DK2596702T3 - Fremgangsmåde til at stabilisere bakterieindhold af vandigt formalet naturligt calciumkarbonat og/eller præcipiteret calciumkarbonat og/eller dolomit og/eller overfladebehandlede calciumkarbonat-omfattende mineralpræparater - Google Patents
Fremgangsmåde til at stabilisere bakterieindhold af vandigt formalet naturligt calciumkarbonat og/eller præcipiteret calciumkarbonat og/eller dolomit og/eller overfladebehandlede calciumkarbonat-omfattende mineralpræparater Download PDFInfo
- Publication number
- DK2596702T3 DK2596702T3 DK11190704.4T DK11190704T DK2596702T3 DK 2596702 T3 DK2596702 T3 DK 2596702T3 DK 11190704 T DK11190704 T DK 11190704T DK 2596702 T3 DK2596702 T3 DK 2596702T3
- Authority
- DK
- Denmark
- Prior art keywords
- calcium carbonate
- biocide
- linear
- aqueous
- triamine compound
- Prior art date
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- A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
- A01N31/08—Oxygen or sulfur directly attached to an aromatic ring system
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
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- A—HUMAN NECESSITIES
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- A01N35/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical
- A01N35/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical containing aliphatically bound aldehyde or keto groups, or thio analogues thereof; Derivatives thereof, e.g. acetals
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- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
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- A—HUMAN NECESSITIES
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- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
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- A—HUMAN NECESSITIES
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- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/36—Biocidal agents, e.g. fungicidal, bactericidal, insecticidal agents
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- A—HUMAN NECESSITIES
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- A—HUMAN NECESSITIES
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- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/52—Stabilizers
Landscapes
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- Agricultural Chemicals And Associated Chemicals (AREA)
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- Detergent Compositions (AREA)
- Paints Or Removers (AREA)
- Paper (AREA)
- Medicines Containing Material From Animals Or Micro-Organisms (AREA)
- Coloring Foods And Improving Nutritive Qualities (AREA)
Claims (24)
1. Fremgangsmåde til at stabilisere et vandigt mineralpræparat omfattende et trin at: (a) tilføje mindst et aldehyd-indeholdende og/eller aldehyd-frigivende og/eller fenol- og/eller isothiazolin-biocid til det vandige mineralpræparat; kendetegnet ved at: - mineralet omfatter mindst en af: et formalet naturligt calciumkarbonat, et præcipiteret calciumkarbonat, en dolomit, et overfladebehandlet calciumkarbonat, ler, talkum, "ΠΟ2, kaolin, kaolinler, kalcineret kaolinler, calciumsulfat, kvarts, attapulgit, montmorillonit, kiselgur, fint inddelt silika, aluminiumoxid, aluminiumhydroxid, silikater, pimpsten og merskum, eller en blanding deraf; - fremgangsmåden omfatter et trin (b), som kan være samtidigt med og/eller særskilt fra trin (a), af at tilføje mindst en lineær eller cyklisk diamin- eller triamin-forbindelse til det vandige mineralpræparat, den lineære eller cykliske diamin- eller triamin-forbindelse indeholdende mindst en primær amingruppe, og hvor den lineære diamin- eller triamin-forbindelse har den følgende formel (I):
(I) hvor: m er et heltal og er enten 0 eller 1, n er et heltal og er fra 2 til 8, o er et heltal og er fra 0 til 3, Ri er en Ci til C12 alkylgruppe, og R2 er CH3 eller NH2, og med den betingelse at når m = 0, så er o = 0 og R2 er NH2; og hvor den cykliske diamin- eller triamin-forbindelse har en af de følgende formler (II) og (III):
(II) (ill) hvor: k og I er de samme eller forskellige og er enten 0 eller 1, R3 er enten H eller CH3, og FU og Rs er de samme eller forskellige og valgt fra H og CH3, - biociden/biociderne tilføjes til det vandige præparat i en mængde svarende til fra 90 til 1 350 ppm baseret på vægten af den vandige fase af det vandige præparat; og - den/de lineære eller cykliske diamin- eller triamin-forbindelser tilføjes til det vandige præparat i en mængde svarende til fra 600 til 1 200 ppm, baseret på vægten af den vandige fase af det vandige præparat.
