-07-17 | 2004-01-21 | Universiteit Leiden | Drier for alkyd based coating |
US7235603B2 (en) | 2003-04-07 | 2007-06-26 | Rohm And Haas Company | Ambient curable polymer |
CN1333029C (zh) * | 2004-11-17 | 2007-08-22 | 上海市涂料研究所 | 乙酰乙酸烷基酯金属螯合物涂料催干剂及其制备方法 |
FR2892122A1 (fr) | 2005-10-14 | 2007-04-20 | Rhodia Recherches & Tech | Procede pour preparer un copolymere greffe par des acides gras polyinsatures, copolymere greffe par des acides gras polyinsatures susceptible d'etre obtenu par ce procede et ses utilisations |
EP1870442A1 (en) | 2006-06-19 | 2007-12-26 | DSMIP Assets B.V. | Air drying resin and composition |
EP2038356B8 (en) * | 2006-07-07 | 2011-06-22 | Unilever PLC | Liquid hardening |
DE102009057222A1 (de) * | 2009-12-05 | 2011-06-09 | Clariant International Ltd. | Bleichkatalysator-Compounds, Verfahren zu ihrer Herstellung und ihre Verwendung |
WO2011098584A1 (en) | 2010-02-11 | 2011-08-18 | Dsm Ip Assets B.V. | Manganese salt complex as drier for coating compositions |
PT2550283T (pt) | 2010-03-03 | 2016-08-16 | Catexel Ltd | Preparação de catalisadores de branqueamento |
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2011
- 2011-12-20 EP EP11194692.7A patent/EP2607435A1/en not_active Withdrawn
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2012
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- 2012-12-17 US US14/365,213 patent/US9587085B2/en active Active
- 2012-12-17 EP EP12809736.7A patent/EP2794787B1/en active Active
- 2012-12-17 WO PCT/EP2012/075682 patent/WO2013092442A1/en active Application Filing
- 2012-12-17 AU AU2012357981A patent/AU2012357981B2/en active Active
- 2012-12-17 BR BR112014013947-4A patent/BR112014013947B1/pt active IP Right Grant
- 2012-12-17 CA CA2858929A patent/CA2858929A1/en not_active Abandoned
- 2012-12-19 AR ARP120104811A patent/AR089318A1/es active IP Right Grant
-
2014
- 2014-06-09 TN TNP2014000251A patent/TN2014000251A1/en unknown
- 2014-06-10 ZA ZA2014/04274A patent/ZA201404274B/en unknown
- 2014-06-11 MA MA37119A patent/MA35828B1/fr unknown
Also Published As
Publication number | Publication date |
---|---|
AU2012357981B2 (en) | 2016-07-07 |
MA35828B1 (fr) | 2014-12-01 |
EP2794787B1 (en) | 2015-09-16 |
WO2013092442A1 (en) | 2013-06-27 |
HUE027054T2 (en) | 2016-08-29 |
AU2012357981A1 (en) | 2014-06-12 |
EP2607435A1 (en) | 2013-06-26 |
PL2794787T3 (pl) | 2016-02-29 |
RU2626860C2 (ru) | 2017-08-02 |
RU2014128538A (ru) | 2016-02-10 |
BR112014013947A2 (pt) | 2017-06-13 |
AR089318A1 (es) | 2014-08-13 |
MY170134A (en) | 2019-07-05 |
US20140349138A1 (en) | 2014-11-27 |
CN103998545A (zh) | 2014-08-20 |
EP2794787A1 (en) | 2014-10-29 |
SG11201402678SA (en) | 2014-10-30 |
CA2858929A1 (en) | 2013-06-27 |
CN103998545B (zh) | 2016-09-07 |
TN2014000251A1 (en) | 2015-09-30 |
BR112014013947A8 (pt) | 2017-06-13 |
BR112014013947B1 (pt) | 2021-08-10 |
US9587085B2 (en) | 2017-03-07 |
ES2554279T3 (es) | 2015-12-17 |
ZA201404274B (en) | 2017-08-30 |
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