DK2002032T3 - Lagring og transport af energi - Google Patents

Lagring og transport af energi Download PDF

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Publication number
DK2002032T3
DK2002032T3 DK07758658.4T DK07758658T DK2002032T3 DK 2002032 T3 DK2002032 T3 DK 2002032T3 DK 07758658 T DK07758658 T DK 07758658T DK 2002032 T3 DK2002032 T3 DK 2002032T3
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DK
Denmark
Prior art keywords
slurry
hydrogen
metal hydride
hydride
charging device
Prior art date
Application number
DK07758658.4T
Other languages
English (en)
Inventor
Andrew W Mcclaine
Kenneth Brown
Original Assignee
Safe Hydrogen Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Safe Hydrogen Llc filed Critical Safe Hydrogen Llc
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Publication of DK2002032T3 publication Critical patent/DK2002032T3/da

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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/0005—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes
    • C01B3/001—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof
    • C01B3/0073—Slurries, Suspensions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/20—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/0005—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/02—Hydrogen or oxygen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00743—Feeding or discharging of solids
    • B01J2208/00769—Details of feeding or discharging
    • B01J2208/00787—Bringing the solid in the form of a slurry before feeding it to the reactor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00105—Controlling the temperature by indirect heating or cooling employing heat exchange fluids part or all of the reactants being heated or cooled outside the reactor while recycling
    • B01J2219/00114—Controlling the temperature by indirect heating or cooling employing heat exchange fluids part or all of the reactants being heated or cooled outside the reactor while recycling involving reactant slurries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/32—Hydrogen storage
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y02P20/133—Renewable energy sources, e.g. sunlight

Claims (11)

1. Fremgangsmåde omfattende frigivelse af hydrogen fra vand på et første sted under anvendelse af energi fra en første energikilde, fortrinsvis en vedvarende energikilde, mere foretrukket en vedvarende energikilde, som er valgt blandt vind, vandkraft, geotermi, oceankraft, solenergi og kombinationer af disse; oplagring af det frigivne hydrogen, fortrinsvis på det nævnte første sted, i en me-talhydridopslæmning, idet opslæmningen omfatter en organisk bærervæske, og idet opslæmningen fortrinsvis omfatter magnesium, magnesiumhydrid og mineralolie, eventuelt sammen med et dispergeringsmiddel; og transportering af metalhydridopslæmningen til et andet sted fjernt fra det første sted, fortrinsvis via en bærer, som er valgt blandt en jernbanevogn, en lastvogn, en tanker, et rør, en pram og en hvilken som helst kombination af disse; og frigivelse af hydrogenet fra metalhydridopslæmningen ved opvarmning under betingelser, som er udformet til at udelukke luft og vand, til dannelse af hydrogen, fortrinsvis til anvendelse som energikilde, og en metalhydridopslæmning, som er i det mindste delvist depleteret.
2. Fremgangsmåde ifølge krav 1, som desuden omfatter transportering af den delvist depleterede metalhydridopslæmning fra det andet sted til det første sted.
3. Fremgangsmåde ifølge krav 2, som desuden omfatter genopladning af den depleterede metalhydridopslæmning ved at frigive energi fra vand på det første sted under anvendelse af energi fra den første energikilde og oplagre det frigivne hydrogen i den depleterede metalhydridopslæmning til dannelse af metalhydridopslæmningen, hvilket fortrinsvis gentages i mindst 50 cykler for metalhydridet.
4. Fremgangsmåde ifølge krav 1, hvor det første sted har et første energibehov, det andet sted har et andet energibehov, og det første energibehov er lavere end det andet energibehov.
5. System til udførelse af fremgangsmåden ifølge krav 1, omfattende: en elektrolysator til at frigive hydrogenet fra vandet under anvendelse af energi fra den første energikilde på det første sted; en opladningsindretning, som er koblet til elektrolysatoren på det første sted til at modtage detfrigivne hydrogen, idet opladningsindretningen omfatter et indløb til en metalhydridopslæmning, et udløb til opladet metalhydridopslæmning og en opvarmningsindretning, som er i stand til at opvarme en opslæmning i opladningsindretningen til mindst ca. 320°C; en lagerbeholder til en metalhydridopslæmning til at lagre den opladede metalhydridopslæmning, fortrinsvis på det første sted; en bærer, som fortrinsvis er valgt blandt en jernbanevogn, en lastvogn, en tanker, et rør, en pram og en hvilken som helst kombination af disse, til at transportere metal-hydridopslæmningen til et andet sted; og en udtømningsindretning, som er tilpasset til at udelukke luft og vand på det andet sted, og som omfatter en opvarmningsindretning, der er i stand til at opvarme en hy-dridopslæmning, som er indeholdt i udtømningsindretningen, til mindst ca. 370°C.
6. System ifølge krav 5, hvor systemet er i stand til at opretholde et tryk i opladningsindretningen på mindst ca. 150 psia (1,034*106 Pascal).
7. System ifølge krav 5, hvor opladningsindretningen desuden omfatter en pumpe til at transportere metalhydridopslæmningen fra opladningsindretningen gennem udløbet til opslæmningen.
8. System ifølge krav 5, hvor opladningsindretningen desuden omfatter en regulator til at opretholde en temperatur i den opslæmning, der er indeholdt i opladningsindretningen, på ikke mere end ca. 350°C.
9. System ifølge krav 5, som desuden omfatter en lagerbeholder, der er koblet til opladningsindretningens udløb til opslæmningen.
10. System ifølge krav 5, hvor opladningsindretningen desuden omfatter et hydrogenudløb, gennem hvilket hydrogen, der er udviklet fra en hydridopslæmning, kan passere.
11. System ifølge krav 5, som desuden omfatter en pumpe, der er koblet til lagerbeholderen til at overføre en opslæmning fra metalhydridopslæmningslagerbeholderen til bæreren.
DK07758658.4T 2006-03-29 2007-03-16 Lagring og transport af energi DK2002032T3 (da)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US11/392,149 US7790013B2 (en) 2006-03-29 2006-03-29 Storing and transporting energy
PCT/US2007/064129 WO2007117858A2 (en) 2006-03-29 2007-03-16 Storing and transporting energy