2. Fremgangsmåde ifølge krav 1, kendetegnet ved at mineralet omfatter mindst en af: et formalet naturligt calciumkarbonat, et præcipiteret calciumkarbonat, en dolomit, et overfladebehandlet calciumkarbonat.
3. Fremgangsmåde ifølge krav 1 eller 2, kendetegnet ved at mineralet omfatter aluminiumsilikat.
4. Fremgangsmåde ifølge et hvilket som helst af kravene 1 til 3, kendetegnet ved at Ri i formel (I) er CH3, CH2CH3 eller en lineær C12H25 alkylgruppe.
5. Fremgangsmåde ifølge et hvilket som helst af kravene 1 til 4, kendetegnet ved at det/de aldehyd-indeholdende og/eller aldehyd-frigivende og/eller fenol-og/eller isothiazolin-biocider tilføjes til det vandige præparat i en samlet mængde på fra 100 ppm til 1 000 ppm, fortrinsvis i mængde på fra 150 ppm til 800 ppm, udregnet i forhold til vandet i præparatet.
6. Fremgangsmåde ifølge et hvilket som helst af kravene 1 til 5, kendetegnet ved at det aldehyd-baserede biocid vælges fra gruppen bestående af formaldehyd, acetaldehyd, glyoxal, succinaldehyd, glutaraldehyd, 2-propenal, ftaldialdehyd og blandinger deraf, og fortrinsvis er formaldehyd, glutaraldehyd og blandinger deraf, og/eller kendetegnet ved at de aldehyd-frigivende biocider vælges fra gruppen bestående af formaldehyd-frigivende biocider, acetaldehyd-frigivende biocider, succinaldehyd-frigivende biocider, 2-propenal-frigivende biocider og blandinger deraf, hvor de aldehyd-frigivende biocider fortrinsvis vælges fra gruppen bestående af benzyl alkoholmono(poly)-hemiformal, ethyleneglycolhemiformal (EGHF), [l,2-Ethanediylbis(oxy)]-bis-methanol, tetrahydro-1,3,4,6-tetrakis(hydroxylmethyl)imidazo[4,5-d]imidazol-2,5(lH,3H)-dion (også alment kendt som TetraMethylolAcetyleneDiurea TMAD) og blandinger deraf.
7. Fremgangsmåde ifølge et hvilket som helst af kravene 1 til 6, kendetegnet ved at fenolbiocidet er orthophenylphenol (OPP), og/eller kendetegnet ved at isothiazolinbiocidet vælges fra gruppen bestående af 2-methyl-4-isothiazolin-3-one (MIT), 5-chloro-2-methyl-2H-isothiazolin-3-one (CIT), l,2-benzisothiazolin-3-one (BIT), og blandinger deraf.
8. Fremgangsmåde ifølge et hvilket som helst af kravene 1 til 7, kendetegnet ved at det aldehyd-frigivende og/eller aldehyd-baserede biocid anvendes sammen med biocider valgt fra gruppen bestående af 5-chloro-2-methyl-2H-isothiazolin-3-one (CIT), 2-methyl-2H-isothiazolin-3-one (MIT) og blandinger deraf.
9. Fremgangsmåde ifølge et hvilket som helst af kravene 1 til 5, kendetegnet ved at biociderne er en kombination af glutaraldehyd, 5-chloro-2-methyl-2H-isothiazolin-3-one (CIT) og 2-methyl-2H-isothiazolin-3-one (MIT), eller en kombination af ethyleneglycol-hemiformal, 5-chloro-2-methyl-2H-isothiazolin-3-one (CIT) og 2-methyl-2H-isothiazolin-3-one (MIT).
10. Fremgangsmåde ifølge et hvilket som helst af kravene 1 til 9, kendetegnet ved at mineralet omfatter en eller flere af: formalet naturligt calciumkarbonat, præcipiteret calciumkarbonat, dolomit og overfladebehandlet calciumkarbonat, og en eller flere af: kaolin, kaolinler, kalcineret kaolinler, talkum, calciumsulfat, kvarts, attapulgit, montmorillonit, kiselgur, fint inddelt silika, aluminiumoxid, aluminiumhydroxid, silikater såsom aluminiumsilikat, pimpsten og merskum, hvor det formalede naturlige calciumkarbonat og/eller præcipiterede calciumkarbonat og/eller dolomit og/eller overfladebehandlede calciumkarbonat fortrinsvis er til stede i en mængde på større end eller lig med 50 vægtprocent, mere fortrinsvis større end eller lig med 60 vægtprocent, endnu mere fortrinsvis større end eller lig med 70 vægtprocent, endnu mere fortrinsvis større end eller lig med 80 vægtprocent, og most fortrinsvis større end eller lig med 90 vægtprocent, i forhold til den samlede vægt af mineralfaststofferne.
11. Fremgangsmåde ifølge et hvilket som helst af kravene 1 til 10, kendetegnet ved at mineralet består af kun formalet naturligt calciumkarbonat, præcipiteret calciumkarbonat, dolomit, overfladebehandlet calciumkarbonat eller blandinger deraf, og fortrinsvis består kun af formalet naturligt calciumkarbonat.
12. Fremgangsmåde ifølge et hvilket som helst af kravene 1 til 11, kendetegnet ved at det vandige mineralpræparat har et faststofindhold på fra 40 til 82 vægtprocent, fortrinsvis på fra 50 til 80 vægtprocent, og endnu mere fortrinsvis på fra 60 til 80 vægtprocent; og/eller kendetegnet ved at det vandige mineralpræparat har en pH på mellem 8 og 10, forud for tilføjelsen af et hvilket som helst biocid og/eller lineær eller cyklisk diamin- eller triamin-forbindelse indeholdende mindst en primær amingruppe.
13. Fremgangsmåde ifølge et hvilket som helst af kravene 1 til 12, kendetegnet ved at den lineære eller cykliske diamin- eller triamin-forbindelse indeholdende mindst en primær amingruppe vælges fra gruppen omfattende 1,3-bis(aminomethyl)cyclohexan, l,3-bis(aminomethyl)benzen, 1,7-diaminoheptan, 1.8- diaminooktan, diethylaminoethylamin, ethylendiamin, N,N-bis-(3-aminopropyljmethylamin, isophorondiamin, og N-(3-aminopropyl)-N-dodecylpropan-l,3-diamin, og er fortrinsvis valgt fra gruppen bestående af 1,3-bis(aminomethyl)cyclohexan, l,3-bis(aminomethyl)benzen, 1,7-diaminoheptan, 1.8- diaminooktan, diethylaminoethylamin, og ethylendiamin.
14. Fremgangsmåde ifølge et hvilket som helst af kravene 1 til 5, kendetegnet ved at i tilfældet hvor biocidet er et aldehyd-baseret biocid, den lineære eller cykliske diamin- eller triamin-forbindelse indeholdende mindst en primær amingruppe tilføjes i en mængde således at vægtforholdet biocid : lineær eller cyklisk diamin-eller triamin-forbindelse er fra 1 : 4 til 1 : 1, eller kendetegnet ved at i tilfældet hvor biocidet er et fenolbiocid, den lineære eller cykliske diamin- eller triamin-forbindelse indeholdende mindst en primær amingruppe tilføjes i en mængde således at vægtforholdet biocid : lineær eller cyklisk diamin- eller triamin-forbindelse er fra 1 : 4 til 1 : 2.
15. Fremgangsmåde ifølge et hvilket som helst af kravene 1 til 14, kendetegnet ved at biocidet/biociderne og den lineære eller cykliske diamin- eller triamin-forbindelse indeholdende mindst en primær amingruppe tilføjes adskilt til det vandige præparat, hvor hele den lineære eller cykliske diamin- eller triamin-forbindelse indeholdende mindst en primær amingruppe fortrinsvis tilføjes før et hvilket som helst af biocidet/biociderne.