Publications (1)

Publication Number Publication Date
DK2002032T3 true DK2002032T3 (da) 2017-04-03

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DK07758658.4T DK2002032T3 (da) 2006-03-29 2007-03-16 Lagring og transport af energi

Country Status (10)

Country Link
US (5) US7790013B2 (da)
EP (1) EP2002032B1 (da)
CN (1) CN101448979B (da)
AU (1) AU2007235120C1 (da)
CA (1) CA2648026C (da)
DK (1) DK2002032T3 (da)
ES (1) ES2619639T3 (da)
HK (1) HK1128311A1 (da)
MX (1) MX2008012464A (da)
WO (1) WO2007117858A2 (da)

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Also Published As

Publication number Publication date
WO2007117858A9 (en) 2008-11-13
US7790013B2 (en) 2010-09-07
AU2007235120C1 (en) 2012-01-19
EP2002032A4 (en) 2012-12-26
HK1128311A1 (en) 2009-10-23
AU2007235120B2 (en) 2011-08-04
US20100252423A1 (en) 2010-10-07
EP2002032B1 (en) 2016-12-28
MX2008012464A (es) 2009-02-06
CA2648026C (en) 2016-09-27
US9580308B2 (en) 2017-02-28
US20170267522A1 (en) 2017-09-21
CN101448979A (zh) 2009-06-03
CN101448979B (zh) 2011-10-19
US20200165126A1 (en) 2020-05-28
WO2007117858A3 (en) 2008-12-31
US10549990B2 (en) 2020-02-04
WO2007117858A2 (en) 2007-10-18
US20140205535A1 (en) 2014-07-24
CA2648026A1 (en) 2007-10-18
EP2002032A2 (en) 2008-12-17
US20070227899A1 (en) 2007-10-04
US8715583B2 (en) 2014-05-06
AU2007235120A1 (en) 2007-10-18
ES2619639T3 (es) 2017-06-26

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