16. Fremgangsmåde ifølge et hvilket som helst af kravene 1 til 15, kendetegnet ved at forud for tilføjelsen af en hvilket som helst af den lineære eller cykliske diamin- eller triamin-forbindelse indeholdende mindst en primær amingruppe eller biocidet, det vandige præparat indeholder bakterier valgt fra gruppen bestående af Thermus sp., Propionibacterium sp., Rhodococcus sp., Panninobacter sp., Caulobacter sp., Brevundimonas sp., Asticcacaulis sp., Sphingomonas sp., Rhizobium sp., Ensifer sp., Bradyrhizobium sp., Tepidimonas sp., Tepidicella sp., Aquabacterium sp., Pelomonas sp., Alcaligenis sp., Achromobacter sp., Ralstonia sp., Limnobacter sp., Massilia sp., Hydrogenophaga sp., Acidovorax sp., Curvibacter sp., Delftia sp., Rhodoferax sp., Alishewanella sp., Stenotrophomonas sp., Dokdonella sp., Methylosinus sp., Hyphomicrobium sp., Methylosulfomonas sp., Methylobacteria sp., Pseudomonas sp. og blandinger deraf, og mere fortrinsvis indeholder bakterier valgt fra gruppen bestående af Pseudomonas putida, Pseudomonas mendocina, Pseudomonas fluorescens, Pseudomonas alcaligenes, Pseudomonas pseudoalcaligenes, Pseudomonas alcaliphila, Pseudomonas entomophila, Pseudomonas syringae, Methylobacterium extorquens, Methylobacterium radiotolerans, Methylobacterium dichloromethanicum, Methylobacterium organophilu, Hyphomicrobium zavarzini og blandinger deraf.
17. Fremgangsmåde ifølge krav 16, kendetegnet ved at alle eller en del af bakterierne er resistente over for, tolerante over for og/eller nedbryder biociderne i fraværet af den lineære eller cykliske diamin- eller triamin-forbindelse(s) indeholdende mindst en primær amingruppe.
18. Vandigt præparat opnået ved fremgangsmåden ifølge et hvilket som helst af kravene 1 til 17.
19. Anvendelse af mindst en lineær eller cyklisk diamin- eller triamin-forbindelse, den lineære eller cykliske diamin- eller triamin-forbindelse indeholdende mindst en primær amingruppe, og hvor den lineære diamin- eller triamin-forbindelse har den følgende formel (I):
(I) hvor: m er et heltal og er enten 0 eller 1, n er et heltal og er fra 2 til 8, o er et heltal og er fra 0 til 3, Ri er en Ci til C12 alkylgruppe, og R2 er CH3 eller NH2, og med den betingelse at når m = 0, så er o = 0 og R2 er NH2; og hvor den cykliske diamin- eller triamin-forbindelse har en af de følgende formler (II) og (III):
(II) (III) hvor: k og I er de samme eller forskellige og er enten 0 eller 1, R3 er enten H eller CH3, og R4 og Rs er de samme eller forskellige og valgt fra H og CH3, som en biocidaktivitetsfremmende forbindelse i et vandigt mineralpræparat omfattende mindst en af vandigt formalet naturligt calciumkarbonat, præcipiteret calciumkarbonat, dolomit, overfladebehandlet calciumkarbonat, ler, talkum, "ΠΟ2, kaolin, kaolinler, calcineret kaolinler, calciumsulfat, kvarts, attapulgit, montmorillonit, kiselgur, fint inddelt silika, aluminiumoxid, aluminiumhydroxid, silikater, pimpsten og merskum, eller en blanding deraf, og omfattende mindst en aldehyd-indeholdende og/eller aldehyd-frigivende og/eller fenol- og/eller isothiazolinbiocid, hvor den samlede mængde på biocidet/biociderne i det vandige præparat er fra 90 ppm til 1 350 ppm, udregnet i forhold til vægten af den vandige fase af præparatet, og den samlede mængde på den lineære eller cykliske diamineiler triamin-forbindelse(r) i det vandige præparat er fra 600 til 1 200 ppm, udregnet i forhold til vægten af den vandige fase af præparatet.
20. Anvendelse ifølge krav 19, kendetegnet ved at mineralet omfatter mindst en af: et formalet naturligt calciumkarbonat, et præcipiteret calciumkarbonat, en dolomit, et overfladebehandlet calciumkarbonat.
21. Anvendelse ifølge krav 19 eller 20, kendetegnet ved at mineralet omfatter aluminiumsilikat.
22. Anvendelse ifølge et hvilket som helst af kravene 19 til 21, kendetegnet ved at Ri i formel (I) er en lineær C12H25 alkylgruppe.
23. Anvendelse ifølge krav 19 eller 22, kendetegnet ved at den lineære eller cykliske diamin- eller triamin-forbindelse indeholdende mindst en primær amingruppe er valgt fra gruppen omfattende l,3-bis(aminomethyl)cyclohexan, l,3-bis(aminomethyl)benzen, 1,7-diaminoheptan, 1,8-diaminooktan, diethylaminoethylamin, ethylendiamin, N,N-bis-(3-aminopropyl)methylamin, isophorondiamin, og N-(3-aminopropyl)-N-dodecylpropan-l,3-diamin, og er fortrinsvis valgt fra gruppen bestående af l,3-bis(aminomethyl)cyclohexan, 1,3-bis(aminomethyl)benzen, 1,7-diaminoheptan, 1,8-diaminooktan, diethylaminoethylamin, og ethylendiamin.
24. Anvendelse af det vandige præparat ifølge krav 18 i papirfremstilling, maling, vaskemidler eller kosmetik.
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EP11190704.4A EP2596702B1 (en) | 2011-11-25 | 2011-11-25 | Process for stabilizing bacterial content of aqueous ground natural calcium carbonate and/or precipitated calcium carbonate and/or dolomite and/or surface-reacted calcium carbonate-comprising mineral preparations |
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DK2596702T3 true DK2596702T3 (da) | 2015-08-10 |
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DK11190704.4T DK2596702T3 (da) | 2011-11-25 | 2011-11-25 | Fremgangsmåde til at stabilisere bakterieindhold af vandigt formalet naturligt calciumkarbonat og/eller præcipiteret calciumkarbonat og/eller dolomit og/eller overfladebehandlede calciumkarbonat-omfattende mineralpræparater |
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EP (2) | EP2596702B1 (da) |
JP (1) | JP2015504435A (da) |
KR (1) | KR101663395B1 (da) |
CN (1) | CN103945694B (da) |
AR (1) | AR088937A1 (da) |
BR (1) | BR112014012454A2 (da) |
CA (1) | CA2853641C (da) |
DK (1) | DK2596702T3 (da) |
ES (1) | ES2545810T3 (da) |
HK (1) | HK1185762A1 (da) |
HU (1) | HUE025278T2 (da) |
IN (1) | IN2014MN00965A (da) |
MX (1) | MX346369B (da) |
PL (1) | PL2596702T3 (da) |
PT (1) | PT2596702E (da) |
RU (1) | RU2560433C1 (da) |
SI (1) | SI2596702T1 (da) |
TW (1) | TWI538618B (da) |
UY (1) | UY34466A (da) |
WO (1) | WO2013076188A1 (da) |
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EP2929781A1 (en) | 2014-04-10 | 2015-10-14 | Omya International AG | MIC reduction with lithium ions |
CN103923856B (zh) * | 2014-04-17 | 2016-07-13 | 天津市农业生物技术研究中心 | 一株嗜碱假单胞菌ad-28及其在水体脱氮中的应用 |
SI2957301T1 (sl) * | 2014-06-20 | 2017-07-31 | Omya International Ag | Postopek za nadzor vonja |
TWI541353B (zh) | 2014-12-25 | 2016-07-11 | 財團法人工業技術研究院 | 產生嗜熱性鹼性蛋白酶生產菌屬(Tepidimonas)之胞外蛋白的方法 |
EP3184644A1 (en) * | 2015-12-22 | 2017-06-28 | Omya International AG | Microbial cell viability assay for detection of or determining slurry contamination |
EP3183969A1 (en) | 2015-12-22 | 2017-06-28 | Omya International AG | Metal oxides and/or hydrates thereof for stabilising an aqueous preparation against microbial growth |
EP3557993A1 (en) * | 2016-12-21 | 2019-10-30 | Dow Global Technologies LLC | Synergistic combination of ortho-phenylphenol and bis-(3-aminopropyl)dodecylamine |
EP3403505A1 (en) | 2017-05-16 | 2018-11-21 | Omya International AG | Biocide free preservation |
WO2019005438A1 (en) * | 2017-06-28 | 2019-01-03 | Dow Global Technologies Llc | MICROBICIDE COMPOSITION |
CN114656744B (zh) * | 2022-05-20 | 2022-07-29 | 广东乔艺塑胶有限公司 | 低气味pp/as/pok三元复合树脂、化妆品包材及其制备方法 |
WO2023242363A1 (en) | 2022-06-15 | 2023-12-21 | Omya International Ag | Storage stabilization agent for stabilizing aqueous compositions, process for stabilizing and uses thereof |
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2011
- 2011-11-25 SI SI201130536T patent/SI2596702T1/sl unknown
- 2011-11-25 ES ES11190704.4T patent/ES2545810T3/es active Active
- 2011-11-25 PT PT111907044T patent/PT2596702E/pt unknown
- 2011-11-25 DK DK11190704.4T patent/DK2596702T3/da active
- 2011-11-25 EP EP11190704.4A patent/EP2596702B1/en not_active Not-in-force
- 2011-11-25 HU HUE11190704A patent/HUE025278T2/en unknown
- 2011-11-25 PL PL11190704T patent/PL2596702T3/pl unknown
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2012
- 2012-11-08 TW TW101141516A patent/TWI538618B/zh not_active IP Right Cessation
- 2012-11-21 AR ARP120104374A patent/AR088937A1/es unknown
- 2012-11-22 US US14/353,412 patent/US20140288188A1/en not_active Abandoned
- 2012-11-22 IN IN965MUN2014 patent/IN2014MN00965A/en unknown
- 2012-11-22 CA CA2853641A patent/CA2853641C/en not_active Expired - Fee Related
- 2012-11-22 CN CN201280057463.0A patent/CN103945694B/zh not_active Expired - Fee Related
- 2012-11-22 JP JP2014542826A patent/JP2015504435A/ja active Pending
- 2012-11-22 RU RU2014125547/13A patent/RU2560433C1/ru not_active IP Right Cessation
- 2012-11-22 EP EP12790896.0A patent/EP2747559A1/en not_active Withdrawn
- 2012-11-22 BR BR112014012454A patent/BR112014012454A2/pt not_active Application Discontinuation
- 2012-11-22 WO PCT/EP2012/073333 patent/WO2013076188A1/en active Application Filing
- 2012-11-22 MX MX2014006086A patent/MX346369B/es active IP Right Grant
- 2012-11-22 KR KR1020147017583A patent/KR101663395B1/ko active IP Right Grant
- 2012-11-23 UY UY0001034466A patent/UY34466A/es not_active Application Discontinuation
-
2013
- 2013-11-28 HK HK13113325.4A patent/HK1185762A1/xx not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
CN103945694B (zh) | 2016-07-13 |
EP2747559A1 (en) | 2014-07-02 |
EP2596702A1 (en) | 2013-05-29 |
HUE025278T2 (en) | 2016-02-29 |
CA2853641C (en) | 2017-01-03 |
MX346369B (es) | 2017-03-16 |
CA2853641A1 (en) | 2013-05-30 |
KR101663395B1 (ko) | 2016-10-06 |
KR20140098206A (ko) | 2014-08-07 |
PT2596702E (pt) | 2015-09-21 |
JP2015504435A (ja) | 2015-02-12 |
BR112014012454A2 (pt) | 2017-06-06 |
EP2596702B1 (en) | 2015-05-27 |
UY34466A (es) | 2013-06-28 |
PL2596702T3 (pl) | 2015-10-30 |
CN103945694A (zh) | 2014-07-23 |
TWI538618B (zh) | 2016-06-21 |
TW201328597A (zh) | 2013-07-16 |
MX2014006086A (es) | 2014-07-11 |
WO2013076188A1 (en) | 2013-05-30 |
AR088937A1 (es) | 2014-07-16 |
ES2545810T3 (es) | 2015-09-16 |
HK1185762A1 (en) | 2014-02-28 |
SI2596702T1 (sl) | 2015-08-31 |
US20140288188A1 (en) | 2014-09-25 |
IN2014MN00965A (da) | 2015-04-24 |
RU2560433C1 (ru) | 2015-08-20 |
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